Vyrtga 1

Safety data sheet Safety data sheet
acc. to Regulation (EC) No. 1907/2006 (REACH)
Phenol ≥99 %, Ph.Eur., crystalline
article number: 3215 date of compilation: 2015-08-11

Version: 5.0 en Revision: 2022-08-08
Replaces version of: 2020-02-14
Version: (4)
SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Identification of the substance Phenol ≥99 %, Ph.Eur., crystalline
Article number 3215
EC number 203-632-7
CAS number 108-95-2
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Laboratory chemical
Laboratory and analytical use
Uses advised against: Do not use for squirting or spraying. Do not use
for products which come into direct contact with
the skin. Do not use for products which come in-
to contact with foodstuffs. Do not use for private
purposes (household).
1.3 Details of the supplier of the safety data sheet
Carl Roth GmbH + Co KG
Schoemperlenstr. 3-5
D-76185 Karlsruhe
Germany
Telephone:+49 (0) 721 - 56 06 0

Telefax: +49 (0) 721 - 56 06 149
e-mail: sicherheit@carlroth.de
Website: www.carlroth.de
Competent person responsible for the safety data :Department Health, Safety and Environment
sheet:
e-mail (competent person): sicherheit@carlroth.de
1.4 Emergency telephone number
Name Street Postal Telephone Website
code/city
National Poisons Information Dudley Rd B187QH 844 892 0111

Service Birmingham
City Hospital
SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification acc. to GHS
United Kingdom (en) Page 1 / 18

article number: 3215
Section Hazard class Cat- Hazard class and Hazard

egory category statement
3.1O Acute toxicity (oral) 3 Acute Tox. 3 H301
3.1D Acute toxicity (dermal) 3 Acute Tox. 3 H311
3.1I Acute toxicity (inhal.) 3 Acute Tox. 3 H331
3.2 Skin corrosion/irritation 1B Skin Corr. 1B H314
3.3 Serious eye damage/eye irritation 1 Eye Dam. 1 H318
3.5 Germ cell mutagenicity 2 Muta. 2 H341
3.9 Specific target organ toxicity - repeated exposure 2 STOT RE 2 H373
4.1C Hazardous to the aquatic environment - chronic hazard 2 Aquatic Chronic 2 H411
For full text of abbreviations: see SECTION 16
The most important adverse physicochemical, human health and environmental effects
Skin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epi-
dermis and into the dermis. Delayed or immediate effects can be expected after short or long-term
exposure. Spillage and fire water can cause pollution of watercourses.
2.2 Label elements
Labelling
Signal word Danger
Pictograms
GHS05, GHS06,
GHS08, GHS09
Hazard statements
H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled
H314 Causes severe skin burns and eye damage
H341 Suspected of causing genetic defects
H373 May cause damage to organs through prolonged or repeated exposure
H411 Toxic to aquatic life with long lasting effects
Precautionary statements
Precautionary statements - prevention
P270 Do not eat, drink or smoke when using this product
P280 Wear protective gloves/protective clothing/eye protection/face protection
Precautionary statements - response
P302+P352 IF ON SKIN: Wash with plenty of water
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER/doctor
For professional users only


2.3 Other hazards
This material is combustible, but will not ignite readily.
Results of PBT and vPvB assessment
According to the results of its assessment, this substance is not a PBT or a vPvB.
SECTION 3: Composition/information on ingredients

3.1 Substances
Name of substance Phenol
Molecular formula C₆H₆O
Molar mass 94,11 g/mol
CAS No 108-95-2
EC No 203-632-7
Substance, Specific Conc. Limits, M-factors, ATE
Specific Conc. Limits M-Factors ATE Exposure route
Skin Corr. 1B; H314: C ≥ 3 % - 100 mg/kg oral

Skin Irrit. 2; H315: 1 % ≤ C < 3 % 630 mg/kg dermal
Eye Dam. 1; H318: C ≥ 3 % 0,5 mg/l/4h inhalation: dust/
Eye Irrit. 2; H319: 1 % ≤ C < 3 % mist
SECTION 4: First aid measures

