SAFETY DATA SHEET DIURON 80 WDG

SDS NUMBER: 000648-15-LPI SDS REVISIONS: FORMAT DATE OF ISSUE: 02/03/15 SUPERSEDES: 10/16/14

FOR CHEMICAL EMERGENCY, SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT, CALL CHEMTREC - DAY OR NIGHT 1-800-424-9300

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER

1.1 PRODUCT IDENTIFIER:
TRADE NAME: DIURON 80 WDG WEED KILLER
1.2 RECOMMENDED USE: HERBICIDE – NOT FOR HOME USE
1.3 SUPPLIER DETAILS:
LOVELAND PRODUCTS, INC.
P.O. Box 1286 • Greeley, CO 80632-1286
1.4 24 Hour Emergency Phone: 1-800-424-9300 - Medical Emergencies: 1-866-944-8565 – Product Information: 1-888-574-2878 (LPI-CUST)
U.S. Coast Guard National Response Center: 1-800-424-8802

2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
Classification according to 29 CFR 1910.1200
Acute Toxicity – Oral Category 4 H302
Acute Toxicity – Dermal Category 4 H312
Eye Damage/Irritation Category 2B H320

2.2 Label elements

Signal word: WARNING

Hazard Statement: H302 – Harmful if swallowed.
H312 – Harmful in contact with skin.
H320 – Causes eye irritation.
Precautionary
Statement: P260 – Do not breathe dust/fume/gas/mist/vapors/spray.
P262 – Do not get in eyes, on skin, or on clothing.
P264 – Wash thoroughly after handling.
(Prevention): P270 – Do not eat, drink or smoke when using this product.
P280 – Wear protective gloves/eye protection/face protection.
P102 – Keep out of reach of children.

Precautionary
Statement: P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P330 – Rinse mouth.
P302+P312: IF ON SKIN: Call a POISON CENTER or doctor/physician if you feel unwell.
P352 – Wash with soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy
to do. Continue rinsing.
(Response): P101 – If medical advice is needed, have the product container or label at hand.
P362 – Take off contaminated clothing and wash before reuse.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337 – If eye irritation persists: Get medical advice/attention.
P362 – Take off contaminated clothing and wash before reuse.
P370 – In case of fire: Use dry chemical, carbon dioxide, foam, water spray or fog to extinguish.
P391 – Collect spillage.
Precautionary
Statement:
(Storage): P420 – Store away from other materials.

2.3 Other hazards

None known.

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 SAFETY DATA SHEET DIURON 80 WDG
SDS NUMBER: 000648-15-LPI SDS REVISIONS: FORMAT DATE OF ISSUE: 02/03/15 SUPERSEDES: 10/16/14

3. COMPOSITION, INFORMATION ON INGREDIENTS

3.1 Substances

3.2 Mixtures

Classification according to 29 CFR 1910.1200

Chemical Name: CAS No. Concentration

[%]
Diuron 330-54-1 80.00

*Inert ingredients n/a 20.00

*Ingredients not specifically listed are non-hazardous or are to be considered proprietary or confidential business information per 29 CFR 1910.1200(i)

4. FIRST AID MEASURES

4.1 Description of First Aid Measures
General Advice: Get medical attention if symptoms occur.

If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5
minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
If swallowed: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow.
Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to an
unconscious person.
If on skin or clothing: Take of contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or
doctor for treatment advice.
If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably
mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice.

4.2 Most Important Symptoms and Effects, Acute and Delayed

Symptoms: Eyes: Causes eye irritation.
Oral: Harmful if swallowed.
Dermal: Harmful in contact with skin.
4.3 Immediate Medical Attention and Special Treatment

Treatment: Treat symptomatically. Symptoms may be delayed.

FOR A MEDICAL EMERGENCY INVOLVING THIS PRODUCT CALL: 1-866-944-8565
Take container, label or product name with you when seeking medical attention.

NOTES TO PHYSICIAN: Treat symptomatically.

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 SAFETY DATA SHEET DIURON 80 WDG
SDS NUMBER: 000648-15-LPI SDS REVISIONS: FORMAT DATE OF ISSUE: 02/03/15 SUPERSEDES: 10/16/14

5. FIRE FIGHTING MEASURES

5.1 EXTINGUISHING MEDIA:
Suitable Extinguishing Media: Use medium appropriate to surrounding fire. Dry chemical, carbon dioxide (CO2), alcohol foam, foam,
water spray or fog.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
Specific Hazards During Firefighting: Oxides of nitrogen and other unknown hazardous material may be formed in a fire situation. Oxides of
carbon and/or other asphyxiants may be formed from incomplete combustion.
5.3 SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS
Special Protective Equipment for Firefighters: Self-contained breathing apparatus and full protective gear should be worn in fighting large fires
involving chemicals. Use water spray to keep fire exposed containers cool. Keep people away. Isolate
fire and deny unnecessary entry.

