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Midterm 221

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Hoangngoc Nhi
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28 views

Midterm 221

Uploaded by

Hoangngoc Nhi
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 7

Giảng viên ra đề: (Ngày ra đề) Người phê duyệt: (Ngày duyệt đề)

(Chữ ký, Chức vụ và Họ tên)

(phần phía trên cần che đi khi in sao đề thi)

Semester/year 1 2022-2023
MIDTERM EXAM
Date 19/10/2022
Course Organic Chemistry
Ho Chi Minh City University of Technology Course No. CH2021
(HCMUT), VNU-HCM
FACULTY OF CHEMICAL ENGINEERING Duration 60 min Code 02
Note: - Materials, cell phones, or any communication devices are not allowed.
- Read the questions carefully. There are 8 of them (10 points).

Question 1) (L.O.1, 1 point): Fill in the blanks with the number of asymmetric carbons and the

configuration of two labelled carbons in the following structure.

i) There are ……… asymmetric carbons in the given molecule.

ii) The configuration of the labelled Ca is ………………….

iii) The configuration of the labelled Cb is …………………

7 asymmetric carbons (0.5 point)

Configuration of Ca is (S).

Configuration of Cb is (S).

Both configurations are correct: 0.5 point. If not, 0 point.

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Question 2) (L.O.1, 1 point): You are given a pool of nine (09) structures as follows. Fill in the blanks

with the correct structures.

i) Structure(s) …………………………………. is/are enantiomer(s) of structure (1).

ii) Structure(s) …………………………………. is/are diastereomer(s) of structure (3).

i) Only structure (8) is enantiomer of structure (1): 0.5 point.

ii) Structures (1), (8), and (9) are diastereomers of structure (3): 0.5 point. Missing any of the three

compounds: 0 point.

Question 3 (L.O.1, 1 point): Arrange seven (07) compounds below following the order of decreasing

acidity.

Answer: (3) > (2) > (7) > (5) > (6) > (4) > (1). Students must show the correct order to get the full credit.

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Question 4 (L.O.1, 1 point): Which of the following structures is AROMATIC?

Answer: (5), (8), (10), (11), (13), and (15): 1 point.

Students get 4 or 5 correct structures: 0.5 point.

Any wrong structure in the answer: 0 point.

Question 5 (L.O.3, 2 points): What is the structure of compounds (A), (B), (C), and (D) respectively in

the following reaction sequences? NO STEREOCHEMISTRY IS REQUIRED.

Student ID: ............................ Student name: .................................................... Page 3/7


Answer:

(A) (B)

(C) (D)

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Question 6 (L.O.3, 1 point): You are given a pool of molecules: (C6H5)3P=CH2, N2H4, Br2, -OH

(hydroxides), NaNH2, H2O, H2O2, CH3ONa, CH2Cl2, R2BH (with R is an alkyl group). From the given

compounds ONLY, complete the following transformation with detailed reactions and conditions. You

are allowed to use UV light if necessary. Reactions are allowed to run at any given temperature. NO

STEREOCHEMISTRY IS REQUIRED.

Answer:

Question 7 (L.O.2, 1.5 point): What is the structure of the product(s) in each of the following reaction?

NO STEREOCHEMISTRY IS REQUIRED.

Answer:

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Question 8 (L.O.2, 1.5 point): What is the structure of the product(s) in each of the following reaction?

STEREOCHEMISTRY MUST BE SHOWN IF NECESSARY.

Answer:

- Both are correct: 0.5 point. Missing any: 0 point.

Product(s) could be presented by EITHER

perspective formula OR Fisher projection.

Student ID: ............................ Student name: .................................................... Page 6/7


Product(s) MUST be presented by perspective

formula.

Product(s) MUST be presented by Fisher

projection AND hydrogens of the chiral carbons

MUST be placed on horizontal bonds.

THIS IS THE END OF THE EXAM.

Student ID: ............................ Student name: .................................................... Page 7/7

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