4.1 Description of first aid measures
General notes
Take off immediately all contaminated clothing. Self-protection of the first aider.
Following inhalation
Call a physician immediately. If breathing is irregular or stopped, administer artificial respiration.
Following skin contact
After contact with skin, wash immediately with plenty of water. Immediate medical treatment re-
quired because corrosive injuries that are not treated are hard to cure.
Following eye contact
In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes hold-
ing eyelids apart and consult an ophthalmologist. Protect uninjured eye.
Following ingestion
Rinse mouth immediately and drink plenty of water. If swallowed danger of perforation of the eso-
phagus and the stomach (strong corrosive effects). In case of accident or unwellness, seek medical
advice immediately (show directions for use or safety data sheet if possible).
4.2 Most important symptoms and effects, both acute and delayed
Corrosion, Vomiting, Gastric perforation, Risk of serious damage to eyes, Risk of blindness, Headache,
Vertigo, Dyspnoea, Dizziness, Unconsciousness, Circulatory collapse


4.3 Indication of any immediate medical attention and special treatment needed
none
SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing media

co-ordinate firefighting measures to the fire surroundings
water, foam, alcohol resistant foam, dry extinguishing powder, ABC-powder
Unsuitable extinguishing media
water jet
5.2 Special hazards arising from the substance or mixture
Combustible. Vapours are heavier than air, spread along floors and form explosive mixtures with air.
Hazardous combustion products
In case of fire may be liberated: Carbon monoxide (CO), Carbon dioxide (CO₂)
5.3 Advice for firefighters
In case of fire and/or explosion do not breathe fumes. Do not allow firefighting water to enter drains
or water courses. Fight fire with normal precautions from a reasonable distance. Wear self-contained
breathing apparatus. Wear full chemical protective clothing.
SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel

Use personal protective equipment as required. Avoid contact with skin, eyes and clothes. Do not
breathe dust.
6.2 Environmental precautions
Keep away from drains, surface and ground water. Retain contaminated washing water and dispose
of it.
6.3 Methods and material for containment and cleaning up
Advice on how to contain a spill
Covering of drains. Take up mechanically.
Advice on how to clean up a spill
Take up mechanically. Control of dust.
Other information relating to spills and releases
Place in appropriate containers for disposal. Ventilate affected area.


6.4 Reference to other sections
Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incom-
patible materials: see section 10. Disposal considerations: see section 13.
SECTION 7: Handling and storage

7.1 Precautions for safe handling
Provision of sufficient ventilation. Use extractor hood (laboratory). Handle and open container with
care. Avoid exposure. Avoid dust formation. Clear contaminated areas thoroughly.
Measures to prevent fire as well as aerosol and dust generation
Keep away from sources of ignition - No smoking.
Removal of dust deposits.

Measures to protect the environment
Avoid release to the environment.
Advice on general occupational hygiene
When using do not eat or drink. Thorough skin-cleansing after handling the product.
7.2 Conditions for safe storage, including any incompatibilities
Store in a dry place. Hygroscopic solid. Store contents under inert gas.
Incompatible substances or mixtures
Observe hints for combined storage.
Protect against external exposure, such as
humidity, UV-radiation/sunlight, contact with air/oxygen
Consideration of other advice:
Store locked up.
Ventilation requirements
Keep any substance that emits harmful vapours or gases in a place that allows these to be perman-
ently extracted. Use local and general ventilation.
Specific designs for storage rooms or vessels
Recommended storage temperature: 15 – 25 °C
7.3 Specific end use(s)
No information available.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
National limit values
Occupational exposure limit values (Workplace Exposure Limits)
Coun Name of agent CAS No Identifi- TWA STEL Ceil- Nota- Source
try er [mg/ [mg/ ing-C tion
m³] m³] [mg/
m³]
EU phenol 108-95-2 IOELV 8 16 H 2009/161/

