C25 CHEMISTRY Practice Sheet -Nomenclature

BAKLIWAL TUTORIALS
C25 CHEMISTRY PRACTICE SHEET

Nomenclature
SINGLE CORRECT TYPE
Q.1
(A) Methyl-3-oxo-2-ethanoyl ethanoate (B) Methyl-2, 2-diacetyl ethanoate

(C) Methyl-2-acetyl-3-oxo butanoate (D) Methyl-2-ethanoyl-3-oxo-butanoate
Q.2 Which is the correct structure of 3-cyclohexylmethyl butanamide?
(A) (B)
(C) (D)
Q.3 Write the IUPAC name of following.
(A) 2-methyl-1-(3'-hydroxy butyl)-6-heptenal

(B) 9-hydroxy-2-methyl-5-decene
(C) 6-(3'-hydroxy butyl)-2-methyl-6-heptenal
(D) None of these
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Q.4 An alkene X has molecular formula C6 H12 with a quaternary carbon atom. Which is the correct
IUPAC name possible for X?
(A) 2, 3-dimethyl-1-butene (B) 2, 3-dimethyl-2-butene
(C) 3, 3-dimethyl-1-butene (D) 3, 3-dimethyl-2-butene
Q.5 A halogenated compound X has molecular formula C3 H3 Cl3 and no cyclic structure. Also sum of the
positions of all three chlorine is 8. What is the correct IUPAC name of X?
(A) 2, 3, 3-trichloro-2-propene (B) 2, 3, 3-trichloro-1-propene
(C) 2, 2, 4-trichloro-2-propene (D) 2, 2, 4-trichloro-1-propene
Q.6 What is the correct IUPAC name of the Compound?
(A) 3-cyano-2, 5-dimethyl heptanedinitrile (B) 5-cyano-3, 6-dimethyl heptanedinitrile

(C) 2, 5-dimethyl-1, 3, 7-heptanedinitrile (D) 2-methyl hexane-1, 4, 5 tricarbonitrile
Q.7 The IUPAC name of the structure is
(A) 3-t-butyl-4-ethyl-5-isopropyl-2-methyl-3-heptene
(B) 4, 5-diethyl-2, 2, 6-trimethyl-3-(1-methylethyl)-3-heptene
(C) 3-(1, 1-dimethyl ethyl)-4, 5-diethyl-2, 6-dimethyl-3-heptene
(D) 4-ethyl-2, 2-dimethyl-3, 5-bis (1-methylethyl)-3-heptene
Q.8 IUPAC name of the following compound is :
(A) 1-hydroxy spiro [3,4] oct-2-ene-6-carboxylic acid

(B) 6-carboxy spiro [3,4] oct-2-ene-1-ol
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(C) 3-hydroxy spiro [3,4] oct-1-ene-6-carboxylic acid
(D) 2-carboxy spiro [3,4] oct-7-ene-6-ol
Q.9 The correct IUPAC name of the following compound is
(A) 3-ethtyl-3-isopropyl-4-tertiarybutyl hexane

(B) 3, 3, 4-triethyl-2, 5, 5-trimethyl hexane
(C) 3,4-diethyl-4-isopropyl-2, 2-dimethyl hexane
(D) 3, 4, 4triethyl-2, 2, 5-trimethyl hexane
Q.10 What is the correct IUPAC name of the compound shown below?
(A) 4-butyl-6-chloro-3, 5, 6-trimethyl-1-heptyne

(B) 4-butyl-6-chloro-3, 5, 6, 6-tetramethyl-1-heptyne
(C) 4-butyl-2-chloro-2, 3, 5-trimethyl-6-heptyne
(D) 4-(2-chloro-1, 2-dimethylpropyl)-3methyl-1-octyne
Q.11 Which one of the following structures has the IUPAC name 3-ethynl-2-hydroxy-4-methylhex-3-en-
5-ynoic acid?
(A) (B)
(C) (D)
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Q.12 The correct IUPAC name of the following compound
is :
(A) 3, 3-Diformyl propanoic acid (B) 3-Formyl-4-oxo-butanoic acid
(C) 3, 3-Dioxo propanoic acid (D) 3, 3-Dicarbaldehyde propanoic acid
Q.13 Which of the following is correct structure of 3, 3-dibromo-2-chlorobutyl 2-methyl propanoate?
(A) (B)
(C) (D)
Q.14 What is the correct IUPAC name of the compound shown below?
(A) 3, 6-dihydroxy-4-octanamide
(B) 3, 6-dihydroxy-5-octanenamide
(C) 4-hydroxy-2-(1-hydroxy propyl) hexanamide
(D) 3-hydroxy-2-(2-hydroxy butyl) pentanamide
Q.15 What is IUPAC name of the compound given below?
(A) 2-bromo-3, 3-dichloro-1, 5-cyclohexanediol

