DPP - Daily Practice Problems

Name : Date : ��------�

Start Time : End Time :

SYLLABUS :
CHEMISTRY (1
Thermodynamics-1 (First LawofThermodynamics, Thermochemical Equations)
0]
Max. Marks : 120 Time : 60 min.
GENERAL INSTRUCTIONS
•
The Daily Practice Problem Sheet contains 30 MCQ's. For each question only one option is correct. Darken the correct drcle/
bubble in the Response Grid provided on each page.
•
You have to evaluate your Response Grids yourself with the help of solution booklet.
Each correct answer will get you 4 marks and 1 mark shall be deduced for each incorrect answer. No mark will be given/ deducted
if no bubble is filled. Keep a timer in front of you and stop immediately at the end of 60 min.
•

• The sheet follows a particular syllabus. Do not attempt the sheet before you have completed your preparation for that syllabus.
Refer syllabus sheet in the starting of the book for the syllabus of all the DPP sheets.
• After completing the sheet check your answers with the solution booklet and complete the Result Grid. Finally spend time to
analyse your performance and revise the areas which emerge out as weak in your evaluation.
Q.3 �Ht for Al203 is-1670 kJ. Calculate the enthalpy change
for the reaction : 4AI + 3 02 � 2AI203
DIRECTIONS (Q.l-Q.21) : There are 21 multi(>le choice
questions. Each question has 4 choices (a), (b), (c) and (d),
out of which ONLY ONE choice is correct. (a) -2340 kJ (b) -3340 kJ
(c) -1340 kJ (d) -4320 kJ
Q.l What is true regarding complete combustion of gaseous
isobutane? Q.4 The sp ecific heats of iodine vapours and solid are 0.031
and 0.055 Callg respectively. If heat of sublimation of
(a) �H = �E (b) �H>�
iodine is 24 Cal/g at 200°C, what is its value at 250°C ?
(c) �H = �E = 0 (d) �H<�E
(a) 22.8 Cal/g (b) 1 1 .2 Callg
Q.2 How much heat is produced when 4.50 g methane gas is
24.4 Cal/g
(c) 12.8 Cal/g (d)
burnt i n a constant pressure system?
Q.5
:
CH4 + 202 � C02 + 2Hp ; �H =- 802 kJ
Calculate the heat of neutralization by mixing 200 ml of
O.lM �S04 and 200 ml of0.2 M KOH if heat generated
Given
(a) 225.6 kJ (b) 125.6 kJ by the mixing is 2.3 kJ.
(c) 175.6 kJ (d) 325.6 kJ (a) 17.5 kJ (b) 42.5 kJ (c) 57.5 kJ (d) 34.5 kJ