EU
GB dust WEL 10 i EH40/2005
GB dust WEL 4 r EH40/2005
GB phenol 108-95-2 WEL 7,8 16 EH40/2005
Notation
Ceiling-C Ceiling value is a limit value above which exposure should not occur
H Absorbed through the skin
i Inhalable fraction
r Respirable fraction
STEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-
minute period (unless otherwise specified)
TWA Time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8
hours time-weighted average (unless otherwise specified)
Human health values
Relevant DNELs and other threshold levels
Endpoint Threshold Protection goal, Used in Exposure time

level route of exposure
DNEL 8 mg/m³ human, inhalatory worker (industry) chronic - systemic effects
DNEL 16 mg/m³ human, inhalatory worker (industry) acute - local effects
DNEL 1,23 mg/kg bw/ human, dermal worker (industry) chronic - systemic effects
day
Environmental values
Relevant PNECs and other threshold levels
End- Threshold Organism Environmental com- Exposure time

point level partment
PNEC 0,008 mg/l aquatic organisms freshwater short-term (single instance)
PNEC 0,001 mg/l aquatic organisms marine water short-term (single instance)
PNEC 2,1 mg/l aquatic organisms sewage treatment plant short-term (single instance)
(STP)
PNEC 0,091 mg/kg aquatic organisms freshwater sediment short-term (single instance)
PNEC 0,009 mg/kg aquatic organisms marine sediment short-term (single instance)
PNEC 0,136 mg/kg terrestrial organisms soil short-term (single instance)


8.2 Exposure controls
Individual protection measures (personal protective equipment)
Eye/face protection
Use safety goggle with side protection. Wear face protection.

Skin protection
• hand protection
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374.
Check leak-tightness/impermeability prior to use. For special purposes, it is recommended to check
the resistance to chemicals of the protective gloves mentioned above together with the supplier of
these gloves. The times are approximate values from measurements at 22 ° C and permanent con-
tact. Increased temperatures due to heated substances, body heat etc. and a reduction of the effect-
ive layer thickness by stretching can lead to a considerable reduction of the breakthrough time. If in
doubt, contact manufacturer. At an approx. 1.5 times larger / smaller layer thickness, the respective
breakthrough time is doubled / halved. The data apply only to the pure substance. When transferred
to substance mixtures, they may only be considered as a guide.
• type of material
Butyl caoutchouc (butyl rubber)
• material thickness
0,7mm
• breakthrough times of the glove material
>480 minutes (permeation: level 6)
• other protection measures
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is
recommended.
Respiratory protection
Respiratory protection necessary at: Dust formation. Particulate filter device (EN 143). P3 (filters at
least 99,95 % of airborne particles, colour code: White).
Environmental exposure controls
Keep away from drains, surface and ground water.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state solid
Form crystalline
Colour colourless
Odour characteristic
Melting point/freezing point 40 – 42 °C
Boiling point or initial boiling point and boiling 180 – 182 °C
range
Flammability this material is combustible, but will not ignite
readily
Lower and upper explosion limit 1,3 vol% (LEL) - 9,5 vol% (UEL)
Flash point 81 °C at 1.013 hPa (ECHA)
Auto-ignition temperature 715 °C at 1.013 hPa (ECHA)
Decomposition temperature not relevant
pH (value) 4 – 5 (in aqueous solution: 10 g/l, 20 °C)
Kinematic viscosity not relevant

Dynamic viscosity 3 – 4 mPa s at 50 °C
Solubility(ies)
Water solubility 84 g/l at 20 °C
Partition coefficient
Partition coefficient n-octanol/water (log value): 1,47 (30 °C) (ECHA)
Soil organic carbon/water (log KOC) >1,147 – <1,864 (ECHA)
Vapour pressure 0,2 hPa at 20 °C
Density and/or relative density

Density 1,07 g/cm³ at 20 °C
Relative vapour density 3,2 (air = 1)
Particle characteristics No data available.
Other safety parameters

Oxidising properties none
9.2 Other information

Information with regard to physical hazard hazard classes acc. to GHS

classes: (physical hazards): not relevant
Other safety characteristics: There is no additional information.
SECTION 10: Stability and reactivity

10.1 Reactivity
The product in the delivered form is not dust explosion capable; the enrichment of fine dust however
leads to the danger of dust explosion.
10.2 Chemical stability
Moisture-sensitive. Hygroscopic solid. May cause decomposition by long-term light influence.
10.3 Possibility of hazardous reactions
Exothermic reaction with: strong oxidiser, Hydrogen peroxide, Strong acid, Strong alkali, Aldehydes,
Danger of explosion: Nitrites, Nitro compound, Peroxides
10.4 Conditions to avoid
Humidity. UV-radiation/sunlight. Contact with air/oxygen. Keep away from heat.
10.5 Incompatible materials
aluminium, copper, different plastics
10.6 Hazardous decomposition products
Hazardous combustion products: see section 5.
SECTION 11: Toxicological information

