Class 12th NEET

MRNL/105 Milestone Test-05 Phase-1

DATE: 05/11/2023
Answer Key
PHYSICS CHEMISTRY BOTANY ZOOLOGY
1. (1) 51. (2) 101. (1) 151. (1)
2. (4) 52. (3) 102. (1) 152. (4)
3. (2) 53. (3) 103. (2) 153. (4)
4. (3) 54. (1) 104. (4) 154. (3)
5. (3) 55. (3) 105. (3) 155. (3)
6. (1) 56. (4) 106. (3) 156. (1)
7. (3) 57. (1) 107. (2) 157. (2)
8. (3) 58. (3) 108. (1) 158. (3)
9. (2) 59. (3) 109. (3) 159. (1)
10. (3) 60. (2) 110. (4) 160. (1)
11. (1) 61. (2) 111. (2) 161. (2)
12. (3) 62. (3) 112. (2) 162. (4)
13. (3) 63. (2) 113. (2) 163. (2)
14. (1) 64. (2) 114. (4) 164. (4)
15. (1) 65. (3) 115. (4) 165. (1)
16. (4) 66. (2) 116. (4) 166. (2)
17. (2) 67. (3) 117. (3) 167. (2)
18. (3) 68. (4) 118. (4) 168. (3)
19. (3) 69. (1) 119. (4) 169. (3)
20. (2) 70. (4) 120. (1) 170. (4)
21. (3) 71. (4) 121. (1) 171. (3)
22. (2) 72. (1) 122. (4) 172. (1)
23. (4) 73. (4) 123. (1) 173. (2)
24. (3) 74. (2) 124. (2) 174. (2)
25. (4) 75. (4) 125. (4) 175. (3)
26. (3) 76. (3) 126. (4) 176. (3)
27. (4) 77. (3) 127. (1) 177. (2)
28. (3) 78. (3) 128. (2) 178. (2)
29. (2) 79. (2) 129. (3) 179. (4)
30. (2) 80. (3) 130. (1) 180. (3)
31. (2) 81. (3) 131. (3) 181. (1)
32. (1) 82. (3) 132. (1) 182. (1)
33. (4) 83. (4) 133. (2) 183. (1)
34. (4) 84. (3) 134. (3) 184. (4)
35. (2) 85. (1) 135. (1) 185. (1)
36. (2) 86. (2) 136. (4) 186. (2)
37. (1) 87. (3) 137. (3) 187. (2)
38. (2) 88. (2) 138. (1) 188. (2)
39. (2) 89. (2) 139. (3) 189. (2)
40. (1) 90. (2) 140. (1) 190. (3)
41. (4) 91. (2) 141. (4) 191. (2)
42. (2) 92. (3) 142. (1) 192. (1)
43. (4) 93. (2) 143. (1) 193. (4)
44. (1) 94. (3) 144. (2) 194. (2)
45. (1) 95. (4) 145. (2) 195. (2)
46. (4) 96. (2) 146. (1) 196. (3)
47. (3) 97. (2) 147. (2) 197. (4)
48. (2) 98. (3) 148. (1) 198. (1)
49. (4) 99. (3) 149. (3) 199. (3)
50. (3) 100. (3) 150. (2) 200. (3)
NEET- 12th_________________________________________________________________________________Phase-1, Test – 05

SECTION-I (PHYSICS)
1. (1) 6. (1)
H 1.8 As u reaches from 0 to –
Minimum length of the mirror = = = 0.9 m.
2 2 v reaches from + 0 to + f.
2. (3) 7. (3)
v
In given conditions m = − = 2  v = –2u As u → f : v → 
u
1 1 1 And v → f : u → .
From mirror equation + =
v u f
8. (3)
Given f = –0.2 m

1 1 1
 + =  u = – 0.1 m.
−2u u −0.2
3. (2)

c c
=  vm =
vm 

displacement
 Velocity = = vm
time

From figure AM1E = 90° c t nt

=  time =
n time c
 AM1B = 90°
9. (2)
A = B = 45°

In AM1O

60 60
tan 45° = =
OA h

 h = 60 m.

