2 Redox Reaction

For NSEC 2024

EXERCISE # 1
GENERAL INTRODUCTION OF CHEMISTRY & CHARACTERISTICS OF CHEMICAL
REACTIONS
1. Which of the following statements is/are true?
(A) The total mass of the system remains same in a chemical change
(B) A chemical change is permanent and irreversible
(C) A physical change is temporary and reversible
(D) All of these
2. Which of the following statements is/are correct?
(A) A chemical equation tells us about the substances involved in a reaction.
(B) A chemical equation informs us about the symbols and formulae of the substances involved in a
reaction.
(C) A chemical equation tells us about the atoms or molecules of the reactants and products involved in
a reaction.
(D) All are correct

3. Match the column-I with column-II and select the correct option from the codes given below:
Column-I Column-II
a. Expansion of metals on heating. i. Neither physical nor chemical change
b. A stone kept in the sunlight ii. Chemical change
c. Burning of a candle iii. Combination of physical and chemical changes
d. Curdling of milk iv. Physical change
(A) a-iv, b-i, c-iii, d-ii (B) a-iv, b-iii, c-ii, d-i
(C) a-i, b-ii, c-iii, d-iv (D) a-i, b-iv, c-ii, d-iii

4. Select the correct statement among the following.

(A) Crystallization is a chemical change (B) Digestion of food is a chemical change
(C) Burning of paper is a temporary change (D) A reversible change is always chemical

5. Read the given statements and select the correct option.

Statement-1: Breaking of a bone china plate is a physical change
Statement-2: When a bone China plate breaks, the pieces can be joined to get back the original plate.
(A) Both statements 1 and 2 are true and statement-2 is the correct explanation statement-1.
(B) Both statements 1 and 2 are true but statement-2 is not the correct explanation statement-1.
(C) Statement-1 is true and statement-2 is false.
(D) Both Statement-1 is true and statement-2 is false.

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6. The reaction between aqueous solutions of sodium chloride and silver nitrate is –
(A) displacement reaction (B) synthesis reaction
(C) double displacement reaction (D) analysis reaction

7. CH4 + Cl2 ⎯→ CH3Cl + HCl reaction is an example of -

(A) Synthetic (B) Analytical (C) Displacement (D) Neutralisation

8. A Brown and bright element “x” when heated in presence of air turns into black substance “y”. If
Hydrogen gas is passed over this heating material again “x” is obtained. “x” and “y” are –
(A) Cu & CuO (B) S & SO2 (C) C & CO2 (D) Na & NaH
9. Which of the following is endothermic reaction?
(A) C(s) + O2(g) ⎯→ CO2(g) (B) N2(g) + O2(g) ⎯→ 2NO(g)
(C) 2H2(g) + O2(g) ⎯→ 2H2O(l) (D) 2CH3OH (l) + 3O2(g) ⎯→ 2CO2(g)+4H2O(l)

10. When a burning splinter is brought near the gas jar containing hydrogen gas a popping sound is observed.
It is ___________ reaction.
(A) exothermic (B) endothermic
(C) exothermic and endothermic (D) none of these
CHEMICAL EQUATIONS & BALANCING
1. In the balanced equation -
aFe2O3 + bH2 ⎯→ cFe + dH2O
The values of a, b, c, d are respectively -
(A) 1, 1, 2, 3 (B) 1, 1, 1, 1 (C) 1, 3, 2, 3 (D) 1, 2, 2, 3

2. Which of the following reactions is not balanced?

(A) 2NaHCO3 ⎯→ Na2CO3 + H2O + CO2 (B) 2C4H10 + 12O2 ⎯→ 8CO2 + 10H2O
(C) 2Al + 6H2O ⎯→ 2Al(OH)3 + 3H2 (D) 4NH3 + 5O2 ⎯→ 4NO + 6H2O

3. The equation - Cu + xHNO3 → Cu(NO3)2 + yNO2 + 2H2O

The values of x and y are -
(A) 3 and 5 (B) 8 and 6 (C) 4 and 2 (D) 7 and 1

4. In the reaction FeSO4 + x → Na2SO4 + Fe(OH)2 , x is –

(A) Na2SO4 (B) H2SO4 (C) NaOH (D) none of these

5. In the reaction xPb (NO3)2 → yPbO + zNO2 + O2 x, y and z are -

(A) 1,2,2 (B) 2,2,4 (C) 1,2,4 (D) 4,2,2

6. In balancing the reaction.

xH2S + 2NaNO3 + 2HCl → y S + zNO + kNaCl + 4H2O one would get x, y, z and k, respectively, as
(A) 3, 3, 2 and 2 (B) 2, 2, 3 and 3 (C) 3, 3, 4 and 4 (D) 4, 4, 3 and 3
REDOX REACTIONS & OXIDATION NUMBER

1. In the reaction Mg + Cl2 → MgCl2 Magnesium may be regarded as -

(A) an oxidizing agent (B) a reducing agent
(C) a catalyst (D) providing an inert medium
2. When the gases sulphur dioxide and hydrogen sulphide react, the reaction is
SO2 + 2H2S → 2H2O + 3S
Here hydrogen sulphide is acting as -
(A) an oxidizing agent (B) a reducing agent (C) a dehydrating agent (D) a catalyst

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3. Which of the following statements is correct for oxidation reaction?
(A) Gain or addition of electronegative radical or element
(B) Removal of hydrogen atom
(C) Removal or loss of electropositive radical or element
(D) All the above statements are correct.
4. CuO + H2 ⎯→ H2O + Cu, reaction is an example of -
(A) redox reaction (B) synthesis reaction (C) neutralisation (D) analysis reaction

5. Which of the following is an example of oxidation reaction?

(A) Sn+2 – 2e– →Sn+4 (B) Fe+3 + e– → Fe+2 (C) Cl2 + 2e– → 2Cl– (D) None of these
6. In the process of burning of magnesium in air, magnesium undergoes -
(A) reduction (B) sublimation (C) oxidation (D) all of these

7. A substance which oxidizes itself and reduces other is known as -

(A) an oxidizing agent (B) a reducing agent (C) Both of these (D) None of these

8. Oxidation is a process which involves -

(A) addition of oxygen (B) removal of hydrogen
(C) loss of electrons (D) All are correct

9. In the reaction PbO + C → Pb + CO.

(A) PbO is oxidized (B) C acts as oxidizing agent.
(C) C acts as a reducing agent. (D) This reaction does not represent a redox reaction.

