Consortium of Medical Engineering and Dental

Colleges of Karnataka
(COMEDK-2007)
CHEMISTRY

61. During the extraction of gold the following reactions take place -
0 2 _.(X]
Au +CN- +H2 0-�
[X) +Zn� [Y] + Au

r
X and Y are respectively -
2 3 2
1) [Au(CN)2 and[Zn(CN\] - 2) [Au(CN)4 ] - and[Zn(CN)4] -

2
3) [Au(CN) ] - and[Zn(CN\] �
4
2
4) [Au(CN)2 r and[Zn(CN)6]
4
-

62. The number of gram molecules of chlorine in 6.02 x 10 25 hydrogen chloride molecules ·
lS -
1) 5 2) 50
3) 100 4) 10

63. Graphite is a soft solid lubricant extremely difficult to melt. The reason for this anomalous
behaviour is that graphite -
1) has molecules of variable molecular inasses like polymers.
2) has carbon atoms arranged in large plates of rings of strongly bound carbon
atoms with weak interplate bonds.
3) is a non-crystalline substance.
4) is an allotropic form of carbon.

64. Paracetamol is a / an
· 1) antimalarial 2) antipyretic
3) analgesic 4) both 2 and 3

65. Which one of the following has maximum number of atoms of oxygen ?
1) 2 g of water 2) 2 g of sulphur dioxide
3) 2 g of carbon dioxide 4) 2 g of carbon monoxide.
 66. Which one of the following shows functional isomerism ?
2) CzH50H
4) CzH4

. 67. In the ionic equation - Bi 03 + 6H + + Xe- � Bi 3 + + 3H20,

. .

the values of Xis -

1) 3 2) 4
3) 2 4) 6
. .

68. Molarity of a given orthophosphoric acid solution is 3M. It's normality is -

1) 1 N 2) 3 N.
3) 0.3 N 4) 9 N

69. Acidified sodium fusion extract on addition of ferric chloride solution gives blood red
colouration which confirms the presence of -
1) S 2) N
3) N andS 4) Sand Cl

. 70. A body of mass 10 mg is moving with a velocity of 100 ms- 1. The wavelength of de-Broglie
wave associated with it would be -
(Note: h=6.63xlo-34 Js)

1) 6.63 X 10-37 m 2) 6.63xI0-31m

3) 6.63xI0- 34m 4) 6.63xI0-35m

71. Mg 2+ is isoelectronic with

1) Ca 2+ 2) Na
+

3) zn 2+ 4) Cu 2 +

72. Gram molecular volume of oxygen at STP is -

1) 11200 cm 3 2) 22400 cm3
3) 5600 cm3 4) 3200 cm 3

73. · Presence of halogen in organic compounds can be detected using -

1) Beilstien's test 2) kjeldahl test
3) Duma's test 4) Leibig's test

74. The electronic configuration of Cr 3+ is

1) [Ar ]3d 5 4s 1 2) [Ar ]3d 2 4s 1

3) [Ar]3d 3 4s 0 4) [Ar ]3d 4 4s 2

75. The mass of a metal, with equivalent mass 31.75, which would combine with 8 g of oxygen
IS
1) 31.75 2) 3.175
3) 8 4) 1
76. Benzene reacts with chlorine in sunlight to give a final product - .
1) C6H5Cl
3) C6H6Cl6

77. In the periodic table metals usually. used as catalysts belong to

1) s - block 2) p - block
3) d - block 4) f - block

78. Dalton's law of partial pressures is applicable to which one of the following systems ?
1) CO+H2 2) H2 +Cl2
3) N0+02 4) NH3 +HCl

79. The general formula of a cycloalkane is

1) CnH2n+2
3) CnH2n

80. In acetylene molecule, between the carbon atoms there are -

1) three sigma bonds 2) two sigma and one pi bonds
3) one sigma and two pi bonds 4) three pi bonds
81. Denatured alcohol is
1) Rectified spirit
2) Undistilled ethanol
3) Rectified spirit + methanol + naphtha
4) Ethanol + methanol

82. During the formation of a chemical bond

1) energy decreases
2) energy mcreases
3) energy of the system does not change
4) electron-electron repulsion becomes more than the nucleq.s-electron attraction

83. One mole of oxygen at 273 k and one mole of sulphur dioxide at 546 k are taken in two
separate containers, then,
1) kinetic energy of 02 > kinetic energy of S02 .
2) kinetic energy of 02 < kinetic energy of S02 .
3) kinetic energy of both are equal.
4) None of these

84. +I effect is shown by

1) -N02 2) -Cl
3) -Br 4) -CH3

85. Formation of coloured solution is possible when metal ion in the compound contains
1) paired electrons 2) unpaired electrons
3) lone pair of electrons 4) none of these
86. Which of the following is an intensive property ?
1) temperature 2) surface tension
3) viscosity 4) all of these

87 .. Hofmann's bromamide reaction is to convert

. 1) amine to amide 2) amide to amine
3) alcohol to acid 4) acid to alcohol

88. IUPAC name of Na3 [Co(N02)6] is

,1) sodium cobaltinitrite 2) sodium hexanitrito cobaltate (Ill)
3) sodium hexanitro cobalt (Ill) 4) sodium hexanitrito cobaltate (II)