4. (3) By Snell’s law

sin2A = () sinA   = 2cosA

2sinA cosA = sinA

2cosA = 

10. (3)
Relative velocity between the object and the image f 2 = x1x2
= v cos  + v cos  = 2v cos . (as vO = vI = v)
f 2 = 9 × 25
5. (3)
f = 15 cm
360
No. of image = 3  –1=3

11. (1)
 = 90°
NEET- 12th_________________________________________________________________________________Phase-1, Test – 05
Imax = ( I1 + I 2 )2 = ( nI + I )2 = ( n + 1) 2 I

Imin = ( n – 1) 2 I

I max – I min 2 n
= .
I max + I min n +1

19. (3)
Side of square = 3 cm

2 I = 4I0cos2
A0 = 3 × 3 = 9 cm 2
AI = m2 × A0  
i.e. I = 4I0cos2  I  cos2 .
f –10 –10 –2 2 2
m= = = =
f – u –10 – (–25) 15 3 20. (2)
2
 –2  P
AI =    9 = 4 cm2. I= and I  A2
 3  4r 2

12. (3) 1
A .
r
D
m = 1+
fe 21. (3)
For Young's double slit experiment, angular fringe
m = 1+
25 
2.5
; m = 11 width  =
d
13. (3) It does not depend on the distance of screen from the
slit, so statement I is correct.
Angular fringe width  
So if λ increases, angular separation of fringes
increases.
Therefore, statement I is true and statement II is
false.

22. (2)

D
Fringe width  =
d
Here, λ = wavelength of light from coherent sources,
14. (1)
Focal length does not change → Power does not D = distance of screen from the coherent sources,
change
d = separation between coherent sources
15. (1)
When, d = and D 2D
For sustain interference. Two sources must be
coherent (2 D) 4D
New Fringe width,  = =
d/2 d
16. (4)
All the above types of waves   = 4

17. (2) Fringe width becomes 4 times.

Colours of thin film are due to interference of light.

18. (3)
23. (4)
NEET- 12th_________________________________________________________________________________Phase-1, Test – 05
Path difference for destructive interference in 29. (2)
YDSE
Q ne
(2n – 1) Current (i) = = = 1.8 × 1014 × 1.6 × 10–19
Xn =  n = 1, 2, 3 …... t t
2
9 = 28.8 × 10–6 A = 29 A.
X5th = .
2 30. (2)
24. (3) We know that the raltion betweeen  and k is given
For path difference , phase difference = 2 rad. by

  h
For path difference , phase difference = rad. =
4 2 2mk
As K = 4I0 so intensity at given point where path h
Here, for the given value of energy k, is a
 2k
difference is
4 constant
     Thus,  
1
K = 4I0cos2   cos = cos 45 
 
4 4  m
K  p : n : 
= 2I0 =
2 1 1 1 1
: : :
mp mn me m
25. (4)
Given: Since, mp = mn, Hence p = n
Wavelength,  = 600 nm = 600 × 10 m –9

As, m > mp, therefore  < p

and diameter of objective, d = 2 m
Limit of resolution of telescope, As, me < mn, therefore e > n
1.22 1.22  600  10 –9
= = = 3.66 × 10–7 rad Hence,  < p = n < e.
d 2
31. (2)
26. (3)
h h h 1  E2
= =  k = 3 k =   1 =
mv 2mk 2mE E 2 E1
h h
 = = 10−10 E2
2m3k 3 2mk  =  E2 = 4E1
0.5  10−10 E1

  = .
3 energy added = E2 – E1 = 3E1.

