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Pineapple Composite

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Mechanical Properties of Pineapple Leaf Fibre Reinforced Polymer Composites


for Application as Prosthetic Socket

Article in Journal of Engineering Technology · June 2016


DOI: 10.21859/jet-06011

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Journal of Engineering and Technology

MECHANICAL PROPERTIES OF PINEAPPLE LEAF FIBER REINFORCED


POLYMER COMPOSITES FOR APPLICATION AS A PROSTHETIC SOCKET

J. K. Odusote1*, A. T. Oyewo2
1
Department of Materials and Metallurgical Engineering, University of Ilorin,
P.M.B 1515, Ilorin, Kwara State, Nigeria.
2
Department of Mechanical Engineering, University of Ilorin, Ilorin,
P.M.B 1515, Kwara State, Nigeria.

ABSTRACT

Biodegradable fibers derived from natural plants are abundantly available and are
currently considered as waste. This study aims at investigating the mechanical properties
of pineapple leaf fiber reinforced thermoset composites as possible alternatives to the
above-knee glass fiber reinforced prosthetic socket. This study was carried out according
to ASTM (2004) standards at temperature and relative humidity of 26 ± 3 °C and 51 ± 2%,
respectively. Continuous pineapple leaf fibers are treated with sodium hydroxide and acetic
acid, and then added to epoxy and polyester at varying fiber loadings of 0, 20, 30, 40 and
50% to produce fiber reinforced composites using the hand lay-up method. The mechanical
properties of glass fiber polyester composite (GFPC) were compared with pineapple leaf
fiber polyester composites (PLPC) and pineapple leaf epoxy composites (PLEC). The
results showed that PLEC, particularly at 40% fiber loading, had superior mechanical
properties than GFPC and PLPC. The tensile, flexural and impact strengths of PLEC are
76.47 ± 3.85 MPa, 81.27 ± 1.77 MPa and 59.03 ± 0.99 k/Jm2, respectively. These values
are higher than those of PLPC with tensile, flexural and impact strengths of 62.09 ± 4.47
MPa, 53.02 ± 1.20 MPa 45.22 ± 1.10 k/Jm2, respectively. The tensile, flexural and impact
strengths of GFPC are also lower and are respectively 59.03 ± 0.99 MPa, 66.10 ± 1.88
MPa and 52.48 ± 1.77 k/Jm2. Thus, PLEC has the potential to be further developed as a
replacement for glass fiber in above-knee prosthetic sockets.

KEYWORDS: Pineapple leaf fiber; fiber; glass fiber; sodium hydroxide; thermoset; acetic
acid; mechanical properties

1.0 INTRODUCTION

Prosthesis, an artificial device that replaces missing parts of the body, is usually used in
cases of disfigurement, accident and disease. Of all the major types of prosthesis, the
above-knee prosthetic socket is the most difficult to maintain (Rosalam, Rahinah
& Paridah, 2011). Above-knee, also called transtibial, amputees, according to Arvela,
Albck, Aho, Venermo and Lepntalo (2010) require up to 80% additional energy to assume
normal ambulation than a healthy person.

*Corresponding E-mail: jamiukolawole@gmail.com

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Above-knee prostheses, as shown in Figure 1, can be classified into: the foot, used in
ambulation; the suspension system, which enables the wearer to move at the desired degree;
the pylon that connects the foot and the suspension system, which bears body weight; and
the socket, an interface connecting the wearer and the prosthesis. An ideal socket must be
lightweight, easily worn and removed, biocompatible, resist impact and stress in all
directions, relatively cheap and easily available (James et al., 2009). Because it is
constantly put on and taken off, the socket wears out easily and needs to be replaced
periodically. Most imported prosthetic sockets are made from polymeric materials
reinforced with synthetic fibers such as Aramid, carbon, fiber glass and silicon. These
prosthetic sockets cost between $531 and $1,700 depending on the quality and aesthetic
appeal (Kobayashi et al., 2010). This seems too expensive for most prosthetic users,
especially in developing nations such as Nigeria. However, according to Highsmith, Carey,
Koelsch, Lusk and Maitland (2009), 20% of the cost of a prosthetic leg is dependent on the
cost of the socket, excluding the workmanship of the prosthetic leg. Therefore, if this 20%
of the cost could be reduced, then it would greatly reduce the total production cost of the
prosthesis. Hence, this study aims at fabricating a lower limb prosthetic socket from
polymers reinforced with agro-biomass such as pineapple leaf fibers to replace the non-
recyclable synthetic fibers reinforced prosthetic socket. This will relatively reduce the cost
of production and will make the synthetic fibers more readily available, and
environmentally and user friendly.