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Q.6 A system does I 00 J ofwork on surroundings by absorbing Q.12 For a gaseous reaction : 2Aig) + 5B2(g) � 2A2B5(g) at
150 J of heat. Calculate the change in internal energy. 27°C the heat change at constant pressure is fmmd to be
(a) 100 J (b) 50 J (c) 25 J (d) 150 J -501603. Calculate the value of internal energy change
(�E). Given that R = 8.3 1 4 J/K mol.
Q.7 A gas absorbs 200 J of heat and expands against the external
(a) -34689 J (b) -37689 J
(c) -27689 J
pressure of 1 . 5 atm from a volume of 0.5 litre to 1 . 0 litre,
Calculate tl1e change in int-ernal energy. (d) -38689 J
(a) 124.25 J (b) 224 J (c) 1 1 4 J (d) 154 J Q.13 Calculate the work performed when 2 moles of hydrogen
expands isothermally and reversibly at 25°C from 1 5 to
Q.8 Heat of reaction for
50 litres.
C6H 2 06 (s) + 602 (g) � 6C02 (g) + 6�0 (1)
1 (a) -1436 calories (b) - 1 3 1 8 calories
at constant pressure is - 6 5 1 kcal at l7°C. Calculate the
(c) - 1 2 1 5 calories (d) - 1 1 72 calories
heat of reaction at constant volume at l7°C-
Q.14 Which orne of the following equations does not correctly
(a) - 554.5 kcal (b) - 654.5 kcal represent the first law of thermodynamics for the given
(c) - 354.5 kcal (d) - 1 54.5 kcal process?
Q.9 A sample of gas is compressed by an average pressure of (a) isothermal process : q =-w
0.50 atmosphere so as to decrease its voltillle from 400 (b) cyclic process : q = - w
cm3 to 200 cm3. During the process 8.00 J of heat flows (c) expansion of gas into vacuum : �U = q
out to surroundings. Calculate the change in internal energy
(d) adiabatic process : �V = - w
of the system.
Q.lS From the following data of�H ofthe following reactions,
(a) 2.13 J (b) 4.17 J (c) 1.13 J (d) 3.52 J
C(s)+ Y2 02 (g) �co (g) ; fl.H=-l l O kJ
Q.lOThe heat of combustion of napthalene (C 0H8(s))
1 and C (s) + �O (g) �co (g) + H2 (g) ;�H= 132 kJ.
at constant volume was measured to be- 5 1 33 kJ mol-1 at
298 K. Calculate the value of enthalpy charnge Calculate the mole composition of the mixture of oxygen
and steam on being passed over coke at l 273K, keeping
(Given R = 8.314 JK- 1 mol- 1 ).
the reaction temperature constant.
(a) - 3 1 3 7955.14 Joule (b) - 5 1 37955 . 1 4 Joule (a) 0.3 : I (b) 2.1 : l (c) 0.6 : l (d) l : I
(c) - 4 1 27955. 1 4 Joule (d) - 3247955.14 Joule Q. 16 200 ml ofKOH and 200 ml ofHN0 ofsame molarity are
3
Q.ll A cooking gas cylinder i s assumed to contain 1 1 .2kg mixed together and liberated 3.426 kJ of heat. Determine
isobutane. The combustion of isobutane is given by- the molarity of each solution.
(a) 0. 1 mole (b) 1 . 3 mole (c) 0.7 mole(d) 0.3 mole
C4H1 0 (g) + (:)
1
02 (g) � 4C02 (g) + 5�0(1); Q.17 The work done in ergs for the reversible expansion of one
mole ofan ideal gas from a volume of 1 0 litres to 20 litres
fl.H = - 2658 kJ at 25°C is
If a family needs 15000 kJ of energy per day for cooking, (a) 2.303 x 298 x 0.082 log 2
how long would the cylinder last? (b) 298 X 107 X 8 . 3 1 X 2.303 log 2
[1 mole of isobutane = 2658 kJ] (c) 2.303 x 298 x 0.082 log 0.5
(a) 22 days (b) 28 days (c) 32 days (d) 34 days (d) 8.31 x l07x 298 - 2 .303 log 0.5

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Q.18 For the reaction Q.23 Choose tlhe correct options for the process at 25°C of
CH3COOH(l) • 20 2 (g) � 2C02 (g)• 2H20(1) at 25°C dissolving 1.00 mol ofKCl in large excess of water.
t.f H0 [K+(aq)] = - 251.2 kJ mol- 1
and I atm. pressure, H • • 874kJ. Then the change in
�f H0 [CI- (aq)] = 167.08 kJ mol-1
•

internal energy (• E) is
t.rH0 = 437.6 kJ moi-1

+
[KCI]
(a) - 874 kJ
-

(b) - 871.53 kJ
(c) - 876.47 kJ (d) 874 kJ (I) t.�0 for the reaction is + 19.3 kJ moi- 1
Q.19 One mole of an ideal gas is allowed to expand reversibly (2) t.rH0 for the reaction is + 12.3 kJ moi- 1
and adiabatically from a temperature of27°C. If the work (3) The process does not represent an ionisation reaction
done during the process is 3 kJ, then final il:emperature of
(4) The process represent an ionisation reaction
=
the gas is (Cv 20 J I K)

( dH) + ( dE)
(a) 100 K (b) 150 K (c) 195 K (d) 255 K
Q.24 Which statement is incorrect -
Q.20 In a closed insulated container, a liquid is stirred with a
paddle to increase its temperature. In this process, which
of the following is true ?
(2)
dT dT
p v
-
_
R