27. (4) 32. (1)

P= 2mk = 2mqV Initial de-Broglie wavelength of electron,

Pe me qe me .e P me h
= =  e = 0 =
P m q m .2e P 2m mv0

28. (3) Force on electron in electric field,

2rn 2   0 n 2 h 2 2 0 nh 4 2 0n3 h3 F = −eE = −e  − E0iˆ  = eE0iˆ

T= =  2 =
vn me 2 e me 4
q e me5 F eE0 iˆ
Current (In) = = 2 3 3 = 2 3 3 Acceleration of electron a = =
T 40 n h 4 on h m m
4
me
 eE iˆ   eE 
In  e5. v = v0iˆ +  0  t =  v0 + 0 t  iˆ
 m   m 
NEET- 12th_________________________________________________________________________________Phase-1, Test – 05
 eE t  36. (2)
v0 1 + 0  iˆ
 mv0  kmax = 4eV.
de-Broglie wavelength associated with electron at 37. (1)
time t is
From Einstein’s equation of Photoelectric effect,
h
= 1 2 1
mv mv1 = 2hv0 – hv0 or mv12 = hv0 …(i)
2 2
h 0  h 
 =  0 =  1 2 1
  eE    eE0   mv0  mv2 = 5hv0 – hv0 or mv22 = 4hv0 …(ii)
m v0 1 + 0 t   1 + t 2 2
  mv0    mv0 
By eq, (i)  (ii)
33. (4)
v1 1 1
hc hc = =
Kmax = – v2 4 2
 0
38. (2)
hc hc
eV = − 1 2
 0 eVs = mvmax = hv – 0
2
eV hc hc
= − 2 = 5 – 0  0 = 3eV
4 2 0
In second case,
From (i) and (ii)
eVs = 6 – 3 = 3eV  Vs = 3V
1 1
−
 0  VAC = –3V.
4=  0 = 3.
1 1
− 39. (4)
2  0
1
34. (4) v0 

hc
eV0 = − 0 V2 > V1  v2 > v1

Hence, 2 > 1.
hc 0
 V0 = −
e e 40. (1)
Given, v = v0iˆ  B = B0 ˆj
hc 0
 V1 = − Force on moving electron due to magnetic field is,
e e
F = – e(v  B ) = –e(v0iˆ  B0 ˆj ) = –ev0 B0 kˆ
hc 
And V2 = − 0 As this force is perpendicualar to v and B , so the
 e
 e magnitude of v will not change, i.e., momentum =
2
(mv ) will remain constant in magnitude. Hence, de-
2hc 0 2hc 20 20 0 h
V2 = − = − + − Broglie wavelength  = remains constant.
e e e e e e mv
0 41. (4)
V2 = 2V1 +
e
Linear width of central maxima Y
 V2 > 2V1.
2 Da 2 D
=D(2) = 2D = =
35. (2)  a
V0 is independent of intensity.
NEET- 12th_________________________________________________________________________________Phase-1, Test – 05
angle of refraction = 90°

44. (1)

Longest wavelength is of red colour.

45. (1)

For spherical mirrors

m = +ve  virtual image

The central maxima lies between the first minima on m = –ve  real image
both sides.
|m| > 1  magnified image
2
The angular width ‘d’ central maxima = 2 =
b |m| < 1  diminished image
2 D 46. (4)
Linear width of central maxima = 2D =
b Ultrasonic wave
b = width of slits and D = distance between slit and
screen. 47. (3)

42. (2) both interference and diffraction occurs

The fringe width is given as: 48. (2)
D
= D
d
d

We know that the wavelength is inversely 49. (4)
proportional to the refractive index of the medium.
v2
1 h 1–
 c2
 =
m0 v
So, the fringe width will decrease as the refractive
index of water is higher than that of air. 50. (3)

43. (4)
NEET- 12th_________________________________________________________________________________Phase-1, Test – 05
SECTION-II (CHEMISTRY)
51. (2) 56. (4)
The correct name of the compound is 2-chloro-3- Hint: Stronger is the intermolecular force of
methylpent-2-en-3-ol. attraction, higher will be the boiling point.
52. (3) Sol.:
Hint: Aldehydes are more reactive than ketones in • Intermolecular hydrogen bonding in propanoic
nucleophilic addition reactions. acid is greater than propan-1-ol
Sol.: Electron withdrawing groups present at para • Correct order of boiling point is,
position to the aldehyde group increases the Propanoic acid  Propan − 1 − ol  Acetone  Propanal
electrophilicity of carbonyl carbon 414 K 370 K 329 K 322 K
CHO
57. (1)
Hint: Aldehydes which do not have an -hydrogen
So, forms cyanohydrin with fastest rate atom, undergo Cannizzaro reaction.
O