Figure 1. Above-knee prosthesis (ICRC, 2006)

Thermosets such as epoxy and polyester are cheap, offer high-impact strength, rigidity, and
modulus of elasticity, and thus are extensively favored in orthotic and prosthetic industries.
Although natural plant fibers are yet to parallel the strength of synthetics, plant fibers such
as ramie, jute, bamboo and pineapple, which have a high cellulose content, have proved to

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be very successful, especially in low-strength applications. Moreover, compared with the


non-renewable sources of synthetic fibers, natural fibers such as pineapple leaf fibers are
readily available and are harvested yearly, making these sources renewable and
inexhaustible (Begum & Islam, 2013).

According to the Food and Agricultural Organization (FAO) (FAO, 2005; IITA, 2014)
pineapple contributes to 20% of the world production of tropical fruits, and, as a crop, is
second only to banana as the most important harvest fruit. Nigeria produces 889,000 tons of
pineapple fruits annually, which makes the country the top producer of the fruit in West
African countries and the 6th largest global producer after Thailand, the Philippines, Brazil,
China and India (IITA, 2014). After the pineapple fruit is harvested, the leftover leaves are
often left fallow, burned or buried. This approach is not an accepted healthy means of waste
disposal (IITA, 2014). This improper incineration presents an enormous environmental
threat by increasing global warming through emission of poisonous gases such as carbon
monoxide (CO), sulfur dioxide (SO2), unburnt CH4 and nitrogen oxide (NOx). With proper
processing, these leftover leaves can be converted into something useful, such as through
vermicomposting and by fibers being used as reinforcement for composite production
(Navdeep, Khalid and Sona, 2012). Although the lingo-cellulosic nature of the plant fibers
usually result in a poor adhesion between highly hydrophobic thermoset and hydrophilic
plant fibers, this can be rectified with appropriate surface treatment such as alkalization and
acetic acid. With chemical treatment, moisture absorption stops, cross linkage in the
interface increases, fiber surfaces become rougher and, ultimately, a significant increment
in mechanical properties parallel to the synthetic fibers can be obtained (Navdeep et al.,
2012).

The present study focuses on using pineapple leaf fiber as reinforcement in thermoset
composites using the low-cost hand lay-up method. Pineapple leaf fibers, which are eco-
friendly and abundantly available at low cost, are being investigated to replace the
expensive and non-environmentally friendly synthetic glass fiber currently being used for
the production of above-knee prosthetic sockets. Hence, a less expensive and high-quality
prosthetic socket using low-cost polymeric material reinforced with pineapple leaf fiber
will be produced. This will be a huge relief to prosthetic seekers, especially in an emerging
nation like Nigeria with income per capital as low as $1500 per year (News, 2014).

2.0 MATERIALS AND METHODS

2.1 Pineapple Fiber Preparation

Pineapple leaves were locally sourced at Oko-Oba village, near Ibadan, Oyo State, Nigeria.
Polyester resin (methyl 2-methylpropenoate resin), cobalt naphthenate catalyst, and methyl
ethyl ketone peroxide (MEKP) hardener were sourced from Ojota, Lagos, Nigeria. Sodium
hydroxide (NaOH), acetic acid, Epoxy TKL-121 (a bisphenol resin derived from organic
compounds containing bisphenol A and di-glycidyl-ethers, BADGE) and hardener DETA
(diethylenetriamine) were also obtained from Ojota, Lagos, Nigeria.

