Lecture 3 (AIU)
Lecture 3 (AIU)
Lecture 3
At higher pressures, the use of the ideal gas equation-of-state may lead to errors as great as 500%, as
compared to errors of 2–3% at atmospheric pressure.
Basically, the magnitude of deviations of real gases from the conditions of the ideal gas law increases with
increasing pressure and temperature and varies widely with the composition of the gas.
Numerous equations-of-state have been developed in the attempt to correlate the pressure-volume-
temperature variables for real gases with experimental data. In order to express a more exact relationship
between the variables p, V, and T, a correction factor called the gas compressibility factor, z-factor, which is a
dimensionless quantity was introduced:
𝑷𝑽 = 𝒛𝒏𝑹𝑻
The gas compressibility factors for natural gases of various compositions
can be generalized with sufficient accuracies for most engineering
purposes when they are expressed in terms of the following two
dimensionless properties using Kay’s mixing rules :
• Pseudo-reduced pressure, Ppr
• Pseudo-reduced temperature, Tpr
𝑷 𝑻
𝑷𝒑𝒓 = 𝑻𝒑𝒓 =
𝑷𝒑𝒄 𝑻𝒑𝒄
𝑷 𝟑𝟎𝟎𝟎
𝑷𝒑𝒓 = = = 𝟒. 𝟓𝟎
𝑷𝒑𝒄 𝟔𝟔𝟔. 𝟏𝟖
𝑻 𝟏𝟖𝟎 + 𝟒𝟔𝟎
𝑻𝒑𝒓 = = = 𝟏. 𝟔𝟕
𝑻𝒑𝒄 𝟑𝟖𝟑. 𝟑𝟖
Step 2. Determine the z-factor from Figure 2-1 according to the steps shown in the previous example, to give: z = 0.85
Step 3. Calculate the density of the real gas mixture:
𝑷𝑴𝒂 𝟑𝟎𝟎𝟎 ∗ 𝟐𝟎. 𝟐𝟑
𝝆𝒈 = = = 𝟏𝟎. 𝟒 𝒍𝒃/𝒇𝒕𝟑
𝒛𝑹𝑻 𝟎. 𝟖𝟓 ∗ 𝟏𝟎. 𝟕𝟑 ∗ 𝟔𝟒𝟎
EFFECT OF NONHYDROCARBON COMPONENTS ON THE Z-FACTOR
Natural gases frequently contain materials other than hydrocarbon components, such as nitrogen, carbon
dioxide, and hydrogen sulfide. Hydrocarbon gases are classified as sweet or sour depending on the hydrogen
sulfide content. A hydrocarbon gas is termed a sour gas if it contains one gram of H2S per 100 cubic feet.
Concentrations of up to 5 % of nonhydrocarbon components will not seriously affect accuracy. Errors in
compressibility factor calculations as large as 10 % may occur in higher concentrations of nonhydrocarbon
components in gas mixtures.
Katz Correlation for the compressibility factor is extended by Wichert and Aziz for the gas containing H2S and
CO2 to get on account this difference. Wichert and Aziz introduce a new term a “critical temperature
adjustment factor,” Ɛ, which is proportional to the concentrations of H2S and CO2 in the sour gas.
𝑻′𝒑𝒄 = 𝑻𝒑𝒄 − 𝜺
𝑷𝒑𝒄 . 𝑻𝒑𝒄 ′
𝑷𝒑𝒄 ′ =
𝑻𝒑𝒄 + 𝑩(𝟏 − 𝑩)𝜺
where Tpc = pseudo-critical temperature, °R ppc = pseudo-critical pressure, psia
T′pc = corrected pseudo-critical temperature, °R p′pc = corrected pseudo-critical pressure, psia
ε = pseudo-critical temperature adjustment
After calculation of the corrected value of the pseudo critical pressure and temperature value, we need to
calculation the corresponding reduced values.
𝑷
𝑷𝒑𝒓 =
𝑷𝒑𝒄
Finally you can read the Z factor from the regular standing and Katz chart (above chart).
