--t,(1.

5- Cubic system JR r J
.Q.36. Name the three kinds of unit cells in cubic sy stem. r j , C, U b,'<.. S\i~ ~-
-
Ans: ~_l "-e ____ ~Y<..e ___k. J r . :b c
e
t)'J_g_5 ___ .c:>_t ----~-011 ------------
s.
- -----
'!:'-----------------h<J :_~

r~- :~ -
.
y_. -~ --
-
--x;--------- -------6-(~----- ----ii:
---~f2l_e___ (.~-----------~m
±Kd______
::::0::n ~ ~ ~~ ~ ~~~~ ~~ ~ ~: :: :: :: :~: _ --·-
<..:?JJ _____________________________________ _
· - -~~~~::_
·,i~ .8 o dJ__ -___G-e. n lA n{}_____

~_1j_i_>---_f_o,_ ~-~ -G1'Al _k_d _______ unit_ --_B>..J _l_------------------------------------------·

Q.37. Explain with the help of diagram:
i. Simple cubic (sc) unit cell:

Ans: ------------------------ -4a-- - - - -- -------------------------

-- --- - ---- - -- - --- ----------- .....

--------------- --- ----- --- - -- - --- - ----------- ........... .

----------------------_..;--+------- -- - - - - - - - - - - - - - - - - -- - - - - - - - - - - - - - - - - - - - --- ------- - ----·

----...--=--~- --------------------------------------------------------- -
----- --- ----- ----------- --------- --- --- - - --- -- - - - - -- - - - - - - - - --- ----- - ------------

----------------------------1- ------------------------------------------------------------------- - -.. --

16
 th11pter l Solid State

•
• . ...... -------

-- .. - ------ --·-----------------------------------------------------------------------------
fl)CM
entred cubic (fee) unit cell:
iii,
--------------~-------=---• --------------------------------------------- ---·-

...•····-- ----/ ------.- ----------/ / ----------------------------------------------------

·············--·--· ---· -~ ---1-----,,------------ ---------------------------------------- --- ---· -- ---
-- ----------- ----------- - ------------ -----------------------------------------------------
Q

-;,,-.------1----....--...-----=-~=-• ---- -----------------------------------------------

.. --·····-·----- -- - -- --- -- --- --- - ----- --- -- - - ----- -- - --- - --- -- - - - ---- --- - ---- - --- -- - -- - - -- - - - - - --

_,__ _ _=,.,,.,,.,--_..,.~------- -----------------------------------------------------------

------------------------------------------------------- ------ ----------------------------------

---------------- - -- ------------------------------------------

--------------------- - ---- -------------------------------------

QJ8. Calculate the number of particles in primitive or simple cubic unit cell.

Ans: •.. ~;!llpk--cRhi_~ ____CJni _t ______egJL_ -~.s.L ____ -p-t:Mi·J. f4 __ Qf-:i}J _

~
1
~b):-__ ____ ( VY - ~ ,3_•_---- --- -------- ------------------- ----- -------- ---- _----- _-- __ -- -- __ -- ----.
----------------------------------------------------------------------------------------------------- -

~ -- ;}10-1-- <i~ ___ ---p-av.hd(',__-5. ___ -p,e .1--~-_________cJ:_ c_11;rr.u_p----

41.k _~.lL-=-_______ -~__ x_ __ f ___ ---------- -c----~ --t~-b..cl~---FX= --
-- --
···-·-······---------. -------.----------------_i_ ------------------------------------.u- ,,t.a J-----· -----
.
a_[_'}_

17
 Std, XII Sci , Porfrct Ch,.n,l,try (Vo l I)
0

Q..to. C11k11l•h' th,• numlu·r ol 11ton." In h«

111111
"'
11
J-svJ .. !· qr.: Ji. cJ ~.S...! .M H...
\n,: •A: bc:.c l/ 11, tc e; ( . .. L• ,s_ C, }.____ Cf)) fk-
. ) rt- /., r __ ....:pgrv -·
(: it . c ~ &rs··· l::i ,...., ........ ·········· .... ····· ... ·········
·_:{····· .e.~k. r .... CRtnJ...r./' ~
·····~····f ;· .cd-......
___ J ~ --- 'r')(} · 0 t . f? VJ~ -'F.C ----· ------------ -------- ------
.------------------ -----_____ w Yl .t'A-:-.. ee.µ. __ f -.. ---------------

:::.:::::::::::::::~ ·······"15,···~::::f.'.::::::::::::::::::::.......... ::::::::::.......... ::::..

--------------- ---=--------1 _________________________________________________________________________ -

-------------- - - --------
----------------------------------------------- -------------- --------- - - ---------

--- ---------------------------------------- ----- ---------------------- -

--------------------------------------------- ------------------------------------- -- ---~

-----------------------------------------------------------------------------------------------------------·--·-

-------------------------------------------------------------------------------------------------------------
------ -- ------- -------- -- ---------- - ------ ---- --- --- - --- - - - -- - - --------·
Q.40. Calculate the number of atoms in fee unit cell.