10. A redox reaction is one in which -

(A) both the substances are reduced.
(B) both the substances are oxidized.
(C) an acid is neutralised by the base.
(D) one substance is oxidized, while the other is reduced.

11. Which of the following is not an example of redox reaction?

(A) CuO + H2 ⎯→ Cu + H2O (B) Fe2O3 + 3CO ⎯→ 2Fe + 3CO2
(C) 2K + F2 ⎯→ 2KF (D) BaCl2 + H2SO4 ⎯→ BaSO4 + 2HCl

12. When KMnO4 acts as an oxidizing agent and ultimately forms MnO42–, MnO2, Mn2O3 and Mn2+, then the
number of electrons transferred in each case is:
(A) 4, 3, 1, 5 (B) 1, 5, 3, 7 (C) 1, 3, 4, 5 (D) 3, 5, 7, 1

TYPES OF REDOX REACTIONS

1. Neutralization reaction is an example of -
(A) exothermic reaction (B) endothermic reaction
(C) oxidation reaction (D) none of these

2. Zn(s) + H2SO4(aq) ⎯→ ZnSO4(aq) + H2(g) is an example of -

(A) precipitation reaction (B) endothermic reaction
(C) evolution of gas (D) change in colour

3. When dilute hydrochloric acid is added to iron fillings -

(A) hydrogen gas and ferric chloride are produced.
(B) chlorine gas and ferric hydroxide are produced.
(C) no reaction takes place.
(D) iron salt and water are produced.

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4. Chemical reaction 2Na + Cl2 ⎯→ 2NaCl is an example of -
(A) combination reaction (B) decomposition reaction
(C) displacement reaction (D) double displacement reaction
5. Which of the following equations is representing combination of two elements?
(A) CaO + CO2 ⎯→ CaCO3 (B) 4Na + O2 ⎯→ 2Na2O
(C) SO2 + 1/2 O2 ⎯→ SO3 (D) 2Na + 2H2O ⎯→ 2NaOH + H2

6. Which of the following equations is not an example of single displacement reaction?

(A) 2Al + Fe2O3 ⎯→ Al2O3 + 2Fe (B) Ca + Cl2 ⎯→ CaCl2
(C) 2KI + Cl2 ⎯→ 2KCl + I2 (D) 2Na + 2H2O ⎯→ 2NaOH + H2
7. Which of the following is/are a decomposition reaction(s)?
(A) 2HgO ⎯→ 2Hg + O2 (B) CaCO3 ⎯→ CaO + CO2
(C) 2H2O ⎯→ 2H2 + O2 (D) All of these

8. Match the following -

Column-A Column-B
Types of chemical reaction Chemical equations
(a) Combination reaction (i) CaCO3 ⎯→ CaO + CO2
(b) Decomposition reaction (ii) 2H2O ⎯→ 2H2 + O2
(c) Displacement reaction (iii) CaO + CO2 ⎯→ CaCO3
(d) Analysis reaction (iv) Fe(s) +CuSO4 (aq.) ⎯→ FeSO4 (aq) + Cu(s)
(A) a (ii), b (i), c (iv), d (iii) (B) a (i), b (ii), c (iii), d(iv)
(C) a (iii), b (i), c (iv), d (ii) (D) a (iii), b (i), c (iii), d (iv)

9. Which of the following reactions is/are a double displacement reaction(s)?

(i) AgNO3 + NaBr ⎯→ NaNO3 + AgBr (ii) BaCl2 + H2SO4 ⎯→ BaSO4 + 2HCl
(iii) As2O3 + 3H2S ⎯→ As2S3 + 3H2O (iv) NaOH + HCl ⎯→ NaCl + H2O
(A) (i) & (ii) (B) only (iii) (C) only (iv) (D) (i) to (iv) all

10. AgNO3 (aq) + NaCl (aq) ⎯→ AgCl(s) + NaNO3 (aq)

Above reaction is a -
(A) precipitation reaction (B) double displacement reaction
(C) combination reaction (D) (A) and (B) both

11. H2SO4 + 2NaOH ⎯→ Na2SO4 + 2H2O

Above equation is a -
(i) neutralization reaction (ii) double displacement reaction
(iii) decomposition reaction (iv) addition reaction
(A) (i) to (iv) all (B) (i) and (ii) (C) (i) and (iii) (D) (ii) and (iv)

12. Zn + H2SO4 (dil) ⎯→ ZnSO4 + H2 

Above equation is a -
(A) decomposition reaction (B) single displacement reaction
(C) combination reaction (D) synthesis reaction

13. The reaction in which two compounds exchange their ions to form two new compounds is -
(A) a displacement reaction
(B) a decomposition reaction
(C) an addition reaction
(D) a double displacement reaction
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 NSEC 2024
14. Stainless steel form by mixing iron, chromium and nickel is a -
(A) a displacement reaction (B) a decomposition reaction
(C) an oxidation reaction (D) None of these

15. Burning of fuel is an example of -

(A) Redox reaction (B) displacement reaction
(C) combustion reaction (D) (A) & (C)

16. H2S(g) + Cl2 (g) ⎯→ 2 HCl(g) + S(s), The reaction is interpreted as:
(A) H2S is getting oxidized and Cl2 is getting reduced
(B) H2S is getting reduced and Cl2 is getting oxidized
(C) Only H2S is oxidized
(D) Both H2S and Cl2 are reduced
17. Oxidation is defined as:
(A) loss of electron (B) gain of electron (C) loss of proton (D) gain of proton

18. The chemical reaction HNO3 + KOH ⎯→ KNO3 + H2O is an example of

(A) neutralization
(B) double displacement
(C) neutralization and double displacement
(D) combination

APPLICATION OF REDOX REACTION

1. The term ‘rancidity‘ represents -

(A) acid rain (B) oxidation of fatty food
(C) rotting of fruit (D) fading of coloured clothes in the sun.
2. Combination of phosphorus and oxygen is an example of -
(A) oxidation (B) reduction (C) rancidity (D) none of these
3. Rancidity can be prevented by -
(A) adding antioxidants (B) packaging oily food in nitrogen gas
(C) both (A) and (B) (D) none of these

