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    2018DFJGCHBBDI

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    2018DFJGCHBBDI

    Uploaded by

    souravmishra2304
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    3 views3 pages

    2018DFJGCHBBDI

    Uploaded by

    souravmishra2304

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    © All Rights Reserved
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    CHEMISTRY (Hons.

    ) PAPER-III(A), 2018
    GROUP-A
    1 Describe Law ofcorresponding state and derive reduced equation ofstate.
    2. Explain the following terms:
    (a) Viscocity (b) Refractive index
    (c) Liquid crystal (d) Theory of dispersion
    3. (a) Describe the Theory of Bragg's Method of crystal analysis.
    (b) Write note on Bravis Lattices.
    (a) Distinguish between lyophilic and lyophobic colloids.
    (b) Explain Coagulation.
    GROUP-B
    Write notes on the following:
    (a) Carnot cycle
    (b) Application of Gibbs-Helmholtz equation
    6. Describe the concept of Entropy. From the second law of
    show that entropy is state function.
    thermodynamics,
    1. Derive the Clapeyron-Clausius equation
    giving the temperature
    dependence of water pressure indicating clearly the assumption involve.
    8. Explain the following termsS
    (a) Ostwald's dilution Law (b) Commonion effect
    (c) lonic product of water
    GROUP-C
    9. Write notes on the following:
    (a) Enzyme Catalysis (b) Auto Catalysis
    (c) Honmogencous and Hetrozeneous
    Catalysis
    the Kinetic of hydrolysis of Ethyl acetate in Acids medu
    (a) Discuss
    (b) Activation Energy. ion
    1. Derive expression for rate constant
    an of bi-molecular gaseous reacion
    on the basis of Collision Theory.
    tne
    conductivity. EstabIisn
    .Derine cquivalent molecular and specific
    relation between them.
    CHEMISTRY (Hons.) PAPER-II(B), 2018
    GROUP-A of
    (a)State and explain De. Broglieequation for wave particles duality
    electrons.
    (b) Discuss the verification of De. Broglie relation.
    &
    Predict the geometry of the following with the help of Hybridization
    VSEPR theory.
    (a) BF, (b) SF (c)IF, (d) 1
    ) NH,
    for complexes ?
    3. (a) What are the basic postulates of valence bond theory
    following
    (6) Give the Stereo chemistry and magnetic properties of the
    [Ni(CN).l [co(CN),
    4. Explain the following:
    (a) Hydroxides and oxides of metals are insoluble in liquid NH,.
    solvent
    b) Liquid Amonia is not good electrolytic solvent but is good
    for non-polar molecule.
    (c) Auto ionization of liquid NH, and liquid SO,.
    (d) Blue colour solution in liquid NH, is paramagnetic but bronze colour
    solution is diamagnetic.
    GROUP-B
    5. Explain the following:
    (a) All the noble gases are diamagnetic
    b) The Radius of noble gas is the highest in a series
    (c) Inert gas hydrate is not a true chemical compounds
    All inert gases are mono-atomic
    d)
    6. Discuss the chemistry of Titanium with respect to the following
    (a) Position in P. T. (b) Oxidation states
    (c) Complex formation (d) Acid-Base nature its compounds
    Discuss the salient features of transition metals with respect to the
    following:
    (a) Position in P. J. (b) Variable oxidation states
    (c) Magnetic properties (d) Catalytic properties
    Give reasons for the following:
    (a) Diamond and Graphite have widely different physical property.
    (b) Sicily hydrolysis but ccl, does not
    (c) HO exists in iiquid state but H,S exists in gaseous state
    d) cO. exists in gaseous state While Silicon dioxide exists in solid state.
    GROUP-C
    9. What the practical application of i.r. to explain the colour of
    are
    complexes ?
    10. Discuss the application of any twoofthe following reagents in Inorganic
    analysis.
    (a) E. D. T. A. (b) a-Nitroso-ß-Naphthal
    (c) Cupferron
    11. Explain the theory of solubility product and common ion effect in the
    group separation of metal ion in inorganic qualitative analysis.
    12. Discuss the chemistryinvolved in the manufacture of Cement or Glases

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