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    Poll - C-09 (20 Ques.)

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    Mahalaksshmi .D

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    Poll - C-09 (20 Ques.)

    Uploaded by

    Mahalaksshmi .D
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    Poll_C-09 (20 Ques.)

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    Poll - C-09 (20 Ques.)

    Uploaded by

    Mahalaksshmi .D

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    © All Rights Reserved
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    Corp. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Ph.

    011-47623456

    Poll
    CHEMISTRY (C-09)
    Syllabus: Amines

    Choose the correct answer:


    1. Which among the following is an allylamine?
    (1) CH2 = CH – NH2
    (2) CH2 = CH – CH2 – NH2 (3)
    (3) CH3 – CH = CH – NH2
    (4) HC ≡ C – CH2 – NH2
    2. The increasing order of basic character of given
    (4)
    compounds in aqueous medium is
    (1) (CH3CH2)3N < (CH3CH2)2NH < CH3CH2NH2 <
    NH3
    (2) CH3CH2NH2 < NH3 < (CH3CH2)2NH < 4. Bromine water reacts with aniline to give
    (CH3CH2)3N CC-439
    (1) 2-Bromoaniline
    (3) NH3 < CH3CH2NH2 < (CH3CH2)3N <
    (CH3CH2)2NH (2) 4-Bromoaniline
    (4) (CH3CH2)2NH < CH3CH2NH2 < CH3CH2)3N <
    (3) 2,4-Dibromoaniline
    NH3
    3. Consider the following reaction given below (4) 2,4,6-Tribromoaniline
    5. Benzenediazonium chloride on reaction with
    ( CH3CO )2 O Br2 phenol in basic medium majorly gives
    
    →A → B
    Pyridine CH3COOH (Major product)
    (1) p-aminoazobenzene
    The product (A) and (B) respectively are
    (2) p-hydroxyazobenzene
    (3) p-aminohydrazobenzene
    (4) p-hydroxyhydrazobenzene
    (1)
    6. Which among the following amines liberate N2 gas
    when treated with nitrous acid?
    (1) CH3CH2CH2CH2NH2
    (2) CH3CH2 – NH – CH2 – CH3
    (2)

    (3)

    (4)

    [Page 1]
    Poll-09 Chemistry
    7. Consider the following statements (III) Aniline reacts with con. H2SO4 to form
    anilinium hydrogensulphate
    Statement-I: Hinsberg’s reagent reacts with
    ethylamine to yield N-ethylbenzenesulphonyl Choose the correct statement(s)
    amide.
    (1) (I) and (II) only (2) (I), (II) and (III)
    Statement-II: N-ethylbenzenesulphonamide is
    insoluble in alkali. (3) (I) and (III) only (4) (II) and (III) only
    In the light of above statements, choose the 12. Consider the following reaction
    correct option.
    (1) Both statement-I and statement-II are correct
    (2) Statement-I is correct but statement-II is
    incorrect
    (3) Both statement-I and statement-II are
    incorrect
    (4) Statement-I is incorrect but statement-II is
    correct
    Major product (B) and (C) respectively are
    8. Benzenediazonium chloride is reduced to
    benzene in presence of (1) N-ethylphthalimide and butanamine

    (1) Nitric acid (2) N-ethylphthalamine and N-ethylthamine


    (2) Water (3) N-ethylphthalimide and ethanamine
    (3) Hypophosphoric acid (4) N-ethylphthalamide and
    (4) Phosphinic acid N-methylmethanamine

    9. CH3CH2NH2 + CHCl3 + KOH → Nitrogen 13. Butanamide on treatment with bromine in an


    containing compound + KCl + H2O ethanolic solution of NaOH majorly gives

    Nitrogen containing compound is CC-439 (1) CH3CH2CH2–NH2


    (1) CH3 – NH – CH3 (2) CH3 – CH2 – C ≡ N (2) CH3CH2CH2CH2NH2
    (3) CH3–CH2–NH–CH3
    (3) CH3CH2 – N ≡ C (4) (4) CH3CH2–NH–CH2CH3
    14. The correct order of solubility of the given
    10. Given below are two statements one is labelled as compound is
    Assertion (A) other is labelled as Reason (R).
    (1) (CH3)3N > (CH3CH2)2NH > CH3CH2CH2NH2
    Assertion (A) : Direct nitration of aniline yields
    significant amount of meta derivative. (2) CH3CH2NHCH3 > CH3CH2CH2NH2> (CH3)3N
    Reason (R) : In the strongly acidic medium, aniline (3) CH3CH2CH2NH2 > CH3CH2NHCH3 > (CH3)3N
    is protonated to form the anilinium ion.
    (4) CH3CH2NHCH3 > (CH3)3N > CH3CH2CH2NH2
    In the light of above statements, select the correct
    option 15. The following reaction
    (1) Both (A) and (R) are true and (R) is the correct
    explanation of (A).
    (2) Both (A) and (R) are true but (R) is not the
    correct explanation of (A).
    (3) (A) is true statement but (R) is false.
    is known as
    (4) Both (A) and (R) are false statements.
    11. Consider the following statements (1) Gatterman reaction
    (I) Aniline does not undergo Friedel-Crafts (2) Finklestein reaction
    reactions
    (3) Gatterman-koch reaction
    (II) pKb of aniline is lower than ammonia
    (4) Sandmeyer reaction

    [Page 2]
    Chemistry Poll-09
    16. The correct order of pKb value for the following 18. In the reaction
    compounds is

    The reagent ‘A’ is


    (1) H2O (2) H3PO2 and H2O
    (1) (III) > (I) > (II)
    (3) CH3CH2OH (4) KI
    (2) (I) > (II) > (III)
    (3) (II) > (I) > (III)
    19. The IUPAC name of is
    (4) (II) > (III) > (I)
    17. Consider the following reaction sequence (1) N-methylaniline
    (2) N,N-diethylaniline
    (3) N-methyl-N-phenylamine
    (4) N,N-dimethylbenzenamine
    20. Direct nitration of aniline yields

    The major product (C) is

    (1) (2)
    CC-439
    (1) 47% 51% 2%

    (2) 27% 51% 22%


    (3) (4)
    (3) 40% 40% 20%

    (3) 37% 61% 2%

      

    [Page 3]

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