11.1 Information on toxicological effects
Classification acc. to GHS
Acute toxicity
Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled.
Acute toxicity
Exposure route Endpoint Value Species Method Source
oral LD50 317 mg/kg rat TOXNET
dermal LD50 630 mg/kg rabbit TOXNET
Skin corrosion/irritation
Causes severe skin burns and eye damage.
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensitisation
Shall not be classified as a respiratory or skin sensitiser.
Germ cell mutagenicity
Suspected of causing genetic defects.
Carcinogenicity
Shall not be classified as carcinogenic.


Reproductive toxicity
Shall not be classified as a reproductive toxicant.
Specific target organ toxicity - single exposure
Shall not be classified as a specific target organ toxicant (single exposure).
Specific target organ toxicity - repeated exposure
May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard
Shall not be classified as presenting an aspiration hazard.
Symptoms related to the physical, chemical and toxicological characteristics

• If swallowed
If swallowed danger of perforation of the esophagus and the stomach (strong corrosive effects)
• If in eyes
causes burns, Causes serious eye damage, risk of blindness
• If inhaled
irritant effects, cough, Dyspnoea
• If on skin
causes severe burns, causes poorly healing wounds
• Other information
Other adverse effects: Headache, Vertigo, Dizziness, Unconsciousness, Circulatory collapse
11.2 Endocrine disrupting properties
Not listed.
11.3 Information on other hazards
There is no additional information.
SECTION 12: Ecological information

12.1 Toxicity
Toxic to aquatic life with long lasting effects.
.
Aquatic toxicity (acute)
Endpoint Value Species Source Exposure

time
LC50 8,9 mg/l fish ECHA 96 h
EC50 3,1 mg/l aquatic invertebrates ECHA 48 h
Aquatic toxicity (chronic)
Endpoint Value Species Source Exposure

time
LC50 21,93 mg/l fish ECHA 14 d
EC50 10 mg/l aquatic invertebrates ECHA 16 d


Biodegradation
The substance is readily biodegradable.
12.2 Process of degradability
Theoretical Oxygen Demand: 2,38 mg/mg
Theoretical Carbon Dioxide: 2,806 mg/mg
Biochemical Oxygen Demand: 1,68 g/g at 5 h
Process of degradability
Process Degradation rate Time
biotic/abiotic 85 % 14 d
carbon dioxide generation 45,5 % 3d
oxygen depletion 96 % 20 d
12.3 Bioaccumulative potential

Does not significantly accumulate in organisms.
n-octanol/water (log KOW) 1,47 (30 °C) (ECHA)
BCF 17,5 (ECHA)
12.4 Mobility in soil
Henry's law constant 0,022 Pa m³/mol at 20 °C (ECHA)
The Organic Carbon normalised adsorption >1,147 – <1,864 (ECHA)

coefficient
12.5 Results of PBT and vPvB assessment

Data are not available.
12.6 Endocrine disrupting properties
Not listed.
12.7 Other adverse effects
Data are not available.
SECTION 13: Disposal considerations

13.1 Waste treatment methods
This material and its container must be disposed of as hazardous waste. Dispose of contents/contain-
er in accordance with local/regional/national/international regulations.
Sewage disposal-relevant information
Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data
sheets.
Waste treatment of containers/packagings
It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used.


13.2 Relevant provisions relating to waste
The allocation of waste identity numbers/waste descriptions must be carried out according to the
EEC, specific to the industry and process. Waste catalogue ordinance (Germany).
13.3 Remarks
Waste shall be separated into the categories that can be handled separately by the local or national
waste management facilities. Please consider the relevant national or regional provisions.
SECTION 14: Transport information