(a) • E• W • Q • 0 (b) • E • O,Q• W • 0

(c) • E • W • 0, Q • 0 (d) • E · Q • O, W • 0
Q.21 One mole of an ideal gas is allowed to expand freely and DIRECTIONS (Q.25-Q.27) : Read the passage given below
adiabatically into vacuum until its volume has doubled. A and answer the questions that follows :
statement which is not true concerning this expression is
(b) A student performed a number of experiments on
(a) • H• 0 • S 0
thermodynamics. In one experiment, he took a closed vessel in
•

(c) • E• 0 (d) W• 0 which he dissolved 28 g of Fe in HCI at 27°C. In another

experiment, he dissolved the same amount ofiron but in an open
DIRECTIONS (Q.22-Q.24) : I n the following questions,
vessel. However, he compressed the gas to l 0 atm pressure at
more than one of the answers given are correct. Select the
27°C and then again allowed to expand it isothermally and
correct answen and mark it according to the following
reversibly until the pressure fell down to 1 atm.
codes:
Q.25 In the first experiment, the work done by the system is
Codes :
(a) 1246 J (b) zero
(a) 1 , 2 and 3 are correct
(b) I and 2 are correct (c) 2492 J (d) 1145 J
(c) 2 and 4 are correct Q.26ln the second experiment, the work done by the system, if
(d) l and 3 are correct the gas were not condensed, would have been nearly
Q.22 Which of the following processes have positive value for (a) 1246 J (b) zero
t.H? (c) 2492 J (d) 1 1 45 J
( 1) �(g) --+ 2H(g)

+
(2) H+(aq) + OH- (aq) � �0 (I) Q.27 The work done by the compressed gas would be nearly
(3) H(g) --+ W (g) e- (a) 1250 J (b) 2500 J
(4) H20(!)--+ �O(s) (c) 4000 J (d) 5000 J

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DIRECTIONS (Q. 28-Q.30) : Each of these questions contains Q.28 Statement 1 : T, P and V are state variables or state
two statements: Statement-! (Assertion) and Statement-2 functions.
(Reason). Each ofthese (]uestions has four alternative choices, Statement 2 :Their values depends on the state of the
system and how it is reached.
only one of which is the correct answer. You have to select the
correct choice. Q.29 Statement 1 : For an isothermal reversible process Q =­
w i.e. work done by the system equals the heat absorbed by
(a) Statement-! is Tme, Statement-2 is True; Statement-2 is a the system.
correct explanation for Statement-1. Statement 2 : Enthalpy change (• H) is zero for
(b) Satement-!
t is True, Statement-2 is True; Statement-2 isNOT isothermal process.
a correct explanation for Statement-! . Q.30 Statement 1 : Zeroth law can also be termed as law of
Statement -I is False, Statement-2 isTrue. thermal equilibrium.
(c)
Statement 2 : Two objects in thermal equilibrium with
(d) Statement - I is Tme, Statement-2 is False. the third one, are in thermal equilibrium with each other.

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DAILY P RACTICE PROBLEM SH E ET 10 - CHEMISTRY

Tota l Questions 30 Tota l Marks 120
Attempted Correct
Incorrect Net Score
Cut-off Score 36 Qual ifying Score 56
Success Gap = Net Score - Qual ifying Score
N et Score = {Correct x 4} - {I ncorrect x 1 }

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 DPP - Daily Practice Problems
Name : Date : ��------�
Start Time : End Time :

SYLLABUS :
CHEMISTRY ( 11
Thermodynamics-2 (Laws ofThermochemistry, Entropy, Spontaneous Process) ]
Max. Marks : 120 Time : 60 min.
GENERAL INSTRUCTIONS
•
The Daily Practice Problem Sheet contains 30 MCQ's. For each question only one option is correct. Darken the correct drcle/
bubble in the Response Grid provided on each page.
•
You have to evaluate your Response Grids yourself with the help of solution booklet.
Each correct answer will get you 4 marks and 1 mark shall be deduced for each incorrect answer. No mark will be given/ deducted
if no bubble is filled. Keep a timer in front of you and stop immediately at the end of 60 min.
•

• The sheet follows a particular syllabus. Do not attempt the sheet before you have completed your preparation for that syllabus.
Refer syllabus sheet in the starting of the book for the syllabus of all the DPP sheets.
• After completing the sheet check your answers with the solution booklet and complete the Result Grid. Finally spend time to
analyse your performance and revise the areas which emerge out as weak in your evaluation.

