SAFETY DATA SHEET according to Regulation (EC) No.

1907/2006
NALCO® 72215

Section: 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier: NALCO® 72215

Substance type: CLP Mixture

1.2 Relevant identified uses of the substance or mixture and uses advised against:

Use of the Substance/Mixture : BOILER WATER TREATMENT

Identified uses : Boiler treatment under 1T per day

Recommended restrictions on use : Reserved for industrial and professional use.

1.3 Details of the supplier of the safety data sheet:

COMPANY IDENTIFICATION LOCAL COMPANY IDENTIFICATION

NALCO EUROPE B.V. Nalco Ltd.
Postbus 627 P.O. BOX 11, WINNINGTON AVENUE
2300 AP Leiden, The Netherlands NORTHWICH, CHESHIRE, U.K. CW8 4DX
TEL: 0031 71 5241100 TEL: +44 (0)1606 74488

For Product Safety information please contact: msdseame@nalco.com

1.4 Emergency telephone number:

Emergency telephone number : +32-(0)3-575-5555 Trans-European

Date of Compilation/Revision: 23.09.2019

Version Number: 2.0

Section: 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Corrosive to metals, Category 1 H290

Skin corrosion, Sub-category 1A H314
Serious eye damage, Category 1 H318

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Hazard pictograms :

Signal Word : Danger

Hazard Statements : H290 May be corrosive to metals.

H314 Causes severe skin burns and eye damage.

Precautionary Statements : Prevention:

P280 Wear protective gloves/ protective clothing/
eye protection/ face protection.
Response:

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P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do

NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off
immediately all contaminated clothing.
Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh
air and keep comfortable for breathing.
Immediately call a POISON
CENTER/doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously
with water for several minutes. Remove
contact lenses, if present and easy to do.
Continue rinsing. Immediately call a
POISON CENTER or doctor/ physician.
Disposal:
P501 Dispose of contents/ container to an
approved waste disposal plant.

Hazardous components which must be listed on the label:

Sodium Hydroxide

2.3 Other hazards

None known.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures
Hazardous components
Chemical Name CAS-No. Classification Concentration:
EC-No. (REGULATION (EC) No 1272/2008) [%]
REACH No.
Sodium Hydroxide 1310-73-2 Skin corrosion Category 1A; H314 5 - < 10
215-185-5 Corrosive to metals Category 1; H290
01-2119457892-27

For the full text of the H-Statements mentioned in this Section, see Section 16.

Section: 4. FIRST AID MEASURES

4.1 Description of first aid measures

If inhaled : Remove to fresh air.
Treat symptomatically.
Get medical attention if symptoms occur.

In case of skin contact : Wash off immediately with plenty of water for at least 15
minutes.
Use a mild soap if available.
Wash clothing before reuse.
Thoroughly clean shoes before reuse.
Get medical attention immediately.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.

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Remove contact lenses, if present and easy to do. Continue

rinsing.
Get medical attention immediately.

If swallowed : Rinse mouth with water.

Do NOT induce vomiting.
Never give anything by mouth to an unconscious person.
If conscious, give 2 glasses of water.
Get medical attention immediately.

Protection of first-aiders : In event of emergency assess the danger before taking action.
Do not put yourself at risk of injury. If in doubt, contact
emergency responders.Use personal protective equipment as
required.

4.2 Most important symptoms and effects, both acute and delayed
See Section 11 for more detailed information on health effects and symptoms.

4.3 Indication of immediate medical attention and special treatment needed

Treatment : Treat symptomatically.

Section: 5. FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

5.2 Special hazards arising from the substance or mixture

Specific hazards during : Not flammable or combustible.
firefighting

Hazardous combustion : Oxides of phosphorus

products

Depending on combustion properties, decomposition products

may include following materials:
Carbon oxides
nitrogen oxides (NOx)
Sulphur oxides
Oxides of phosphorus

5.3 Advice for firefighters

Special protective equipment : Use personal protective equipment.
for firefighters

Further information : Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations. In the
event of fire and/or explosion do not breathe fumes.

Section: 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Advice for non-emergency : Ensure adequate ventilation.
personnel Keep people away from and upwind of spill/leak.

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Avoid inhalation, ingestion and contact with skin and eyes.