14.1 UN number or ID number
ADRRID UN 1671
IMDG-Code UN 1671
ICAO-TI UN 1671
14.2 UN proper shipping name
ADRRID PHENOL, SOLID
IMDG-Code PHENOL, SOLID
ICAO-TI Phenol, solid
14.3 Transport hazard class(es)
ADRRID 6.1
IMDG-Code 6.1
ICAO-TI 6.1
14.4 Packing group
ADRRID II
IMDG-Code II
ICAO-TI II
14.5 Environmental hazards hazardous to the aquatic environment
14.6 Special precautions for user
Provisions for dangerous goods (ADR) should be complied within the premises.
14.7 Maritime transport in bulk according to IMO instruments
The cargo is not intended to be carried in bulk.
14.8 Information for each of the UN Model Regulations

Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN) - Additional
information
Proper shipping name PHENOL, SOLID
Particulars in the transport document UN1671, PHENOL, SOLID, 6.1, II, (D/E), environ-
mentally hazardous
Classification code T2
Danger label(s) 6.1, "Fish and tree"


Environmental hazards yes (hazardous to the aquatic environment)
Special provisions (SP) 279, 802(ADN)
Excepted quantities (EQ) E4
Limited quantities (LQ) 500 g
Transport category (TC) 2
Tunnel restriction code (TRC) D/E
Hazard identification No 60
Emergency Action Code 2X
Regulations concerning the International Carriage of Dangerous Goods by Rail (RID)Additional
information
Classification code T2
Danger label(s) 6.1
Fish and tree
Environmental hazards Yes

Hazardous to water
Special provisions (SP) 279, 802(ADN)
Transport category (TC) 2
Hazard identification No 60
International Maritime Dangerous Goods Code (IMDG) - Additional information
Proper shipping name PHENOL, SOLID
Particulars in the shipper's declaration UN1671, PHENOL, SOLID, 6.1, II, MARINE POL-
LUTANT
Marine pollutant yes (hazardous to the aquatic environment)
Danger label(s) 6.1, "Fish and tree"
Special provisions (SP) 279

EmS F-A, S-A
Stowage category A


International Civil Aviation Organization (ICAO-IATA/DGR) - Additional information
Proper shipping name Phenol, solid
Particulars in the shipper's declaration UN1671, Phenol, solid, 6.1, II
Environmental hazards yes (hazardous to the aquatic environment)
Danger label(s) 6.1
Special provisions (SP) A113

Limited quantities (LQ) 1 kg
SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Relevant provisions of the European Union (EU)
Seveso Directive
2012/18/EU (Seveso III)
No Dangerous substance/hazard categories Qualifying quantity (tonnes) for the ap- Notes
plication of lower and upper-tier re-
quirements
H2 acute toxic (cat. 2 + cat. 3, inhal.) 50 200 41)
Notation
41) - Category 2, all exposure routes
- category 3, inhalation exposure route
Deco-Paint Directive
VOC content 100 %

1.070 g/l
Industrial Emissions Directive (IED)
VOC content 100 %
VOC content 1.070 g/l
Directive on the restriction of the use of certain hazardous substances in electrical and
electronic equipment (RoHS)
not listed
Regulation concerning the establishment of a European Pollutant Release and Transfer
Register (PRTR)
not listed


Water Framework Directive (WFD)
List of pollutants (WFD)
Name of substance Name acc. to inventory CAS No Listed in Remarks
Phenol Substances and preparations, or a)

the breakdown products of such,
which have been proved to pos-
sess carcinogenic or mutagenic
properties or properties which
may affect steroidogenic, thyroid,
reproduction or other endocrine-
related functions in or via the
aquatic environment
Legend
A) Indicative list of the main pollutants
Regulation on the marketing and use of explosives precursors

not listed
Regulation on drug precursors
not listed
Regulation on substances that deplete the ozone layer (ODS)
not listed
Regulation concerning the export and import of hazardous chemicals (PIC)
not listed
Regulation on persistent organic pollutants (POP)
not listed
National regulations(GB)
List of substances subject to authorisation (GB REACH, Annex 14) / SVHC - candidate list
not listed
Restrictions according to GB REACH, Annex 17
not listed
Other information
Directive 94/33/EC on the protection of young people at work. Observe employment restrictions un-
der the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
National inventories
Country Inventory Status
AU AIIC substance is listed
CA DSL substance is listed
CN IECSC substance is listed
EU ECSI substance is listed
EU REACH Reg. substance is listed
JP CSCL-ENCS substance is listed
JP ISHA-ENCS substance is listed
KR KECI substance is listed