DIRECTIONS (Q.l-Q.21) : There are 21 multiple choice Q.3 Calculate the standard free energy change for the reaction
questions. Each question has 4 choices (a), (b), (c) and (d), N2 (g) + 3H2 (g) � 2NH3 at 298K
out of which ONLY ONE choice is correct. Given L".H0 =- 92.4 kJ and t.S0 = -198.3 JK- 1
(a) - 23.106 kJ (b) - 43.506 kJ
Q.l Calculate the enthalpy change (t.H) for the following (c) - 33.306 kJ (d) - 13.306 kJ
reaction Q.4 Calculate the entropy change in melting l mole of ice at
2C2H2 (g)+ 502(g) � 4C02(g) + 2Hp (g) 273K, Mlr0 = 6.025 kJ/mole-
Given average bond energies of various bonds (a) 11.2 JK-1 moJ-1 (b) 22.1 JK-1 mol-l
i.e. C-H, C""C ,O=O,C=O, O - Has 414, 810, 499, 724and (c) 15.1 JK- 1 mol- l (d) 5.1 JK- 1 mol- l
460 kJ/mok respectively Q.S Determine the standard free energy change for the
(a) - 1861 kJ (b) - 1 361 kJ following reaction at 298 K
(c) - 1261 kJ (d) - 1 161 kJ N2 (g) + 3Hlg) � 2NH3(g)
Q.2 The gaseous endothermic reaction : P + Q � 3R Given L".G0r for Nig) , H2(g) and NH3(g) are 0, 0 and
at 327°C takes place spontaneously, because- - 16.66 kJ mol-l
(a) t.H < 0; t.S < 0 (b) t.H > 0; t..S > 0 (a) - 1 l.22kJ (b) -22.22kJ
(c) t.H<O;t.S>O (d) t.H>O;t..S < O (c) -33.32kJ (d) -44.44 kJ
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42 t---- DPP/ C (1 1 ) w
Q.6 Calculate the standard enthalpy change for a reaction Q.U One mole of an ideal diatomic gas (C" = 5 cal) was
C02(g) + Hlg) ---+ CO(g) + H20 (g) transformed from initial 25°C and 1 L to the state when
given that Lllif for C02(g), CO(g) and H20(g) as-393.5, ­ temperature is I oooc and volume l OL. Then for this process
II 0.5 and-24 1 . 8 kJ/mol respectively. (R = 2 cal.ories/moi/K) (take calories as unit ofenergy and
kelvin for temp.). Which ofthe following is incorrect?
(a) -31.2kJ (b)-2 1 .2 kJ (c) -11.2kJ (d) +41.2kJ
(a) t.H= 525
Q.7 Determine the enthalpy change for the react ion 373
CH4(g) + Cl2(g) ---+ CH3CI(g) + HCI (g) (b) t.S = 5 ln + 2 ln 10
298
Bond energies for C-H, C - CI, CI- CI, H-CI are412, 338, (c) Lili= 525
242,431 kJ/mol. respective! y. (d) t.G of the process cannot be calculated using given
(a) -215 kJ/mol information
(b) -1 1 5 kJ/ mol
(c) -130 kJ/mol (d) -145 kJ/mol Q.12 C(graphite) + 02(g) ---+ C02(g);MI = -94.05 kcal mol-1
Q.8 Calculate the beat change in the reaction C(diamond) + 02 (g) ---+ C02 (g); Llli = -94.50 kc al mol- 1
4NH3 (g) + 302 (g) ---+ 2Nig) + 6Hp(C) therefore,
at 298 K, given that the heats offormation at 298 K for NH3 (a) C(graph.ite) ---+ C(diamond); t,H;98K = -450 cal mol - l
(g) and H20 (e) are - 46.0 and-286.0 kJ mol-l respectively. (b) C(diamond) ---+ C(graphite); Llli298K = +450 cal mol-1
(a) - 1 861 kJ (b)-1361 kJ (c)-1261 kJ (d) -1532kJ
•