When workers are facing concentrations above the exposure
limit they must use appropriate certified respirators.
Ensure clean-up is conducted by trained personnel only.
Refer to protective measures listed in sections 7 and 8.

Advice for emergency : If specialised clothing is required to deal with the spillage, take
responders note of any information in Section 8 on suitable and unsuitable
materials.

6.2 Environmental precautions

Environmental precautions : Do not allow contact with soil, surface or ground water.

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up : Stop leak if safe to do so.
Contain spillage, and then collect with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).
Flush away traces with water.
For large spills, dike spilled material or otherwise contain
material to ensure runoff does not reach a waterway.

6.4 Reference to other sections

See Section 1 for emergency contact information.
For personal protection see section 8.
See Section 13 for additional waste treatment information.

Section: 7. HANDLING AND STORAGE

7.1 Precautions for safe handling

Advice on safe handling : Do not ingest. Do not breathe spray, vapour. Do not get in
eyes, on skin, or on clothing. Wash hands thoroughly after
handling. Use only with adequate ventilation.

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice. Remove and wash contaminated clothing before re-
use. Wash face, hands and any exposed skin thoroughly after
handling. Provide suitable facilities for quick drenching or
flushing of the eyes and body in case of contact or splash
hazard.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage : Do not store near acids. Keep out of reach of children. Keep
areas and containers only in original container. Absorb spillage to prevent material
damage.

Suitable material : The following compatibility data is suggested based on similar

product data and/or industry experience: HDPE (high density
polyethylene), Stainless Steel 304, Compatibility with Plastic
Materials can vary; we therefore recommend that compatibility is
tested prior to use.

Unsuitable material :
Aluminium, Mild steel, Plastic material, including expanded plastics
material

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7.3 Specific end uses

Specific use(s) : BOILER WATER TREATMENT

Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Occupational Exposure Limits

Components CAS-No. Value type (Form Control parameters Basis
of exposure)
Sodium Hydroxide 1310-73-2 STEL 2 mg/m3 UKCOSSTD

DNEL
Sodium Hydroxide : End Use: Workers
Exposure routes: Inhalation
Potential health effects: Long-term local effects
Value: 1 mg/m3

End Use: Consumers

Exposure routes: Inhalation
Potential health effects: Long-term local effects
Value: 1 mg/m3

8.2 Exposure controls

Appropriate engineering controls
Effective exhaust ventilation system.
Maintain air concentrations below occupational exposure standards.

Individual protection measures

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.Remove and wash contaminated clothing before re-
use.Wash face, hands and any exposed skin thoroughly after
handling.Provide suitable facilities for quick drenching or
flushing of the eyes and body in case of contact or splash
hazard.

Eye/face protection (EN : Safety goggles

166) Face-shield

Hand protection (EN 374) : Recommended preventive skin protection

Gloves
Nitrile rubber
butyl-rubber
Breakthrough time: 1 – 4 hours
Minimum thickness for butyl-rubber 0.7 mm for nitrile rubber
0.4 mm or equivalent (please refer to the gloves
manufacturer/distributor for advise).
Gloves should be discarded and replaced if there is any
indication of degradation or chemical breakthrough.

Skin and body protection : Personal protective equipment comprising: suitable protective
(EN 14605) gloves, safety goggles and protective clothing including
appropriate safety shoes

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Respiratory protection (EN : When respiratory risks cannot be avoided or sufficiently

143, 14387) limited by technical means of collective protection or by
measures, methods or procedures of work organization,
consider the use of certified respiratory protection equipment
meeting EU requirements (89/656/EEC, (EU) 2016/425), or
equivalent, with filter type:P

Environmental exposure controls

General advice : Consider the provision of containment around storage
vessels.

Section: 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Appearance : Liquid

Colour : colourless
Odour : odourless
Flash point :
does not flash
pH : > 13, 100 %

Odour Threshold : no data available

Melting point/freezing point : Freezing Point: -3 °C
Initial boiling point and boiling : no data available
range
Evaporation rate : no data available
Flammability (solid, gas) : no data available
Upper explosion limit : no data available
Lower explosion limit : no data available
Vapour pressure : no data available
Relative vapour density : no data available
Relative density : 1.09 - 1.12
Solubility(ies)
Water solubility : completely soluble
Solubility in other solvents : no data available
Partition coefficient: n- : no data available
octanol/water
Auto-ignition temperature : no data available
Thermal decomposition : no data available
Viscosity, dynamic : no data available
Viscosity, kinematic : no data available
Explosive properties : no data available
Oxidizing properties : no data available

9.2 Other information

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no data available

Section: 10. STABILITY AND REACTIVITY

10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : No dangerous reaction known under conditions of normal use.