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The fibers were separated from the matrix leaves using a specially decorticated machine in
order to save time since more than 7 kg of pineapple fiber could be produced with the use
of this machine (Das, Nag, Debnath & Nayak, 2009). The decorticating pineapple leaf fiber
machine removed the waterproof outer layers before the fibers were passed through the
retting stage. With retting, the fibers were soaked in clean water, constantly checked by
hand-touching and were removed when the fibers perceptibly separated from the matrix
after 14 days. The fibers were washed thoroughly in water and subsequently sun dried. The
pineapple leaf fibers (PALF) were immersed in a 5% alkaline solution. NaOH) prepared
using a ratio of 1.5 liters to 100 g (liquid: fiber) for 30 minutes. To neutralize the effect of
the alkali and further strengthen the PALF, a solution of 2% acetic acid solution was used
to treat the PALF for 1 hr. After treatment, the pH of the solution was determined using a
pH meter and the pH was found to be 4. The fibers were further washed thoroughly in
water to remove embedded chemicals, sun dried, and subsequently dried in an oven at
70 °C for 4 hrs to finally obtain continuous pineapple leaf fibers, as shown in Figure 2.

2.2 Production of Composites

Continuous PALF, as shown in Figure 2, used in this fabrication were within the thickness
and width range of 0.3 ± 0.4 mm with a symmetrical fiber orientation. The composite
fabrication of the pineapple leaf polyester composites (PLPC) and pineapple leaf epoxy
composites (PLEC) was produced by hand lay-up method with varying fiber compositions
of 0%, 20%, 30%, 40%, and 50%. Recorded room temperature and relative humidity were
26.3 °C and 57.5%, respectively. Epoxy resin and hardener were mixed in a ratio of 2:1,
while ratio 10:1 was used for the polyester resin and its hardener. These mixtures were
stirred thoroughly for 6 minutes for wetting and proper soaking before fabrication.
However, 30% glass fiber was used for the glass fiber polyester composite (GFPC). To
reduce voids, a load of 20 kg was placed on the mold during lamination and left for 6 hrs.
Figure 3 shows a composite sample produced by hand lay-up method before being cut into
various standards.

Figure 2. Pineapple leaf fibers

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Figure 3. Hand lay-up composite sample before being cut into various standards

2.3 Specimen Testing

Composite samples (GFPC, PLPC and PLEC) were in conformity with ASTM (2004)
standards. That is, ASTM D 3039 – 76 for tensile testing, ASTM D790 – 03 for flexural
test and D256 for impact test (ASTM, 2014). Before the tests were conducted, all the test
samples were conditioned at room temperature of 23.2 ⁰C with relative humidity of 50.5%
for 24 hours.

2.3.1 Tensile Test

Tensile test samples were prepared according to the ASTM D 3039 standard, and the test
was carried out using the Universal Testing Machine (Instron 5567). This machine was
operated at a crosshead speed of 2 mm/min, room temperature of 26 ± 3°C, and relative
humidity of 55 ± 2%. The dimensions of the 6 specimens used for the tensile test are
150 x 20 x 3 mm (length x width x thickness). The average values were reported including
standard deviations. Each sample was loaded to failure. From the tensile test results, tensile
strength, Young’s modulus and percentage elongation were calculated.

2.3.2 Flexural Test

Three-point loading system applied on a supported beam was utilized according to ASTM
D790 – 03 standards. The load was applied midway between the supports with a crosshead
speed of 1.7 mm/min. Test piece specimens were prepared with dimensions of
120 mm × 10 mm × 4 mm for the flexural test using the Universal Testing Machine
(Instron 5567). Each sample was loaded to failure and the average values were thereafter
reported including standard deviations.

2.3.3 Impact Test

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Test method A (Izod type) according to ASTM D256 was used for testing (ASTM, 2014).
Notching was done because it provides a stress concentration area that promotes a brittle
rather than a ductile failure. Furthermore, notching also drastically reduces the energy lost
due to plastic deformation. A few parameters were set according to the standard, for
instance, Hammer Velocity = 3.46 m/s and Hammer Weight = 0.905 kg. Impact strength
was calculated using Equation (1).