(c) Graphite is the stable allotrope

Q.9 The heat of hydration of solutions of anhydrous CuS04 (d) Diamond is harder than graphite
and hydrated CuS04. 5H20 are - 66.5 and I I . 7 kJ mol-1 Q.13 Consider the reactions
respectively Calculate the heat of hydration of CuS04 to C(s)+ 2H2(g) ---+ CH4(g),�H = -x kcal
CuS04. 5H20.
C(g) +4H(g) -+ CH4(g),�H =-x1 kcal
(a) -78.2kJ (b)-8 1 . 2 kJ (c)-68.2kJ (d)-60.1kJ
CH4 (g) ---+ CH3(g) + H(g),�H = +y kcal
Q.10 Calculate the entropy change (t.S) per mole for the following
The bond energy of C - H bond is
reactions:
(a) y kcal mol- l (b) x1 kcal mol- l
(i) Combustion ofhydrogen in a fhel cell at 298 K (c) x /4 kcal mol- 1 (d) x1 /4 kcal mol- 1
H2(g) + Y2 02(g) ---+ H20 (g) Q.14 Iffor a given substance, melting point is T8 and freezing
t.H = -241.6 kJ, t.G = - 228.4 kJ point is TA• then correct variation shown by graph
(ii) Vaporisation ofmethanol at its normal boiling point. between entropy change and temperature is

(iii)
CH,OH (e) ---+ CH,OH (g)
LlHv,'P = 23.9 kJ, boiling point = 338 K
Fusion ofice at its normal melting point,
lee ---+ Water
(a) Ilk
S fl�
S
TB

TA
(b)
T,

TA

mfusion = 6.025 kJ, melting point = 0°C T --+ T --+

Jl J I K
(a) -44.3 JK-1, ?O JK-1 , 22 JK-1
(o) T.
(b) -24.3 JK-1, 60 JK-1 , 1 1 JK-1

�
(d)
(c) - l 4.3 JK-1, 50JK-1 , 3 2 JK-1
1 1
(d) -54.3JK- ,40JK- 1 , 2 ! JK-
T-

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Q.15 When a solid melts reversibly Q.20 The H20(g) molecule dissociates as
(a) H decreases (b) G increases
(i) Hp(g) H(g) + OH(g);6H = 490 k.T
�
(c) E decreases (d) S increases
Q.16 The enthalpies of formation of A1203 and Cr203 are (ii) OH(g) � H(g) + O(g); Ml = 424 kJ
-1596 kJ and -1134 kJ respectively, �H for the reaction The average bond energy (in kJ) for water is
(a) 490 (b) 424 (c) 914 (d) 914/2
2Al + Cr203 � 2Cr + Al203 is
Q.21 Following reaction occurring in an automobile
(a) -2730 kJ (b) ---462 kJ �
2C8H18(g) + 2502(g) 16C02(g)+ 18H20(g). The sign of
(c) -1365kJ (d) +2730kJ
Ml, �s and 60 would be
Q.17 "The quantity ofheat which must be supplied to decompose
a compound into its element is equal to the heat evolved (a) +, -, + (b) -, +, - (c) -, +, + (d) +, +, -
during the fonnation of that compound from the elements." DIRECTIONS (Q.22-Q.24) : In the following questions,
This statement is known as more than one of the answers given are correct. Select the
(a) Hess's law correct answers and mark it according to the following
(b) Joule's law codes:
(c) Le-chatelier 's principle Codes :
(d) Lavoisier and Laplace law (a) 1 , 2 and 3 are correct (b) 1 and 2 are correct
Q.18For the reaction (c) 2 and 4 are correct (d) 1 and 3 are correct
Q.22 In which of the following entropy increases ?
H2(g) +.!_02(g
2
) � H20(1), Ml = -285.8 kJ mol -1 ( 1 ) Rusting of iron
(2) Melting of ice
6S = -0.163 kJ mol- IK-1 . (3) Vaporization of camphor
What is the value of free energy change at 27°C for the (4) Crystallization of sucrose from solution
reaction ?
(a) -236.9 kJ mol- l (b) -281.4 kJ mol-l Q.23 For a reaction tili = 9.08kJ mol-1 and �S = 35.7 JK-1 mol- l
(c) -334.7 kJ mol-l (d) +334.7 kJ mol-l which of the following statements is incorrect for the
reaction?
Q.19The direct conversion of A to B is difficult, hence it is
(I) Reversible and isothermal
carried oul by the following shown path :
C D (2) Reversible and exothermic
(3) Spontaneous and exothermic
t +
A B (4) Spontaneous and endothermic
Given Q.24 Which of the following are correct statements ?
6S(A->C) =SO e.u. , 6S(C- >D) = 30 e.u., �Sea�D) = 20 e.u. , (1) When �G is negative, the process is spontaneous
(2) When �G is zero, the process is in a state ofequilibrium
where e.u. is the entropy unit, then 6S(A�B) is (3) When �G is positive. the process is non-spontaneous
(a) +60e.u (b) +lOO e.u (c) -60e.u. (d) -lOO e.u. (4) When �G is positive, the process is spontaneous