(B) 4-bromo-6, 6-dichloro-1, 3-cyclohexanediol
(C) 1-bromo-3, 3-dichloro-4, 6-dihydroxy cyclohexane
(D) 6-bromo-4, 4-dichloro-1, 3-cyclohexanediol
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Q.16 What is the correct IUPAC name of the following compound?
(A) 4-chloro-N-ethyl-1-methyl-1-pentanamine
(B) 5-chloro-N-ethyl-2-hexanamine
(C) 5-chloro-1-ethyl-1-hexanamine
(D) 2-chloro-N-ethyl-5-hexanamine
Q.17 The IUPAC name of the following compound is
(A) 4-bromo - 3 - chlroformyl benzalaldhyde

(B) 2 - bromo - 5 - formyl benzene carbochloride
(C) 2-chloro carbonyl bromobenzene
(D) 6-bromo - 3 - formylbenzo - 3 - yl chloride
Q.18 Correct IUPAC name of the given compound is
(A) 2-bromo-3-ethyl-4-chlorocyclobutanol
(B) 4-bromo-1-chloro-3-ethylcyclobutanol
(C) 3-bromo-4-chloro-3-ethyl cyclohydroxybutane
(D) 2-bromo-4-chloro-3-ethylcyclobutanol
Q.19 What is the systematic IUPAC name of the following compound?
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(A) 8-methyl bicyclo [3,2,1] oct-3-ene (B) 8 -methyl bicyclo [3,2,1] oct-2-ene
(C) 6-methyl bicyclo [3,2,1] oct-2-ene (D) 6-methyl bicyclo [1,2,3] oct-2-ene
Q.20 What is correct IUPAC name of the compound shown below?
(A) 5, 6-dibromo-6-chloro-1, 3-cyclohexadiene

(B) 2, 3-dibromo-2-chloro-1, 4-cyclohexadiene
(C) 1, 2-dibromo-1-chloro-3, 5-cyclohexadiene
(D) 5, 6-dibromo-5-chloro-1, 3-cyclohexadiene
Q.21 The IUPAC name for the following compound is
(A) 3, 5-dimethyl-4-propylhept-6-en-1-yne
(B) 3-methyl-4-(3-methylprop-1-enyl)-1-heptyne
(C) 3-methyl-4-(1-methylprop-2-enyl)-1-heptene
(D) 3, 5-dimethyl-4-propylhept-1-en-6-yne
Q.22 According to IUPAC, what is the systematic name of the compound shown below?
(A) 2, 5, 6-triethyl-1, 3, 4-trimethyl cyclohexane

(B) 1, 2, 4-triethyl-3, 5, 6-trimethyl cyclohexane
(C) 1, 3, 4-triethyl-2, 5, 6-trimethyl cyclohexane
(D) 1, 2, 5-triethyl-3, 4, 6-trimethyl cyclohexane
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Q.23 Which of the following is an incorrect name according to IUPAC?
(A) 2-cyclopropyl butane (B) 1-bromo-2, 2-dichloro cyclobutane
(C) Cyclohexyl cyclohexane (D) 1-cyclobutyl cyclobutane
Q.24 A hydrocarbon X has molecular formula C10 H14. Also X has one cycloalkyl group and some double
bonds but not triple bond. How many double bonds are present in X?
(A) 2 (B) 3 (C) 4 (D) 5
Q.25 What is the IUPAC name of the following compound?
(A) 2-cyano-2-methyl hex-4-yne-ol

(B) 2-hydroxy methyl-2-methyl-hex-4-yne-nitrile
(C) 2-methyl-2-hydroxy methyl hex-5-yne-nitrile
(D) 1-cyano-2-hydroxymethyl-2-methyl-4-hexyne
Q.26 Which is the correct structure of 4-ethyl-3-methylcyclohexene?
(A) (B)
(C) (D)
Q.27 According to IUPAC system, the compound is named as