Energy of fracture (Joule)


Impact Strength= (1)
Cross-sectional area (m2 )

3.0 RESULTS AND DISCUSSION

3.1 Results

Generally, it was observed that composite samples with fiber loadings of 20, 30 and 40%
were easier to fabricate compared with the composite sample with 50% fiber loading.
Flaws, crazing, void and delamination were observed at 50 wt.% fiber loading composite
samples.

3.1.1 Tensile Properties

From among the derivations of tensile properties, tensile strength, Young’s modulus and
percentage of elongation are directly relevant to prosthetic sockets (Philips et al., 2005),
thus their results are discussed here. As shown in Tables 1 and 2, the tensile properties,
namely tensile strength, Young’s modulus and percentage elongation of the composites,
increased with fiber loading. In both epoxy and polyester composites, the optimum fiber
loadings that yielded highest tensile strength were at 50 wt.% fiber loading. It was also
observed that there was a slight increment between 40 and 50% in tensile properties,
notably with Young’s modulus. There was no appreciable increase in modulus of elasticity
from 40 to 50% fiber loading. Unlike the tensile strength and Young’s modulus, which
increased with fiber loading, some discrepancies were observed with some of the
percentage elongation results. A noteworthy exception was the pineapple leaf epoxy
composite with a small difference of 12.6% between 30 and 40% fiber loading and a sharp
decline from 8.93 ± 0.11 to 8.15 ± 0.22% induced from 40 to 50% fiber loading.
Meanwhile, mechanical properties of GFPC samples were higher than all ratios of PLPC
except at 50 wt.% fiber, while the mechanical properties of PLEC at 40 and 50 wt.% were
higher than those of the GFPC samples.

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Table 1. Tensile properties of pineapple leaf fiber and


glass fiber reinforced polyester composites

Composite Parameter Fiber loadings (wt.%)


0 20 30 40 50
Pineapple UTS 10.22±1.93 30.15±3.03 48.78±3.90 62.09±4.87 69.12±5.20
Y Modulus 1.12±0.02 2.43± 0.07 3.46±0.05 4.81± 0.11 5.03± 0.10
Elongation 0.98 ± 0.01 2.79± 1.10 3.11 ± 0.06 4.99 ± 0.13 5.44± 0.11
Glass fiber UTS 65.72 ± 3.30
Y Modulus 7.33 ± 3.22
Elongation 7.76 ± 1.10

Table 2. Tensile properties of pineapple leaf fiber reinforced epoxy composites

Composite Parameter Fiber loadings (wt.%)

0 20 30 40 50

Pineapple UTS 14.30±2.21 35.88±0.90 62.75±2.10 76.47±3.85 80.12±2.23

Y Modulus 2.43 ±0.19 5.42 ± 0.10 7.80 ± 0.08 8.93± 0. 11 8.15± 0 .22

Elongation 2.56 ± 0.13 5.88 ± 0.20 6.92± 0.17 7.55± 0.31 8.24 ± 0.24

3.1.2 Flexural Strength

Figure 4 shows the flexural strength of pineapple leaf reinforced polyester and epoxy
composites. The flexural strength of all the composites in this study increased with increase
in fiber content. However, there was a slight variance in the flexural strength of the
pineapple leaf polyester composites. A noteworthy exception experienced 3.5% decline in
flexural strength from 0 to 20% fiber loading before following the normal increasing trend.

