We report the atomic layer deposition of titanium dioxide on carbon nanosheet templates and inves... more We report the atomic layer deposition of titanium dioxide on carbon nanosheet templates and investigate the effects of post-deposition annealing in a helium environment using different characterization techniques. The crystallization of the titanium dioxide coating upon annealing is observed using in-situ X-ray diffraction. The (micro)-structural characterization of the films is carried out by scanning electron microscopy and advanced transmission electron microscopy techniques. Our study shows that the annealing of the atomic layer deposition processed and carbon nanosheets templated titanium dioxide layers in helium environment results in the formation of a porous, nanocrystalline and photocatalytically active titanium dioxide-carbon nanosheet composite film. Such composites are suitable for photocatalysis and dye-sensitized solar cells applications.
We investigate topological aspects of sub-nm electron vortex beams upon elastic propagation throu... more We investigate topological aspects of sub-nm electron vortex beams upon elastic propagation through atomic scattering potentials. Two main aspects can be distinguished: (i) Significantly reduced delocalization compared to a similar non-vortex beam if the beam centers on an atomic column and (ii) site symmetry dependent splitting of higher-order vortex beams. Furthermore, the results provide insight into the complex vortex line fabric within the elastically scattered wave containing characteristic vortex loops predominantly attached to atomic columns and characteristic twists of vortex lines around atomic columns.
In this paper we explore the desirability of a transmission electron microscope in which the phas... more In this paper we explore the desirability of a transmission electron microscope in which the phase of the electron wave can be freely controlled. We discuss different existing methods to manipulate the phase of the electron wave and their limitations. We show how with the help of current techniques the electron wave can already be crafted into specific classes of waves each having their own peculiar properties. Assuming a versatile phase modulation device is feasible, we explore possible benefits and methods that could come into existence borrowing from light optics where the so-called spatial light modulators provide programmable phase plates for quite some time now. We demonstrate that a fully controllable phase plate building on Harald Rose׳s legacy in aberration correction and electron optics in general would open an exciting field of research and applications.
In this work we derive expressions for the orbital angular momentum (OAM) density of light, for b... more In this work we derive expressions for the orbital angular momentum (OAM) density of light, for both symmetric and nonsymmetric optical fields, that allow a direct comparison between theory and experiment. We present a simple method for measuring the OAM density in optical fields and test the approach on superimposed nondiffracting higher-order Bessel beams. The measurement technique makes use of a single spatial light modulator and a Fourier transforming lens to measure the OAM spectrum of the optical field. Quantitative values for the OAM density as a function of the radial position in the optical field are obtained for both symmetric and nonsymmetric superpositions, illustrating good agreement with the theoretical prediction.
Electron vortex beams carrying intrinsic orbital angular momentum (OAM) are produced in electron ... more Electron vortex beams carrying intrinsic orbital angular momentum (OAM) are produced in electron microscopes where they are controlled and focused using magnetic lenses. We observe various rotational phenomena arising from the interaction between the OAM and magnetic lenses. First, the Zeeman coupling, proportional to the OAM and magnetic field strength, produces an OAM-independent Larmor rotation of a mode superposition inside the lens. Second, hen passing through the focal plane, the electron beam acquires an additional Gouy phase dependent on the absolute value of the OAM. This brings about the Gouy rotation of the superposition image proportional to the sign of the OAM. A combination of the Larmor and Gouy effects can result in the addition (or subtraction) of rotations, depending on the OAM sign. This behaviour is unique to electron vortex beams and has no optical counterpart, as Larmor rotation occurs only for charged particles. Our experimental results are in agreement with recent theoretical predictions.
Hydrogenation of dilute nitrides GaAs/GaAs1-xNx heterostructures has been demonstrated to strongl... more Hydrogenation of dilute nitrides GaAs/GaAs1-xNx heterostructures has been demonstrated to strongly influence the electronic properties of the system. In such heterostructures, strain and static disorder have been studied by means of high resolution X-ray diffraction and RBS-channeling techniques, showing correlations with the H-induced changes of the electronic properties [1]. Recently quantum confinement has been reported in GaAs/GaAs1-xNx-GaAs1-xNx: H planar heterostructures [2]. It is well known that patterned heterostructures ...