4. Which of the following is a combustion reaction?

(A) Boiling of water (B) Melting of wax (C) Burning of petrol (D) None of these

5. Nitrogen gas is filled in packets of chips because:

(A) It is unreactive (B) It is major part of atmosphere
(C) Air contains oxygen (D) None of these

OXIDATION & REDUCTION

1. The oxidation number of Oxygen in Na2O2 is:
(A) + 1 (B) + 2 (C) – 2 (D) – 1
2. One of the following has both positive and negative oxidation states
(A) F (B) Cl (C) He (D) Na

3. The oxidation state of osmium (Os) in OsO4 is

(A) + 7 (B) + 6 (C) + 4 (D) + 8

4. Oxidation number of nitrogen in (NH4)2SO4 is

1
(A) − (B) – 1 (C) + 1 (D) – 3
3
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 NSEC 2024
5. In which of the following compounds, the oxidation number of iodine is fractional?
(A) IF7 (B) I3– (C) IF5 (D) IF3

6. The oxidation number of cobalt in K3[Co(NO2)6] is

(A) 0 (B) +4 (C) +3 (D) +6

7. Phosphorus has the oxidation state of +3 in

(A) Phosphorous acid (B) Orthophosphoric acid
(C) Hypophosphorous acid (D) Metaphosphoric acid

8. The oxidation number of Phosphorus in Mg2P2O7 is:

(A) + 3 (B) + 2 (C) + 5 (D) – 3

9. In which of the following compounds, nitrogen has an oxidation state of –1?

(A) N2O (B) NO2– (C) NH2OH (D) N2H4

10. Arsenic estimation can be done by Bettendorff's process. The reaction is given below:
As4O6 + SnCl2 + HCl ⎯⎯ → As4 + SnCl4 + H2O
Find out the exact stoichiometric coefficient of the reactants respectively: (in the order as given in
question)
(A) 2, 4, 6 (B) 1, 6, 12 (C) 2, 8, 20 (D) None of these

11. When white phosphorus reacts with caustic soda, the products are PH3 and NaH2PO2. This reaction is an
example of:
(A) Oxidation (B) Reduction (C) Disproportionation (D) Neutralisation

12. Oxidation number of oxygen in OF2 would be:

(A) –2 (B) +1 (C) –1 (D) +2

13. Oxidation number of Chlorine can be:

(A) From +5 to –1 (B) From +7 to –3 (C) From –7 to +1 (D) From +7 to –1

REDOX REACTIONS

1. A reducing agent is a substance:

(A) in which an element undergoes increase in oxidation number.
(B) in which an element undergoes decrease in oxidation number.
(C) which gains electron(s)
(D) which shares electron(s)
2. Consider the following reaction:
3Br2 + 6CO32– + 3H2O ⎯⎯ → 5Br – + BrO3– + 6 HCO3–
Which of the following statements is true regarding this reaction:
(A) Bromine is oxidized and the carbonate radical is reduced.
(B) Bromine is reduced and the carbonate radical is oxidized.
(C) Bromine is neither reduced nor oxidized.
(D) Bromine is both reduced and oxidized.

3. Which of the following is a redox reaction:

(A) 2 CrO42– + 2H+ → Cr2O72– + H2O (B) CuSO4 + 4 NH3 → [Cu (NH3)4] SO4
(C) 2Na2 S2O3 + I2 → Na2S4O6 + 2NaI (D) Cr2O72– + 2OH– → 2 CrO42– + H2O
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4. Consider the reaction, Zn + Cu2+ ⎯⎯ → Zn2+ + Cu
With reference to the above, which one of the following is the correct statement?
(A) Zn is reduced to Zn2+ (B) Zn is oxidised to Zn2+
(C) Zn2+ is oxidised to Zn (D) Cu2+ is oxidised to Cu.

5. Which reaction does not represent auto redox or disproportionation reaction:

(A) Cl2 + OH– ⎯⎯ → Cl– + ClO3– + H2O (B) 2H2O2 ⎯⎯ → H2O + O2
(C) 2Cu ⎯⎯→ Cu + Cu
+ 2+
(D) (NH4)2Cr2O7 ⎯⎯→ N2 + Cr2O3 + 4H2O

6. In the reaction X– + XO3– + H+ ⎯⎯ → X2 + H2O, the molar ratio in which X– and XO3– react is:
(A) 1: 5 (B) 5: 1 (C) 2: 3 (D) 3: 2

7. The compound that can work both as an oxidising as well as a reducing agent is:
(A) KMnO4 (B) H2O2 (C) Fe2(SO4)3 (D) K2Cr2O7

8. Which of the following behaves as both oxidising and reducing agents?

(A) H2SO4 (B) SO4 (C) H2S (D) HNO3

9. Dichromate ion in acidic medium oxidizes stannous ion as:

xSn2+ + yCr2O72– + zH+ ⎯⎯ → aSn4+ + bCr3+ + cH2O
(A) the value of x: y is 1: 3 (B) the value of x + y + z is 18
(C) a: b is 3: 1 (D) the value of z – c is 9

10. The incorrect order of decreasing oxidation number of S in compounds is:

(A) H2S2O7 > Na2S4O6 > Na2S2O3 > S8 (B) H2SO5 > H2SO3 > SCl2 > H2S
(C) SO3 > SO2 > H2S > S8 (D) H2SO4 > SO2 > H2S > H2S2O8

11. K2Cr2O7 + C2O42– + H2SO4 ⎯⎯ → K2SO4 + CO2 + Cr2(SO4)3 + H2O

In above reaction, identify the elements which do not undergo change in their oxidation state:
(A) K, C & O (B) S, H, O & Cr (C) K, O, S & H (D) Cr & C

12. In which of the following reactions is there a change in the oxidation number of nitrogen atom:
(A) 2 NO2 ⎯⎯ → N2O4 (B) NH3 + H2O ⎯⎯ → NH4+ + OH–
(C) N2O5 + H2O ⎯⎯
→ 2HNO3 (D) None of these

CONCEPT OF EQUIVALENT AND TITRATION

1. When N2 is converted into NH3, the equivalent weight of nitrogen will be:
(A) 1.67 (B) 2.67 (C) 3.67 (D) 4.67

2. When HNO3 is converted into NH3, the equivalent weight of HNO3 will be:
(M = molecular weight of HNO3)
(A) M/2 (B) M/1 (C) M/6 (D) M/8

