Location via proxy:   [ UP ]  
[Report a bug]   [Manage cookies]                
skip to main content
10.1145/3366194.3366243acmotherconferencesArticle/Chapter ViewAbstractPublication PagesricaiConference Proceedingsconference-collections
research-article

Graphene Oxide Modified LiNi1/3Co1/3Mn1/3O2 Cathodes with Improved Performance for Lithium-ion Battery

Published: 20 September 2019 Publication History

Abstract

In this work, the surface of LiNi1/3Co1/3Mn1/3O2 (NCM) cathodes prepared by the conventional method is modified with graphene oxide (GO) by dipping method. The X-ray diffraction (XRD) tests display that the crystalline structure of the modified NCM cathodes does not change obviously. The morphology of the pristine and modified NCM cathodes are characterized by scanning electron microscopy (SEM), and the results reveal that increased graphene oxide are detected on the surface of the modified NCM cathodes. The rate capability and cycling performance of both cathodes are evaluated by galvanostatic charge and discharge tests, and it can be concluded that the modified NCM cathodes have better cycling performance and high rate capability than the pristine NCM samples at a cut-off voltage of 4.3V. The results of the CV test and EIS test demonstrate that the additional graphene oxide can slow down the increase of electrochemical polarization.

References

[1]
Sathiya, M., et al., Origin of voltage decay in high-capacity layered oxide electrodes. Nature Materials, 2014. 14(2): p. 230--238.
[2]
Stiaszny, B., et al., Electrochemical characterization and post-mortem analysis of aged LiMn2O4--Li(Ni0.5Mn0.3Co0.2)O2/graphene lithium ion batteries. Part I: Cycle aging. Journal of Power Sources, 2014. 251: p. 439--450.
[3]
Liu, X., et al., Improvement of electrochemical properties of LiNi1/3Co1/3Mn1/3O2 by coating with V2O5 layer. Journal of Alloys and Compounds, 2013. 552: p. 76--82.
[4]
Liu, S., L. Xiong, and C. He, Long cycle life lithium ion battery with lithium nickel cobalt manganese oxide (NCM) cathode. Journal of Power Sources, 2014. 261: p. 285--291.
[5]
Han, X., et al., A comparative study of commercial lithium ion battery cycle life in electric vehicle: Capacity loss estimation. Journal of Power Sources, 2014. 268: p. 658--669.
[6]
He, J.-r., et al., Synthesis and electrochemical properties of graphene-modified LiCo1/3Ni1/3Mn1/3O2cathodes for lithium ion batteries. RSC Adv., 2014. 4(5): p. 2568--2572.
[7]
Gallus, D.R., et al., The influence of different conducting salts on the metal dissolution and capacity fading of NCM cathode material. Electrochimica Acta, 2014. 134: p. 393--398.
[8]
Han, Z., et al., Sb2O3-modified LiNi1/3Co1/3Mn1/3O2 material with enhanced thermal safety and electrochemical property. Journal of Power Sources, 2014. 254: p. 106--111.
[9]
Liu, X., et al., PEDOT modified LiNi1/3Co1/3Mn1/3O2 with enhanced electrochemical performance for lithium ion batteries. Journal of Power Sources, 2013. 243: p. 374--380.
[10]
Lin, B., et al., Electrochemical properties of carbon-coated Li[Ni1/3Co1/3Mn1/3]O2 cathode material for lithium-ion batteries. Solid State Ionics, 2008. 179(27-32): p. 1750--1753.
[11]
Liu, J., et al., Carbon-coated high capacity layered Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathodes. Electrochemistry Communications, 2010. 12(6): p. 750--753.
[12]
Hashem, A.M.A., et al., Study of the surface modification of LiNi1/3Co1/3Mn1/3O2 cathode material for lithium ion battery. Journal of Power Sources, 2011. 196(20): p. 8632--8637.
[13]
Chen, Z., et al., Recent progress in surface coating of layered LiNixCoyMnzO2 for lithium-ion batteries. Materials Research Bulletin, 2017. 96: p. 491--502.
[14]
Zhou, P., et al., SiO2-coated LiNi0.915Co0.075Al0.01O2 cathode material for rechargeable Li-ion batteries. Nanoscale, 2016. 8(46): p. 19263--19269.
[15]
Cho, W., et al., Improved electrochemical and thermal properties of nickel rich LiNi0.6Co0.2Mn0.2O2 cathode materials by SiO2 coating. Journal of Power Sources, 2015. 282: p. 45--50.
[16]
Chen, Y., et al., An approach to application for LiNi0.6Co0.2Mn0.2O2 cathode material at high cutoff voltage by TiO2 coating. Journal of Power Sources, 2014. 256: p. 20--27.
[17]
Liang, H., et al., Improvement in the electrochemical performance of LiNi0.8Co0.1Mn0.1O2 cathode material by Li2ZrO3 coating. Applied Surface Science, 2017. 423: p. 1045--1053.
[18]
Lv, D., et al., Li2O-B2O3-Li2SO4 modified LiNi1/3Co1/3Mn1/3O2 cathode material for enhanced electrochemical performance. Electrochimica Acta, 2017. 247: p. 803--811.
[19]
Shi, S.J., et al., Structure and electrochemical performance of CaF2 coated LiMn1/3Ni1/3Co1/3O2 cathode material for Li-ion batteries. Electrochimica Acta, 2012. 83: p. 105--112.
[20]
Lee, S.-W., et al., Li3PO4 surface coating on Ni-rich LiNi 0.6Co0.2Mn0.2O2 by a citric acid assisted sol-gel method: Improved thermal stability and high-voltage performance. Journal of Power Sources, 2017. 360: p. 206--214.
[21]
Wu, F., et al., Surface of LiCo1/3Ni1/3Mn1/3O2 modified by CeO2-coating. Electrochimica Acta, 2009. 54(27): p. 6803--6807.
[22]
Jung, Y.S., et al., Ultrathin direct atomic layer deposition on composite electrodes for highly durable and safe Li-ion batteries. Adv Mater, 2010. 22(19): p. 2172--6.
[23]
Tan, G., et al., Coralline Glassy Lithium Phosphate-Coated LiFePO4 Cathodes with Improved Power Capability for Lithium Ion Batteries. The Journal of Physical Chemistry C, 2013. 117(12): p. 6013--6021.
[24]
Zhou, A., et al., Sputtering TiO2 on LiCoO2 composite electrodes as a simple and effective coating to enhance high-voltage cathode performance. Journal of Power Sources, 2017. 346: p. 24--30.
[25]
Dai, X., et al., Improved electrochemical performance of LiCoO(2) electrodes with ZnO coating by radio frequency magnetron sputtering. ACS Appl Mater Interfaces, 2014. 6(18): p. 15853--9.
[26]
Zhou, A., et al., Stable, fast and high-energy-density LiCoO2 cathode at high operation voltage enabled by glassy B2O3 modification. Journal of Power Sources, 2017. 362: p. 131--139.
[27]
Xu S D, Zhuang Q C, Tian L L, et al. Impedance spectra of nonhomogeneous, multilayered porous composite graphite electrodes for li-ion batteries: experimental and theoretical studies[J]. Journal of Physical Chemistry C, 2011, 115(18): 9210--9219.