89. Thermodynamic standard conditions of temperature and pressure are

1) o0 c and 1 atm 2) 273 k and 101.3 k Pa
3) 298 k and 1 atm 4) o 0 c and 101.3 k Pa
90. How many chiral carbon atoms are present in 2, 3, 4 - trichloropentane ?
1) 3 2) 2
3) 1 4) 4
91. The number of lIDidentate ligands in the complex ion is called
1) EAN 2) Coordination number
3) primary valency 4) oxidation number

92. 2S0z(g) + Oz(g) ==== is an example for

V205

1) irreversible reaction 2) heterogenous catalysis

3) homogenous catalysis 4) neutralisation reaction

93. The amino acid which is not optically active is

1) glycine 2) alanine
3) serine 4) lactic acid

94. For a stable molecule the value of bond order must be

1) negative
2) positive
3) zero
4) there is no relationship between stability and bond order.

95. Which one of the following is a second order reaction ?

1) CH3COOCH3 +NaOH �CH3COONa +HzO

2) Hz + Clz sunlight 2HCl

4) Hz +Brz�2HBr
96. According to Bayer's strain theory which is highly stable ?
1) cyclohexane 2) cycloheptane
3) cyclopentane 4) cyclobutane

97. The number of antibonding electron pairs in o�- molecular ion on �he basis of molecular
orbital theory is
[Note - Atomic number of O is 18]
1) 2 2) 3,,
3) 4 4) 5

98. Hydroxyl ion concentration of lM HCl is

1) lx10-14mol dm-3

99. Geometrical isomerism is shown by

1) -C-C- 2) -C -i:C -
3) �C =C� 4) None of these

100. The oxidation state of iron in K4[Fe(CN)6] is,

1) 2 · 2) 3

3) 4 4) 1
101. In which of the following process, a maximum increase in entropy is observed?
1) dissolution of salt in water 2) · condensation of water
3) sublimation of naphthalene 4) melting of ice

102. Decompositio_n of benzene diozonium chloride by using Cu2Cl2 I HCZ to form

chlorobenzene is
1) Cannizarro's reaction 2) Kolbe's reaction
3) Sandmeyer's reaction 4) Raschig's reaction

103. Which complex can not ionise in solution?

1) [pt(NH3)6]cz4 2) K2 [pt(F6)]

3) K4[Fe(CN)6] 4) [C0Cl3 (NH3 )3]

104. Considering the reaction C(s) +02(g) ➔C02(g)+393.5 kJ the signs of Ml, 6S and t:i.G
respectively are
1) - ' + ,-. 2) - ' - ' -
3) - ' + ' + 4) +' - ' -
105. The product formed when hydroxylamine condenses with a carbonyl compound is called
1) hydrazone 2) hydrazine
3) oxime 4) hydrazide
106. Which of the following forms a colourless solution in aqueous medium?
1) Ti 3+ 2) Sc 3+

3) V 3+ 4) Cr 3+

107. When a sulphur sol is evaporated sulphur is obtained. On mixing with water sulphur sol
is not formed. The sol is
1) hydrophilic 2) hydrophobic
3) reversible .4) lyophilic

108. An alkyl halide reacts with alcoholic ammonia in a sealed tube, the product formed
will be
1) a primary amine 2) a secondary amine
3) a tertiary amine 4) a mixture of all the three

109. When cone. H2S04 is heated with P2 05, the acid is converted into
1) sulphur
2) sulphur dioxide
3) sulphur trioxide
4) a mixture of sulphur dioxide and sulphur trioxide

110. Entropy of the universe is

1) continuously increasing 2) continuously decreasing
3) zero 4) constant
111. Which of the following salts on being dissolved in water gives pH> 7 at 25°c ?

112. The reagent used in Clemmenson's reduction is

1) ale. KOH 2) aq. KOH
3) Zn -Hg I con. HCl 4) Cone. H2S04

113. When KBr is dissolved in water, K+ ions are

1) oxidised 2) reduced
3) hydrolysed 4) hydrated

114. The noble gas mixture is cooled in a coconut bulb at 173 K. ':{'he gases that are not
adsorbed are
1) He and Ne 2) Ar and Kr
3) He and Xe 4) Ne and Xe

115. The volume of lON and 4N HCl required to make 1 litre of 7N HCl are
1) 0.75 litre of lON HCl and 0.25 litre of 4N HCl
2) 0.80 litre of 10N HCl and 0.20 litre of 4N HCl
3) 0.60 litre of lON HCl and 0.40 litre of 4N HCl
4) o:50 litre of lON HCl and 0.50 litre of 4N HCl
116. A metal present in insulin is
1) copper 2) iron
3) zmc 4) aluminium

117. Carbon forms two oxides which have different compositions. The equivalent mass of
which remains constant ?
1) carbon 2) oxygen
3) neither carbon nor oxygen 4) both carbon and oxygen

118. Maximum number of molecules of CH3/that can react with a molecule of CH3NH2 are
1) 1 2) 2
3) 4 4) 3
119. Ellingham diagram represents a graph of
1) !).GVsT 2) /lGo Vs T
3) $VsP 4) !).GVsP

120. Identify the ore not containing iron

1) chalcopyrites 2) carnallite
3) siderite 4) limonite