Clariant SDS EMULSOGEN 4156 European Community English

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,

as amended
EMULSOGEN 4156 Page 1(12)
Substance key: SXR052866 Revision Date: 25.07.2024
Date of last issue: 17.05.2022
Version : 2 - 12 / EU Date of printing : 07.01.2025
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier

Trade name
EMULSOGEN 4156
Material number: 121313
Chemical nature: An ethoxylated sorbitan monolaurate
CAS number : 9005-64-5
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Industry sector : Crop Protection
Type of use: Special auxiliary for formulation of plant-protection products
1.3. Details of the supplier of the safety data sheet

Identification of the company
Clariant Produkte (Deutschland) GmbH
65926 Frankfurt am Main
Telephone no. : +49 69 305 18000
Information about the substance/mixture
BU Care Chemicals
Product Stewardship
e-mail: SDS.Europe@clariant.com
1.4. Emergency telephone number

00800-5121 5121 (24 h)
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)
Not a hazardous substance or mixture.
2.2 Label elements
Labelling (REGULATION (EC) No 1272/2008)
Not a hazardous substance or mixture.
2.3 Other hazards

This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.
Ecological information: The substance/mixture does not contain components considered to have
endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated
regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
SAFETY DATA SHEET
as amended
Toxicological information: The substance/mixture does not contain components considered to

have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated
regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
The product does not need to be labelled in accordance with EC directives or respective national
laws.
SECTION 3: Composition/information on ingredients
3.1 Substances
Substance name : An ethoxylated sorbitan monolaurate
CAS-No. : 9005-64-5
Components
Remarks : No hazardous ingredients
SECTION 4: First aid measures
4.1 Description of first aid measures

General advice : Remove/ Take off immediately all contaminated clothing.
In case of skin contact : In case of contact, immediately flush skin with soap and plenty
of water.
In case of eye contact : In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms : No symptoms known currently.
Risks : No hazards known at this time.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.
SECTION 5: Firefighting measures
5.1 Extinguishing media

Suitable extinguishing media : Water spray jet
Foam
Carbon dioxide (CO2)
Dry powder
SAFETY DATA SHEET
as amended
5.2 Special hazards arising from the substance or mixture

Specific hazards during : In case of fire hazardous decomposition products may be
firefighting produced such as:
Carbon monoxide
5.3 Advice for firefighters

Special protective equipment : Self-contained breathing apparatus
for firefighters
Further information : Wear suitable protective equipment.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Wear suitable protective equipment.
Ensure adequate ventilation.
6.2 Environmental precautions

Environmental precautions : Do not allow to enter drains or waterways
6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Take up mechanically. Dilute remainder with water and take
up with absorbent material (eg sawdust, sand, universal
binder)
6.4 Reference to other sections

Information regarding Safe handling, see chapter 7., For personal protection see section 8., For
disposal considerations see section 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling

Advice on safe handling : Use only with adequate ventilation and proper protective
eyewear, gloves, and clothing.
Wash thoroughly after handling.
Keep container closed.
Advice on protection against : Observe the general rules of industrial fire protection
fire and explosion
Hygiene measures : Wash hands before breaks and at the end of workday. Use
protective skin cream before handling the product. Take off
immediately all contaminated clothing and wash it before
reuse.
SAFETY DATA SHEET
as amended
7.2 Conditions for safe storage, including any incompatibilities

Further information on : Keep containers tightly closed in a cool, well-ventilated place.
storage conditions Handle and open container with care.
7.3 Specific end use(s)

Specific use(s) : No further recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters

Occupational Exposure Limits
8.2 Exposure controls
Personal protective equipment
Eye/face protection : Safety glasses
Hand protection
Break through time : 480 min
Glove thickness : 0,7 mm
Remarks : Long-term exposure Impervious butyl rubber gloves
Break through time : 30 min

Glove thickness : 0,4 mm
Remarks : For short-term exposure (splash protection): Nitrile rubber
gloves.
Remarks : These types of protective gloves are offered by various

manufacturers. Please note the manufacturers´ detailed
statements, especially about the minimum thickness and the
minimum breakthrough time. Consider also the particular
working conditions under which the gloves are being used.
Skin and body protection : Wear suitable protective equipment.
Protective measures : Avoid contact with skin.

