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    Common Organic Solvents - Table of Properties

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    This document provides a table summarizing key properties of various common organic solvents, including their boiling point, melting point, density, solubility in water, dielectric constant, and flash point. Over 50 organic solvents are listed, such as acetone, benzene, chloroform, ethanol, hexane, methanol, and xylene, with their chemical formula, molecular weight, and physical characteristics for easy comparison. Notes provide additional sources for more detailed property information on safety, physical properties, and regulations.

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    Common Organic Solvents - Table of Properties

    Uploaded by

    psam111
    545 views2 pages
    This document provides a table summarizing key properties of various common organic solvents, including their boiling point, melting point, density, solubility in water, dielectric constant, and flash point. Over 50 organic solvents are listed, such as acetone, benzene, chloroform, ethanol, hexane, methanol, and xylene, with their chemical formula, molecular weight, and physical characteristics for easy comparison. Notes provide additional sources for more detailed property information on safety, physical properties, and regulations.

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    Common Organic Solvents_ Table of Properties

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    This document provides a table summarizing key properties of various common organic solvents, including their boiling point, melting point, density, solubility in water, dielectric constant, and flash point. Over 50 organic solvents are listed, such as acetone, benzene, chloroform, ethanol, hexane, methanol, and xylene, with their chemical formula, molecular weight, and physical characteristics for easy comparison. Notes provide additional sources for more detailed property information on safety, physical properties, and regulations.

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    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    545 views2 pages

    Common Organic Solvents - Table of Properties

    Uploaded by

    psam111
    This document provides a table summarizing key properties of various common organic solvents, including their boiling point, melting point, density, solubility in water, dielectric constant, and flash point. Over 50 organic solvents are listed, such as acetone, benzene, chloroform, ethanol, hexane, methanol, and xylene, with their chemical formula, molecular weight, and physical characteristics for easy comparison. Notes provide additional sources for more detailed property information on safety, physical properties, and regulations.

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    Download as PDF, TXT or read online from Scribd
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    Common Organic Solvents: Table of Properties

    http://www2.onu.edu/~b-myers/organic_solvents.html

    Common Organic Solvents: Table of Properties1,2,3


    Solvent

    boiling melting
    solubility Dielectric flash
    density
    point
    point
    point
    in water
    3,4
    (g/mL)
    Constant
    (C)
    (C)
    (g/100g)
    (oC)

    formula

    MW

    acetic acid

    C2H4O2

    60.05

    118

    16.6

    1.049

    Miscible

    6.15

    39

    acetone

    C3H6O

    58.08

    56.2

    -94.3

    0.786

    Miscible

    20.7(25)

    -18

    acetonitrile

    C2H3N

    41.05

    81.6

    -46

    0.786

    Miscible

    37.5

    benzene

    C6H6

    78.11

    80.1

    5.5

    0.879

    0.18

    2.28

    -11

    1-butanol

    C4H10O

    74.12

    117.6

    -89.5

    0.81

    6.3

    17.8

    35

    2-butanol

    C4H10O

    74.12

    98

    -115

    0.808

    15

    15.8(25)

    26

    2-butanone

    C4H8O

    72.11

    79.6

    -86.3

    0.805

    25.6

    18.5

    -7

    t-butyl alcohol

    C4H10O

    74.12

    82.2

    25.5

    0.786

    Miscible

    12.5

    11

    CCl4

    153.82

    76.7

    -22.4

    1.594

    0.08

    2.24

    --

    chlorobenzene

    C6H5Cl

    112.56

    131.7

    -45.6

    1.1066

    0.05

    5.69

    29

    chloroform

    CHCl3

    119.38

    61.7

    -63.7

    1.498

    0.795

    4.81

    --

    cyclohexane

    C6H12

    84.16

    80.7

    6.6

    0.779

    <0.1

    2.02

    -20

    1,2-dichloroethane

    C2H4Cl2

    98.96

    83.5

    -35.3

    1.245

    0.861

    10.42

    13

    diethyl ether

    C4H10O

    74.12

    34.6

    -116.3

    0.713

    7.5

    4.34

    -45

    diethylene glycol

    C4H10O3

    106.12

    245

    -10

    1.118

    10

    31.7

    143

    diglyme (diethylene glycol


    dimethyl ether)

    C6H14O3

    134.17

    162

    -68

    0.943

    Miscible

    7.23

    67

    1,2-dimethoxyethane (glyme, DME)

    C4H10O2

    90.12

    85

    -58

    0.868

    Miscible

    7.2

    -6

    C2H6O

    46.07

    -22

    -138.5

    NA

    NA

    NA

    -41

    dimethylformamide (DMF)