3. In the ionic equation 2K++ BrO3– + 12H+ + 10e– ⎯⎯ → Br2 + 6H2O + 2K+, the equivalent weight of
KBrO3 will be: (where M = molecular weight of KBrO3)
(A) M/5 (B) M/2 (C) M/6 (D) M/4

4. If molecular weight of KMnO4 is 'M', then its equivalent weight in acidic medium would be:
(A) M (B) M/2 (C) M/5 (D) M/4
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5. In the conversion NH2OH ⎯⎯ → N2O, the equivalent weight of NH2OH will be:
(M = molecular weight of NH2OH)
(A) M/4 (B) M/2 (C) M/5 (D) M/1

6. In the reaction between SO2 and O3, the equivalent weight of ozone is:
(A) the same as its molecular weight
(B) half the molecular weight
(C) one-third of the molecular weight
(D) one-fourth of the molecular weight

7. The equivalent weight of phosphoric acid (H3PO4) in the reaction:

NaOH + H3PO4 ⎯⎯
→ NaH2PO4 + H2O
(A) 59 (B) 49 (C) 25 (D) 98

8. The equivalent weight of MnSO4 is half its molecular weight when it is converted into
(A) Mn2O3 (B) MnO4– (C) MnO2 (D) MnO42–

9. The equivalent weight of Mohr's salt, FeSO4.(NH4)2SO4.6H2O is equal to

(A) Its molecular weight
(B) Atomic weight
(C) half-its molecular weight
(D) one-third its molecular weight

10. 2 g of a base whose eq. wt. is 40 reacts with 3 g of an acid. The eq. wt. of the acid is-
(A) 40 (B) 60 (C) 10 (D) 80

11. How many millilitres of 0.1N H2SO4 solution will be required for complete reaction with a solution
containing 0.125 g of pure Na2CO3:
(A) 23.6 mL (B) 25.6 mL (C) 26.3 mL (D) 32.6 mL

12. If 25 mL of a H2SO4 solution reacts completely with 1.06 g of pure Na2CO3, what is the normality of this
acid solution:
(A) 1 N (B) 0.5 N (C) 1.8 N (D) 0.8 N

13. How much water is to be added to dilute 10 mL of 10 N HCl to make it decinormal?

(A) 990 mL (B) 1010 mL (C) 100 mL (D) 1000 mL

14. 250 ml of 0.1 N solution of AgNO3 are added to 250 ml of a 0.1 N solution of NaCl. The concentration of
nitrate ion in the resulting solution will be -
(A) 0.1N (B) 1.2 N (C) 0.01 N (D) 0.05 N

15. 2g of NaOH and 4.9 g of H2SO4 were mixed and volume is made 1 litre. The normality of the resulting
solution will be -
(A) 1N (B) 0.05 N (C) 0.5 N (D) 0.1N

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16. The volume of water to be added to 200 mL of seminormal HCl solution to make it decinormal is -
(A) 200 mL (B) 400 mL (C) 600 mL (D) 800 mL

17. Normality of 1% H2SO4 solution is nearly -

(A) 2.5 (B) 0.1 (C) 0.2 (D) 1
18. Temporary hardness is due to bicarbonates of Mg2+ and Ca2+. It is removed by addition of CaO as follows:
Ca(HCO3)2 + CaO ⎯⎯
→ 2CaCO3 + H2O
Mass of CaO required to precipitate 2 g CaCO3 is:
(A) 2 g (B) 0.56 g (C) 0.28 g (D) 1.12 g

19. The mass of oxalic acid crystals (H2C2O4 . 2H2O) required to prepare 50 mL of a 0.2 N solution is:
(A) 4.5 g (B) 6.3 g (C) 0.63 g (D) 0.45 g

20. 125 mL of 63% (w/v) H2C2O4.2H2O solution is made to react with 125 mL of a 40% (w/v) NaOH solution.
The resulting solution is: (ignoring hydrolysis of ions)
(A) neutral
(B) acidic
(C) strongly acidic
(D) alkaline

21. If equal volumes of 0.1 M KMnO4 and 0.1 M K2Cr2O7 solutions are allowed to oxidise Fe2+ to Fe3+ in
acidic medium, then Fe2+ oxidised will be:
(A) more by KMnO4
(B) more by K2Cr2O7
(C) equal in both cases
(D) cannot be determined.

22. How many grams of NaHCO3 are required to neutralise 1 mL of 0.0902 N vinegar?
(A) 8.4 × 10–3 g (B) 1.5 × 10–3 g (C) 0.758 × 10–3 g (D) 1.07 × 10–3 g

23. 0.7 g of Na2CO3.xH2O was dissolved in water and the volume made up to 100 mL, 20 mL of it required
19.8 mL of 10 N HCl for complete neutralisation. The value of x is:
(A) 7 (B) 3 (C) 2 (D) 5

24. Calculate the equivalent mass of Na2CO3 when it is titrated against HCl in presence of phenolphthalein
(A) 106 (B) 53 (C) 26.5 (D) 212

25. 1 mol H2SO4 can not neutralise:

(A) 2 mol of ammonia (B) 1 mol of Ba(OH)2 (C) 0.5 mol of Ba(OH)2 (D) 2 mol of KOH

26. Which of the following gives equivalent mass of Na2CO3 when titrated against HCl in the presence of
methyl orange?
(A) 5.3 (B) 53 (C) 10.6 (D) 106

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 NSEC 2024

1. In the balanced equation -

aHgS+bHCl + cHNO3 ⎯→ dH2HgCl4 + eNO + fS + gH2O
The values of b, c, e, and g are respectively -
(A) 2, 2, 4, 12 (B) 6, 1, 1, 2 (C) 12, 2, 2, 4 (D) both (B) and (C)

2. In the reaction FeSO4 + x ⎯→ Na2SO4 + Fe(OH)2, x is -

(A) Na2SO4 (B) H2SO4 (C) NaOH (D) none of these

3. In the reaction the possible state of Ca(OH)2 is -

(A) liquid (B) aqueous (C) gaseous (D) solid

4. Combustion is a process involving -

(A) oxidation (B) reduction (C) liberation of heat (D) All (A), (B) & (C)