Ans:A..fcc .....Y.od~...cdL....hcis...f W.i·d~......oJ .. -Ht .....1! i!fliJ

.c_.~ .nU¥-.. . .pl/LJ.~...... pa.~b:dri ...flt: ....&...u. nm.....P.t.. !
.6. ~~ .. _fg_Cf....S. ____________________________________ ___ ___ ______ ___ _____________________________ ------··
 Ch11ptN 1: Solid State

:i ~ _
(_-M,---°-L-------p0~t-k___ --P«-I.A1'l_1J: ____ cdL__:-____________________
p~h de----e-e«Y-n1La..lJ-,-______
______ __ ___ _________ __ ___ -:::- __ _1_ __tL_ ______ ~ __ li_ _
_ 1

ENRICH YOuR l<NOWLEoGE

~ -
Jlll.-_________________________________ -,
~ I
Toe following figure will help you to understand particles present at the face, edge and corner are shared by I
. urut. ce lls.
neighbounng
1
1

I
I
I
I
I
I

al~ a;
13) G'.i~ (fl
I Each face is part of two cubes Each edge is part of four Each comer is part of eight
cubes cubes

---------------------------------- -----------------
19
Std XII Sci f' "'
n\' l Ch ini,,tiy (Vol 1)

I
Ii
,,
Q.4 I. Uh,n H I tt tl" QI''-'" unll ('{)I
01 1u11 ,h 111
1hi,"
Ho ' 1l ' r-1111,1011" Ot \ 111 pr, unit r, llf

- -- - - -------- - -- - --- ---- --- -------- ----------- --- --- -- -- - - - --- - -- - - - - -- - - - - - -- - - - -- -- -- -

--- - -------------------------------------------------·-

- ----- - - -- - ----- --- - - -- ---- -- - - - - - -- -- -- -- ---- ---- ------···

--- ----- -- ----- -- - -- ---- --- - -- ... --- - ---- --- - --- -- -- -- - -- -- -- - -- - - -- -- -- -- - - - -- -- -- .. --- -- --- --------··

-~- -- ----- ---- - .. ------ - -- --- .. -- --- -- - --- --- - -- - --- -- - ----- -- - - -- -- - -- --- - - -
- --------------------------- - -- - ... - -- --- -------- ... -- ----·····

- - --------- -- ---------------------------------------- ------------ - ---- ---- -- ----- -·------------·

--·- -- - ·-------·- ··--- ----- -- - --- --- --- ------ ---------

--- ---- ---- ----- -.------ -- ---- ------ -----------
 lh'
'
--------- ...
.-.,,!ti,,, ,1 01lh , , , II Int ttt ~ f
~ .. 11, 1,1 5t,1l1I, :\11111\t "',,.I• I
,, hr" ,..
1l 11 ' h " (Hl
, ,u,1H,,·~ int,• ltt\ c , ,•uh•,, , uhh 1r11ath of unit t
(,~,,,I<(l,•tl'll
I '1
\ ,,t g,,l,1. 1Moliu "'"''i "' w•hl

-- ---------- -----------
---- -----------------------------

--------- -- ---------- -------------------------------------------------------------------

-- -------------'=--------~ ~ i __ 15-____cJCJftt -~-4-,
-.: __ __ ~ ----------------
r] - ---------------------------------- -------

---------- ---------------- ----- ------------------------------------------------------

----- -- ----- ------ - -- -- - --- - -------------------------------------------
---------
------------ ----- --- ---- - -- -- ------- --- --- ---- -- - -- --------------------------------------

---------- -------- ------ -------- -- ---------------------------------------------

-------- -------------------- ------------------- ----------------------------

------ ------ ------- ------------------ -------------------
-------------------------------
 ( un1r "'"··- - - - -- ~-
(VOi I) 1c11glh "
Std KIi 5'1 P rf tt tf n,i trY " Jf r,f~C
r ,11 uch1f(,
Q.44. ~lhN [l\6HtlllW (n t,
.111 • 108),
( \tomlr mn\:' of ,,,,.
l\

f I I\ - .... ------
\
1_: tt ~-~ •••• • •••····· •·
O
::.. ~ G6 LI. XI(, •• . •··••···

· Q.45. An element with molar mass 27 !efmol forms cubic unit cell with edge length of 405 pm. U
the element is 2. 7 g/cm3, what is the nature of cubic unit cell?
I

Solution: _(ri.'::!{t._·.- _ M : - 2-t ~ fmr:i_l __________________ _

:::::::::::::::::::::······f-·~~.::;.'.~~.~........................................· : : _
--------------- ------------------------
--- - -- -- - ---- -- -- --- - ------ ---------------