NO2
Sol.: has -hydrogen therefore it will not
53. (3)
Hint: Benzaldehyde is produced by Gatterman- give Cannizzaro reaction. It will undergo aldol
Koch reaction. condensation reaction.
Sol.:
58. (3)
CHO
Hint: Ammoniacal silver nitrate is called Tollens’
reagent.
Sol.: Ketones do not respond to Tollens’ test.
(A) Aldehydes are oxidised to corresponding
COOH CH2OH carboxylate anion with Tollens’ reagent
O O

(C) (D)
54. (1) CHO COO
Hint: NaBH4 is a mild reducing agent. It does not
59. (3)
reduce ester group
Hint: Ketone on reaction with one equivalent of
Sol.:
alcohol in presence of dry HCl gives hemiketal.
Sol.:

O OH
+ CH3OH ⎯⎯⎯→
HCl(g) OCH3

55. (3)
Ketone Methanol Hemiketal
OH
COOH
C6H5OH + CCl4 ⎯⎯⎯→
NaOH
NEET- 12th_________________________________________________________________________________Phase-1, Test – 05
60. (2)

OH
OH

: Catechol,

OH
64. (2)
Hint: In semicarbazide, –NH2 group which is
directly attached with carbonyl carbon does not
take part in nucleophilic addition reaction.
OH: Resorcinol
O
OH || +
R – CH 2 – CH 2 – CHO + H 2 N – C – NH – NH 2 ⎯⎯→
H

O
||
: Quinol R – CH 2 – CH 2 – CH = N – NH – C– NH 2

65. (3)
OH – +
O OMgl
OH || |
C2H5Mgl + CH 3 – C– C3 → H 3C – C – CH 3
CH3 |
C2H5

: o-Cresol

61. (2)

Oxidation of 1, 4-Dihydroxy benzene.

66. (2)
O H O (a) (iii) Hell-Volhard-Zelinsky reaction
(b) (i) Stephen reaction
(c) (ii) Etard reaction
(d) (iv) Rosenmund reduction

67. (3)
O H O
O
||
62. (3) C6H5CH = CH – C– C6 H 5
Hint: Ketone does not respond to Tollens’ test and 68. (4)
Fehling test
Hint: Carbonyl compounds on reaction with
O ammonia form imine.
||
Sol.: Methyl ketones having CH3 – C– group
undergo haloform reaction. Thus C6H5COCH3 will
give yellow precipitate with {I2 + NaOH} but
(C6H5)2CO will not 69. (1)
Dehydrogenation of alcohol takes place
63. (2)
R – CH 2 – OH ⎯⎯→
Cu
 R – CHO + H 2
(Aldehiyde)
Hint: During the esterification tetrahedral
intermediate is formed. 70. (3)
Sol.: Esterification reaction Codensation of two acetone molecules occurs when
acetone reacted with dil. NaOH followed by
heating
NEET- 12th_________________________________________________________________________________Phase-1, Test – 05
Aldol condensation reaction 76. (3)
O In the preparation of benzaldehyde from benzene
 and (CO + HCl) in presence of anhy. AlCl3, new
CH3 C O + CH2 C CH3
carbon-carbon bond formation takes place.
CH3 H dil. NaOH Gattermann Koch reaction (SE reaction)
CH2 CHO
CH3
C CH2 C CH3
CH3
OH

CH3 O
 77. (3)
C CH C CH3
H2 O When phenol reacts with FeCl3 gives purple
CH3 Mesityl oxide colour.