5. aK2Cr2O4 + bKCl + cH2SO4 ⎯→ xCrO2Cl2 + y KHSO4 + zH2O

The above equation balances when
(A) a = 2, b = 4, c = 6 and x = 2, y = 6, z = 3 (B) a = 4, b = 2, c = 6 and x = 6, y = 2, z = 3
(C) a = 6, b = 4, c = 6 and x = 6, y = 3, z = 2 (D) a = 1, b = 4, c = 6 and x = 2, y = 6, z = 3

6. In the reaction Mg + Cl2 → MgCl2

Chlorine may be regarded as -
(A) an oxidizing agent (B) a reducing agent
(C) a catalyst (D) providing an inert medium

7. The antioxidant which is used to prevent rancidity in foods is

(A) butylated hydroxyl anisole. (B) sodium hydroxide.
(C) sodium carbonate. (D) methylated hydroxyl anisole

8. The colour of the chemical that changes when it is left open in sunlight is -
(A) FeSO4 (s) (B) Pb(NO3) 2 (s) (C) AgCl (s) (D) BaCl2 (aq)

9. Sun produces heat and light by -

(A) combustion (B) inflammation (C) nuclear reactions (D) photochemical reactions

10. Heating of calcium carbonate to give calcium oxide and carbon dioxide is -
(A) An oxidation process (B) A reduction process
(C) Disproportionation (D) Decomposition

11. Which of the following statement(s) is/are correct?

(A) Many compounds can be used as oxidizing as well as reducing agent
(B) We need equal moles and equal volumes of strong monobasic acid and strong monoacidic base to
completely neutralize themselves
(C) The quantity of a catalyst does not change at the end of a chemical reaction
(D) All of these are correct

12. The elements undergoing reduction and oxidation during the reaction,
(NH4) 2Cr2O7 ⎯→ N2 + Cr2O3 + 4H2O are respectively
(A) N and Cr (B) Cr and N (C) N and O (D) Cr and O

13. The decomposition of KClO3 to KCl and O2 on heating is an example of:

(A) Intermolecular redox change (B) Intramolecular redox change
(C) Disproportionation or auto redox change (D) None of the above

PW OLYMPIAD WALLAH 10
 NSEC 2024
14. Which of the following can act as oxidant?
(A) H2O2 (B) H2S (C) NH3 (D) None of these

15. Conversion of PbSO4 to PbS is -

(A) reduction of S (B) oxidation of S (C) dissociation (D) none of these

16. Which of the following is redox reaction?

(A) NaOH + HCl ⎯→ NaCl + H2O
(B) AgNO3 + KI ⎯→ AgI + KNO3
(C) BaO2 + H2SO4 ⎯→ BaSO4 + H2O2
(D) SnCl2 + HgCl2 ⎯→ SnCl4 + Hg

17. In a conjugate pair of reductant and oxidant, the reductant has:

(A) Lower ox. no. (B) Higher ox. no. (C) Same ox. no. (D) Either of these

18. Oxidation is process which involves:

(A) De-electronation (B) Electronation
(C) Addition of hydrogen (D) Addition of metal

19. Oxidants are substances which:

(A) Show a decrease in their oxidation number during a change
(B) Gain electrons during a change
(C) Oxidize others and reduce themselves
(D) All of the above

20. If an iron rod is dipped in CuSO4 solution:

(A) Blue colour of the solution turns red
(B) Brown layer is deposited on iron rod
(C) No change occurs in the colour of the solution
(D) None of the above

21. Which of the following is a redox reaction?

(A) CaCO3 ⎯→ CaO + CO2
(B) H2 + Cl2 ⎯→ 2HCl
(C) CaO + 2HCl⎯→ CaCl2 + H2O
(D) NaOH + HCl ⎯→ NaCl + H2O

22. Which of the following statement about the following reaction is correct?
ZnO + CO ⎯→ Zn + CO2
(A) ZnO is being oxidized (B) CO is being reduced
(C) CO2 is being oxidized (D) ZnO is being reduced

23. Calorific value of a fuel may be defined as -

(A) The amount of heat produced when 1000 kg of a fuel is completely burnt.
(B) The amount of heat produced when 1g of fuel is incompletely burnt.
(C) The amount of heat produced when 10 g of a fuel is completely burnt.
(D) The amount of heat produced in kilo joules when unit mass of a fuel is completely burnt.

24. Which of the following fuels has the highest calorific value?
(A) Petrol (B) Hydrogen (C) LPG (D) Natural gas

PW OLYMPIAD WALLAH 11
 NSEC 2024
25. In which zone of a candle flame does complete combustion take place?
(A) Inner (B) Outer (C) Middle (D) All three zones

26. The zone of no combustion is -

(A) the middle zone (B) outermost zone
(C) the base of the flame (D) innermost zone.

27. The colour of the flame in luminous zone is -

(A) blue (B) red (C) yellow (D) black

28. The non-combustible substance among the following is -

(A) coal (B) glass (C) wood (D) paper

29. Combustion is a -
(A) physical process (B) chemical process
(C) biological process (D) mechanical process

30. A circular blackish ring on the glass plate kept over the candle flame indicates-
(A) complete combustion
(B) dark zone of the flame
(C) non-luminous zone
(D) luminous zone

31. The oxidation number of sulphur in S8, S2F2 and H2S respectively are:
(A) 0, + 1 and – 2 (B) + 2, + 1 and – 2 (C) 0, + 1 and + 2 (D) – 2, + 1 and – 2

32. Which of the following compounds have sulphur atom in its maximum oxidation state:
X = H2SO4 ; Y = H2SO5 ; Z = H2S2O8
(A) Z only (B) Y and Z only (C) Y only (D) X, Y and Z

33. Manganese achieves its maximum oxidation state in which of these compounds:
(A) MnO2 (B) Mn3O4 (C) KMnO4 (D) K2MnO4

34. Oxidation number of underlined elements in N2O5, SO32–, NH+4 are:

(A) +5, +2, –3 (B) +6, –2, +3 (C) +6, +2, –3 (D) +5, +4, –3

35. Which of the following changes does not involve either oxidation or reduction:
(A) VO2+ → V2O3 (B) Na → Na+ (C) Zn+2 → Zn (D) CrO4–2 → Cr2O7–2