Example
A sour natural gas has a specific gravity of 0.7. The compositional analysis of the gas shows that it contains
5% CO2 and 10% H2S. Calculate the density of the gas at 3,500 psia and 160°F
Step 1. Calculate the uncorrected pseudo-critical properties of the gas from Equations 2-18 and 2-19:
Step 2. Calculate the pseudo-critical temperature adjustment factor from Equation 2-24:
𝑷 𝟑𝟓𝟎𝟎
𝑷𝒑𝒓 = = = 𝟓. 𝟓𝟓
𝑷′𝒑𝒄 𝟔𝟑𝟎. 𝟒𝟒
𝑻 𝟏𝟔𝟎 + 𝟒𝟔𝟎
𝑻𝒑𝒓 = = = 𝟏. 𝟔𝟖
𝑻′𝒑𝒄 𝟑𝟔𝟖. 𝟔𝟒
Step 6. Determine the z-factor from Figure 2-1, to give: z = 0.89
➢ Then Calculate the pseudo-critical temperature and pressure for the presence of N2 and H2O in
the gas mixture.
𝑻′𝒑𝒄 −𝟐𝟐𝟕.𝟐 𝒚𝑵𝟐 −𝟏,𝟏𝟔𝟓 𝒚𝑯𝟐 𝑶
𝑻′′
𝒑𝒄 = + 𝑻𝒑𝒄,𝒄𝒐𝒓
𝟏 − 𝒚𝑵𝟐 − 𝒚𝑯𝟐 𝑶
After calculation of the corrected value of the pseudo critical pressure and temperature value, we need to
calculation the corresponding reduced values. 𝑷 𝑻
𝑷𝒑𝒓 = 𝑻𝒑𝒓 =
𝑷′′𝒑𝒄 𝑻′′𝒑𝒄
Finally you can read the Z factor from the regular standing and Katz chart (above chart).
CORRECTION FOR HIGH-MOLECULARWEIGHT GASES
The relationships for calculating pseudocritical pressure and temperature Kay’s mixing rules , result in
unsatisfactory z-factors for high-molecular-weight reservoir gases. The large deviations occur to gases with
high heptanes-plus (C7+) concentrations.
Kay’s mixing rules should not be used to determine the pseudo-critical pressure and temperature for
reservoir gases with specific gravities > 0.75. This deviation can be minimized by utilizing the mixing rules,
together with newly introduced empirical adjustment factors.
➢ ISOTHERMAL GAS COMPRESSIBILITY COEFFIECIENT
Knowledge of the variability of fluid compressibility with pressure and temperature is essential in performing
many reservoir engineering calculations. For a liquid phase, the compressibility is small and usually assumed
to be constant. For a gas phase, the compressibility is neither small nor constant.
The isothermal gas compressibility, Cg (psi-1) is the change in volume per unit volume for a unit change in pressure :
𝟏 𝟏 𝝏𝒛
𝒄𝒈 = −
𝑷 𝒛 𝝏𝑷 𝑻
𝝏𝒛 𝟏
For an ideal gas, z = 1 and = 𝟎 , therefore: 𝒄𝒈 =
𝝏𝑷 𝑻 𝑷
Solution
𝑷 𝟐𝟎𝟎𝟎
𝑷𝒑𝒓 = = = 𝟐. 𝟗𝟗
𝑷𝒑𝒄 𝟔𝟔𝟖. 𝟒
𝑻 𝟏𝟒𝟎 + 𝟒𝟔𝟎
𝑻𝒑𝒓 = = = 𝟏. 𝟓𝟐
𝑻𝒑𝒄 𝟑𝟗𝟓. 𝟓
𝒄𝒑𝒓 𝟎. 𝟑𝟔
𝒄𝒈 = = = 𝟎. 𝟎𝟎𝟎𝟓𝟑𝟗 𝒑𝒔𝒊−𝟏
𝑷𝒑𝒄 𝟔𝟔𝟖. 𝟒
➢ GAS FORMATION VOLUME FACTOR
The gas formation volume factor (Bg) is used to relate the volume of gas, as measured at reservoir
conditions, to the volume of the gas as measured at standard conditions, i.e., 60°F and 14.7 psia.
