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Chemical Bonding I

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CHEMICAL BONDING

Lewis’s theory follows:

1. Electrons, especially those of the outermost (valence) electronic shell,


play a fundamental role in chemical bonding.

2. In some cases, electrons are transferred from one atom to another.


Positive and negative ions are formed and attract each other through
electrostatic forces called ionic bonds.
Gilbert N. Lewis :
Gilbert N. Lewis published a paper about chemical bonding in 1916 with
the title «The atom and the molecule» (Lewis, 1916).
He describes the concepts of electron arrangements. His theory about
bonding is based on the number of outer shell electrons (valence
electrons) in an atom.
He suggested that when two atoms shares a pair of electrons, they form a
chemical bond. Lewis dot diagrams are still in use today.
Lewis

Gilbert N. Lewis suggested that when two atoms shares a pair of


electrons, they form a chemical bond.

Lewis dot diagrams are still in use today.


Lewis Symbols and Lewis Structures

A Lewis symbol consists of a chemical symbol to represent the


nucleus and core (inner-shell) electrons of an atom, together with
dots placed around the symbol to represent the valence(outer-shell)
electrons.

Thus, the Lewis symbol for silicon, which has the electron
configuration , is [Ne]3s23p2
Octet Rule

Most elements follow the octet rule in chemical bonding, which means
that an element should have contact to eight valence electrons in a
bond or exactly fill up its valence shell. Having eight electrons total
ensures that the atom is stable.
Octet Rule

Having eight electrons total ensures that the atom is stable. The noble
gases have the most stable configuration (full octet, no charge),
so they have no reason to react and change their configuration.
They rarely form compounds.
All other elements attempt to gain, lose, or share electrons to
achieve a noble gas configuration.

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