36. Which of the following is not a redox reaction:

(A) Mg + N2 ⎯⎯ → Mg3N2
(B) MnO4– + C2O42– ⎯⎯
→ Mn2+ + CO2
(C) CuSO4 + KI ⎯⎯
→ 2CuI + I2 + K2SO4
(D) AgCl + NH3 ⎯⎯
→ [Ag(NH3)2]Cl

37. Vapour density of a metal chloride is 66. Its oxide contains 53% metal. The atomic weight of metal is -
(A) 21 (B) 54 (C) 26.74 (D) 2.086

38. Equivalent mass of KMnO4, when it is converted to MnSO4 is -

(A) M/5 (B) M/3 (C) M/6 (D) M/2
PW OLYMPIAD WALLAH 12
 NSEC 2024
39. In a compound AxBy -
(A) Mole of A = Mole of B = mole of AxBy
(B) Eq. of A = Eq. of B = Eq. of AxBy
(C) X × mole of A = y × mole of B = (x + y) × mole of AxBy
(D) X × mole of A = y × mole of B

40. A certain weight of pure CaCO3 is made to react completely with 200 mL of a HCl solution to give 224
mL of CO2 gas at STP. The normality of the HCl solution is:
(A) 0.05N (B) 0.1 N (C) 1.0 N (D) 0.2 N

41. 0.2 g of a sample of H2O2 required 10 mL of 1N KMnO4 in a titration in the presence of H2SO4. Purity of
H2O2 is-
(A) 25% (B) 85% (C) 65% (D) 95%

42. 150 ml of 10N HCl is required to react completely with 1.0 g of a sample of limestone. The percentage
purity of calcium carbonate is -
(A) 75% (B) 50% (C) 80% (D) 90%

43. An oxide of metal have 20% oxygen, the eq. wt. of metal oxide is -
(A) 32 (B) 40 (C) 48 (D) 52

44. For the redox reaction MnO4– + C2O42– + H+ ⎯⎯ → Mn2+ + CO2 + H2O, the correct stoichiometric
coefficients of MnO4–, C2O42– and H+ are respectively:
(A) 2, 5, 16 (B) 16, 5, 2 (C) 5, 16, 2 (D) 2, 16, 5

45. In the half reaction 2ClO3– → Cl2

(A) 5 electrons are gained
(B) 5 electrons are liberated
(C) 10 electrons are gained
(D) 10 electrons are liberated

46. 1g of a metal carbonate neutralises completely 200 mL of 0.1N HCl. The equivalent weight of metal
carbonate is
(A) 25 (B) 50 (C) 100 (D) 75

47. 100 mL of 0.5 N NaOH were added to 20 ml of 1N HCl and 10 mL of 3 N H2SO4. The solution is -
(A) acidic (B) basic (C) neutral (D) none of these

48. 1M solution of H2SO4 is diluted from 1 litre to 5 litres, the normality of the resulting solution will be -
(A) 0.2 N (B) 0.1 N (C) 0.4 N (D) 0.5 N

49. 0.7 g of Na2CO3 .xH2O is dissolved in 100 mL. 20 mL of which required to neutralize 19.8 mL of 0.1 N
HCl. The value of x is -
(A) 4 (B) 3 (C) 2 (D) 1

50. 0.45 g of an acid of molecular weight 90 was neutralised by 20 mL of 0.5 N caustic potash. The basicity
of the acid is -
(A) 1 (B) 2 (C) 3 (D) 4
51. 1 litre of 18 molar H2SO4 has been diluted to 100 litres. The normality of the resulting solution is -
(A) 0.09 N (B) 0.18 (C) 1800 N (D) 0.36

N N
52. 50 ml of HCl is treated with 70 ml NaOH. Resultant solution is neutralized by 100 ml of
10 10
sulphuric acid. The normality of H2SO4 -
(A) N/50 (B) N/25 (C) N/30 (D) N/10
PW OLYMPIAD WALLAH 13
 NSEC 2024
N
53. 200 mL of HCl were added to 1 g calcium carbonate, what would remain after the reaction?
10
(A) CaCO3 (B) HCl (C) Neither of the two (D) Part of both

54. An element A in a compound ABD has oxidation number –n. It is oxidised by Cr2O72– in acid medium. In
the experiment, 1.68 × 10–3 moles of K2Cr2O7 were used for 3.36 × 10–3 moles of ABD. The new
oxidation number of A after oxidation is:
(A) 3 (B) 3 – n (C) n – 3 (D) +n

55. The eq. wt. of an element is 4. Its chloride has a VD 59.25. Then the valency of the element is.
(A) 4 (B) 3 (C) 2 (D) 1
56. If 250 mL of a solution contains 24.5 g H2SO4 the molarity and normality respectively are -
(A) 1 M, 2 N (B) 1M, 0.5 N (C) 0.5 M, 1N (D) 2M, 1N

57. Which of the following has the highest normality?

(A) 1 M H2SO4 (B) 1 M H3PO3 (C) 1 M H3PO4 (D) 1 M HNO3

58. What mass of Na2S2O3.5H2O is needed to make 500 cm3 of 0.200 N solution for the reactions
2S2O3 2– + I2 → S4O6 2– + 2I–
(A) 4.8 gm (B) 14.8 gm (C) 24.8 gm (D) 16.8 gm

59. What volume of 3 molar HNO3 is needed to oxidise 8 g of Fe2+ to Fe3+, HNO3 gets converted to NO:
(A) 8 mL (B) 16 mL (C) 32 mL (D) 64 mL

60. The reaction,

2K2MnO4 + Cl2 → 2KMnO4 + 2KCl is an example of -
(A) Oxidation (B) Reduction (C) Redox (D) Chlorination

61. In the reaction, 3Br2 + 6CO3 2– + 3H2O → 5Br– + BrO3–+ 6HCO3–

(A) Bromine is oxidised and carbonate is reduced
(B) Bromine is oxidised as well as reduced
(C) Bromine is reduced and water is oxidised
(D) Br2 is neither oxidised nor reduced

62. The charge on cobalt in [Co(CN)6]3– is-

(A) – 6 (B) – 3 (C) + 3 (D) + 6

63. In the chemical reaction, K2Cr2O7 + X H2SO4 + Y SO2 →K2SO4 + Cr2(SO4)3 + ZH2O X, Y and Z are -
(A) 1, 3, 1 (B) 4, 1, 4 (C) 3, 2, 3 (D) 2, 1, 2