Country Inventory Status
MX INSQ substance is listed
NZ NZIoC substance is listed
PH PICCS substance is listed
TR CICR substance is listed
TW TCSI substance is listed
US TSCA substance is listed
Legend
AIIC Australian Inventory of Industrial Chemicals
CICR Chemical Inventory and Control Regulation
CSCL-ENCS List of Existing and New Chemical Substances (CSCL-ENCS)
DSL Domestic Substances List (DSL)
ECSI EC Substance Inventory (EINECS, ELINCS, NLP)
IECSC Inventory of Existing Chemical Substances Produced or Imported in China
INSQ National Inventory of Chemical Substances
ISHA-ENCS Inventory of Existing and New Chemical Substances (ISHA-ENCS)
KECI Korea Existing Chemicals Inventory
NZIoC New Zealand Inventory of Chemicals
PICCS Philippine Inventory of Chemicals and Chemical Substances (PICCS)
REACH Reg. REACH registered substances
TCSI Taiwan Chemical Substance Inventory
TSCA Toxic Substance Control Act
15.2 Chemical Safety Assessment

No Chemical Safety Assessment has been carried out for this substance.
SECTION 16: Other information

Indication of changes (revised safety data sheet)
Alignment to regulation:
Restructuring: section 9, section 14
Section Former entry (text/value) Actual entry (text/value) Safety-
relev-
ant
2.1 Classification acc. to GHS: yes

change in the listing (table)
2.1 The most important adverse physicochemical, yes

human health and environmental effects:
Skin corrosion produces an irreversible dam-
age to the skin; namely, visible necrosis through
the epidermis and into the dermis. Delayed or
immediate effects can be expected after short
or long-term exposure. Spillage and fire water
can cause pollution of watercourses.
2.2 Precautionary statements - prevention: yes

2.2 Labelling of packages where the contents do yes

not exceed 125 ml:
Signal word: Danger

not exceed 125 ml:

not exceed 125 ml:

Section Former entry (text/value) Actual entry (text/value) Safety-

relev-
ant

not exceed 125 ml:
2.3 Other hazards: Other hazards: yes

There is no additional information. This material is combustible, but will not ignite
readily.
2.3 Results of PBT and vPvB assessment: yes

According to the results of its assessment, this
substance is not a PBT or a vPvB.
Abbreviations and acronyms

Abbr. Descriptions of used abbreviations
2009/161/EU Commission Directive establishing a third list of indicative occupational exposure limit values in imple-
mentation of Council Directive 98/24/EC and amending Commission Directive 2000/39/EC
ADN Accord européen relatif au transport international des marchandises dangereuses par voies de naviga-
tion intérieures (European Agreement concerning the International Carriage of Dangerous Goods by In-
land Waterways)
ADR Accord relatif au transport international des marchandises dangereuses par route (Agreement concern-
ing the International Carriage of Dangerous Goods by Road)
ATE Acute Toxicity Estimate
BCF Bioconcentration factor
CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)
Ceiling-C Ceiling value
DGR Dangerous Goods Regulations (see IATA/DGR)
DNEL Derived No-Effect Level
EC50 Effective Concentration 50 %. The EC50 corresponds to the concentration of a tested substance causing
50 % changes in response (e.g. on growth) during a specified time interval
EC No The EC Inventory (EINECS, ELINCS and the NLP-list) is the source for the seven-digit EC number, an identi-
fier of substances commercially available within the EU (European Union)
EH40/2005 EH40/2005 Workplace exposure limits (http://www.nationalarchives.gov.uk/doc/open-government-li-

cence/)
EINECS European Inventory of Existing Commercial Chemical Substances
ELINCS European List of Notified Chemical Substances
EmS Emergency Schedule
GB REACH The REACH etc. (Amendment etc.) (EU Exit) Regulations 2019, SI 2019/758 (as amended)
GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Na-
tions
IATA International Air Transport Association
IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)
ICAO International Civil Aviation Organization
ICAO-TI Technical instructions for the safe transport of dangerous goods by air
IMDG International Maritime Dangerous Goods Code

