TARGET : PRE-MEDICAL 2021

ENTHISIAST COURSE
(RACE # 01)
TOPIC NAME : SOLUTION CHEMISTRY
1. One among the following is an incorrect 8. The density (in g mL–1 ) of a 3.60 M sulphuric
statement- acid solution that is 29% H2 SO4 (Molar mass
(1) Molality of a solution is dependent on the = 98 g mol–1 ) by mass will be -
temperature (1) 1.64 (2) 1.88
(2) Molarity of a solution is dependent on the (3) 1.22 (4) 1.45
temperature 9. A sugar syrup of weight 214.2 grams contains
(3) Normality of 0.5 M aqueous solution of 34.2 grams of sugar. The molal concentration is-
H2C2 O4 .2H2 O is 1 N (1) 0.55 (2) 5.5 (3) 55 (4) 0.1
(4) Molality of a solution relates moles of solute 10. The normality of 0.3 M phosphorous acid
and mass of solvent (H3PO3) is -
2. 1000 g aqueous solution of CaCO3 contains 10 (1) 0.1 (2) 0.9 (3) 0.3 (4) 0.6
g of calcium carbonate. Concentration of 11. 10 gram of glucose are dissolved in 150 gram
solution is- of water. The mass % of glucose is-
(1) 10 ppm (2) 100 ppm (1) 5% (2) 6.25% (3) 93.75% (4) 15%
(3) 1000 ppm (4) 10000 ppm 12. If 18 gram of glucose (C 6H12 O6 ) is present in
3. Which of the following concentration factor is 1000 gram of an aqueous solution of glucose
affected by change in temperature ? it is said to be-
(1) Molarity (2) Molality (1) 39.2 molal (2) 1.1 molal
(3) Mol fraction (4) Weight fraction (3) 0.5 molal (4) 0.1 molal
13. What is the molarity of H2SO4 solution that has
4. 25 ml of a solution of barium hydroxide
a density of 1.84 gm/cc at 350°C and contains
required 35 ml on titration with a 0.1 molar
98% by weight-
solution of hydrochloric acid. Molarity of
(1) 4.18 M (2) 8.14 M
barium hydroxide solution was -
(3) 18.4 M (4) 18 M
(1) 0.28 (2) 0.35 (3) 0.07 (4) 0.14
14. In order to prepare 100 cm3 of 0.250 M barium
5. To neutralise completely 20 mL of 0.1 M
chloride solution the amount of BaCl 2 .2H 2 O
aqueous solution of phosphorous acid
required will be- (Atomic wt. of Ba = 137 )
(H3PO 3), the volume of 0.1 M aqueous KOH
(1) 0.250 moles
solution required is -
(2) 0.0025 moles
(1) 10 mL (2) 20 mL
(3) 2.5 moles
(3) 40 mL (4) 60 mL
(4) 6.1 gram of BaCl2.2H2 O
6. Two solutions of a substance (non electrolyte)
15. 25 mL of 3 M HCl were added to 75 mL of 0.05
are mixed in the following manner. 480 ml of
M HCl. The molarity of HCl in the resulting
1.5 M first solution + 520 mL of 1.2 M second
solution is approximately -
solution. What is the molarity of the final
(1) 0.055 M (2) 0.35 M
mixture ? (3) 0.787 M (4) 3.05 M
(1) 1.50 M (2) 1.20 M 16. 0.2 mole of HCl and 0.1 mole of CaCl2 were
(3) 2.70 M (4) 1.344 M dissolved in water to have 500 ml of solution,
7. Density of a 2.05 M solution of acetic acid in the molarity of Cl¯ ions is-
water is 1.02 g/mL. The molality of the solution (1) 0.04 M (2) 0.8 M (3) 0.4 M (4) 0.08 M
is - 17. The molarity of a glucose solution containing
(1) 3.28 mol kg–1 (2) 2.28 mol kg–1 36 g of glucose per 400 mL of the solution is-
(3) 0.44 mol kg–1 (4) 1.14 mol kg–1 (1) 1.0 (2) 0.5 (3) 2.0 (4) 0.05