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100
Flexural strength, MPa 90
80
70
60
50
40
30
20
10

Pineapple leaf Pineapple leaf Glass fibre


polyester epoxy polyester
Composites
0% 20 % 30 % 40 % 50 %

Figure 4. Flexural Strength of pineapple leaf fiber reinforced


in epoxy and polyester composites

3.1.3 Impact Strength

The impact test samples as shown in Figure 5 also witnessed successive increased impact
strength with addition of fibers. However, GFPC, particularly at 30% fiber loading, had
higher impact strength values than corresponding PPFC and PEFC. This is closely followed
by PPFC and PEFC.
70
60
Impact strength, kJ/m2

50
40 0%
30 20 %
20 30 %
10 40 %
0 50 %
Pineapple leaf Pineapple leaf Glass fibre
polyester epoxy polyester
Composites

Figure 5. Impact test of pineapple leaf and glass fiber reinforced


in epoxy/polyester composite

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3.2 Discussion

The general observation of crazing, void, delamination, brittleness, and inability of the
composites to form properly at 50% fiber loading may probably due to inadequate amount
of matrix to effectively support the fibers, thereby leading to inhomogeneity of the
composites. This inevitably led to flaws and crazing, thus creating a stress concentration
area which lowered the stiffness of the composite. This phenomenon has also been reported
by Philips and Craelius (2005).

For high-strength applications such as prosthetic sockets, higher tensile and Young’s
modulus need to be sought, whereas an increase in elongation, a function that determines
the ductility of materials, is disadvantageous. Hence, a lower percentage of elongation is
desirable for prosthetic socket materials, as reported by Irawan, Soemardi, Widjajalaksmi
and Reksoprodjo (2010). Increase in tensile properties of the composites – tensile strength,
Young’s modulus and percentage elongation – arising from fiber loading, as evident from
Tables 1 and 2, is normal and has been reported by several authors (Fischer, 2010; Irawan
et al., 2010). The reversible behavior of Young’s modulus often shows a linear relation
between stress and strain. To minimize deformation, especially with a prosthetic socket that
bears the weight of the body, a material with a large elastic modulus must be sought. This
corresponds to the result in this study, as modulus of elasticity of the composite samples
increased with increase in fiber loading. The slight increment between 40 and 50 wt.% in
tensile properties, especially for tensile strength and Young’s modulus, depicted that the
polyester/epoxy composites were becoming stiff and could not withstand higher stress. This
also could be attributed to the increase in stiffness of the polymer when fibers were added.

The treated fiber composites exhibit stronger bonding between the fiber and the polymer
matrix, and this apparently affected the elasticity of the polymer (Augustinus & Sukaina,
2012). The fiber serves as reinforcement because the major share of the load has been taken
up by the crystalline fibrils, resulting in extension of the helically wound fibrils along with
the matrix (Phillips & Craelius, 2005). As for the percentage of elongation, the presence of
the fibers in the matrix constrains the stretching of the matrix and reduces its elasticity.
However, this lowers the extent of strain occurring within the polymer during loading. The
small difference observed between 30 and 40% fiber loading and sharp decline from 8.93 ±
0.11 to 8.15 ± 0.22% induced from 40 to 50% fiber loading can probably be attributed to
defects in the hand lay-up method of fabrication used in this study.

The tensile strength of the composite increased due to the chemical treatment, which
induced greater adhesion between the polymer matrix and the fibers. The higher strength of
the composites compared to that of the pure epoxy and polyester polymers suggest an
efficient composite system is achieved, with better fiber-matrix adhesion. Continuous fibers
such as pineapple leaf used in this study yield higher strength, while short fibers with
discontinuity and irregularity in the polymer structure result in a weakened frame, as
reported by Anyakora and Abubakre (2011).

Fiber ratio, chemical surface treatment and reaction between the matrix and fiber have been
reported to have a tremendous effect on composites (Phillips & Craelius, 2005; Irawan

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et al., 2010). Fabrication techniques also strongly influence the strength of composites.
Ramie Epoxy Reinforced Composite, RERC, fabricated using the filament winding method
(Irawan et al., 2010) displayed higher tensile strength and modulus of elasticity than
Bamboo Epoxy Reinforced Composite (BERC) produced by hand lay-up (Irawan et al.,
2010). The tensile strength and modulus of elasticity values of RERC were also compared
with the results in the present study (Table 3), and were found to also be higher, probably
due to the hand lay-up method used here. Although the hand lay-up method of fabrication
used in this study is simple and cost effective, it is labor intensive, non-homogenous and
difficult to attain uniform thickness. The filament winding method, however, eliminates
these deficiencies. Therefore, the strength of the RERC was higher than in this study due to
the filament fabrication method used for the RERC (Phillips & Craelius, 2005).