Avoid contact with eyes.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties

Physical state : Liquid
Colour : brown
Odour : fatty odour

SAFETY DATA SHEET
as amended
pour point : < 0 °C

Method: ISO 3016
Boiling point : > 150 °C
Upper explosion limit / upper : no data available

flammability limit
Lower explosion limit / Lower : no data available

flammability limit
Flash point : > 150 °C

Method: DIN 51758
Auto-ignition temperature : no data available
Decomposition temperature : No decomposition if used as directed.
pH : 5 - 7 (20 °C)
Concentration: 10 g/l
Method: DGF-H-III 1
Viscosity
Viscosity, dynamic : approx. 530 mPa.s (20 °C)
Method: Bohlin Rheometer, CP 4°/40 mm
approx. 170 mPa.s (40 °C)

Method: Bohlin Rheometer, CP 4°/40 mm
Viscosity, kinematic : no data available
Solubility(ies)
Water solubility : (20 °C)
soluble
Partition coefficient: n- : Not applicable

octanol/water
Vapour pressure : not tested.
Density : approx. 1,1 g/cm3 (20 °C)

Method: DIN 51757
Relative vapour density : no data available

SAFETY DATA SHEET
as amended
Particle characteristics
Particle size : Not applicable
9.2 Other information

Metal corrosion rate : Not applicable
SECTION 10: Stability and reactivity
10.1 Reactivity
See section 10.3. "Possibility of hazardous reactions"
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : No dangerous reaction known under conditions of normal use.
10.4 Conditions to avoid

Conditions to avoid : Keep away from heat.
Keep away from open flames, hot surfaces and sources of
ignition.
10.5 Incompatible materials

Materials to avoid : not known
10.6 Hazardous decomposition products

When handled and stored appropriately, no dangerous decomposition products are known
SECTION 11: Toxicological information
11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Acute toxicity
Product:
Acute oral toxicity : LD50 (Rat): > 2.000 mg/kg
Remarks: CESIO
Acute inhalation toxicity : Remarks: not tested.
Acute dermal toxicity : LD50 (Hamster): > 2.000 mg/kg

Remarks: CESIO
SAFETY DATA SHEET
as amended
Skin corrosion/irritation
Product:
Result : No skin irritation
Remarks : CESIO
Serious eye damage/eye irritation

Product:
Result : No eye irritation
Remarks : CESIO
Respiratory or skin sensitisation

Product:
Species : Humans
Method : tests on human beings
Result : non-sensitizing
Remarks : The product was tested in the patch test in concentrations up
to 6 %.
Germ cell mutagenicity

Product:
Germ cell mutagenicity- : Not mutagenic in Ames Test
Assessment
Carcinogenicity
Product:
Carcinogenicity - : No information available.
Assessment
Reproductive toxicity
Product:
Reproductive toxicity - : No information available.
Assessment
No information available.
STOT - single exposure

Product:
Remarks : not tested.
STOT - repeated exposure

Product:
SAFETY DATA SHEET
as amended
Repeated dose toxicity

Product:
11.2 Information on other hazards

Endocrine disrupting properties
Product:
Assessment : The substance/mixture does not contain components
considered to have endocrine disrupting properties according
to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at
levels of 0.1% or higher.
SECTION 12: Ecological information
12.1 Toxicity
Product:
Toxicity to fish : LC50 (Danio rerio (zebra fish)): > 100 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203
Toxicity to daphnia and other : Remarks: not tested.

aquatic invertebrates
Toxicity to algae/aquatic : Remarks: not tested.

plants
Toxicity to microorganisms : IC0 (Pseudomonas putida): > 10.000 mg/l
12.2 Persistence and degradability

Product:
Biodegradability : Biodegradation: 35 %
Exposure time: 28 d
Method: OECD Test Guideline 301B
12.3 Bioaccumulative potential

Product:
Bioaccumulation : Remarks: not tested.
12.4 Mobility in soil

Product:
Distribution among : Remarks: not tested.
environmental compartments
SAFETY DATA SHEET
as amended
12.5 Results of PBT and vPvB assessment

Product:
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.
12.6 Endocrine disrupting properties

Product:
Assessment : The substance/mixture does not contain components
considered to have endocrine disrupting properties according
to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at
levels of 0.1% or higher.
12.7 Other adverse effects

Product:
Environmental fate and : no data available
pathways
Additional ecological : no data available

information
SECTION 13: Disposal considerations
13.1 Waste treatment methods

Product : In accordance with local authority regulations, take to special
waste incineration plant
Contaminated packaging : Packaging that cannot be cleaned should be disposed of as

product waste
SECTION 14: Transport information
Section 14.1. to 14.5.

