Chem Acids, Bases and Salts
Chem Acids, Bases and Salts
Chem Acids, Bases and Salts
Jun Zhe
What is an acid?
An acid is a substance that dissolves in water to produce hydrogen ions.
Have a sour taste.
Strong ones are corrosive.
Contains an excess of hydrogen ions.
Turns blue litmus paper red.
Has a pH value lower than 7.
The more acidic a solution, the lower the pH.
Organic and mineral acids
Non-metal oxides:
Water can be thought of as hydrogen oxide, which is a non-metal oxide. It has a pH value
of 7. Therefore it is a neutral oxide.
Another example of unusual non-metal oxides is CO, which is also a neutral oxide like
water.
Special cases
Metal oxides:
Amphoteric hydroxide (or amphoteric metal oxide) – a hydroxide or metal oxide that reacts
with both an acid and an alkali to give a salt and water.
E.g. zinc hydroxide, aluminium hydroxide
If sodium hydroxide solution is added to a solution of a salt of either of these metals, a
white precipitate of the metal hydroxide is formed.
For example, ZnCl2(aq) + 2NaOH(aq) Zn(OH)2(aq) + 2NaCl(aq)
What is a salt?
Salt: a compound made from an acid when a metal takes the place of the hydrogen in the
acid.
E.g. NaOH + HCl NaCl + H2O
A salt is formed when an acid reacts with an alkali, a metal, a metal oxide, a metal
hydroxide or metal carbonate.
Examples
Chlorides are salts formed from hydrochloric acid. For example sodium chloride:
Hydrochloric acid + sodium hydroxide sodium chloride + water
Sulfates are salts formed from sulfuric acid. For example lithium nitrate:
Sulfuric acid + potassium hydroxide potassium sulfate + water
Nitrates are salts formed from nitric acid. For example lithium nitrate:
Nitric acid + lithium hydroxide lithium nitrate + water
Chemical reactions of acids
1. Neutralisation
Acid + base salt + water
Acid + alkali salt + water
Example: hydrochloric acid + sodium hydroxide sodium chloride + water
HCl(aq) + NaOH(aq) NaCl(s) + H20(l)
H(aq) + OH-(aq) H2O(l)
So, an acid and an alkali can also be defined as:
Acid: a molecule or ion that is able to donate a proton (H+ ion) to a base.
Alkali: a molecule or ion that is able to accept a proton.
2. Reaction with metals
Metal + acid metal salt + hydrogen
Example: Zinc + hydrochloric acid zinc chloride + hydrogen
Zn + 2HCl ZnCl2 + H2
3. Reaction with metal oxides
Metal oxide + acid metal salt + water
Example: copper oxide + hydrochloric acid copper chloride + water
CuO + 2HCL CuCl2 + H2O
4. Reaction with metal hydroxides
Metal hydroxide + acid metal salt + water
Example: sodium hydroxide + nitric acid sodium nitrate + water
NaOH + HCl NaCl + H20
5. Reaction with aqueous ammonia
A solution of aqueous ammonia contains hydroxide ions. So ammonia also reacts to form a
salt.
Example: Ammonia + hydrochloric acid ammonium chloride
NH3 + HCl NH4Cl
6. Reaction with carbonates
Metal carbonate + acid salt + water + carbon dioxide
Example: calcium carbonate + hydrochloric acid calcium chloride + water + carbon
dioxide.
CaCO3 + 2HCl CaCl2 + H2O + CO2