Sample Paper 1

Class Xll 2024-25

Chemistry (043)
Time: 3 Hours Max. Marks: 70
GeneralInstructions:
There are 33 qucnstionsin this questionpaper with internal choice.
2, SECTION A consists of 16 multiple-choicequestions carrying 1 mark each.
SECTION B consists of 5 very short answer questions carrying 2 marks each,
SECTION C consists Of7 short answer questions carrying 3 Inarks each,
5. SECTIOND consistsof 2 case-basedquestionscarrying 4 marks each,
6, SECTIONE consistsOf3 long answerquestionscarrying 5 marks each,
7. All questionsare compulsory,
8. Use Oflog tables and calculators is not allowed,

SECTION-A

Directions(Q. Nos. 1-16) : The followingquestionsare multipÄhoicequestionswithonecorrectanswer.Each

questioncarries I mark. There is no internal choicein this section.

1. Order of reaction can be

(a) zero (b) fraction
(c) whole number (d) integer, fraction, zero

2. The complexes and are the examples ofwhich type of isomerism?

(a) Linkage isomerism (b) Ionisation isomerism
(c) Coordination isomerism (d) Geometrical isomerism

3. Match the followingconcentration units with their correct formulas:

Column A (Concentration Unit) Column B (Formula)
Molality mass of solute x 0
total mass of solution 10

B Molarity ii rnol€%s
of solute
volumeof solution(L)

c Normality gram equivalent weight of solute

Volumeof solution(L)

D Parts per million (ppm) Molesof solute

mass of solvent Kg

(a) A - iv13 -iii l) -i

(b)A-iB - iii D - iv
(c) A-iB - iii D - iv
(d)A-iB - iii D - iv
Page 2 CBSE Chemistry Class 12

4. Studythe graphshowingthe boilingpointsof carboxylicacids and identifythe Compounds:

450 410
390
400
350
300

150
100
50
3
CarboxylicAcids

(a) I = Aceticacid, 2 = Propionicacid,3 = Butyricacid,4 = Valerieacid

(b) I = Butyricacid, 2 = Valerieacid, 3 = Acetic acid, = Propionicacid
(c) I = Propionicacid,2 = Aceticacid,3 = Valerieacid, = Butyric acid
(d) I = Valerieacid,2 = Butyric acid,3 = Propionicacid, = Aceticacid

5. Colligativepropertiesof the solutiondependon:

(u) Nature of solute (b) Nature of solvent
(c) Numberof particlespresentin the solution (d) Number of molesof solventonly

6. The fuelusedin the cell usedin Apollomissionwas

(d) 02

7. The rate of a chemicalreaction

(u) increasesas the reaction proceeds (b) decreases as the reaction proceeds
(c) may incretuseor decreaseduring the reaction (d) remainsconstant the reactionproceeds

8. An exampleOfa cornpoundwith functionalgroup— IS

(a) Aceticacid (b) Methyl alcohol
(c) Diethyl ether (d) Acetone

9. Acetamideis treated with the followingreagents separately,Which one of these wouldyieldmethylamine?

(a) NaOH-13r2 (b) Sodalime
(c) Hot con. H (d) PCL

10. In hydrogen-oxygenfuel cell, combustionof hydrogen occursto

(u) produce high purity water
(b) create potential difference between two electroclcns
(c) generate heat
(d) removeabsorbedoxygen from electrodesurfaces

11. YVhichOfthe followingis a disaccharide?

(a) Lactose (b) Starch
(c) Cellulose (d) Fructose
 Page 3

12. Whichreagentcannotbe usedto preparean alkylhalidefroman alcohol?

(a) HCI +ZnC12 (b) NaC1
(c) PCI% (d) SOCL

Directions (Q. Nos. 13-16): Eachof the followingquestionsconsistsof twostatements,one is Assertionand the other
is Reason. Give answer :

13. Assertion: Benzenediazoniumsalt on boilingwith waterformsphenol.

Reason : C-N bond is polar.
(a) Both Assertionand Reasonare correct and Reasonis a correct explanationof the Assertion.
(b) Both Assertionand Reasonare correct but Reasonis not the a correct explanationof the Assertion,
(c) Assertionis correct but Reasonis incorrect.
(d) Both the Assertionand Reasonare incorrect.

14. Assertion: In acidicmedium, exists as (orange)whilein basic mediumit is converted

to Crof- (yellow).
Assertion: is hygroscopicin nature and changescolouron reactionwith water.
(a) Both Assertionand Reasonare correct and Reasonis a correct explanationof the Assertion,
(b) Both Assertionand Reasonare correct but Reasonis not the a correct explanationof the AKsertion.
(c) Assertionis correct but Reasonis incorrect.
(d) Both the Assertionand Reasonare incorrect.

15. Assertion : (NHJ)SIdoes not show optical isomerism.

Reason : It has a plane of symmetry.
(n) Both Assertionand Reasonare correct and Reasonis a correct explanationof the Assertion,
(b) Both Assertionand Reasonare correct but Reasonis not the a correct explanationof the Assertion.
(c) Assertionis correct but Reasonis incorrect.
(d) Both the Assertionand Reasonare incorrect.

16. Assertion: Benzenediazoniurnchloridedoesnot givetest for nitrogen,

Reason : Lcxssof N2gas takes place during heating.
(a) Both Assertionand Reasonare correct and Reasonis a correct explanationof the Assertion,
(b) Both Assertionand Reasonare correct but Reasonis not the a correct explanationof the Assertion,
(c) Assertionis correctbut Reasonis incorrect.
(d) Both the Assertionand Reasonare incorrect.

