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    Wed Sep 25 2024

    Uploaded by

    Waqas Ahmad

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    Wed Sep 25 2024

    Uploaded by

    Waqas Ahmad
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    Wed-Sep-25-2024

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    2 views7 pages

    Wed Sep 25 2024

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    Waqas Ahmad

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    Wide Bandgap Perovskite Solar Cells, their

    Challenges, and Mitigation

    1
    Fabricated Wide Bandgap Semi-Transparent PSCs

    • Cs0.05FA0.8MA0.15Pb(I0.75Br0.25)3

    • Eg = 1.68 eV

    • PVK/HTL interface passivation with 2-chloro-phenethylammonium iodide (2-Cl-PEAI)

    Ag Ag Ag Ag Ag Ag
    IZO IZO
    MoO3 MoO3
    Spiro-OMeTAD Spiro-OMeTAD

    PVK PVK/2-Cl-PEAI

    SnO2 SnO2
    Glass/FTO Glass/FTO

    Device-1: without 2-Cl-PEAI Device-2: with 2-Cl-PEAI

    2
    Adverse Effects of N, N-dimethylformamide (DMF) solvent

    Handling and
    Toxicity
    Safety Issues

    Wide Eg
    Perovskites
    Problems
    Regulatory Health Risks
    Ristrictions

    EnvironmentI
    mpact

    3
    Literature: Mitigating Wide Bandgap PSCs’ Problems

    Compositional
    Engineering

    Lower Light Mitigation A-site Cation


    Instensity
    Strategies Mixing

    Interface
    Passivation https://doi.org/10.1016/j.nanoen.2024.10998

    4
    Literature: Device Structure

    PVK composition: FA0.8Cs0.2Pb(I0.6Br0.4)3


    Eg = 1.79 eV
    Structure: Inverted (PIN)
    Additives: potassium thiocyanate and potassium chloride (KSCN+KCl)
    Passivation: 2-thiophene methylamine iodine (2-ThMAI)

    Ag Ag Ag
    BCP
    C60 (ETL)
    2-ThMAI

    PVK + (KCL+KSCN)

    SAM (HTL)
    ITO-coated glass

    5
    Dual Approach Mitigating Voc Loss

    reduce grain boundaries

    Mixed potassium thiocyanate


    and potassium chloride enlarge grain size
    (KSCN+KCl) additives

    suppress ions migration

    +
    homogeneous PVK surface potential

    2-thiophene methylamine
    PVK/ETL energy alignment
    iodine (2-ThMAI)

    reduce non-radiative recombination

    6
    Literature: Results

    Effect of changing KSCN & KCL content on the devices’ performance

    Effect of changing 2-ThMAI content on the devices’ performance

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