Abbr. Descriptions of used abbreviations
IMDG-Code International Maritime Dangerous Goods Code
IOELV Indicative occupational exposure limit value
LC50 Lethal Concentration 50%: the LC50 corresponds to the concentration of a tested substance causing 50 %
lethality during a specified time interval
LD50 Lethal Dose 50 %: the LD50 corresponds to the dose of a tested substance causing 50 % lethality during a
specified time interval
LEL Lower explosion limit (LEL)
NLP No-Longer Polymer
PBT Persistent, Bioaccumulative and Toxic
PNEC Predicted No-Effect Concentration
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals
RID Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regula-
tions concerning the International carriage of Dangerous goods by Rail)
STEL Short-term exposure limit
TWA Time-weighted average
UEL Upper explosion limit (UEL)
VOC Volatile Organic Compounds
vPvB Very Persistent and very Bioaccumulative
WEL Workplace exposure limit
Key literature references and sources for data

Agreement concerning the International Carriage of Dangerous Goods by Road (ADR). Regulations
concerning the International Carriage of Dangerous Goods by Rail (RID). International Maritime Dan-
gerous Goods Code (IMDG). Dangerous Goods Regulations (DGR) for the air transport (IATA).
List of relevant phrases (code and full text as stated in section 2 and 3)
Code Text
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H331 Toxic if inhaled.
H341 Suspected of causing genetic defects.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
Disclaimer
This information is based upon the present state of our knowledge. This SDS has been compiled and
is solely intended for this product.

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Safety data sheet Safety data sheet

acc. to Regulation (EC) No. 1907/2006 (REACH)

Phenol ≥99 %, Ph.Eur., crystalline

article number: 3215 date of compilation: 2015-08-11

SECTION 1: Identification of the substance/mixture and of the company/

Telephone:+49 (0) 721 - 56 06 0

National Poisons Information Dudley Rd B187QH 844 892 0111

SECTION 2: Hazards identification

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Phenol ≥99 %, Ph.Eur., crystalline

article number: 3215

Section Hazard class Cat- Hazard class and Hazard

3.1O Acute toxicity (oral) 3 Acute Tox. 3 H301

3.1D Acute toxicity (dermal) 3 Acute Tox. 3 H311

3.1I Acute toxicity (inhal.) 3 Acute Tox. 3 H331

3.2 Skin corrosion/irritation 1B Skin Corr. 1B H314

3.3 Serious eye damage/eye irritation 1 Eye Dam. 1 H318

3.5 Germ cell mutagenicity 2 Muta. 2 H341

3.9 Specific target organ toxicity - repeated exposure 2 STOT RE 2 H373

For full text of abbreviations: see SECTION 16

Signal word Danger

For professional users only

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Phenol ≥99 %, Ph.Eur., crystalline

article number: 3215

SECTION 3: Composition/information on ingredients

Substance, Specific Conc. Limits, M-factors, ATE

Specific Conc. Limits M-Factors ATE Exposure route

Skin Corr. 1B; H314: C ≥ 3 % - 100 mg/kg oral

SECTION 4: First aid measures

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Phenol ≥99 %, Ph.Eur., crystalline

article number: 3215

SECTION 5: Firefighting measures

Suitable extinguishing media

SECTION 6: Accidental release measures

For non-emergency personnel

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Phenol ≥99 %, Ph.Eur., crystalline

article number: 3215

SECTION 7: Handling and storage

Keep away from sources of ignition - No smoking.

Removal of dust deposits.

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Phenol ≥99 %, Ph.Eur., crystalline

article number: 3215

SECTION 8: Exposure controls/personal protection

EU phenol 108-95-2 IOELV 8 16 H 2009/161/

GB dust WEL 10 i EH40/2005

GB dust WEL 4 r EH40/2005

GB phenol 108-95-2 WEL 7,8 16 EH40/2005

Human health values

Relevant DNELs and other threshold levels

Endpoint Threshold Protection goal, Used in Exposure time

DNEL 8 mg/m³ human, inhalatory worker (industry) chronic - systemic effects

DNEL 16 mg/m³ human, inhalatory worker (industry) acute - local effects

Relevant PNECs and other threshold levels

End- Threshold Organism Environmental com- Exposure time

PNEC 0,008 mg/l aquatic organisms freshwater short-term (single instance)