71. (4) 78. (3)

A is propan-2-ol Hint: More the electrophilicity of carbonyl carbon,
B is propan-1-ol more will be its reactivity towards nucleophile.
• Electrophilicity of carbonyl carbon in RCHO and
72. (1)
RCOR decreases due to +l effect of R group(s).
CO2 is the elecrtophile in the given reaction.
• Electrophilicity of carbonyl carbon in
73. (4) benzaldehyde is less as (+)ve charge is
O
||
delocalized in the benzene ring.
Compounds containing CH 3 − C– group on • Hence among given options, HCHO is most
treatment with l2/NaOH gives yellow precipitate of reactive towards nucleophile due to maximum
lodoform. electrophilicity of carbonyl carbon.
Test Name CH3 – CHO CH3COCH3 79. (2)
Benedict test Red ppt × More the dipole-dipole interactions between the
Fehling test Red ppt × molecules, more will be the boiling point of
Great test Silver mirror × compound.
lodoform test Yellow ppt Yellow ppt Compound Boiling point (K)
CH3CH2CH2CH3 273
74. (2)
CH3COCH3 329
Gemi di-ethers are known as acetal or ketals.
CH3CH2CHO 322
OC2 H5
C2H5OCH3 281
CH3 CHO CH3 HC
Hemiacetal
OH 80. (3)
(i)O
OC2 H5 CH3 – CH2 – CH = CH2 ⎯⎯⎯⎯⎯
3
→
(ii)Zn/H2O
CH3 HC But-1-ene

Acetal
OC2 H5 CH3 CH2CHO + HCHO

75. (4)
Wolff Kishner reduction takes place in basic
medium.
Wolff Kishner reduction.
R R
C O C N NH2
R R
(i)O
R CH3 – CH2 – CH = CH3 ⎯⎯⎯⎯⎯
3
→ 2CH3 – CHO
(ii)Zn/H2O
But-1-ene
CH2 + N2
R
NEET- 12th_________________________________________________________________________________Phase-1, Test – 05
81. (3) CH3
Primary alcohols gives red colour in Victor Meyer CH3 H3C C O O H
test. H3C C H
82. (3)
Ethanol undergoes intermolecular dehydration
when heated at 413 K in the presence of protic acids Cumene
while it undergoes intra-molecular dehydration (Cumene) hydropeoxide
when heated in the presence of conc. H2SO4 at (X)
443K.
OH
H SO
(a) CH3CH2OH ⎯⎯⎯⎯
2
443 K
4
→ CH2 = CH2
O
H SO
(b) CH3CH2OH ⎯⎯⎯⎯
2
413 K
4
→ C2H5OC2H5 + CH3 C CH2
ZnO–Cr O Phenol
(c) CO + 2H2 ⎯⎯⎯⎯⎯ 2 3
⎯
→
200–300 atm CH3OH
Acetone
573–673 K (Y) (Z)

(d) CH3CHO + H2 ⎯⎯→

Pd
CH3CH2OH 86. (2)
Presence of electron withdrawing groups increases
83. (4) acidic strength of the phenols.
Chlorine deactivates the benzene ring towards Due to strong -R, of -NO2 group, p- nitrophenol is
electrophilic substitution reaction because of its a strong acid.
strong -I effect
Acidic strength order
Cl Cl Cl
OH OH OH
NO2 OH

+ OCH3
> > >
1-chloro NO2
-2-nitrobenzene NO2 NO2 OCH3
(Minor)
1-chloro
-4-nitrobenzene 87. (3)
(Major) PCC (pyridinium chlorochromate) oxidises
primary alcohol to aldehyde
84. (3)
CH3 – CH3 = CH – CH2 – OH ⎯⎯⎯
PCC
→
The presence of an electron withdrawing group at
ortho- and para-positions increases the reactivity of CH3 – CH = CH – CHO
(P)
haloarenes towards nucleophilic substitution
reaction. 88. (2)
–NO2, due to its –R, –I effects is an electron PCC (pyridinium chlorochromate) oxidises
withdrawing group, so, increases the stability of primary alcohol to aldehyde
carbanion intermediate formed while –OH, –OCH3
CH2 OH COOH
and –CH3 are electron donating groups, so,
decreases the rate of SNAr reactions.

85. (1)
Most of the worldwide production of phenol is from CH2 OH CHO
cumene (Isopropyl benzene).

