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    carbon black

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    carbon black

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    Proceeding of IMECE2006-15671

    2006 ASME International Mechanical Engineering Congress


    Chicago Illinois, November 5-10, 2006

    IMECE2006-15671

    ESTIMATION OF TEMPERATURE AND RESIDENCE TIME


    OF CARBON BLACK OIL FURNACE INDUSTRIAL REACTORS

    1,2 1 1 1 2
    A. Javadi , M. Soltanieh , S. Sahebdelfar D . Bastani , and K. Javadi

    1- Department of Chemical and Petroleum Engineering, Sharif University of Technology, Tehran,


    P.O. Box, 11365-9465, Iran

    2- Aerospace Research Institute, Ministry of Science and Research and Technology,


    Tehran, P. O. Box, 15875-3885, Iran

    ABSTRACT

    Keywords: carbon black, oil-furnace reactor, soot formation,


    pyrolysis, combustion

    INTRODUCTION
    CALCULATION METHODOLOGY
    Total Process Air Flow) =2.315 kg/s=0.0803 kmol/s,
    (Air/fuel) =27.873, and (Air/Feedstocks) =3.622,
    , Fuel = 0.083 kg/s=0.0048 kmol/s
    Considering a typical natural gas composition of 90%
    methane and 10% Ethane, M w ), oil = 0.639 kg/s =
    0.00213 kmol/s,

    w wa b

    w .

    C H aO bCO cCO dH eH O

    c e

    c
    ESTIMATION OF CARBON YIELD

    Mwf

    Fef

    ENERGY BALANCE: Estimation Of Temperature


    1- Energy input with the process air
    Q air m a c p T Air

    ma cp
    T

    2- Heat generation by combustion of fuel


    Q fuel m fu H u fuel
    mfu Hu

    3- Incomplete combustion of burned oil

    4- Energy consumption for vaporization of oil from inlet


    temperature.

    T
    Qoil V T dT Q
    T

    5- Energy consumption for pyrolyis oil


    Referring to

    H reac kcal mol

    6- Total energy balance

    Q mc p T
    m cp
    Q

    ESTIMATION OF RESIDENCE TIME

    Vg =16.9 m3/sec
    Residence Time (t) = (Vo/Vg ) = 13.4 ms.
    Table 6.

    Table 7.

    Table 8.

    RESULTS AND DISCUSSION

    Comparison of Results with CFD Simulation


    E P
    N C Mf
    T t Fsf

    Mf Fef M wf

    Mwf
    PPS-L- prsent predicted
    55 PPS-L-CFD Predicted
    PPS-S-Industrial Data
    PPS-S-Present Predicted
    PPS-B-Typical Practical Data
    50
    PRIMARY PARTICLE SIZE( nm )

    45

    40

    35

    30

    25

    3 4 5 6 7 8
    AIR/OIL

    Fig 6:
    CONCLUSIONS

    Combustion and Flame 117

    ACKNOWLEDGMENTS

    REFERENCES

    Carbon
    (carbon black)

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