Furthermore, this present study used NaOH and acetic acid to ameliorate the adhesion
between resin and plant fibers by removing hemicellulose and lignin responsible for plant
fiber hydrophilic behavior. However, in addition to NaOH and acetic acid, a silane coupling
agent (amino-ethyl-propyl amino silane trimetoxy) was also used for treatment in
fabrication of the RERC (Phillips & Craelius, 2005). Fiber pre-treated with NaOH for
approximately half an hour before coupling with silane has been reported to generate more
reactive sites by minimizing sensitivity to humidity and number of cellulose hydroxyl
groups in the fiber-matrix interface (Irawan et al., 2010). Thus, reactivity between the fibers
and the resin greatly improves mechanical interlocking of the fibers in the matrix while also
inducing a chemical linkage between the cellulose and polymer chain (Ilomäki, 2012;
Augstburger et al., 2011; Yaseer, 2009). This justifies the higher strength of Ramie
composites compared to others, as shown in Table 4.

According to Phillips and Craelius (2005) and Augustinus, Tresna and Agus (2009),
laminate composites used in prosthetics and orthotics can be classified into three categories
as shown in Table 3. It is highly recommended to consider this classification when
selecting a prosthetic socket. The results of this study showed that GFPC, 64 ± 4.20 MPa,
was below the recommended middle-range strength while PLEC (77.47 ± 3.85 MPa) is
classified as a middle-range strength material, which is in agreement with Augustinus and
Sukaina (2012), Phillips and Craelius (2005) and Augustinus et al. (2009).

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Table 3. Tensile strength and Young’s modulus of socket materials (Taylor, Gilbert and
Lautenschlager, 1992; Augustinus & Sukaina, 2012; and Phillips & Craelius, 2005)

Strength Fiber Types UTS Range Young’s Modulus


Range (MPa) (GPa)
Low Perlon, nylon, cotton, 18 – 42 1.8 – 5.1
nyglass, spectralon.
Middle Glass 67 – 109 5.0 – 17.3
Rattan Epoxy 66.25 ± 0. 81 8.68 ± 0.68
Ramie Epoxy 86 ± 6.07 9.40 ± 0.68
Ramie Polyester 67 ± 5.11 7.45 ± 0.57
Bamboo Epoxy 78.09 ± 1.97 8.96 ± 0.33
Pineapple polyester 62.09±4.87 4.81 ± 0.11
Glass fiber Polyester 65.72 ± 3.30 7.33 ± 3.22
Pineapple Epoxy 77.47 ± 3.85 7.93 ± 0.11
High Carbon 236 – 249 20.6 – 25.5

3.2.1 Flexural Strength

Flexural properties are very important in prosthetic sockets as the material used must be
strong, elastic to support the body’s weight, and able to receive dynamic load, which may
happen in gaiting system (Phillips & Craelius, 2005). It was observed that the flexural
strength of all the composite samples, except the 20% pineapple fiber epoxy composite,
increased with fiber loading. This exception could probably be due to insufficient fiber
loading. Phillips and Craelius (2005) reported increase in the flexural modulus and flexural
strength to the increasing fiber to-fiber contact when the fibers were impregnated. And the
higher strength of the epoxy composite compared to the glass fiber and pineapple polyester
composites can be interpreted as the pineapple leaf fiber reinforced epoxy composites can
withstand bending forces better than tensile stress due to their higher flexural and modulus
strength. These observations prove that pineapple leaf, which has high strong crystalline
content, can share the load applied in a matrix effectively due to the crystalline fibrils in it
and can also withstand bending with various fiber loadings (Sumaila and Amber, 2013).

Compared with previous work on prosthetic and orthotic materials, Table 4 shows that
Ramie epoxy composite clearly exhibit superior flexural strength which could be attributed
to the use of filament winding method coupled with pre-treatment process of the fiber using
silane coupling agent.