This gas property is then defined as the actual volume occupied by a certain amount of gas at a specified
pressure and temperature, divided by the volume occupied by the same amount of gas at standard conditions.
𝑽𝑷,𝑻
𝑩𝒈 =
𝑽𝒔𝒄
For real gases, where Psc =14.7 psia, Tsc = 520, zsc (z-factor at standard conditions) = 1.0
𝒇𝒕𝟑 𝒛𝑻 𝑴𝒂
𝑩𝒈 = 𝟎. 𝟎𝟐𝟖𝟐𝟕 = 𝟎. 𝟎𝟎𝟐𝟔𝟑𝟓
𝒔𝒄𝒇 𝑷 𝝆𝒈
𝒃𝒃𝒍 𝒛𝑻 𝑴𝒂
𝑩𝒈 = 𝟎. 𝟎𝟎𝟓𝟎𝟑𝟓 = 𝟎. 𝟎𝟎𝟎𝟒𝟔𝟗
𝒔𝒄𝒇 𝑷 𝝆𝒈
𝑷𝑴𝒂
𝝆𝒈 =
𝑹𝑻
𝒏𝑹𝑻𝒔𝒄 𝟏 . 𝟏𝟎. 𝟕𝟑𝟎 . (𝟔𝟎 + 𝟒𝟔𝟎)
𝑽𝒔𝒄 = = = 𝟑𝟕𝟗. 𝟒 𝒇𝒕𝟑
𝑷𝒔𝒄 𝟏𝟒. 𝟕
𝑷𝑽 = 𝒛 𝒏𝑹𝑻
➢ GAS EXPANSION FACTOR
The reciprocal of the gas formation volume factor is called the gas expansion factor and is designated by the
symbol Eg,
𝒔𝒄𝒇 𝑷 𝝆𝒈
𝑬𝒈 = 𝟑𝟓. 𝟑𝟕 = 𝟑𝟕𝟗. 𝟓𝟐
𝒇𝒕𝟑 𝒛𝑻 𝑴𝒂
𝒔𝒄𝒇 𝑷 𝝆𝒈
𝑬𝒈 = 𝟏𝟗𝟖. 𝟔 = 𝟐𝟏𝟑𝟏. 𝟎
𝒃𝒃𝒍 𝒛𝑻 𝑴𝒂
Solution
Step 1. Calculate Tpc and ppc
Step 5. Calculate the gas flow rate in scf/day by dividing the gas flow rate (in ft3/day) by the gas
formation volume factor Bg as expressed in scf/ft3:
𝑽𝑷,𝑻
𝑩𝒈 =
𝑽𝒔𝒄
𝒇𝒕𝟑൘
𝒔𝒄𝒇 𝑽𝑷,𝑻 𝒅𝒂𝒚 𝟏𝟓, 𝟎𝟎𝟎 𝒔𝒄𝒇
𝑮𝒂𝒔 𝒇𝒍𝒐𝒘 𝒓𝒂𝒕𝒆 = 𝑽𝒔𝒄 = = = 𝟐𝟐𝟔𝟕𝟓𝟕𝟒 = 𝟐. 𝟐𝟔𝟖 𝑴𝑴𝒔𝒄𝒇/𝒅𝒂𝒚
𝒅𝒂𝒚 𝑩𝒈 𝟎. 𝟎𝟎𝟔𝟔𝟏𝟓 𝒅𝒂𝒚
➢ GAS VISCOSITY
The viscosity of a fluid is a measure of the internal fluid
friction (resistance) to flow due to the internal friction
between the molecules. It the resistance to the flow of a
fluid.
(μg/μ1) = 1.5
𝝁𝒈 = 𝟏, 𝟓 ∗ 𝝁𝟏 = 𝟏. 𝟓 ∗ 𝟎. 𝟎𝟏𝟏𝟑 = 𝟎. 𝟎𝟏𝟔𝟗𝟓 𝒄𝒑
End of Lecture 3