Maitra HBCSE 2014
Maitra HBCSE 2014
Maitra HBCSE 2014
2nd Semester
Synthetic methodology, heterocyclic chemistry, natural products
3rd Semester
Physical organic chemistry???
Organic photochemistry and radical reactions
4th Semester
Organotransition metal chemistry, Asymmetric synthesis, synthesis
of complex organic molecules, natural products
Organic specialization
Heterocyclic chemistry, medicinal chemistry, stereochemistry of
polycylic compounds, bioorganic chemistry
Chemistry Education Links…
Links for Chemists
http://www.liv.ac.uk/chemistry/links/link.html
Organic Chemistry Division, ACS
http://www.organicdivision.org/
Organic Data tables
http://www.chem.wisc.edu/areas/organic/index-chem.htm
Learn Chemistry
http://www.rsc.org/learn-chemistry/
Science is Fun
http://scifun.chem.wisc.edu/
Indian Academy of Sciences (Bangalore)
http://www.ias.ac.in
…Chemistry Education Links
Periodic Table
http://www.meta-synthesis.com/webbook/35_pt/pt.html
Classic Chemistry
https://web.lemoyne.edu/giunta/
Classic Papers
https://web.lemoyne.edu/giunta/papers.html
List of Name reactions (about 145)
http://www.monomerchem.com/display4.html
Demystifying Synthetic Organic Experimental Techniques
http://chem.chem.rochester.edu/~nvd/
Molecule of the Month
http://www.bris.ac.uk/Depts/Chemistry/MOTM/motm.htm
Demonstrations and Experiments
Delights of Chemistry
http://www.chem.leeds.ac.uk/delights/
Lab experiments
http://www.oc-praktikum.de/nop/en-experiment-3021-overview
Free Chemistry Software Links
http://www.sciencegeek.net/Chemistry/chemware/chemware.shtml
http://www.claessen.net/chemistry/soft_en.html
http://www.internetchemistry.com/chemistry-index.html
http://ww2.chemistrycoach.com/
http://hbell.chem.vt.edu/simulation/hb2/TESTPAGE.htm
A simple demo on reactions
Br
-
CH3-CH2-CH2-CH2Br CH3-CH2-CH-CH3 (CH3)3C-Br
Primary bromide Secondary bromide Tertiary bromide
(CH3)3C-Br (CH3)3C-Cl
Tertiary bromide Tertiary chloride
Optical rotation
GC Instrument simulator
A few interesting thoughts...
• No routine home asssignments
Br Me NH2
NH2
A few interesting thoughts...
(a) Solvolysis
R of compound 1 (t-Bu vs. t-Bu-d9) gives a steric isotope effect
t-Bu O
(kR H/kD ) of 1.1. What would you guess to be the KIE for the solvolysis of
O compound 2? Give a brief explanation. [2 +
1: R = H NO2 2 = 4]
2: R = CH3
This is because the C-H bond is longer than the C-D bond and thus less strain is
relieved in compound 2.
A few lectures from my website (need to be updated)
http://orgchem.iisc.ernet.in/faculty/um/teaching.html