10.4 Conditions to avoid

10.5 Incompatible materials
Materials to avoid : Strong acids
Mild steel
Aluminium

10.6 Hazardous decomposition products

Hazardous decomposition : Depending on combustion properties, decomposition products
products may include following materials:
Carbon oxides
nitrogen oxides (NOx)
Sulphur oxides
Oxides of phosphorus

Section: 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Information on likely routes of : Inhalation, Eye contact, Skin contact

exposure

Toxicity

Product
Acute oral toxicity : There is no data available for this product.
Acute inhalation toxicity : There is no data available for this product.
Acute dermal toxicity : There is no data available for this product.
Skin corrosion/irritation : There is no data available for this product.

Serious eye damage/eye : There is no data available for this product.

irritation

Respiratory or skin : There is no data available for this product.

sensitization

Carcinogenicity : No component of this product present at levels greater

than or equal to 0.1% is identified as probable, possible

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or confirmed human carcinogen by IARC.

Reproductive effects : No toxicity to reproduction

Germ cell mutagenicity : Contains no ingredient listed as a mutagen

Teratogenicity : There is no data available for this product.

STOT - single exposure : Based on available data, the classification criteria are
not met.
STOT - repeated exposure : There is no data available for this product.

Aspiration toxicity : No aspiration toxicity classification

Potential Health Effects

Eyes : Causes serious eye damage.

Skin : Causes severe skin burns.

Ingestion : Causes digestive tract burns.

Inhalation : May cause nose, throat, and lung irritation.

Chronic Exposure : Health injuries are not known or expected under normal
use.

Experience with human exposure

Eye contact : Redness, Pain, Corrosion

Skin contact : Redness, Pain, Corrosion

Ingestion : Corrosion, Abdominal pain

Inhalation : Respiratory irritation, Cough

Further information : no data available

Section: 12. ECOLOGICAL INFORMATION

12.1 Ecotoxicity

Product
Environmental Effects : This product has no known ecotoxicological effects.

Toxicity to fish : no data available

Toxicity to daphnia and other : no data available

aquatic invertebrates

Toxicity to algae : no data available

Components
Toxicity to daphnia and other : Sodium Hydroxide
aquatic invertebrates 48 h EC50: 40 mg/l

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12.2 Persistence and degradability

Product
Biodegradability : Greater than 95% of this product consists of inorganic
substances for which a biodegradation value is not
applicable.

Biodegradation Assessment : Greater than 95% of this product consists of inorganic

substances for which a biodegradation value is not
applicable.

Components
Biodegradability : Sodium Hydroxide
Result: Not applicable - inorganic

12.3 Bioaccumulative potential

Product
Bioaccumulation : This preparation or material is not expected to bioaccumulate.

Components
Bioaccumulation : Sodium Hydroxide
study scientifically unjustified

12.4 Mobility in soil

Product
This substance is water soluble and is expected to remain primarily in water.

12.5 Results of PBT and vPvB assessment

Product
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.

12.6 Other adverse effects

No adverse effects expected.

Section: 13. DISPOSAL CONSIDERATIONS

Dispose of in accordance with the European Directives on waste and hazardous waste.Waste codes should
be assigned by the user, preferably in discussion with the waste disposal authorities.

13.1 Waste treatment methods

Product : Where possible recycling is preferred to disposal or
incineration.
If recycling is not practicable, dispose of in compliance with

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local regulations.
Dispose of wastes in an approved waste disposal facility.

Contaminated packaging : Dispose of as unused product.

Empty containers should be taken to an approved waste
handling site for recycling or disposal.
Do not re-use empty containers.

Guidance for Waste Code : Inorganic wastes containing dangerous substances. If this
selection product is used in any further processes, the final user must
redefine and assign the most appropriate European Waste
Catalogue Code. It is the responsibility of the waste generator
to determine the toxicity and physical properties of the
material generated to determine the proper waste
identification and disposal methods in compliance with
applicable European (EU Directive 2008/98/EC) and local
regulations.