(A) 1–Hydroxyhex-2-ene (B) Cyclohex -1-en -2-ol
(C) Cyclohex-1-en -3-ol (D) Cyclohex -2-en -1-ol
Q.28 IUPAC name of following compound is :
(A) 2-Aminopentanenitrile (B) 2-Aminobutanenitrile

(C) 3-Aminopropanenitrile (D) 3-Aminobutanenitrile
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Q.29 Identify structure of 2, 3-dibromo-1-phenylpentane.
(A) (B)
(C) (D)
Q.30 What is the IUPAC name of following compound?
(A) 1-Methoxy-2, 2-dimethyclobutane (B) 1-Methoxy-4, 4-dimethyclobutane

(C) 2-Methoxy-1, 1-dimethyclobutane (D) 2, 2-dimethylcyclobutoxymethane
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BAKLIWAL TUTORIALS
SOLUTIONS
Q.1 (D)
Q.2 (D)
Open chain contain functional group so that it must be parent chain
Ring works as side chain

Q.3 (C)
Parent chain must be preferred for numbering Fn.

group (−CH = O) > multiple bond (=) > side chain (−OH)
Q.4 (C)
Q.5 (B)
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Q.6 (D)
Q.7 (D)
Parent chain must contain maximum number of side chain including double bond
Q.8 (C)
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Q.9 (D)
Parent chain must be contain maxi no of side chain.

Q.10 (D)
Parent chain must be contain following in given priority
Principle fi gr. > multiple bond > maxi no of C
Q.11 (D)
3-ethynyl, 2-hydroxyl, 4-methyl hex-3-en-5-ynoic acid

Q.12 (B)
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Q.13 (B)
Q.14 (C)
Q.15 (D)
Q.16 (B)
Q.17 (B)
Q.18 (D)
−Principle Fn. gr =→ OH
− Side chain → Bromo Chloro ethyl
− Albhabet rule Applies
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Q.19 (B)
Q.20 (D)
Q.21 (D)
3, 5-dimethyl-4-propylhept-6-en-1-yne
Longest carbon chain, including multiple bonds, and numbering starts from double bond.
Q.22 (B)
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Q.23 (B)
In "1-bromo-2, 2-dichloro cyclobutane" parent chain is wrongly numbered, correct numbering is
So, correct name is 2-bromo-1, 1-dichloro cyclobutane according to least locant number rule.
Q.24 (B)
14
−DU = (10 + 1) − =4
2
− DU for ring = 1
− No triple bond present
− Rest DU = 3, for double bond
Q.25 (B)
Q.26 (C)
Q.27 (D)
Q.28 (D)
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Q.29 (B)
Q.30 (C)
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C25 CHEMISTRY PRACTICE SHEET

(A) Methyl-3-oxo-2-ethanoyl ethanoate (B) Methyl-2, 2-diacetyl ethanoate

(A) 2-methyl-1-(3'-hydroxy butyl)-6-heptenal

(A) 3-cyano-2, 5-dimethyl heptanedinitrile (B) 5-cyano-3, 6-dimethyl heptanedinitrile

(A) 1-hydroxy spiro [3,4] oct-2-ene-6-carboxylic acid

(A) 3-ethtyl-3-isopropyl-4-tertiarybutyl hexane

(A) 4-butyl-6-chloro-3, 5, 6-trimethyl-1-heptyne

(A) 2-bromo-3, 3-dichloro-1, 5-cyclohexanediol

(A) 4-bromo - 3 - chlroformyl benzalaldhyde

(A) 5, 6-dibromo-6-chloro-1, 3-cyclohexadiene

(A) 2, 5, 6-triethyl-1, 3, 4-trimethyl cyclohexane

(A) 2-cyano-2-methyl hex-4-yne-ol

Q.27 According to IUPAC system, the compound is named as

(A) 2-Aminopentanenitrile (B) 2-Aminobutanenitrile

(A) 1-Methoxy-2, 2-dimethyclobutane (B) 1-Methoxy-4, 4-dimethyclobutane

Ring works as side chain

Parent chain must be preferred for numbering Fn.

Parent chain must be contain maxi no of side chain.

3-ethynyl, 2-hydroxyl, 4-methyl hex-3-en-5-ynoic acid

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