ADR not restricted
ADN not restricted
RID not restricted
IATA not restricted
IMDG not restricted
14.6. Special precautions for user

See sections 6 to 8 of this Safety Data Sheet.
14.7. Maritime transport in bulk according to IMO instruments

SAFETY DATA SHEET
as amended
No transport as bulk according IBC - Code.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
REACH - Restrictions on the manufacture, placing on : Not applicable
the market and use of certain dangerous substances,
mixtures and articles (Annex XVII)
REACH - Candidate List of Substances of Very High : Not applicable

Concern for Authorisation (Article 59).
Regulation (EC) on substances that deplete the ozone : Not applicable

layer
Regulation (EU) 2019/1021 on persistent organic : Not applicable

pollutants (recast)
Council Regulation (EC) No 111/2005 laying down rules : Neither banned nor restricted
for the monitoring of trade between the Community and
third countries in drug precursors
Council Regulation (EC) No 273/2004 on drug : Not applicable

precursors
Regulation (EU) No 649/2012 of the European : Not applicable

Parliament and the Council concerning the export and
import of dangerous chemicals
REACH - List of substances subject to authorisation : Not applicable

(Annex XIV)
Seveso III: Directive 2012/18/EU of the Not applicable

European Parliament and of the Council on the
control of major-accident hazards involving
dangerous substances.
Other regulations:
Apart from the data/regulations specified in this chapter, no further information is available
concerning safety, health and environmental protection.
15.2 Chemical safety assessment

No Chemical Safety Assessment (CSA) is yet available for the substance, or for the component
substances, contained in this product.
SAFETY DATA SHEET
as amended
SECTION 16: Other information
Full text of other abbreviations
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways; ADR - Agreement concerning the International Carriage of Dangerous Goods by
Road; AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the
Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regulation;
Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN -
Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada);
ECHA - European Chemicals Agency; EC-Number - European Community number; ECx -
Concentration associated with x% response; ELx - Loading rate associated with x% response;
EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx -
Concentration associated with x% growth rate response; GHS - Globally Harmonized System;
GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA -
International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory
concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing
Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50
- Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test
population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic
Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention;
PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship;
REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council
concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RID -
Regulations concerning the International Carriage of Dangerous Goods by Rail; SADT - Self-
Accelerating Decomposition Temperature; SDS - Safety Data Sheet; SVHC - Substance of Very
High Concern; TCSI - Taiwan Chemical Substance Inventory; TECI - Thailand Existing Chemicals
Inventory; TRGS - Technical Rule for Hazardous Substances; TSCA - Toxic Substances Control
Act (United States); UN - United Nations; vPvB - Very Persistent and Very Bioaccumulative
Further information
Other information : Observe national and local legal requirements
This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express
or implied, as to the information's accuracy, adequacy, sufficiency or freedom from defect and
assumes no liability in connection with any use of this information. Any user of this product is
responsible for determining the suitability of Clariant's products for its particular application.
Nothing included in this information waives any of Clariant's General Terms and Conditions of
Sale, which control unless it agrees otherwise in writing. Any existing intellectual/industrial
property rights must be observed. Due to possible changes in our products and applicable
national and international regulations and laws, the status of our products could change. Material
Safety Data Sheets providing safety precautions, that should be observed when handling or
SAFETY DATA SHEET
as amended
storing Clariant products, are available upon request and are provided in compliance with
applicable law. You should obtain and review the applicable Material Safety Data Sheet
information before handling any of these products. For additional information, please contact
Clariant.
REG_EU / EN

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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006,

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

2.3 Other hazards

Toxicological information: The substance/mixture does not contain components considered to

SECTION 3: Composition/information on ingredients

Remarks : No hazardous ingredients

SECTION 4: First aid measures

4.1 Description of first aid measures

Risks : No hazards known at this time.

SECTION 5: Firefighting measures

5.1 Extinguishing media

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

Further information : Wear suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

6.2 Environmental precautions

6.3 Methods and material for containment and cleaning up

6.4 Reference to other sections

SECTION 7: Handling and storage

7.1 Precautions for safe handling

7.2 Conditions for safe storage, including any incompatibilities

7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Break through time : 30 min

Remarks : These types of protective gloves are offered by various

Skin and body protection : Wear suitable protective equipment.

Protective measures : Avoid contact with skin.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Odour : fatty odour

pour point : < 0 °C

Boiling point : > 150 °C

Upper explosion limit / upper : no data available

Lower explosion limit / Lower : no data available

Flash point : > 150 °C

Auto-ignition temperature : no data available

Decomposition temperature : No decomposition if used as directed.

approx. 170 mPa.s (40 °C)

Viscosity, kinematic : no data available

Partition coefficient: n- : Not applicable

Vapour pressure : not tested.

Density : approx. 1,1 g/cm3 (20 °C)

Relative vapour density : no data available

9.2 Other information

SECTION 10: Stability and reactivity

10.4 Conditions to avoid

10.5 Incompatible materials

10.6 Hazardous decomposition products

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Acute inhalation toxicity : Remarks: not tested.

Acute dermal toxicity : LD50 (Hamster): > 2.000 mg/kg