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Table 4. Flexural strength of prosthetic socket material (Augustinus & Sukaina, 2012)

Socket materials Flexural strength (MPa)

Ramie Epoxy 103 ± 15.62


Ramie Polyester 84.8 ± 6.93
Pineapple Polyester 53.02 ± 1.20
Polyester Glass fiber 66.10 ± 1.88
Pineapple Epoxy 81.27 ± 1.27

3.2.2 Impact Strength

Impact strength of a material is defined as the material’s ability to absorb applied energy,
and is directly related to its overall toughness. Area under the stress-strain curve is
proportional to the toughness of the material. Nevertheless, impact strength is a measure of
toughness. Impact strength is required for prosthetic socket materials. The quality of
prosthetic socket materials also depends on the impact strength necessary to provide safety,
and that they are not easily damaged when receiving impact loads (Phillips & Craelius,
2005). This greatly affects the user’s sense of safety when using a prosthetic socket
product. Based on the foregoing explanation, the results of this study that increased with
fiber loadings also agreed with the study of Augustinus and Sukaina (2012), as shown in
Figure 6. Higher impact strength values of epoxy composites compared with polyester
composites are probably an indication of better matrix-fiber interaction assisted by
chemical treatment, of the former

70
60
Impact strength, kJ/m2

50
40
30
20
10
0
20 % 30 % 40 % 50 %

Fiber loadings

Bamboo epoxy Pineapple epoxy Pineapple polyester


Figure 6. Impact strength of bamboo epoxy (Irawan et al., 2010),
pineapple epoxy and pineapple polyester

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4.0 CONCLUSION

From the experimental results, the following can be concluded:


a) Pineapple fiber reinforced epoxy composites had better flexural, impact and tensile
properties than fiber glass and pineapple fiber reinforced polyester composites.
b) Chemical surface treatment was responsible for the good adhesion between epoxy
and pineapple leaf fiber than pineapple leaf fiber and glass fiber polyester composites.
c) 40% fiber loading was the best and is preferred to the higher value of 50% fiber
loading, ostensibly because there are fewer voids, and less crazing, delamination and
complexity during fabrication.
d) Overall, GFPC composites exhibit most prominent strength in comparison to those of
the PLPC and PLEC composites. However, this is not the case for the 30 wt.% GFPC
composites.
e) Finally, the results of this study showed that PLEC has the potential to be further
developed as a substitute for fiber glass polyester prosthetic sockets, particularly for
above-knee ones, where higher strength is required. Pineapple leaf fiber is locally
available, bio-mechanically appropriate, as lightweight as possible, comfortable and
psychosocially acceptable.

REFERENCES

American Society for Testing. (2004). Annual Book of ASTM Standards: ASTM D 3039,
ASTM D 256 and ASTM D 790-03. West Conshohocken, PA: ASTM International.

Anyakora, A. N. & Abubakre, O. K. (2011). Effect of silane treatment on the impact


strength properties of oil palm empty fruit bunch fiber-reinforced polyester
composites. World Journal of Engineering and Pure & Applied Sciences,
1(2): 40-45.

Arvela, E., Albck, A. S. M., Aho, P., Venermo, M. & Lepntalo, M. (2010). Arm vein
conduit versus prosthetic graft in infrainguinal revascularization for critical leg
ischemia. Journal of Vascular Surgery, 52(3):616-623.

Augustinus, I. P. & Sukaina, I.W. (2012). Tensile and impact strength of bamboo fiber
reinforce epoxy composite as alternative materials for above knee prosthetic
socket. Proceeding of the 2nd International Conference on Sustainable Technology
Development, ICSTD, Bali: Udayana University Press.

Augustinus, I. P., Tresna, P. S. W., & Agus, H. S. R. (2009). Komposit laminate rami
epoksi sebagai bahan alternatif socket prosthesis. Jurnal Teknik Mesin,
11(1): 41-45.

Begum, K. & Islam, M.A. (2013). Natural fiber as a substitute to synthetic fiber in polymer
composites: A review. Research Journal of Engineering Sciences,
2(3): 46-52.

