Chemistry f2
Chemistry f2
Chemistry f2
Mogadishu - Somalia
مؤســـسـة أبﻼل
CHEMISTRY
CHAPTER ONE: QUESTION AND ANSWER
1. Describe the modern periodic table?
The modern periodic table: is table in which all known elements are arranged in order of their
increasing atomic number
The block of the elements can be determined by identifying the last sub-shell
Ionization energy: is the energy required to remove an electron from an atom of the element in the
gaseous state
The periods of element can be determined by identifying the largest number of the shell in the electron
configuration of the element in main shell or sub-shell notation
Atomic radius: is the distance between the nucleus of the atom and the outermost shell of the atom
Nuclear charge: is the amount of positive charge in the nucleus of the atom
CHAPTER EXERCISE
1. Sketch a periodic table, labeling the s, p, d and f blocks.
Because Mendeleev's Classification was not Giving importance to the electronic Structure of the atom
which is very important factor in deciding Chemical property.
3. Why do you think the noble gases are placed in a separate group?
4. What can be said about elements within a given group on the periodic table?
The S-block and p-block elements are collectively known as representative elements
Properties of helium are - low boiling point, low density, low Solubility, high Thermal
Conducting and inertness.
8. Why are the noble gases almost completely uncreative?
F-block elements
Fluorine (F) is the most electronegative element on the periodic table, because it attracts the electrons
in the bond more strongly than the carbon does
Across period, effective nuclear charge increases as electron shielding remains constant. A higher
effective nuclear charge causes greater attractions to the electrons pulling the electrons could closer to
the nucleus which results in a smaller atomic radius
Because the nuclear charge increase with the same number of shells
Because the nuclear charge increases with the same number of shells, this result to become more
difficult to remove the valence electron of an atom, hence greater energy is required to remove the
electrons
Because the number of shells increases successfully and the nucleus, hence lesser energy is required to
remove the valence electrons
The Metallic Character increases as you go down a group, since the ionization decreases going down
group (or increases going up a group) the increased ability for metals lower in a group to lose electrons
make them more reactive
The periodic table can be predict the properties of new elements, because it organizes the elements
according to their atomic numbers
18. How do understanding periodic trends allow us to predict properties of different elements?
What properties can be predicted by understanding trends?
An understanding of periodic trends is necessary when analyzing and predicting molecular properties
and interactions
19. Where on the periodic table (upper/lower, right/left) would you find atoms with the
following?
a. largest atomic radius: find in lower left
b. largest electron affinity: upper right
c. smallest ionization energy: lower left
20. Choose the more metallic element from each pair:
a. Sn or Te: Sn is more metallic then Te
b. Si or Sn: Sn is more metallic then Si
c. Br or Te:Te is more metallic then Br
d. Se or l: I is more metallic then Se
A chemical bonding is defined as the attractive force which holds atoms together to form molecules
The electronic theory of valence says that” every atom tends to achieve a stable octet electronic
configuration in the valence shell by losing, gaining or sharing of electrons
Lewis electron dot diagram is a representation of the valence electrons of an atom by using dots around
the symbol of the element.
In the formation of ionic bond, metal atoms donate electrons to the formation of positive ions (anions)
Covalent bond is the bond of attraction between non-metals that results from valence electrons being
shared between two nuclei
Ionic compound: is a compound formed by ions bonding together through electrostatic force
When electrons are shared between two atoms, they form a bond called a covalent bond
Molecular compounds: are compounds that form two or more non-metallic elements
Lone pairs: a pair of electrons occupying an orbital in an atom or molecule and not directly involved in
bonding.4
Polar covalent bond: is a covalent bond which forms between different non-metal atoms with different
Electronegativity
No polar covalent bonds: are the bonds formed between same atoms or different atoms with close
Electronegativity
A precipitate is an insoluble solid that forms as a result of chemical reaction in aqueous solutions
Precipitate reaction: is a reaction that occurs between 2 Aqueous solutions and forms a precipitate
during chemical reaction
The law of conservation mass states that “mater is neither created nor destroyed in a chemical
reaction”
The law of definite proportional states that “a chemical compound always contains elements combined
together in the same definite proportion by mass”
The reaction arrow indicates change and the direction of the reaction
Balancing is the process of making the number of elements on both sides of the equation equal
Balanced equation: is the chemical equation in which the number of atoms in the reactants is equal to
the number of atoms in the products
Coefficient: is the number placed in front of the symbols and formulas in the chemical equation
Combination reaction: is the reaction in which two or more substance react to form a single substance
Decomposition reaction: is the reaction in which single compound is broken down into two or more
products
Single displacement reaction: is the reaction in which one substance is replaced from its compound by
another substance
Double displacement reaction: is the reaction in the constituents exchange their place
The general form for the electron configuration of each alkali metal is ns 1
2. What is the electron configuration of a noble gas? Why is this configuration important
Noble gases all have s2p6 s2 p6 electron configurations in their valence shell for a total of eight valence electrons. This
makes them very stable to the point that several of the noble gases form no known compounds
Atoms of non metals tend to gain electrons in order to fill their outermost principle energy level with an