We report the atomic layer deposition of titanium dioxide on carbon nanosheet templates and inves... more We report the atomic layer deposition of titanium dioxide on carbon nanosheet templates and investigate the effects of post-deposition annealing in a helium environment using different characterization techniques. The crystallization of the titanium dioxide coating upon annealing is observed using in-situ X-ray diffraction. The (micro)-structural characterization of the films is carried out by scanning electron microscopy and advanced transmission electron microscopy techniques. Our study shows that the annealing of the atomic layer deposition processed and carbon nanosheets templated titanium dioxide layers in helium environment results in the formation of a porous, nanocrystalline and photocatalytically active titanium dioxide-carbon nanosheet composite film. Such composites are suitable for photocatalysis and dye-sensitized solar cells applications.
We investigate topological aspects of sub-nm electron vortex beams upon elastic propagation throu... more We investigate topological aspects of sub-nm electron vortex beams upon elastic propagation through atomic scattering potentials. Two main aspects can be distinguished: (i) Significantly reduced delocalization compared to a similar non-vortex beam if the beam centers on an atomic column and (ii) site symmetry dependent splitting of higher-order vortex beams. Furthermore, the results provide insight into the complex vortex line fabric within the elastically scattered wave containing characteristic vortex loops predominantly attached to atomic columns and characteristic twists of vortex lines around atomic columns.
In this paper we explore the desirability of a transmission electron microscope in which the phas... more In this paper we explore the desirability of a transmission electron microscope in which the phase of the electron wave can be freely controlled. We discuss different existing methods to manipulate the phase of the electron wave and their limitations. We show how with the help of current techniques the electron wave can already be crafted into specific classes of waves each having their own peculiar properties. Assuming a versatile phase modulation device is feasible, we explore possible benefits and methods that could come into existence borrowing from light optics where the so-called spatial light modulators provide programmable phase plates for quite some time now. We demonstrate that a fully controllable phase plate building on Harald Rose׳s legacy in aberration correction and electron optics in general would open an exciting field of research and applications.
In this work we derive expressions for the orbital angular momentum (OAM) density of light, for b... more In this work we derive expressions for the orbital angular momentum (OAM) density of light, for both symmetric and nonsymmetric optical fields, that allow a direct comparison between theory and experiment. We present a simple method for measuring the OAM density in optical fields and test the approach on superimposed nondiffracting higher-order Bessel beams. The measurement technique makes use of a single spatial light modulator and a Fourier transforming lens to measure the OAM spectrum of the optical field. Quantitative values for the OAM density as a function of the radial position in the optical field are obtained for both symmetric and nonsymmetric superpositions, illustrating good agreement with the theoretical prediction.
Electron vortex beams carrying intrinsic orbital angular momentum (OAM) are produced in electron ... more Electron vortex beams carrying intrinsic orbital angular momentum (OAM) are produced in electron microscopes where they are controlled and focused using magnetic lenses. We observe various rotational phenomena arising from the interaction between the OAM and magnetic lenses. First, the Zeeman coupling, proportional to the OAM and magnetic field strength, produces an OAM-independent Larmor rotation of a mode superposition inside the lens. Second, hen passing through the focal plane, the electron beam acquires an additional Gouy phase dependent on the absolute value of the OAM. This brings about the Gouy rotation of the superposition image proportional to the sign of the OAM. A combination of the Larmor and Gouy effects can result in the addition (or subtraction) of rotations, depending on the OAM sign. This behaviour is unique to electron vortex beams and has no optical counterpart, as Larmor rotation occurs only for charged particles. Our experimental results are in agreement with recent theoretical predictions.
Hydrogenation of dilute nitrides GaAs/GaAs1-xNx heterostructures has been demonstrated to strongl... more Hydrogenation of dilute nitrides GaAs/GaAs1-xNx heterostructures has been demonstrated to strongly influence the electronic properties of the system. In such heterostructures, strain and static disorder have been studied by means of high resolution X-ray diffraction and RBS-channeling techniques, showing correlations with the H-induced changes of the electronic properties [1]. Recently quantum confinement has been reported in GaAs/GaAs1-xNx-GaAs1-xNx: H planar heterostructures [2]. It is well known that patterned heterostructures ...
Uploads