    C3H7NO

    73.09

    153

    -61

    0.944

    Miscible

    36.7

    58

    dimethyl sulfoxide
    (DMSO)

    C2H6OS

    78.13

    189

    18.4

    1.092

    25.3

    47

    95

    dioxane

    C4H8O2

    88.11

    101.1

    11.8

    1.033

    Miscible

    2.21(25)

    12

    ethanol

    C2H6O

    46.07

    78.5

    -114.1

    0.789

    Miscible

    24.6

    13

    ethyl acetate

    C4H8O2

    88.11

    77

    -83.6

    0.895

    8.7

    6(25)

    -4

    ethylene glycol

    C2H6O2

    62.07

    195

    -13

    1.115

    Miscible

    37.7

    111

    glycerin

    C3H8O3

    92.09

    290

    17.8

    1.261

    Miscible

    42.5

    160

    heptane

    C7H16

    100.20

    98

    -90.6

    0.684

    0.01

    1.92

    -4

    7.2

    1.03

    Miscible

    31.3

    105

    carbon tetrachloride

    dimethylether

    Hexamethylphosphoramide
    C6H18N3OP 179.20 232.5
    (HMPA)

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    Common Organic Solvents: Table of Properties

    Solvent

    http://www2.onu.edu/~b-myers/organic_solvents.html

    formula

    Hexamethylphosphorous
    triamide (HMPT)

    MW

    C6H18N3P 163.20

    boiling melting
    solubility Dielectric flash
    density
    point
    point
    point
    in water
    3,4
    (g/mL)
    (C)
    (C)
    (g/100g) Constant
    (oC)
    150

    -44

    0.898

    Miscible

    ??

    26

    hexane

    C6H14

    86.18

    69

    -95

    0.659

    0.014

    1.89

    -22

    methanol

    CH4O

    32.04

    64.6

    -98

    0.791

    Miscible

    32.6(25)

    12

    methyl t-butyl
    ether (MTBE)

    C5H12O

    88.15

    55.2

    -109

    0.741

    5.1

    ??

    -28

    methylene chloride

    CH2Cl2

    84.93

    39.8

    -96.7

    1.326

    1.32

    9.08

    1.6

    CH5H9NO

    99.13

    202

    -24

    1.033

    10

    32

    91

    CH3NO2

    61.04

    101.2

    -29

    1.382

    9.50

    35.9

    35

    C5H12

    72.15

    36.1

    -129.7

    0.626

    0.04

    1.84

    -49

    --

    --

    30-60

    -40

    0.656

    --

    --

    -30

    1-propanol

    C3H8O

    88.15

    97

    -126

    0.803

    Miscible

    20.1(25)

    15

    2-propanol

    C3H8O

    88.15

    82.4

    -88.5

    0.785

    Miscible

    18.3(25)

    12

    pyridine

    C5H5N

    79.10

    115.2

    -41.6

    0.982

    Miscible

    12.3(25)

    17

    tetrahydrofuran (THF)

    C4H8O

    72.11

    66

    -108.4

    0.886

    30

    7.6

    -21

    C7H8

    92.14

    110.6

    -93

    0.867

    0.05

    2.38(25)

    C6H15N

    101.19

    88.9

    -114.7

    0.728

    0.02

    2.4

    -11

    0.00

    0.998

    --

    78.54

    --

    N-methyl-2-pyrrolidinone
    (NMP)
    nitromethane
    pentane
    Petroleum ether (ligroine)

    toluene
    triethyl amine
    water

    H2O

    18.02 100.00

    water, heavy

    D2O

    20.03

    101.3

    1.107

    Miscible

    ??

    --

    o-xylene

    C8H10

    106.17

    144

    -25.2

    0.897

    Insoluble

    2.57

    32

    m-xylene

    C8H10

    106.17 139.1

    -47.8

    0.868

    Insoluble

    2.37

    27

    p-xylene

    C8H10

    106.17 138.4

    13.3

    0.861

    Insoluble

    2.27

    27

    Notes:
    1. This table was orginally from: Prof. Murov's Orgsoltab, which was edited and reposted by Erowid
    2. You can find more detailed information (Health & Safety, Physical, Regulatory, Environmental) on
    various organic solvents from NCMS
    3. The values in the table above were obtained from ChemFinder Web Server, the CRC, or Vogel's
    Practical Organic Chemistry (5th ed.).
    4. T = 20 C unless specified otherwise.
    divider.gif
    Questions or Comments? Please Contact:
    Brian J. Myers
    Web Master, Division of Organic Chemistry, ACS
    This Page was Updated: Tuesday, November 24, 2009

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