ISSN: 2180-3811 Vol. 7 No. 1 January – June 2016 137


Journal of Engineering and Technology

Das, P. K., Nag, D., Debnath, S. & Nayak, L.K. (2010). Machinery for extraction and
spinning of plant fibers. Indian Journal of Traditional Knowledge, 9(2): 386-393.

Food and Agriculture Organization of the United State (FAO). (2005). Pineapple: Post
Harvest Operation. Venezuela: FAO Inc.

Fischer, A. A. (2010). Pressure tolerance over muscles and bones in normal subjects.
Archives of Physic Medicine Rehabilitation, 67: 407-408.

Augstburger, J., Berger, J., Censkowsky, U., Heid, P. Milz, J. & Streit, C. (2001). Organic
farming in the tropic and sub tropic: Exemplary description of 20 crops. 2nd
Edition. German: Natureland.
Highsmith, M. J., Carey, S. L., Koelsch, K.W., Lusk, C. P. & Maitland, M. E. (2009).
Design and fabrication of a passive-function, Cylindrical Grasp Terminal Device.
Prosthetics and Orthotics International, 33(4): 391-398.

International Committee of the Red Cross, (ICRC). (2006). Manufacturing guidelines:


Trans-femoral prosthesis, physical rehabilitation programme. Geneva,
Switzerland: ICRC publisher Inc.

International Institute of Tropical Africa (IITA). (2014). Banana and plantain. Retrieved
from http://iita.org/banana-and-plaintain.

Irawan, A. P., Soemardi, T. P., Widjajalaksmi, K. & Reksoprodjo, A. H. S. (2010). Tensile


and flexural strength of ramie fiber reinforced epoxy composites for socket
prosthesis application. International Journal of Mechanical and Materials
Engineering, 6(1): 46-50.

Kobayashi, L., Inaba, K., Barmparas, G., Criscuoli, M., Lustenberger, T., Talving, P., Lam,
L. & Demetriades, D. (2010). Traumatic limb amputations at a level I trauma
center. European Journal of Trauma and Emergency Surgery, 37(1): 67-72.

Iomäki, K. (2012). Adhesion between fibers and thermoset. M Sc. Tampere University of
Technology, Finland.

James, M. A., Bagley, M. A., Brasington, K., Lutz, C., McConnell, S. & Molitor, F. (2009).
Impact of prostheses on function and quality of life for children with unilateral
congenital below- the-elbow deficiency. Journal of Bone and Joint Surgery,
34: 2357-2365.

Navdeep, M., Khalid, S. & Sona, R. (2012). A review on mechanical characterization of


Natural fiber reinforced polymer composites. Journal of Engineering Research and Studies,
3(1): 75- 80.

News Timeline. Nigerian National Bureau of Statistics. Retrieved from


http://nigeriastat.gov.ng/ng/ncidoc/6991.htm.

ISSN: 2180-3811 Vol. 7 No. 1 January – June 2016 138


Journal of Engineering and Technology

Rosalam, C. M., Rahinah, I. B. & Paridah, M. T. (2011). Natural based bio-composite


material for prosthetic socket fabrication. Alam Cipta, 5(1): 27-34.

Phillips, S. L., & Craelius, W. (2005). Material properties of selected prosthetic laminates.
Journal of Prosthetics & Orthotic, 17(1): 27-32.

Sumaila, M. I. & Amber, M. B. (2013). Effect of fiber length on the physical and
mechanical properties of random oriented, non-woven short banana (Musa
Balbisiana) fiber/epoxy composite. Asian Journal of Natural & Applied Sciences,
2(1): 39-49.

Taylor, D. A., Gilbert, J. C. & Lautenschlager, E. P. (1992). Testing of composite materials


used in orthotics and prosthetics. Journal of the Association of Children’s
Prosthetic-Orthic Clinics, 27(2): 62.

Yaseer, M. (2009). Feasibility study on setting up banana and pineapple fiber based in
Tripur. MS Indus Tree Craft Foundation. Bangalore, South India. 1-7.

ISSN: 2180-3811 Vol. 7 No. 1 January – June 2016 139

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