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Chem Acids, Bases and Salts

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Acids, bases and salts

Jun Zhe
What is an acid?
 An acid is a substance that dissolves in water to produce hydrogen ions.
 Have a sour taste.
 Strong ones are corrosive.
 Contains an excess of hydrogen ions.
 Turns blue litmus paper red.
 Has a pH value lower than 7.
 The more acidic a solution, the lower the pH.
Organic and mineral acids

Organic acids examples Mineral acids examples


Acids produced by plants and animals. Acids not produced by living things.
 Ethanoic acid  Hydrochloric acid
 Methanoic acid  Nitric acid
 Lactic acid  Sulfuric acid
 Citric acid  Carbonic acid
Strong and weak acids

Strong acids Weak acids


 Maximum conc. of hydrogen ions  Partially dissociate into ions when dissolved
in water
 Fully ionize when dissolved In water
 E.g. HCOOH, H2CO3
 The stronger the acid, the lower the pH value
 E.g. HCl, HNO3
What is a base?
 Bases is a substance which neutralizes an acid to form a salt and water.
 Bases are usually oxides or hydroxides of metals.
 An alkali is a soluble base.
 The hydroxides of Group 1 metals and aqueous ammonia, are alkalis.
 Alkalis turn red litmus blue.
 Alkalis have a pH value above 7.
 The more alkaline a solution, the higher the pH value.
Strong and weak alkalis

Strong alkalis Weak alkalis


 Maximum possible conc. of OH- ions  Partially dissociate into ions when dissolved
in water.
 Completely ionize when dissolved in water
 E.g. NH3(aq)
 E.g. NaOH, KOH
Indicators
Universal indicator
The characteristics of oxides
 Non-metals generally form acidic oxides that dissolve in water to form acidic solutions.
 E.g. CO2, SiO2
 Metals form oxides that are solids. If they dissolve in water, those oxides give alkaline
solutions. These metal oxides neutralize acids and are basic oxides.
 E.g. MgO, FeO
Special cases

Non-metal oxides:
 Water can be thought of as hydrogen oxide, which is a non-metal oxide. It has a pH value
of 7. Therefore it is a neutral oxide.
 Another example of unusual non-metal oxides is CO, which is also a neutral oxide like
water.
Special cases

Metal oxides:
 Amphoteric hydroxide (or amphoteric metal oxide) – a hydroxide or metal oxide that reacts
with both an acid and an alkali to give a salt and water.
 E.g. zinc hydroxide, aluminium hydroxide
 If sodium hydroxide solution is added to a solution of a salt of either of these metals, a
white precipitate of the metal hydroxide is formed.
 For example, ZnCl2(aq) + 2NaOH(aq)  Zn(OH)2(aq) + 2NaCl(aq)
What is a salt?
 Salt: a compound made from an acid when a metal takes the place of the hydrogen in the
acid.
 E.g. NaOH + HCl  NaCl + H2O
 A salt is formed when an acid reacts with an alkali, a metal, a metal oxide, a metal
hydroxide or metal carbonate.
Examples
 Chlorides are salts formed from hydrochloric acid. For example sodium chloride:
 Hydrochloric acid + sodium hydroxide  sodium chloride + water
 Sulfates are salts formed from sulfuric acid. For example lithium nitrate:
 Sulfuric acid + potassium hydroxide  potassium sulfate + water
 Nitrates are salts formed from nitric acid. For example lithium nitrate:
 Nitric acid + lithium hydroxide  lithium nitrate + water
Chemical reactions of acids
1. Neutralisation
 Acid + base  salt + water
 Acid + alkali  salt + water
 Example: hydrochloric acid + sodium hydroxide  sodium chloride + water
 HCl(aq) + NaOH(aq)  NaCl(s) + H20(l)
 H(aq) + OH-(aq)  H2O(l)
 So, an acid and an alkali can also be defined as:
 Acid: a molecule or ion that is able to donate a proton (H+ ion) to a base.
 Alkali: a molecule or ion that is able to accept a proton.
2. Reaction with metals
 Metal + acid  metal salt + hydrogen
 Example: Zinc + hydrochloric acid  zinc chloride + hydrogen
 Zn + 2HCl  ZnCl2 + H2
3. Reaction with metal oxides
 Metal oxide + acid  metal salt + water
 Example: copper oxide + hydrochloric acid  copper chloride + water
 CuO + 2HCL  CuCl2 + H2O
4. Reaction with metal hydroxides
 Metal hydroxide + acid  metal salt + water
 Example: sodium hydroxide + nitric acid  sodium nitrate + water
 NaOH + HCl  NaCl + H20
5. Reaction with aqueous ammonia
 A solution of aqueous ammonia contains hydroxide ions. So ammonia also reacts to form a
salt.
 Example: Ammonia + hydrochloric acid  ammonium chloride
 NH3 + HCl  NH4Cl
6. Reaction with carbonates
 Metal carbonate + acid  salt + water + carbon dioxide
 Example: calcium carbonate + hydrochloric acid  calcium chloride + water + carbon
dioxide.
 CaCO3 + 2HCl  CaCl2 + H2O + CO2

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