Index Terms

  1. Graphene Oxide Modified LiNi1/3Co1/3Mn1/3O2 Cathodes with Improved Performance for Lithium-ion Battery

    Recommendations

    Comments

    Information & Contributors

    Information

    Published In

    cover image ACM Other conferences
    RICAI '19: Proceedings of the 2019 International Conference on Robotics, Intelligent Control and Artificial Intelligence
    September 2019
    803 pages
    ISBN:9781450372985
    DOI:10.1145/3366194
    Permission to make digital or hard copies of all or part of this work for personal or classroom use is granted without fee provided that copies are not made or distributed for profit or commercial advantage and that copies bear this notice and the full citation on the first page. Copyrights for components of this work owned by others than ACM must be honored. Abstracting with credit is permitted. To copy otherwise, or republish, to post on servers or to redistribute to lists, requires prior specific permission and/or a fee. Request permissions from [email protected]

    Publisher

    Association for Computing Machinery

    New York, NY, United States

    Publication History

    Published: 20 September 2019

    Permissions

    Request permissions for this article.

    Check for updates

    Author Tags

    1. LiNi1/3Co1/3Mn1/3O2 cathodes
    2. dipping method
    3. graphene oxide
    4. surface modification

    Qualifiers

    • Research-article
    • Research
    • Refereed limited

    Conference

    RICAI 2019

    Acceptance Rates

    RICAI '19 Paper Acceptance Rate 140 of 294 submissions, 48%;
    Overall Acceptance Rate 140 of 294 submissions, 48%

    Contributors

    Other Metrics

    Bibliometrics & Citations

    Bibliometrics

    Article Metrics

    • 0
      Total Citations
    • 103
      Total Downloads
    • Downloads (Last 12 months)6
    • Downloads (Last 6 weeks)0
    Reflects downloads up to 18 Aug 2024

    Other Metrics

    Citations

    View Options

    Get Access

    Login options

    View options

    PDF

    View or Download as a PDF file.

    PDF

    eReader

    View online with eReader.

    eReader

    Media

    Figures

    Other

    Tables

    Share

    Share

    Share this Publication link

    Share on social media