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DIRECTIONS (Q.25-Q.27) : Read the passage given below and Q.27 Internal energy change at 25°C is LlE 1 while at 35°C it is Ll�
answer the questions that follows : then -
(a) L'lE1 = L'lE2 (b) L'l� > L'lE1
(c) L'..E 1 > L'..E2
J. W. Gibbs and H.Von Helmholtz: had given two equations which
are known as Gibbs-Helmholtz equation. One equation can be (d) None of these
expressed in terms of change in free energy (LlG) and enthalpy DIRECIIONS (Q. 28-Q.30) : Each ofthese questions contains two
(M-1) while other can be expressed in terms ofchange in internal statements: Statement-! (Assertion)andStatement-2(Reason). Each
energy (L'..E) and work function (L\.W)
ofthese questions has four alternative choices, only one ofwhich is
LlG = LlH + T . d (��)P ............. (!)
the correct answer. You have to select the correct choice.
(a) Statement-! is True, Statement-2 is True; Statement-2 is a

= L'lE+ T . ct( �)
Ll correct explanation for Statement-!.
LlW ............. (2) (b) Statement-! isTrue, Statement-2 is True; Statement-2 is NOT
d v
a correct explanation for Statement-!.
Where T is temperature

,
(c) Statement - 1 is False, Statement-2 is True.
Equation ( I ) is obtained at constant pressure while equation (2) is
obtained at constant volume. I t is observed that for the reaction (d) Statement - I is True Statement-2 is False.
N2(g) + 3Hig) 2NH3(g) Q.28 Statement 1 : Entropy ofice is less than water.
Free energy change at 25°C is -33 kJ while at 35°C it is -28 kJ Statement 2 : Ice has cage like structure.
which are at a constant pressure. Q.29 Statement 1 : There is no reaction known for which LlG is
Q.25 What would be the difference between enthalpy change at positive, yet it is spontaneous.
25°C and 35°C for a given reaction ? Statement 2 : For photochemical reactions LlG is positive.
(a) 4 kJ (b) 5 kJ (c) 3 kJ (d) zero Q.30 Statement 1 : Enthalpy and entropy of any elementary
Q.26 What would be the free energy change at 30°C ? substance in the standard state are taken as zero.
(a) 30.5 kJ (b) 33 kJ Statement 2 : Even at zero degree absolute, the constituent
� �8 � � �0.5 kJ particles are not complete!y motionless.

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DAILY P RACTICE PROBLEM SH E ET 11 - CHEMISTRY

Tota l Questions 30 Tota l Marks 120
Attempted Correct
Incorrect Net Score
Cut-off Score 32 Qual ifying Score 52
Success Gap = Net Score - Qual ifying Score
N et Score = (Correct x 4} - (Incorrect x 1}

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