E Your Hard Work Leads to Strong Foundation 5

 TARGET : PRE-MEDICAL 2021 ENTHUSIAST COURSE
18. Which of the following is correct 25. In the aqueous solution of sulphuric acid the
wt. mole fraction of water is 0.85. The molality of
(1) mole = molarity × V(L) =
mol.wt. the solution is-
wt. (1) 8.9 m (2) 0.19 m
(2) milli mole = molarity × V(mL) = × 1000
mol.wt. (3) 9.8 m (4) 15 m
(3) Moles and millimoles of reactants react 26. 1000 gram aqueous solution of CaCO3 contains
according to stoichiometric ratio of 10 gram of carbonate. Concentration of
balanced chemical equation solution is-
(4) All (1) 10 ppm (2) 100 ppm
19. 5.85 g of NaCl are dissolved in 90 g of water. (3) 1000 ppm (4) 10,000 ppm
The mole fraction of NaCl is- 27. Equal volumes of 0.1 M AgNO 3 and 0.2 M
(1) 0.1 (2) 0.01 NaCl are mixed. The concentration of NO3– ions
(3) 0.2 (4) 0.0196 in the mixture will be-
20. The molality of 15% (wt./vol.) solution of (1) 0.1 M (2) 0.05 M
H2 SO4 of density 1.1 g/cm3 is approximately- (3) 0.2 M (4) 0.15 M
(1) 1.2 (2) 1.4 (3) 1.8 (4) 1.6 28. H2O 2 solution used for hair bleaching is sold
21. 10 mL of concentrated H2SO4 (18M) is diluted as a solution of approximately 5.0 g H2 O2 per
to one litre. The approximate strength of the 100 mL of the solution. The molecular weight
dilute acid is- of H2O2 is 34. The molarity of this solution is
(1) 18 M (2) 180 M approximately-
(3) 0.18 M (4) 1.8 M (1) 3.0 (2) 1.47 (3) 0.15 (4) 4.0
22. 2.3 g of C2 H5OH (mol. wt. 46) are dissolved 29. All of the water in a 0.20 M solution of NaCl
in 500 mL of water. The molarity of the was evaporated and 0.150 mol of NaCl was
solution is- obtained. What was the original volume of the
(1) 0.01 (2) 0.1 sample ?
(3) 0.05 (4) 2.0 (1) 30 mL (2) 333 mL
23. A solution contains one mole of alcohol and (3) 750 mL (4) 1000 mL
four moles of water. What are the mole fractions 30. 25 mL of 3.0 M HNO3 are mixed with 75 mL
of water and alcohol- of 4.0M HNO3. If the volumes are additive, the
(1) 1/4, 4/1 (2) 4/1, 1/4 molarity of the final mixture would be-
(3) 4/5, 1/5 (4) 1/5, 4/5 (1) 3.25 M (2) 4.0 M
24. The mole fraction of NaCl in a solution (3) 3.75 M (4) 3.50 M
containing 1 mole of NaCl in 1000 g of 31. The mole fraction of water in 20% (w/W)
water is- aqueous solution of H 2O2 is
(1) 0.0177 (2) 0.001
(3) 0.5 (4) 0.244 77 68 20 80
(1) (2) (3) (4)
68 77 80 20

ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans 1 4 1 3 3 4 2 3 1 4 2 4 3 4 3
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans 2 2 4 4 4 3 2 3 1 3 4 2 2 3 3
Que. 31
Ans 2
6 Your Hard Work Leads to Strong Foundation E
 TARGET : PRE-MEDICAL 2021
ENTHISIAST COURSE
(RACE # 02)
TOPIC NAME : RAOULT'S LAW CHEMISTRY
1. Which are the affecting factors on the vapour 7. Vapour pressure of solution follows which
pressure ? law ?
(1) The nature of liquid (1) Henry’s (2) Charles
(2) Temperature (3) Boyle’s (4) Raoult’s
(3) (1) and (2) both 8. When gaseous solute dissolve in liquid solvent,
(4) None of these its vapour pressure is given by which
2. The vapour pressure of solvent of liquid formula ?
solution is directly proportional to which of the (1) PA = P°A XA
following ? (2) PA = KH XA
(1) Mole fraction of solute (3) PA = P°A / XA
(2) Molality of solvent
(4) PA = KH / XA
(3) Mole fraction of solvent
9. What is the total pressure of a mixture prepared
(4) Mole fraction of solution
by mixing 2 mole methanol and 4 mole
3. Raoult’s law is not applicable to which ethanol ? (V.P of methonal = 42 mm, V.P of
solution ?
ethanol = 88 mm)
(1) Very dilute solution
(1) 7.266 mm (2) 72.66 mm
(2) Ideal solution
(3) 40.66 mm (4) 27.66 mm
(3) Solution with volatile solute
10. What will be the vapour pressure of 4% W/W
(4) Solution with non-volatile solute
aqueous solution of urea at 298K temperature?
4. The vapour pressure of solution is ..... than that
(P 0H O = 0.025 bar at 298 K)
of pure solvent. 2
(1) 0.02469 bar
(1) less (2) more
(3) equal (4) None of these (2) 0.2469 bar
5. The correct formula for Raoult’s law is... (3) 24.69 bar
n = Mole fraction of solute (4) 246.9 bar
N = Mole fraction of solvent 11. The vapour pressure of solution of 2 gram
unknown substance in 90 gram water is
p - p° n p°- p n
(1) = (2) = changed from 27.5 mm to 27.1 mm. What will
p° n+N p° n+N
be the molar mass of the substance ?
p°- p n
(3) = (4) None of these (1) 27.1 g/mole (2) 25.7 g/mole
p n+N
(3) 26.5 g/mole (4) 28.5 g/mole
6. According to Raoult’s law, for which system of
solution, the vapour pressure of both i.e. solute 12. The mole fraction of solute in solution at room
and solvent will be proportional to their mole temperature is 0.25; and vapour pressure of
fraction ?
solvent is 0.80 atmosphere. What will be the
(1) Both are volatile.
decrease in the vapour pressure ?
(2) Solute is volatile, solvent is non volatile.
(3) Both are nonvolatile. (1) 0.75 (2) 0.60
(4) Solute is nonvolatile, solvent is volatile.
(3) 0.20 (4) 0.80

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 TARGET : PRE-MEDICAL 2021 ENTHUSIAST COURSE
13. The vapour pressure of the two liquids A and 18. Which is correct about Henry’s law
B are 120 mm and 180 mm respectively. If (1) The gas in contact with the liquid should
solution prepared by mixing 2 mole of liquid behave as an ideal gas
A and 3 mole of liquid B, then what will be the (2) There should not be any chemical
V.P of this solution. interaction between the gas and liquid
(3) The pressure applied should be high
(1) 156 (2) 143 (3) 150 (4) 108
(4) All of these
14. What will be the vapour pressure of solution 19. A solution has a 1 : 4 mole ratio of pentane to
prepared by dissolving 18 gram Glucose to hexane. The vapour pressure of the pure
178.2 gram water at 373K ? hydrocarbons at 20°C are 440 mmHg for
(1) 759.00 mm (2) 7.60 mm pentane and 120 mmHg for hexane. The mole
fraction of pentane in the vapour phase would
(3) 76.00 mm (4) 752.40 mm be
15. The partial pressure ratio PA° : PB° for the two (1) 0.549 (2) 0.200 (3) 0.786 (4) 0.478
volatile liquid A and B are PA° : PB° = 1 : 2 and 20. For a dilute solution, Raoult's law states that
mole ratio is XA : XB = 1 : 2. What is the mole (1) The lowering of vapour pressure is equal
fraction of A in vapour phase ? to mole fraction of solute
(2) The relative lowering of vapour pressure is
(1) 0.33 (2) 0.25
equal to mole fraction of solute
(3) 0.20 (4) 0.52 (3) The relative lowering of vapour pressure is
16. An azeoptropic solution of two liquids has proportional to the amount of solute in solution
boing point lower than either when it : (4) The vapour pressure of the solution is equal
to the mole fraction of solvent
(1) Shows negative deviation from Raoult’s law
21. Formation of a solution from two components
(2) Shows a positive deviation from Raoult’s can be considered as
law (i) Pure solvent ® separated solvent molecules DH1
(3) Shows no deviation from raoult’s law (ii) Pure solute ® separated solute molecules DH2
(iii)Separated solvent and solute molecules ®
(4) Is saturated
solution DH 3
17. At 353 K, the vapour pressure of pure liquid Solution so formed will be ideal if
A and B are 520 mm and 1000 mm (1) DH soln =DH 3 - DH1 - DH 2
respectively. If a mixture of solutions of A and
(2) DH soln = DH1 + DH 2 + DH 3
B boils at 353 K and 1 bar pressure, the mole
percent of A mixture is ...... (1 bar = 760mm) (3) DH soln =DH1 + DH 2 - DH 3