Section: 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in
compliance with the selected mode of transport.

Land transport (ADR/ADN/RID)

14.1 UN number: UN 1824
14.2 UN proper shipping name: SODIUM HYDROXIDE SOLUTION
14.3 Transport hazard class(es): 8
14.4 Packing group: II
14.5 Environmental hazards: No
14.6 Special precautions for user: Not applicable.

Air transport (IATA)

14.1 UN number: UN 1824
14.2 UN proper shipping name: SODIUM HYDROXIDE SOLUTION
14.3 Transport hazard class(es): 8
14.4 Packing group: II
14.5 Environmental hazards: No
14.6 Special precautions for user: Not applicable.

Sea transport (IMDG/IMO)

14.1 UN number: UN 1824
14.2 UN proper shipping name: SODIUM HYDROXIDE SOLUTION
14.3 Transport hazard class(es): 8
14.4 Packing group: II
14.5 Environmental hazards: No
14.6 Special precautions for user: Not applicable.
14.7 Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78 and the IBC
Code:

Section: 15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:

INTERNATIONAL REGULATIONS

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FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act
When use situations necessitate compliance with FDA regulations, this product is acceptable under: 21 CFR
173.310 Boiler Water Additives

Limitations: no more than required to produce intended technical effect. Steam produced may be used in
contact with any food type, defined under 21 CFR 170.3, which includes milk or milk products.

KOSHER
This product has been certified as KOSHER/PAREVE for year-round use EXCEPT FOR THE PASSOVER
SEASON by the CHICAGO RABBINICAL COUNCIL.

NSF NON-FOOD COMPOUNDS REGISTRATION PROGRAM (former USDA List of Proprietary

Substances & Non-Food Compounds):
NSF Registration number for this product is: 143887
This product is acceptable for treating boilers or steam lines where steam produced may contact edible
products and/or cooling systems where the treated water may not contact edible products in and around
food processing areas (G6).

INTERNATIONAL CHEMICAL CONTROL LAWS

United States TSCA Inventory

This product has not been evaluated for TSCA and may contain substances not found on the TSCA 8(b)
Inventory List. This product may be used under the TSCA 5(h)(3) Research Exemption if all requirements
are met.

NATIONAL REGULATIONS GERMANY

Water contaminating class : WGK 1
(Germany) Classification according to AwSV, Annex 1

15.2 Chemical Safety Assessment:

A Chemical Safety Assessment has been carried out for some of the substances in this mixture.

Section: 16. OTHER INFORMATION

Procedure used to derive the classification according to REGULATION (EC) No 1272/2008

Classification Justification
Corrosive to metals 1, H290 Calculation method
Skin corrosion 1A, H314 Calculation method
Serious eye damage 1, H318 Calculation method
Full text of H-Statements
H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.

Full text of other abbreviations

ADN – European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways; ADR – European Agreement concerning the International Carriage of Dangerous Goods by
Road; AICS – Australian Inventory of Chemical Substances; ASTM – American Society for the Testing of
Materials; bw – Body weight; CLP – Classification Labelling Packaging Regulation; Regulation (EC) No
1272/2008; CMR – Carcinogen, Mutagen or Reproductive Toxicant; DIN – Standard of the German Institute
for Standardisation; DSL – Domestic Substances List (Canada); ECHA – European Chemicals Agency; EC-
Number – European Community number; ECx – Concentration associated with x% response; ELx –
Loading rate associated with x% response; EmS – Emergency Schedule; ENCS – Existing and New
Chemical Substances (Japan); ErCx – Concentration associated with x% growth rate response; GHS –