octet
5. What column of the periodic table has Lewis electron dot diagrams with two electrons?
Helium
6. Draw Lewis electron dot diagram for each of the following elements
a. Silicon
c. Bromine
Ca(OH)2+CO2→CaCO3+H2O
Zn+2AgNO3→Zn(NO3)2+2Ag
Ag
2Al+3CuCl2→2AlCl3+3Cu
BaCl2+K2SO4→BaSO4+2KCl
9. Classify each of the following reactions as a synthesis of either decomposition, single-
displacement or double-displacement
displacement
a. N2(g) + 3H2(g) 2NH3(g)
b. 2Li(s) + 2H2O(l) 2LiOH(aq)+ H2(g)
c. 2NaNO3(s) 2NaNO2(s) + O2(g)
Answer
a. Combination reaction
b. Single displacement reaction
c. Decomposition reaction
10. A precipitation of iron (III) hydroxide is produced by reacting an aqueous solution of iron (III)
chloride with an aqueous solution of sodium hydroxide. Write its balanced chemical equation
2NaOH+H2SO4→Na2SO4+2H2O
12. Write the world and the formula equations for the reaction between hydrogen sulfide gas
and oxygen gas that produce sulfur dioxide gas and water vapor
Word equation:
Hydrogen sulfide gas + oxygen gas sulfur dioxide gas + water vapor
Formula equation:
Answer
a. Potassium react with water to produce potassium hydroxide and hydrogen gas
b. Iron react with chlorine to produce iron chloride
c. Zinc sulfide react with oxygen to produce zinc oxide and sulfur dioxide
d. Calcium hydride react with water to produce calcium hydroxide and hydrogen gas
e. Silver nitrate react with potassium iodide to produce silver iodide and potassium nitrate
14. In a chemical reaction of sodium carbonate 5.3g and ethanoic acid 6g, 8.2g sodium ethanoate,
2.2g carbon dioxide and 0.9g water is formed. Does this product formed follow the low of
conservation of mass?
Solution
15. Aluminum sulfate and calcium hydroxide react to form aluminum hydroxide and calcium
sulfate. Write its balanced equation?
16. In a chemical reaction 0.096g of boron combine with 0.144g of oxygen to form a compound.
Calculate the mass of compound formed
1. Select the reactant(s) for the double displacement reaction that produces PF 5 and AsF3
a. PCl5 and AsF3
b. PCl3 and AsF5
c. PCl3 and AsF3
d. None of the above
2. A chemical bond between atoms results from the attraction between the valence electron and
of different atoms
a. Nuclei
b. Inner electrons
c. Isotopes
d. Lewis structure
3. A covalent bond consists of
a. Shared electrons
b. Shared electron pairs
c. Two different ions
d. An octet of electrons
4. If two covalent bonded atoms are identical, the bond is identified as
a. Non polar covalent
6. Atoms with strong attraction for electrons that they share with another atom exhibit
a. Zero Electronegativity
b. Low Electronegativity
c. High Electronegativity
d. Lewis Electronegativity
7. In the given reaction:
2H2 + O2 → 2H2O
a. Atoms of hydrogen and oxygen in reactant are equal to the atoms in product
b. Mass of hydrogen and oxygen atoms in the reactant is equal to the mass of water in the
product
c. Atoms of hydrogen and oxygen combine to form water
d. None of the above
8. Balancing chemical equation is based on the
a. Law of conservation of momentum
b. Law of conservation of weight
c. Law of conservation of mass
d. Law of proportion
9. In the chemical reaction of hydrogen and oxygen to form water
2H2 + O2 → 2H2O
4 grams of oxygen reacts with hydrogen to form 36g of water. The mass of hydrogen is
a. 8 g
b. 30 g
c. 32 g
d. 4 g
10. In the given reaction
a. X=2, Y=4
b. X=2, Y=2
c. X=1, Y=2
d. X=2,Y=1