6. ACCIDENTAL RELEASE MEASURES

6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
Personal Precautions: Respiratory protection is not normally required, if dusts or mists exceed acceptable levels, wear a
NIOSH approved respirator with cartridges and dust pre-filters for pesticides. Wear suitable protective
clothing.
6.2 ENVIRONMENTAL PRECAUTIONS
Environmental Precautions: Do not apply directly to water, or to areas where surface water is present or to intertidal areas below
the mean high water mark. Do not contaminate water when disposing of equipment wash waters.
6.3 METHODS AND MATERIALS FOR CONTAINMENT AND CLEAN-UP
Methods for Clean-Up: Control the spill at its source. Sweep up material and place in a container for possible land application
according to label use or for proper disposal. Check local, state and federal regulations for proper
disposal.
Never return spills to original containers for re-use.

7. HANDLING AND STORAGE

7.1 PRECAUTIONS FOR SAFE HANDLING:
Advice on Safe Handling: Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. Remove clothing
immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. Remove PPE
immediately after handling this product. Wash the outside of gloves before removing. As soon as
possible, wash thoroughly and change into clean clothing.
7.2 CONDITIONS FOR SAFE STORAGE:
Requirements for Storage Areas and Containers: Store product in original container only, away from other pesticides, fertilizer, food or feed. Do not
contaminate water, food or feed by storage or disposal.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS
U.S. Workplace Exposure Level (ACGIH) TLVs
Components Type Value
3
Diuron TLV 10 mg/m

U.S. Workplace Exposure Level (OSHA) PELs

Components Type Value
3
Particulates (PNOC**) TLV 15 mg/m (total dust)

Biological limit values

ACGIH Biological Exposure Indices
Components Value Specimen

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 SAFETY DATA SHEET DIURON 80 WDG
SDS NUMBER: 000648-15-LPI SDS REVISIONS: FORMAT DATE OF ISSUE: 02/03/15 SUPERSEDES: 10/16/14

8.2 EXPOSURE CONTROLS:

Engineering Measures
When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets with requirements listed in the Worker Protection Standard
(WPS) for agricultural pesticides [40CFR 170.240 (d)(4-6)], the handler PPE requirements may be reduced or modified as specified in the WPS.
Individual Protection Measures:
Eye / Face Protection: Goggles or shielded safety glasses are recommended.
Skin Protection: Long-sleeved shirt and long pants. Chemical-resistant gloves. Shoes plus socks.
Respiratory Protection: Not normally required, if dusts or mists exceed acceptable levels, wear a NIOSH approved respirator with cartridges
and dust pre-filters for pesticides. If respirators are used, a program should be in place to assure compliance with 29
CFR 1910.134, the OSHA Respiratory Protection standard. Wear air supplied respiratory protection if exposure
concentrations are unknown.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 APPEARANCE : Granules
ODOR: Virtually none.
ODOR THRESHOLD: No data available.
COLOR: Beige.
pH: 8.5 (1% solution).
MELTING POINT / FREEZING POINT: No data available
BOILING POINT: No data available
FLASH POINT: Does not flash.
FLAMMABILILITY (solid, gas): No data available.
UPPER / LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: No data available.
VAPOR PRESSURE: Not applicable.
SOLUBILITY: Disperses.
PARTITION CO-EFFICIENT, n-OCTANOL / WATER: No data available.
AUTO-IGNITION TEMPERATURE: No data available.
DECOMPOSITION TEMPERATURE: No data available.
VISCOSITY: No data available.
SPECIFIC GRAVITY (Water = 1): 0.48 – 0.64 g/ml
3 3
BULK DENSITY: 30 - 40 lbs./ft / 480 - 640 kg/m
Note: These physical data are typical values based on material tested but may vary from sample to sample.
Typical values should not be construed as a guaranteed analysis of any specific lot or as specification items.
10. STABILITY AND REACTIVITY
10.1 REACTIVITY
Stable
10.2 CHEMICAL STABILITY
Stable under normal temperature conditions
10.3 POSSIBILITY OF HAZARDOUS REACTIONS
No data available. Will not polymerize.
10.4 CONDITIONS TO AVOID
Excessive heat and moisture.
10.5 INCOMPATIBILE MATERIALS
Strong acids.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS
Oxides of nitrogen and other unknown hazardous material may be formed in a fire situation. Oxides of carbon and/or other asphyxiants may be formed
from incomplete combustion.

