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    Quiz 2 Che 171

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    John Lloyd Generoso
    quiz

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    Quiz 2 Che 171

    Uploaded by

    John Lloyd Generoso
    4 views2 pages
    quiz

    Original Title

    QUIZ 2 CHE 171

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    quiz

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    © All Rights Reserved
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    Download as docx, pdf, or txt
    4 views2 pages

    Quiz 2 Che 171

    Uploaded by

    John Lloyd Generoso
    quiz

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 2

    ( )( [ [ ]] )

    QUIZ 2 CHE 171 (Reaction Mechanism) k4 HBr


    If ≪ 1, show that the proposed
    k3 Br 2
    1. The gas-phase reaction of chlorine with
    chloroform is described by the equation: mechanism is consistent with the
    experimentally determined rate law.
    Cl2(g) + CHCl3(g)  HCl(g) + CCl4(g)

    The rate law determined from experiment has a QUIZ 2 CHE 171 (Reaction Mechanism)
    noninteger order:
    rate=k[Cl2]1/2[CHCl3] 4. The gas-phase reaction of chlorine with
    chloroform is described by the equation:
    A proposed mechanism for this reaction follows: Cl2(g) + CHCl3(g)  HCl(g) + CCl4(g)

    The rate law determined from experiment has a


    noninteger order:
    rate=k[Cl2]1/2[CHCl3]

    A proposed mechanism for this reaction follows:


    Is this an acceptable mechanism for this reaction?

    2. The compound NO2Cl is thought to


    decompose to NO2 and Cl2 by the following
    mechanism:

    Is this an acceptable mechanism for this reaction?

    5. The compound NO2Cl is thought to decompose to


    Derive the rate law for the production of Cl2 NO2 and Cl2 by the following mechanism:
    using the steady-state approximation.

    3. The kinetics of the reaction between H2 and Br2


    were determined experimentally by Bodenstein
    around 100 years ago. The overall reaction has Derive the rate law for the production of Cl2
    the equation
    using the steady-state approximation.
    d [ HBr] 1/ 2
    H2 + Br2 2HBr =k [H 2 ][Br 2 ] 6. The kinetics of the reaction between H2 and Br2
    dt
    The following mechanism has been proposed: were determined experimentally by Bodenstein
    Br2 2Br (k1 is forward and k5 is reverse around 100 years ago. The overall reaction has the
    rate constant) equation

    Br + H2 k 2 HBr+H d [ HBr] 1/ 2
    → H2 + Br2 2HBr =k [H 2 ][Br 2 ]
    dt
    H + Br2 k 3 HBr + Br
    → The following mechanism has been proposed:
    H + HBr k 4 H2 + Br Br2 2Br (k1 is forward and k5 is reverse
    → rate constant)
    Br + H2 k 2 HBr+H
    →

    H + Br2 k 3 HBr + Br
    →
    H + HBr k 4 H2 + Br
    →

    If ( )( [ [ ]] )
    k4
    k3
    HBr
    Br 2
    ≪ 1, show that the proposed

    mechanism is consistent with the


    experimentally determined rate law.

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