(1) 52% (2) 34% (3) 48% (4) 50% (4) DH soln =DH1 - DH 2 - DH 3

ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11
Ans 3 3 3 1 2 1 4 4 2 2 1
Que. 12 13 14 15 16 17 18 19 20 21
Ans 1 3 1 4 3 2 4 4 4 2
8 Your Hard Work Leads to Strong Foundation E
 TARGET : PRE-MEDICAL 2021
ENTHISIAST COURSE
(RACE # 03)
TOPIC NAME : COLLIGATIVE PROPERTIES CHEMISTRY
1. The molar heat of vapourisation of water is 6. Which of the following statements is correct
9700 Cal / mole and if the b.p. is 100 o C , for the boiling point of solvent containing a
ebullioscopic constant (Kb) of water is dissolved solid substance
(1) 0.513 k kg/mole (2) 1.026 k kg/mole (1) Boiling point of the liquid is depressed
(2) Boiling point of the liquid is elevated
(3) 10.26 k kg/mole (4) 1.832 k kg/mole
(3) There is no effect on the boiling point
2. The molal elevation constant of water = 0.52 o C .
(4) The change depends upon the polarity of
The boiling point of 1.0 molal aqueous KCl
liquid
solution (assuming complete dissociation of
7. When a substance is dissolved in a solvent,
KCl ), therefore, should be
the vapour pressure of solvent decreases. It
(1) 100 . 52 o C (2) 101. 04 o C brings
(3) 99.48 o C (4) 98.96 o C (1) A decrease in boiling point of solution
3. The rise in the boiling point of a solution (2) An increase in boiling point of the solution
containing 1.8 gram of glucose in 100 g of a (3) A decrease in freezing point of the solution
solvent in 0.1o C . The molal elevation constant (4) An increase in freezing point of the solution
(Kb) of the liquid is 8. Elevation in boiling point was 0.52 o C when
(1) 0.01 K / m 6 gm of a compound X was dissolved in 100 gm

(2) 0.1 K / m of water. Molecular weight of X is (K b for

(3) 1 K / m water is 0.52 per 1000 gm of water)
(1) 120 (2) 60
(4) 10 K / m
(3) 180 (4) 600
4. If 0.15 g of a solute dissolved in 15 g of solvent 9. When common salt is dissolved in water
is boiled at a temperature higher by 0.216 o C (1) Melting point of the solution increases
than that of the pure solvent. The molecular (2) Boiling point of the solution increases
weight of the substance (molal elevation (3) Boiling point of the solution decreases
constant for the solvent is 2.16 k kg/mole) is (4) Both melting point and boiling point
(1) 1.01 (2) 10 decreases
(3) 10.1 (4) 100 10. During the evaporation of liquid
5. Pressure cooker reduces cooking time for food (1) The temperature of the liquid will rise
because (2) The temperature of the liquid will fall
(1) Heat is more evenly distributed in the (3) May rise or fall depending on the nature
cooking space (4) The temperature remains unaffected
(2) Boiling point of water involved in cooking 11. At higher altitudes the boiling point of water
is increased lowers because
(3) The higher pressure inside the cooker (1) Atmospheric pressure is low
crushes the food material (2) Temperature is low
(4) Cooking involves chemical changes helped (3) Atmospheric pressure is high
by a rise in temperature (4) None of these