------------~- =---. 1Mt) ---------------

··· ... ............ . o .NA ..............::::: --- -- -------------·

----------------------··

---- -- -- --- -- -- __________ ,,,

 olld ~, ,.,
G C) A

------- --- ------------ ·------ --- -

---------·-----------
----------•-------•-•M•-••--•--•--••---•••••••- -----------------------
-- ----------- ------- ------------- -
------------------------------------------------------- --
------- -------- -- -------- --------------------- ---------------------------------------------------
---------
----------------------- ----------------------
-------------- ---------- -----------------------------------
-------------------------
----- -------------------------------------------- -------------------- -
-------------------------
--------------------------------------------- ------------ -- -------------
---- --------------------------------- --------------------------- ---------------------------------------
QA6· Unit cell of a metal has edge length 288 pm and density 7.86 g cm-3. Determine the type of the crystal
lattice.
(Atomic mass of metal= 56 g mor1] [Feb 20]
2::6_i _p_rn__:;____.2.:_~_i__~ __xj__o_~-- _cm_ ________________________ _
Solution: ___(n_v_fn__'::~--- -_Q __':""____

___________________ ____ __ ____ __&~i_c;.___ m_0_s;;::;;:c __s _6_(J_ lru~l-__-: _____ J ___:;: ___ _1_, _i _6- c,,,:1 _s/
______________________________ _f_::::: --- 1 ------------------------------------------------------------------------
---------------------- ~---= 1!1 0 - ---------------------------------------

_________________________________a '1 __ N.A ----------------------------------------------------------------------

------------ ----- --------------------------------------------------------
____ ;.]_,_~~~-----::_______ _ S 8 >c ~ ____ _
------------------------- { 2..-~ i x c~-ls) s~--~'.
a 2-2 ___ >< t~_~Ao 0 ____ _ _ _. . . - -- ----

i _~--~ x C2-.. i i XL(t~~)-~____ X__ 6__:_Q__~-~- _X_! Q~~------

__"f+ __-:_____ 3 !_
------ ---- ---- ------------------------------------~ -~ -----------------------------------------------------
 Std. XII Sci • Prrf rtl Ch mMtV (Vol I) --- ··----
. I .. ..
B~ X/o .....
j
~6
w .. ······ .

- 2 ..
(J J - .: ....

----- -----------·-····.

--
- - .. - - - -- - - - - - - - - -- - - - - - -- - ---- - - --- ----- - ---- ---- -

-- ---- - -- - - - - - - - - -- - -- - - - -- --- -- ----- - --- ---- ----- -

- - - - - - - - -- - -- - -- - - - - --- - ----- - -- ----- -- - ---- ------
------- ---- -- - --- ..........
- - - - - - - - -- - -- -- --- - ----- ------- ------ --- ----------

--- - -- - ---- -- - - -- -- -- - ---- ---- - -- - ---------- - ---------- ------------ --- -- --- - - - - - --- - - -- - -- - -- --- ........ _

- - - ---- - - - - --- - - --- ----- - - - ---- ---- - - -- -- -- ---- --- ---- - ----- ------- ---------------------- -----

-- - - - - - - -- -- -- --- - ---- --- - -- - - -- - - - --- ------ -- ---- - --------- ---- - - - - -- - - -- - ...........

- -- -- - - -- --- - -- - -- -- -- --- -- ---- - - ------------ - ----- - -- - ----- -- -- - --- -----·--

--- - -- ---- - -- - -- --- ------ - - - -- -- - ------- - ------ --- --- - -- - -------- -- --- - - - -- - - ------- - ---- - - -- -- ----·-···-

JJ-47. A metal crystallises into two cubic lattices namely face centred (fee) and body centred (bee~ w
unit cell edge lengths are 3.5 Aand 3.0 Arespectively. Find the ratio of the densities of fee and bet.
(Jaly
Solution: ______Q..,_~ ___ J :__'§_J..__ ________________ q_2:... ______-: ._ __ ._3__· 6 A...............-
:::::::::::::::::: ::~ --.-=-. - ~ -f=-::::::::: ::::::::::::::::::::::::----.-.-.....·-·...._. _. _. _.~_
-- -- -- -- ----- ----- ---- --- ... ---- ----- - ------- - --- - --- -- -- -- --- --- ----- --- .. --- -- ------- ---- ------- -- --- .... ----------·

---- -- .... ·---- ---- -- -- -------- --------·--- ..............

24
 ;

b C(:

... -- --------
__ .. __ _

- ------------
--------------------------------------------------------------------- (\_,

--------------~ --------- ~ ------· S" y ■-------------==------J__~__:S_f) ___ =___ J_._u;__

----------
·---------
--------------~L ______________ Y2_..~:2--s
-I=
___________________________________________________ _
--------------------- - -- ------·----------------------- - -----
r..~b·_o____ of____ d eh s.it-j_c_i __ u _~_____f _c _c ______?___b.c c ____.s_hu~-~
__ _1' s ____ J:2.-~ ----------------------------------------------------------------------------------------------
-------- --------------------------------------- -------------------------------------------------------------------

-- - --------------------------------------------------------------------------------------------------

---------------------------------------------------------------------------------------------------