K Cr O
CH3CH 2 OH ⎯⎯⎯⎯→
2 2 7
H+
CH3COOH
NEET- 12th_________________________________________________________________________________Phase-1, Test – 05
89. (2) O
Diazotisation reaction of aniline will take place. CH2 C OCH3
O
N2 Cl

OH OH
NH2 CH2 C OCH3
O
Benzene
NaNO2 +HCl diazonium H 2O
⎯⎯⎯⎯⎯⎯
0–5C
→ chloride ⎯⎯⎯→
Warm Phenol 95. (4)
Aniline (A) (B)
Grignard reagent is highly reactive towards any
90. (2)
source of proton (H+ ion)
Cis-diol forms cyclic acetal with an aldehyde but – +  –
Non aqueous
not trans-diol. R – X + Mg ⎯⎯⎯⎯⎯⎯⎯→
Medium (dry ether)
R– Mg X

96. (2)

Methanol, CH3OH, also known as ‘wood spirit’ is

produced by destructive distillation of wood.
91. (2)
97. (2)
Carbonyl compounds (aldehydes/ketones) when
treated with R-MgX, followed by hydrolysis, C12 H22O11 + H2O ⎯⎯⎯⎯
Invertase
→C6 H12O6 + C6 H12O6
Sucrose Glu cose Fructose
produce alcohols
Zymase
92. (3) C6 H12 O6 ⎯⎯⎯⎯ → 2C2 H5OH+ 2CO2
In Reimer-Tiemann reaction, phenol is converted
into ssalicylaldehyde 98. (3)
OH OH LiAIH4 reduces –CHO group into –CH2OH
CHO
R − X ⎯⎯ ⎯⎯
Alc. KOH

→ Alkene
(major)

CH3CHO ⎯⎯⎯
LiAlH4
→ CH3CH 2 OH ⎯⎯⎯
PBr3
→
(x)
93. (2)
CH3CH 2 – Br ⎯⎯⎯⎯– HBr
Alc.KOH 
→ H 2 C = CH 2
(Y) (Z)
OH OH
Br Br 99. (3)

Tertiary alcohols give immediate turbidity with

Lucas reagent (conc. HCI and ZnCl2) as they form
halides easily, primary alcohols do not produce
Br
turbidity at room temperature.
2, 4 ,6-tribromophenol is a white coloured compound 100. (3)
94. (3) When functional group (–OH) remains attached to
NaBH4 does not reduce esters. primary carbon then it is called as primary alcohol.
NEET- 12th_________________________________________________________________________________Phase-1, Test – 05
SECTION-III (BOTANY)
101. (1) 126. (4)
102. (1) 127. (1)
103. (2) 128. (2)
104. (4) 129. (3)
105. (3) 130. (1)
106. (3) 131. (3)
107. (2) 132. (1)
108. (1) 133. (2)
109. (3) 134. (3)
110. (4) 135. (1)
111. (2) 136. (4)
112. (2) 137. (3)
113. (2) 138. (1)
114. (4) 139. (3)
115. (4) 140. (1)
116. (4) 141. (4)
117. (3) 142. (1)
118. (4) 143. (1)
119. (4) 144. (2)
120. (1) 145. (2)
121. (1) 146. (1)
122. (4) 147. (2)
123. (1) 148. (1)
124. (2) 149. (3)
125. (4) 150. (2)

SECTION-IV (ZOOLOGY)
151. (1) 157. (2)
152. (4) 158. (3)
153. (4) 159. (1)
154. (3) 160. (1)
155. (3) 161. (2)
156. (1) 162. (4)
NEET- 12th_________________________________________________________________________________Phase-1, Test – 05
163. (2) 182. (1)

164. (4) 183. (1)

165. (1) 184. (4)

166. (2) 185. (1)

167. (2) 186. (2)

168. (3) 187. (2)

169. (3) 188. (2)

170. (4) 189. (2)

171. (3) 190. (3)

172. (1) 191. (2)

173. (2) 192. (1)

174. (2) 193. (4)

175. (3) 194. (2)

176. (3) 195. (2)

177. (2) 196. (3)

178. (2) 197. (4)

179. (4) 198. (1)

180. (3) 199. (3)

181. (1) 200. (3)