64. Select the incorrect statement from the following option.

(A) Water which does not form lather with soap and forms white scum is called hard water
(B) Hard water contains dissolved calcium and magnesium salts in it
(C) In hard water, cleansing quality of soap is depressed
(D) Due to the presence of dissolved hardness-producing salts, the boiling point of water is depressed

65. Select the incorrect statement from the following option.

(A) Permanent hardness is due to dissolved chlorides and sulphates of calcium and magnesium
(B) It can be removed by mere boiling of water
(C) It is also known as non-alkaline hardness
(D) The difference between the total hardness and the alkaline hardness gives the non-alkaline hardness

66. The volume strength of 1.5 N H2O2 is

(A) 4.8 (B) 8.4 (C) 3.0 (D) 8.0
PW OLYMPIAD WALLAH 14
 NSEC 2024

EXERCISE # 3

NSEC (PREVIOUS YEARS)

1. If the equivalent weight of an element is 32, then the percentage of oxygen in its oxide is : [NSEC-2000]
(A) 16 (B) 40 (C) 32 (D) 20

2. In alkaline medium, KMnO4 reacts as follows (Atomic weights K = 39.09, Mn = 54.94, O = 16.00)
2KMnO4 + 2KOH → 2K2MnO4 + H2O + [O] Hence, its equivalent weight is : [NSEC-2000]
(A) 31.6 (B) 63.2 (C) 126.4 (D) 158

3. When 25 g of Na2SO4 is dissolved in 103 Kg of solution, its concentration will be [NSEC-2000]

(A) 2.5 ppm (B) 25 ppm (C) 250 ppm (D) 100 ppm

4. Which amongst the following has the highest normality ? [NSEC-2002]

(A) 16.0 g of NaOH in 200 mL of water
(B) 1 N oxalic acid
(C) 2 M sulphuric acid
(D) 1.5 hydrochloric acid

5. The volume of water which must be added to 0.4 dm3 of 0.25 N oxalic acid in order to make it exactly
decinormal is : [NSEC-2002]
3 3 3 3
(A) 0.2 dm (B) 0.4 dm (C) 0.6 dm (D) 0.8 dm

6. The quantity of electricity required to reduce 0.05 mol of MnO4– to Mn2+ in acidic medium would be
[NSEC-2003]
(A) 0.01 F (B) 0.05 F (C) 0.15 F (D) 0.25 F

7. You are given a solution of an alkali. In order to estimate its concentration in terms of normality, you
need to know [NSEC-2003]
(A) the volume of the solution, the volume of the alkali present in it and its formula weight
(B) the mass of the solution, the mass of the alkali present in it and its equivalent weight.
(C) the volume of the solution, the mass of the alkali present in it and its equivalent weight
(D) the mass of the solution, the volume of the alkali present in it and its equivalent weight.

8. The normality of ‘20 volume’ H2O2 solution is [NSEC-2005]

(A) 2.0 (B) 2.5 (C) 3.0 (D) 3.5

9. Hydrazine N2H4 acts as a reducing agent. To prepare 100 ml of 2 N hydrazine solution, the weight required
will be [NSEC-2006]
(A) 6.4 g (B) 1.6 g (C) 3.2 g (D) 0.8 g

10. For the reaction shown below, which statement is true ? [NSEC-2007]
2Fe + 3CdCl2  2FeCl3 + 3Cd
(A) Fe is the oxidizing agent
(B) Cd undergoes oxidation
(C) Cd is the reducing agent
(D) Fe undergoes oxidation

PW OLYMPIAD WALLAH 15
 NSEC 2024
11. Oxalic acid (H2C2O4) reacts with permanganate ion according to the balanced equation given below:
5H2C2O4(aq) + 2MnO4 (aq) + 6H+(aq) → 2Mn2+ (aq) + 10CO2(g) + 8H2O(l)
How many mL of 0.0154 M KMnO4 solution are required to react with 25.0 mL of 0.0208 M H2C2O4
solution? [NSEC-2008]
(A) 13.5 mL (B) 18.5 mL (C) 33.8 mL (D) 84.4 mL

12. What volume of water should be added to 1600 ml of a 0.205 N solution so that the resulting solution
will be 0.2 N ? [NSEC-2008]
(A) 40 mL (B) 50 mL (C) 100 mL (D) 20 mL

13. The compound which can act as an oxidizing agent as well as reducing agent is [NSEC-2010]
(A) HNO2 (B) HI (C) HCN (D) HCOOH

14. Oxalic acid, H2C2O4, reacts with paramanganate ion according to the balanced equation
5H2C2O4(aq) + 2MnO4–(aq) + 6H+(aq)  2Mn2+(aq) + 10 CO2(g) + 8 H2O(l). The volume in mL of 0.0162
M KMnO4 solution required to react with 25.0 mL of 0.022 M H2C2O4 solution is [NSEC-2011]
(A) 13.6 (B) 18.5 (C) 33.8 (D) 84.4

15. A 500 g toothpaste sample has 0.4 g fluoride concentration. The fluoride concentration in terms of ppm
will be [NSEC-2012]
(A) 200 (B) 400 (C) 500 (D) 800

16. The number of moles of KMnO4 that will be needed to react completely with one mole of ferrous oxalate
[Fe(C2O4)] in acidic solution is [NSEC-2012]
(A) 1 (B) 2/5 (C) 3/5 (D) 4/5

17. The rate of the reaction MnO4–(aq.) + 8H+(aq.) + 5Fe2+(aq.) → Mn2+(aq.) + 5Fe3+(aq.) + 4H2O can be best
measured by monitoring colorimetrically the concentration of : [NSEC-2012]
– 2+ 2+ 3+
(A) MnO4 (aq.) (B) Mn (aq.) (C) Fe (aq.) (D) Fe (aq.)

