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Advanced Organic Assignments (4)

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jlk;u Ik=-5

Answers of
GENERAL
REACTION
Assignment-
IUPACORGANIC
&
-1
ISOMERISM
GENERAL
MECHANISM
CHEMISTRY
CHEMISTRY
04 jlk;u Ik=-1
-4
-3
-2
ORGANIC CHEMISTRY ADVANCED

Head Office -: Rasayanam Tower, Opp. Jwalapur Railway Station, Haridwar / Branch Office -: 33 Saket, Roorkee, (U.K)
09
,

, ,
10
Assignment - 18

O
h

& &

&
&
Assignment - 21
ORGANIC CHEMISTRY ADVANCED

Q. Which Resonating structure is more stable?

Head Office -: Rasayanam Tower, Opp. Jwalapur Railway Station, Haridwar / BranchOffice -: 33, Saket, Roorkee(U.K)
II

II

II
Arrange the following in Acid Character
Q.1 CH3SO3H CH3COOH CH3CH2COOH H2O CH3OH

Q.2

Q.3

Q.4

Q.5 HClO4 CH3COOH CF3COOH CH3OH H2O

Q.6

Q.7 H2CO3 CH3SO3H CH3COOH C2H5OH H2O


Q.8 Picric acid Squaric acid CH3SO3H H2O

Q.9

CH CH
Q.10

Q.11 CH≡CH CH2=CH2 NH3 CH3OH H 2O

Q.12

Q.13
I

Q.14

COOH COOH COOH COOH


Q.15
Ac2NH

Ph2NH
23

O
24
25
Assignment 26

(1)

(2)

(3)

(4)

(5)

(6)

(7)

(8)

(9)

(10)

(11)
Assignment 26

(12)

(13)

(14)

(15)

(16)

(17)

(18)
Assignment 26

(19)

(20)

(21)

(22)

(23)

(24)

(25)

(26)
213
Assignment 27
Assignment 27
27
Assignment 28
Assignment 28
Assignment 28
28
Nucleophility, Leaving group, Basicity Arrangements
1 OH SH SeH (Nu )
2 OH SH SeH (Nu in

(Nu )
3
N
N

4 (Basic Nature)
N
N

5 CH3COO CF3COO CF3SO3 (L.G.)


6 CH3COO CF3COO CF3SO3 (Nu )

7 F Cl Br I (L.G.)
8 F Cl Br DMSO)
I (Nu )
9 F Cl Br I (Nu in Acetone)

10 F Cl Br I (Basic Nature)
11 OH N3 Br PhO (Nu )
12 Cl F ROH H2O (Nu )
13 SH I OH N3 (Nu )
14 NH2 CH3 NH3 (Nu )

15 CH3OH CH3 O (Nu )


O

16 CH3SO3 PhO (L.G.)


NO2
17 B
18 NH3 NH2 Ph2 (Nu )
19 OTs CH3COO OH (L.G.)
20 CN I OH Br (Nu )
21 NH2 Ph2 AsH2 SbH2 (Nu )
22 NH2 Ph2 AsH2 SbH2 (Nu in DMSO)
23 NH2 NH2 NH2
CH3
(B.C)
CH3

24 CH COOH HOOC C H
CF3SO3H (A.C)
CH COOH H C COOH

OH OH OH OH
NO2
25
NO2
NO2
Q. Arrange in order of Rate of SN1 reaction
2

Cl

Cl
21

22

23

24

25 Cl
31

21

22

23

24

25 Cl
2
31

21

22

23

24

25 Cl
3 1 4 2
(b)

(a)

(c) (d)

(e) (f)

(g) (h)

(i) (j)

(k) (l)

(n)
(m)

(o) (p)

(q) (r)

(s) (t)
Assignment 32
(Epoxides / Ether + HI)

(u)
(v)

(w) (x)

(y) (z)
32

3 1 4 2
Assignment 33 (Elimination)

Cl Br Br

Cl Br Br
Assignment 34 (Grignard)

(a) (b) (c) (d)

(b)
(a)

(c)
(d)

(e) (f )

(g) (h)

(j)
(i)

(k)
(l)

(m)
(n)
Assignment 34 (Grignard)

(o)

(p) (q)

Cl Br Br

(r)
(s)

Cl Br Br

(t) (u)

(v)
(w)

(x)

(y)

(z)
32
Answers of Assignment 34

3 1 4 2
32
Answers of Assignment 34

3 1 4 2
Assignment 35 (Grignard)

(o)

(p) (q)

Cl Br Br

(r)
(s)

Cl Br Br

(t) (u)

(v)
(w)

(x)

(y)

(z)
32
Answers of Assignment 35

3 1 4 2

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