E Your Hard Work Leads to Strong Foundation 9

 TARGET : PRE-MEDICAL 2021 ENTHUSIAST COURSE
12. The elevation in boiling point for one molal 17. Which one of the following would produce
solution of a solute in a solvent is called maximum elevation in boiling point
(1) Boiling point constant (1) 0.1 M glucose
(2) Molal elevation constant (2) 0.2 M sucrose
(3) Cryoscopic constant
(3) 0.1 M barium chloride
(4) None of these
(4) 0.1 M magnesium sulphate
13. Which of the following aqueous molal solution
18. Which of the following aqueous solutions
have highest freezing point
containing 10 gm of solute in each case has
(1) Urea
highest B.P.
(2) Barium chloride
(1) NaCl solution (2) KCl solution
(3) Potassium bromide
(3) Sugar solution (4) Glucose solution
(4)Aluminium sulphate
19. How many grams of dibasic acid (mol. wt. 200)
14. Which will show maximum depression in
should be present in 100ml of its aqueous
freezing point when concentration is 0.1M
solution to give decinormal strength
(1) NaCl (2) Urea
(1) 1 g (2) 2g
(3) Glucose (4) K 2 SO4
(3) 10g (4) 20g
15. The freezing point of a 0.01M aqueous glucose
20. 10.6 grams of a substance of molecular weight
solution at 1 atmosphere is - 0. 18 o
C . To it, an
106 was dissolved in 100ml. 10ml of this
addition of equal volume of 0.002 M glucose
solution was pipetted out into a 1000ml flask
solution will; produce a solution with freezing
and made up to the mark with distilled water.
point of nearly (Assume molarity ; molality)
The molarity of the resulting solution is
(1) o
- 0.036 C (2) - 0.108 C o

(1) 1.0 M
(3) o
- 0.216 C (4) - 0.422 C o

(2) 10 -2 M
16. Which of the following will have the highest
boiling point at 1 atm pressure (3) 10 -3 M
(1) 0.1 M NaCl (2) 0.1M sucrose
(4) 10 -4 M
(3) 0.1M BaCl2 (4) 0.1M glucose

ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11
Ans 1 2 3 4 2 2 2 2 2 2 1
Que. 12 13 14 15 16 17 18 19 20
Ans 2 1 4 2 3 3 1 1 2

10 Your Hard Work Leads to Strong Foundation E

 TARGET : PRE-MEDICAL 2021
ENTHISIAST COURSE
(RACE # 04)
TOPIC NAME : SOLUTION CHEMISTRY
1. The vapour pressure of water at 20°C is 17.54 7. The freezing point of a solution prepared from
mm. When 20g of a non-ionic, substance is
1.25 gm of a non-electrolyte and 20 gm of water
dissolved in 100g of water, the vapour pressure
is lowered by 0.30 mm. What is the molecular is 271 .9 K . If molar depression constant is
weight of the substances 1.86 K mole -1 , then molar mass of the solute will
(1) 150.2 (2) 206.89 be
(3) 315.2 (4) 100.8 (1) 105.7 (2) 106.7 (3) 115.3 (4) 93.9
2. A 5% solution of canesugar (mol. wt. =342) is 8. When benzoic acid dissolve in benzene, the
isotonic with 1% solution of a substance X . The
observed molecular mass is
molecular weight of X is
(1) 244 (2) 61 (3) 366 (4) 122
(1) 34.2 (2) 171.2 (3) 68.4 (4) 136.8
3. If 20 g of a solute was dissolved in 500 ml of 9. The ratio of the value of any colligative
water and osmotic pressure of the solution was property for KCl solution to that for sugar
found to be 600 mm of Hg at 15o C, then solution is nearly
molecular weight of the solute is (1) 1 (2) 0.5 (3) 2.0 (4) 3
(1) 1000 (2) 1200 (3) 1322.8 (4) 1800
10. Van’t Hoff factor of Ca(NO3 ) 2 is
4. A solution of urea contain 8.6 gm/litre (mol. wt.
60.0). It is isotonic with a 5% solution of a non- (1) 1 (2) 2 (3) 3 (4) 4
volatile solute. The molecular weight of the
11. Acetic acid dissolved in benzene shows a
solute will be
molecular weight of
(1) 348.9 (2) 34.89
(1) 60 (2) 120 (3) 180 (4) 240
(3) 3489 (4) 861.2
12. On adding solute to a solvent having vapour
5. Elevation in boiling point was 0.52 o C when
pressure 0.80 atm, vapour pressure reduces to
6 gm of a compound X was dissolved in
0.60 atm. Mole fraction of solute is
100 gm of water. Molecular weight of X is
(K b for water is 0.52 k kg/mole) (1) 0.25 (2) 0.75 (3) 0.50 (4) 0.33