SECTION-B

Directions (Q. Nos. 17-21) : This sectioncontains 5 questionswith internal choice in one question.The following
questions are very short answer type and carry 2 marks each.

17. DefineOrder Ofa reaction. IlltLstrateyour answerwith an example.

OR
What are complexreactions?Name one complexreaction.
Page 4 CBSE Chemistry 12

18. What is salt bridge? What are its us€\S?

19. Why the properties of third transition series are very Similar to second transition series?

20. Howwill you convert Phenol to benzene?

21. What are reducing and non reducing sugars?

SECTION-C

Directions (Q. Nos. 22-28) : This sectioncontains questions with internal choice in one question.The fbllowing
questions are short answer type and carry marks each.

22. Derive the structure of cyclohex-3-en-1-ol.

23. State colligativeproperties of dilute solution, Write down the different types of colligative properties.

24. Write the followingreactions OfBenzene cliazoniumchloride,

(i) Sandmeyer reaction
(ii) Gatterman reaction
OR
Wlint,do you mean by invert sugar?

25. Explain rnagnetic behaviour of transition metals,

26. Draw the structure of all isomericalcohols of molecular formula C0110()and give their IUPAC names,

27. What are the common types of secondary (20) structure of proteins?

28. (i) Define the followingterms:

(a) Enantiomers
(b) Racemie mixture
Why is chlorobenzene resistant to nucleophiliesubstitution reaction?

SECTION-D

Directions (Q. Nos. 29-30) : The followingquestions are case4)aseclquestions. Each question has an internal choice
and carries marks each. Read the passage carefully and answer the questions that follow.

29. Carbohydrates are polyhydroxy aldehydes and and those compounds which on hydrolysis
give such compounds are also carbohydrates, The carbohydrates which are not hydrolysed are called
monosaccharides, Monosaccharide; with aldehydic group are called aldose and those which free ketonic
groups are called ketose, Carbohydrates are optically active, Number Ofoptical isomers = ,
 Page 5

Where n — numberOfasymmetriccarbons.Carbohydratcns are mainly synthesisedby plants during

The
photosynthesis. monosaccharides
give the characteristicreactionsOfalcoholsand carbonylgroup
(aldehydes and ketones). It has been found that these monosaccharidesexist in the form of cyclic structures.
In cyclization,the —OH groups(generally or in aldohexose*; and ('5or Coinketohexos€\s)
combine
with the aldehydeor ketogroup.As a result,cyclicstructuresof fiveor six memberedringscontaining
one oxygenatom are formed,e.g., glucoseformsa ring structure.Glucosecontainsone aldehydegroup,
One10 alcoholicgroupand four20alcoholicgroupsin its OpenchainStructure.
Answerthe followingquestions:
(a) What is the name the first merrlber Ofketose sugar?
(b) Howmany optical isomersare present in ?
(c) Write the reaction Ofglucosewith hydroxylamine.
OR
(d) Howmany molesof acetic anhydrideare neededfor acetylationof glucose?What does it confirm?

30. A solutioncontaining30 g of non-volatilesoluteexactlyin 90 g of water has a vapourpreeasureof 2.8 K

Pa at 298k Further 18 g of water is added to this solution,The new vapour pressurebecomes2.9 k Pa
at 298K Whena non-volatilesoluteis addedto a solvent,the surfacehas moleculesof soluteand solvent
both. Thus, the numberof moleculesof solventpresentin upper surfaceis less. The nurnberof solvent
moleculesescapingfrom the surfaceis reduced
Answerthe followingquestions:
Write downthe expressionfor relativeloweringof vapourprcnssure with the mole fractionof the
solute,
(b) Calculate the vapour pressure of water at 298 K.
(c) Find out the molecularmass of solute?
OR
(d) Name two factors on which the vapour pressure of the liquid depends.

SECTION-E

Directions (Q. Nos. 31-33) : The followingquestions are long answer type and carry 5 marks each. All questions have
an internal choice.

31. Give two reactions that show the acidic nature OfPhenol, Compare its acidity with that Ofethanol,
OR
Write equationsOfthe followingreactions:
Friedel-Craft 's reaction-alkylation Of anisole,
2, Nitration Ofanisole,
3, Bromiantion Ofanisole in ethanolic acid medium,
4, Friedel-Crafts acetylation Of anisole ,

32. (a) Differentiate between Osmosis and diffusion. How is osmotic pressure determined by Berkeley-
Hartlay method?
(b) 18 g Ofgluccxse was added to I kg water at 1.013bar atmospheric pressure in a vessel,
At which temperature will water boil? KbFor water is 0.52 K Kg mol¯l

Continue on next page....

Page 6 CBSE Chemistry Class 12

OR
(a) What do you mean by the term 'elevation of boiling point' ?
(b) State Raoult's law. How is it useful in determining the molecular weight of non-electrolyte solute?

33. Arrange the compounds of each set in order of reactivity towards SN2 displacement:
2-13romo-2-methylbutane
(b) 1-13romopentane
2-13romopentane
(a) I-Bromobutane-3-rnethylbutane
(b) 2-13rorno-2-methylbutane
2-Brorno-3-rnethylbutane
(iii) Bromobutane
(b) I-Bromo-2, 2-dirnethylpropane
(c) I-Bromo-2-methylbutane
(d) I-Bromo-g-methylbutane,
OR
Write the structure of the major organic product in each of the followingreaction :
1, CH3CH2CH2Cl+Na1
2, (CH3)3CBr+ KOH
3, CH3CH (BC) Na0H
+ KCN
CH3C112Br
5. C211bC1

6, -F SOC12

8, CH%CH = C (CH:02 +