Group Seminar On Desalter
Group Seminar On Desalter
Group Seminar On Desalter
1. 2.
3.
Importance of Desalting Operating Principles of Desalting Desalter efficiency and its significance
Submitted by:
IMPORTANCE OF DESALTING
WHAT IS DESALTING?
Contaminants are broadly classified into: 1. Water 2. Salts 3. Bottom sediments 4. Trace metals
MERITS OF DESALTING
Removes contaminants Prevents corrosion and fouling Saves energy Reduces maintenance Increases the capacity of CDU Stabilizes the operation
TYPES OF DESALTING
TO At mos Colum n
1ST STAGE
2ND STAGE
MIX VAL E V
BRINE EXCHANGE R
METHODS
Settling
of chemicals
Addition
Electrical
desalting
STEPS:
Heating Mixing: emulsion Settling
CHEMICAL ADDITION
The Desalter removes contaminants from crude oil by first emulsifying the crude oil with chemicals and wash water to promote thorough contact of the water and oil. The salts containing some of the metals that can poison catalysts are dissolved in the water phase. After the oil has been washed and mixed as an emulsion of oil and water, demulsifying chemicals are then added. Solids present in the crude will accumulate in the bottom of the desalter vessel.
ELECTRICAL DESALTERS
Forming an emulsion Demulsification process:breaking of emulsion is accomplished by coalescing the small particles of emulsion.
Electrical Coalescence
Dipole Coalescence
+++ ++ +
---+++ ++ +
Force of Attraction
----
F = K E2 r6/a4
Where: K = Dielectric constant of oil E = Voltage gradient r = Droplet radius a = Distance between
Effluen t water
Heated to temp in the range 120-130 oC Water is added to the crude stream and passed through a mixing valve. The emulsified crude oil is subjected to high voltage (20000 to 24000 volts) electric field.
Performance Evaluation
Desalting efficiency
Dewatering/ dehydrating efficiency Wi - inlet water content Ww - wash water rate Wo-outlet water content
Performance Evaluation
Mixing index
Metal Contaminants
Jersey Nickel Equivalent Index 1000 * (Ni + 0.2V +0.1 Fe) Shell Contamination Index 1000 * (14Ni + 14Cu + 4V + Fe)
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