(1) 120 (2) 60 (3) 180 (4) 600 13. A solution containing 30 gms of non-volatile
solute in exactly 90 gm water has a vapour
6. When 10g of a non-volatile solute is dissolved
in 100 g of benzene, it raises boiling point by pressure of 20 mm Hg at 25 o C . Further 18 gms
1o C then molecular mass of the solute is (K b for of water is then added to the solution. The
benzene =2.53k-m ) –1
resulting solution has a vapour pressure of 21 mm Hg
(1) 223 g/mole at 25 o C . Calculate the molecular weight of the
(2) 233 g/mole solute
(3) 243 g/mole (1) 30 (2) 45
(4) 253 g/mole (3) 15 (4) 75
E Your Hard Work Leads to Strong Foundation 11
 TARGET : PRE-MEDICAL 2021 ENTHUSIAST COURSE
14. of a solute is dissolved in 0.1 litre of a
0.6 g 19. 6.02 ´ 1020 molecules of urea are present in 100
solvent which develops an osmotic pressure ml of its solution. The concentration of urea
solution is
of 1.23 atm at 27 o C . The molecular mass of
(1) 0.02 M (2) 0.01 M
the substance is
(3) 0.001 M (4) 0.1 M
(1) 149.5 g mole -1 (2) 120 g mole -1
20. Vapour pressure of CCl4 at 25o C is 143mm
(3) 430 g mole -1 (4) None of these of Hg 0.5 gm of a non-volatile solute (mol.
15. Boiling point of chloroform was raised by wt. = 65) is dissolved in 100 ml CCl4 . Find
0.323 K, when 0.5143 g of anthracene was the vapour pressure of the solution (Density of
dissolved in 35 g of chloroform. Molecular CCl4 = 1.58 g / cm3 )
mass of anthracene is
(1) 141.43 mm (2) 94.39 mm
( K b for CHCl 3 = 3.9 kg mol–1 )
(3) 199.34 mm (4) 143.99 mm
(1) 79.42 g/mol (2) 132.32 g/mol
21. The relative lowering of the vapour pressure is
(3) 177.42 g/mol (4) 242.32 g/mol
equal to the ratio between the number of
16. The boiling point of water ( 100 o C ) becomes (1) Solute molecules and solvent molecules
100.52 o C , if 3 grams of a nonvolatile solute is
(2) Solute molecules and the total molecules in
dissolved in 200 gm of water. The molecular
the solution
weight of solute is
(3) Solvent molecules and the total molecules
( K b for water is 0.6 K/m) in the solution
(1) 12.2 g mol -1 (2) 15.4 g mol (4) Solvent molecules and the total number of
(3) 17.3 g mol -1 (4) 20.4 g mol ions of the solute
22. When mercuric iodide is added to the aqueous
17. A 0.2 molal aqueous solution of a weak acid
solution of potassium iodide, the
(HX) is 20% ionised. The freezing point of this
solution is (Given K f = 1.86 o C / m for water) (1) Freezing point is raised
(2) Freezing point is lowered
(1) - 0.31o C (2) - 0.45 o C
(3) Freezing point does not change
(3) - 0 .53 o C (4) - 0 .90 o C
(4) Boiling point does not change
18. of 1,4-dioxane is 4.9 k mol for 1000 g.
Kf –1
23. During depression of freezing point in a
The depression in freezing point for a 0.001 m solution, the following are in equilibrium
solution in dioxane is
(1) liquid solvent - solid solvent
(1) 0.0049 (2) 4.9 + 0.001
(2) liquid solvent - solid solute
(3) 4.9 (4) 0.49 (3) liquid solute - solid solute
(4) liquid sloute - solid solvent

ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11 12
Ans 2 3 2 1 2 4 1 1 3 3 2 1
Que. 13 14 15 16 17 18 19 20 21 22 23
Ans 3 2 3 3 2 1 2 1 2 1 1

12 Your Hard Work Leads to Strong Foundation E