Fullerene Rosette: Two-Dimensional Interactive Nanoarchitectonics and Selective Vapor Sensing
Abstract
:1. Introduction
2. Results
2.1. Characterizations of the Prepared C60 Self-Assembled Structures
2.2. Sensing of Organic Vapors by Quartz Crystal Microbalance
3. Discussion
4. Materials and Methods
4.1. Materials
4.2. Synthesis of C60 Rosettes
4.3. Characterizations
4.4. Sensing of Vapor by Quartz Crystal Microbalance (QCM)
5. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Entry | C60in
m-xylene (mL) 1 | IPA (mL) | MM in EDA (mL) | Shapes | Remarks |
---|---|---|---|---|---|
1 | 8.0 | 2.0 | 0.5 | | Edge tends to cleave |
2 | 8.0 | 2.0 | 0.6 | | Edge cleaving started |
3 | 8.0 | 2.0 | 0.7 | | Edge cleaving increases |
4 | 8.0 | 2.0 | 0.8 | | Edge cleaving increases more |
5 | 8.0 | 2.0 | 1.0 | | Beautiful flower shape formed |
6 | 8.0 2 | 2.0 | 1.0 | − | No edge cleaving/heterogeneous shapes |
7 | 8.0 | 1.0 | 2.0 | − | No edge cleaving/heterogeneous shapes |
8 | 8.0 | 1.0 | 2.0 3 | − | Heterogeneous shapes |
9 | 8.5 | 1.5 | 0.5 | − | Heterogeneous shapes |
10 | 8.5 | 1.5 | 0.6 | − | Heterogeneous shapes with sheet types |
11 | 8.5 | 1.5 | 0.7 | − | Heterogeneous flower shapes |
12 | 8.5 | 1.5 | 0.8 | | Most perfect and homogeneous beautiful flower shape formed |
Materials | ΔF (Hz) | ΔF (Hz) Ratio of FA/PRD (Acid/Base) | ΔF (Hz) Ratio of FA/AA (Acid/Acid) | ΔF (Hz) Ratio of FA/Hydrocarbon (Acid/Neutral) | Reference |
---|---|---|---|---|---|
PANI−QCM | 20 | − | − | − | [48] |
DAP−QCM | 824 | − | − | − | [49] |
MWCNT | 196 | − | 1.3 | − | [50] |
MCN−ATN | 1195 | ~4 | 1.16 | 10.5 (toluene) | [51] |
Ph−g−C3N4 | 13,417 | 15.8 | 3.1 | 106.5 (benzene) | [52] |
MOF−GC@COF | 98 | ~2 (Et3N) | − | 12.0 (n-hexane) | [53] |
FNR−EDA | 1758 | ~17 | 1.45 | 14.9 (toluene) | [40] |
CHFC | 1700 | 7.7 | 0.69 | 30.7 (toluene) | [54] |
C60−fullerphene | 21,204 | − | 18.8 | 375 (benzene) | [41] |
C60−R | 12,930 | 31.5 | 1.8 | 112 (toluene) | This study |
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Chen, G.; Bhadra, B.N.; Sutrisno, L.; Shrestha, L.K.; Ariga, K. Fullerene Rosette: Two-Dimensional Interactive Nanoarchitectonics and Selective Vapor Sensing. Int. J. Mol. Sci. 2022, 23, 5454. https://doi.org/10.3390/ijms23105454
Chen G, Bhadra BN, Sutrisno L, Shrestha LK, Ariga K. Fullerene Rosette: Two-Dimensional Interactive Nanoarchitectonics and Selective Vapor Sensing. International Journal of Molecular Sciences. 2022; 23(10):5454. https://doi.org/10.3390/ijms23105454
Chicago/Turabian StyleChen, Guoping, Biswa Nath Bhadra, Linawati Sutrisno, Lok Kumar Shrestha, and Katsuhiko Ariga. 2022. "Fullerene Rosette: Two-Dimensional Interactive Nanoarchitectonics and Selective Vapor Sensing" International Journal of Molecular Sciences 23, no. 10: 5454. https://doi.org/10.3390/ijms23105454