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Globally Harmonized System; GLP – Good Laboratory Practice; IARC – International Agency for Research
on Cancer; IATA – International Air Transport Association; IBC – International Code for the Construction
and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 – Half maximal inhibitory
concentration; ICAO – International Civil Aviation Organization; IECSC – Inventory of Existing Chemical
Substances in China; IMDG – International Maritime Dangerous Goods; IMO – International Maritime
Organization; ISHL – Industrial Safety and Health Law (Japan); ISO – International Organisation for
Standardization; KECI – Korea Existing Chemicals Inventory; LC50 – Lethal Concentration to 50 % of a test
population; LD50 – Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL – International
Convention for the Prevention of Pollution from Ships; n.o.s. – Not Otherwise Specified; NO(A)EC – No
Observed (Adverse) Effect Concentration; NO(A)EL – No Observed (Adverse) Effect Level; NOELR – No
Observable Effect Loading Rate; NZIoC – New Zealand Inventory of Chemicals; OECD – Organization for
Economic Co-operation and Development; OPPTS – Office of Chemical Safety and Pollution Prevention;
PBT – Persistent, Bioaccumulative and Toxic substance; PICCS – Philippines Inventory of Chemicals and
Chemical Substances; (Q)SAR – (Quantitative) Structure Activity Relationship; REACH – Regulation (EC)
No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals; RID – Regulations concerning the International Carriage of
Dangerous Goods by Rail; SADT – Self-Accelerating Decomposition Temperature; SDS – Safety Data
Sheet; TCSI – Taiwan Chemical Substance Inventory; TRGS – Technical Rule for Hazardous Substances;
TSCA – Toxic Substances Control Act (United States); UN – United Nations; vPvB – Very Persistent and
Very Bioaccumulative

Further information
Sources of key data used to : IARC Monographs on the Evaluation of the Carcinogenic Risk
compile the Safety Data of Chemicals to Man, Geneva: World Health Organization,
Sheet International Agency for Research on Cancer.

The possible key literature references and data sources which

may have been used in conjunction with the consideration of
expert judgment to compile this Safety Data Sheet: European
regulations/directives (including (EC) No. 1907/2006, (EC) No.
1272/2008), supplier data, inter-net, ESIS, IUCLID, ERIcards,
Non European official regulatory data and other data sources.

Prepared By : Regulatory Affairs

Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1
tenth and 0.001 = 1 thousandth

REVISED INFORMATION: Significant changes to regulatory or health information for this revision is
indicated by a bar in the left-hand margin of the SDS.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information
and belief at the date of its publication. The information given is designed only as a guidance for safe
handling, use, processing, storage, transportation, disposal and release and is not to be considered a
warranty or quality specification. The information relates only to the specific material designated and
may not be valid for such material used in combination with any other materials or in any process, unless
specified in the text.

Annex: Exposure Scenarios

Exposure Scenario: Boiler treatment under 1T per day

Life Cycle Stage : Industrial uses: Uses of substances as such or in preparations at industrial
sites

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Sector of use : SU23 Electricity, steam, gas water supply and sewage treatment

Contributing scenario controlling environmental exposure for:

Environmental release category : ERC4 Industrial use of processing aids in processes and products,
not becoming part of articles

Daily amount per site : 1000 kg

Type of Sewage Treatment : none

Plant

Contributing scenario controlling worker exposure for:

Process category : PROC15 Use as laboratory reagent

Exposure duration : 60.00 min

Operational conditions and risk : Indoor

management measures

Local Exhaust Ventilation with 90% efficiency is required

General ventilation Ventilation rate per hour: 1

Skin Protection : Yes: See Section 8

Respiratory Protection : No

Contributing scenario controlling worker exposure for:

Process category : PROC1 Use in closed process, no likelihood of exposure

Exposure duration : 60 min

Operational conditions and risk : Indoor

management measures

Local Exhaust Ventilation is not required

General ventilation Ventilation rate per hour: 1

Skin Protection : Yes: See Section 8

Respiratory Protection : No

Contributing scenario controlling worker exposure for:

Process category : PROC8a Transfer of substance or preparation (charging/ discharging)

from/ to vessels/ large containers at non-dedicated facilities

Exposure duration : 15 min

Operational conditions and risk : Indoor

management measures

Local Exhaust Ventilation is not required

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General ventilation Ventilation rate per hour: 1

Skin Protection : Yes: See Section 8

Respiratory Protection : No

Contributing scenario controlling worker exposure for:

Process category : PROC28 Manual maintenance (cleaning and repair) of machinery

Exposure duration : 240 min

Operational conditions and risk : Indoor

management measures

Local Exhaust Ventilation is not required

General ventilation Ventilation rate per hour: 1

Skin Protection : Yes: See Section 8

Respiratory Protection : No

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