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Miller Indices

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Miller indices

Introduction
• Atoms are arranged in certain repeated
manner in crystalline crystal.
• The layers of atoms or the planes along which
atoms re arranged are known as atomic or
crystallographic planes.
• Miller indices is a system of notation to
denote crystallographic planes and directions.
• Crystal structure is determined by the XRD ( X
– Ray diffraction)
Miller indices
• It is necessary to use some notation to specify
directions and planes in a crystal.
• It is the vector components of the direction
resolved along each of the crystallographic
and the reciprocal of the intercepts made by
the plane on the crystallographic axes of the
unit cell of the crystal when reduced to
smallest numbers respectively.
Determination of Miller Indices
(denoted by hkl):
• Determine the intercepts along the
crystallographic axes, in terms of unit cell
dimensions
• Take the reciprocals
• Clear fractions
• Reduce to lowest terms
Example
• if the x-, y-, and z- intercepts are 3, 1, and 2,
the Miller indices are calculated as:
• Take reciprocals: 1/3, 1/1, 1/2
• Clear fractions (multiply by 6): 3, 6, 2
• Reduce to lowest terms
Representation of crystal planes and
the corresponding miller indices
Features
• A plane which is parallel to any one of the coordinate axes has an
intercept of infinity and therefore, Miller index for that is zero.
• All equally spaced parallel planes with a particular orientation have
same index number (h k l).
• Miller indices do not only define particular plane but set of parallel
planes.
• All parallel equidistant planes have the same Miller indices.
• A plane parallel to one of the coordinate axes has an intercept of
infinity.
• If the Miller indices of two planes have same ratio such as (844),
(422) and (211), then these planes are said to be parallel to each
other. Therefore, all equally spaced parallel planes with the same
orientation have same Miller indices such as [h k l].
• The crystal directions of a family are not necessarily parallel to one
another. Similarly, not all members of a family of planes are parallel
to one another.
• The normal to the plane with indices (h k l) is the direction of [h k l].
• Draw planes with miller indices given by (110)
and (111) in a cubic cell. Find directions
common to both.
• Determine the interplaner spacing between
(200), (220) and (111) plane in a FCC o
structure. Take atomic radius as 1.246 A .
Linear density
• Number of effective atoms (Nel) per unit
length present on certain length ‘L’ along any
direction in a unit cell.

Nel
L 
L
• Find the linear density in direction [110] in a
FCC unit cell.

o
• Lattice constant of a copper unit cell is 3.61 A .
Determine the linear density along directions
[110] and [111].
Planar density in a unit cell
• The number of atoms per unit area of a crystal
plane is known as planar density.
• It expresses the packing of atoms in a plane of
unit cell.
• The rate of plastic deformation is significantly
influenced by planar density.
Ne
P 
A
• Find the planar density of simple cubic planes
of (100), (110) and (111).

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