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 SAFETY DATA SHEET DIURON 80 WDG
SDS NUMBER: 000648-15-LPI SDS REVISIONS: FORMAT DATE OF ISSUE: 02/03/15 SUPERSEDES: 10/16/14

11 TOXICOLOGICAL INFORMATION
11.3 LIKELY ROUTES OF EXPOSURE
Eye contact. Skin absorption. Skin contact.
LC50 (rat): > 2.03 mg/L (4 HR)(similar product)
LD50 Oral (rat): 1,879 mg/kg (similar product)
LD50 Dermal (rat): > 5,000 mg/kg
Acute Toxicity Estimates: No data available
Skin Irritation (rabbit): Mild irritant.
Eye Irritation (rabbit): Causes moderate eye irritation.
Specific Target Organ Toxicity: Eyes, skin, resp sys, blood.
Aspiration: No data available
Skin Sensitization (guinea pig): Not a sensitizer
Carcinogenicity: ACGIH TLV-A4 (Not Classifiable as a Human Carcinogen).
Germ Cell Mutagenicity: No data available
Interactive Effects: None known

12 ECOLOGICAL INFORMATION
12.3 ECOTOXICITY
Ecotoxicological Data
Species Test Results______________________________
No data available.

Drift or runoff may adversely affect non-target plants.

Do not apply directly to water.
Do not contaminate water when disposing of equipment wash water.
Do not apply when weather conditions favor drift from target area.

12.2 PERSISTENCE AND DEGRADABILITY

Biodegradability: No data available.
12.3 BIOACCUMULATIVE POTENTIAL
Bioaccumulation: No data available.
12.4 MOBILITY IN SOIL
No data available.
12.5 OTHER ADVERSE EFFECTS
Assessment: No data available.

13 DISPOSAL CONSIDERATIONS
13.1 WASTE TREATMENT METHODS
Open dumping is prohibited. Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal
facility. Completely empty bag into application equipment. Then dispose of empty bag in a sanitary landfill or by incineration, or, if allowed by
State and local authorities, by burning. If bag is burned, stay out of smoke. Do not contaminate water, food or feed by storage or disposal.

14 TRANSPORT INFORMATION
14.3 LAND TRANSPORT
DOT Shipping Description: NOT REGULATED BY DOT
U.S. Surface Freight Classification: COMPOUND, TREE OR WEED KILLING, NOI (NMFC 50320, SUB 2: CLASS: 60)

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 SAFETY DATA SHEET DIURON 80 WDG
SDS NUMBER: 000648-15-LPI SDS REVISIONS: FORMAT DATE OF ISSUE: 02/03/15 SUPERSEDES: 10/16/14

15 REGULATORY INFORMATION
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS

NFPA & HMIS Hazard Ratings: NFPA HMIS

2 Health 0 Least 2 Health
0 Flammability 1 Slight 0 Flammability
0 Instability 2 Moderate 0 Reactivity
3 High F PPE
4 Severe
SARA Hazard Notification/Reporting
SARA Title III Hazard Category: Immediate __Y__ Fire __N__ Sudden Release of Pressure __N__
Delayed __Y__ Reactive __N__

Reportable Quantity (RQ) under U.S. CERCLA: Diuron (CAS: 330-54-1) 100 pounds.
SARA, Title III, Section 313: Diuron (CAS: 330-54-1) 80.0%
RCRA Waste Code: Not listed.
CA Proposition 65: WARNING: This product contains chemicals known to the State of California to cause cancer or birth defects or other reproductive
harm.

This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements
under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and
for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:

CAUTION
Harmful if swallowed.
Causes moderate eye irritation.
Harmful if absorbed through skin.
Avoid contact with eyes, skin or clothing.

16 OTHER INFORMATION
SDS STATUS: Format revised.
PREPARED BY: Registrations and Regulatory Affairs REVIEWED BY: Environmental Health and Safety
EPA REG. NO.: 34704-648

Disclaimer and Limitation of Liability: This data sheet was developed from information on the constituent materials identified herein and does not
relate to the use of such materials in combination with any other material or process. No warranty is expressed or implied with respect to the
completeness or ongoing accuracy of the information contained in this data sheet, and LOVELAND PRODUCTS, INC. disclaims all liability for reliance
on such information. This data sheet is not a guarantee of safety. Users are responsible for ensuring that they have all current information necessary to
safely use the product described by this data sheet for their specific purpose.

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