18. I. 5H2O + 2MnO4– + 6H+ → 2Mn2+ + 5O2 + 8H2O

II. H2O2 + Ag2O → 2Ag + H2O + O2
The role of hydrogen peroxide in the above reaction is [NSEC-2014]
(A) oxidising in I and reducing in II
(B) reducing in I and oxidising in II
(C) reducing in I as well as in II
(D) oxidising in I as well as in II

19. A bottle of H3PO4 solution contains 70% acid. If the density of the solution is 1.54 g cm–3, the volume of
the H3PO4 solution required to prepare 1L of IN solution is. [NSEC-2015]
(A) 90mL (B) 45mL (C) 30mL (D) 23mL

20. The unbalanced equation for the reaction of P4S3 with nitrate in aqueous acidic medium is given below.
P4S3 + NO3– → H3PO4 + SO42– + NO
The number of mol of water required per mol of P4S3 is [NSEC-2015]
(A) 18 (B) 8/3 (C) 8 (D) 28

21. In the redox reaction

2MnO4– + 5C2O42– + 16H+ → 2Mn2+ + 10CO2 + 8H2O, 20 mL of 0.1 M KMnO4 react quantitatively with
[NSEC-2015]
(A) 20 mL of 0.1 M oxalate (B) 40 mL of 0.1 M oxalate
(C) 50 mL of 0.25 M oxalate (D) 50 mL of 0.1 M oxalate
PW OLYMPIAD WALLAH 16
 NSEC 2024
22. 1.250 g of metal carbonate (MCO3) was treated with 500 mL of 0.1 M HCl solution. The unreacted HCl
required 50.0 mL of 0.500 M NaOH solution for neutralization. Identify the metal M [NSEC-2016]
(A) Mg (B) Ca (C) Sr (D) Ba

23. Battery acid (H2SO4) has density 1.285 g cm–3. 10.0 cm3 of this acid is diluted to 1L. 25.0 cm3 of this diluted
solution requires 25.0 cm3 of 0.1 N sodium hydroxide solution for neutralization. The percentage of
sulphuric acid by mass in the battery acid is : [NSEC-2016]
(A) 98 (B) 38 (C) 19 (D) 49

24. A sample of water from a river was analyzed for the presence of metal ions and the observations were
recorded as given below
Reagent added Observation
dil. HCl No change
aq. Na2CO3 White precipitate
aq. Na2SO4 No change
The water sample is likely to contain [NSEC-2018]
(A) Ba2+ (B) Cu2+ (C) Li+ (D) Mg2+

25. An ion exchange resin, RH2 can replace Ca2+ in hard water as RH2 + Ca2+ → RCa2+ + 2H+. When a 1.0 L
hard water sample was passed through the resin, all H+ ions were replaced by Ca2+ ions and the pH of
eluted water was found to be 2.0. The hardness of water (as ppm of Ca2+) in the sample of water treated is
[NSEC-2018]
(A) 50 (B) 100 (C) 125 (D) 200

26. Among the following, the reaction/s that can be classified as oxidation-reduction is/are. [NSEC-2018]
(i) Cr2O72− (aq.) 2OH− (aq) → 2CrO42− + H2O(l )
(ii) SiCl4(l) + 2Mg(s) → 2MgCl2(l) + Si(s)
(iii) 6Cl2(l) + 12KOH(l) → 2KClO3(g) + 10 KCl + 6H2O(l)
(iv) 2H2O2 → 2H2O(l) + O2(g)
(A) I and IV (B) I, II and III (C) II, III and IV (D) IV only

27. In the following reaction, the values of a, b and c, respectively are

aF2(g) + b OH– (aq)→ cF–(aq) + d OF2(g) + e H2O(l) [NSEC-2018]
(A) 3, 2, 4 (B) 3, 4, 2 (C) 2, 2, 4 (D) 2, 2, 2

PW OLYMPIAD WALLAH 17
 NSEC 2024

GENERAL INTRODUCTION OF CHEMISTRY & CHARACTERISTICS OF CHEMICAL

REACTIONS
1. (D) 2. (D) 3. (A) 4. (B) 5. (C) 6. (C) 7. (C)
8. (A) 9. (B) 10. (A)
CHEMICAL EQUATIONS & BALANCING
1. (C) 2. (B) 3. (C) 4. (C) 5. (B) 6. (A)
REDOX REACTIONS & OXIDATION NUMBER
1. (B) 2. (B) 3. (D) 4. (A) 5. (A) 6. (C) 7. (B)
8. (D) 9. (C) 10. (D) 11. (D) 12. (C)
TYPES OF REDOX REACTIONS
1. (A) 2. (C) 3. (A) 4. (A) 5. (B) 6. (B) 7. (D)
8. (C) 9. (D) 10. (D) 11. (B) 12. (B) 13. (D) 14. (D)
15. (D) 16. (A) 17. (A) 18. (B)
APPLICATION OF REDOX REACTION
1. (B) 2. (A) 3. (C) 4. (C) 5. (A)
OXIDATION & REDUCTION
1. (D) 2. (B) 3. (D) 4. (D) 5. (B) 6. (C) 7. (A)
8. (C) 9. (C) 10. (B) 11. (C) 12. (D) 13. (D)
REDOX REACTIONS
1. (A) 2. (D) 3. (C) 4. (B) 5. (D) 6. (B) 7. (B)
8. (D) 9. (B) 10. (C) 11. (C) 12. (D)
CONCEPT OF EQUIVALENT AND TITRATION
1. (D) 2. (D) 3. (A) 4. (C) 5. (B) 6. (B) 7. (D)
8. (C) 9. (A) 10. (B) 11. (A) 12. (D) 13. (A) 14. (D)
15. (B) 16. (D) 17. (C) 18. (B) 19. (C) 20. (A) 21. (B)
22. (C) 23. (C) 24. (A) 25. (C) 26. (B)

Ques. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. D C B D D A A C C D D B B A A D A A D B
Ques. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
Ans. B D D B B D C B B D A D C D D D C A B B
Ques. 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. B A B A A B C C C B D A C B B A C C B C
Ques. 61 62 63 64 65 66
Ans. B C A D B B
PW OLYMPIAD WALLAH 18
 NSEC 2024

EXERCISE # 3

NSEC (PREVIOUS YEARS)

1. (D) 10. (D) 19. (C)
2. (D) 11. (A) 20. (B)
3. (B) 12. (A) 21. (D)
4. (C) 13. (A) 22. (B)
5. (C) 14. (A) 23. (B)
6. (D) 15. (D) 24. (D)
7. (C) 16. (C) 25. (D)
8. (D) 17. (A) 26. (C)
9. (B) 18. (C) 27. (D)

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PW OLYMPIAD WALLAH 19