A pilot scale installation 1.8 m long and 1.6 m wide was designed to simulate a surface treatment... more A pilot scale installation 1.8 m long and 1.6 m wide was designed to simulate a surface treatment tank incorporating a lateral capture system and a distribution network that permits the surface emission of tracer (SF6). The capture efficiency, ET, was determined as a function of the specific capture flow qc, m3/sm2, for three tank lengths, L, (1.2, 1.53, and 1.8 m) and several temperatures, T, from ambient to 95 degrees C, keeping the surrounding air velocity low (v < or = 0.1 m/sec). The data showed a satisfactory fit to a model that related capture efficiency with two exponential functions: the first dependent on the ratio capture velocity/air velocity in the vicinity of the tank, and the second on the ratio capture velocity/velocity of rising drafts provoked by the temperature of the tank.
The raw water used in Drinking Water Treatment Plants (DWTPs) can present high values of naturall... more The raw water used in Drinking Water Treatment Plants (DWTPs) can present high values of naturally occurring radionuclides. In order to reduce this content, the routine working conditions of DWTPs were successfully modified. This meant that those radionuclides were accumulated in the sludges generated, whose radioactive content was frequently above the exemption levels. It therefore becomes necessary to assess the association of naturally occurring radionuclides in the sludges for their potential use as agricultural fertilizers. Two approaches were studied: (a) the effect of different sequential extraction methods applied to a selected sludge; and (b) the effect of the different contents of inorganic complexes dissolved in the input water on the composition of the sludges generated by two DWTPs with different origins of their input water. Uranium and radium were mainly associated with the carbonated and reducible fractions, while (210)Po and (228)Th were associated with the residual fraction. There were differences between the two speciation methods, but the order of bioavailable radionuclides was roughly the same: (226)Ra≈(234,238)U>(228)Th>(210)Po. The major inorganic complexes content, mainly carbonate, in the raw water affected the radionuclide association. The greater the carbonate content in the raw water, the greater was the association of uranium and radium with the carbonated and easily reducible fractions.
A real-scale pilot installation simulating an open surface treatment tank with a push-pull ventil... more A real-scale pilot installation simulating an open surface treatment tank with a push-pull ventilation system has been designed. From experiments carried out, typical representations of the total and transversal linear efficiencies show that when total efficiency is related to push flow rate, taking as a parameter the pull flow rate, a parabolic profile is obtained with a maximum point or plateau that increases as the pull flow increases. When the transversal linear efficiency is analysed, three general zones where losses occur to the exterior can be detected: (i) when the push flow rate is low, any distortion in the wall jet, whether external (e.g. in the air flow inside the workshop) or internal (e.g. thermal effects), provokes an escape from contaminant; (ii) in the impact zone, where the push flow impacts on the tank surface, distortion increases as the push flow rate increases; (iii) when the push/pull flow rate ratio increases and preferential currents are produced inside the exhaust hood, these escape and cause substantial losses in efficiency.
Elastic scattering of 35Cl and 37Cl on 24Mg was measured at two c.m. energies. Optical model anal... more Elastic scattering of 35Cl and 37Cl on 24Mg was measured at two c.m. energies. Optical model analysis with different potentials are compared. Isotopics effects on absorption are observed. The closure approximation model is found to give a good reproduction of experimental data.
Nuclear Instruments & Methods in Physics Research Section a-Accelerators Spectrometers Detectors and Associated Equipment, 2011
The analysis of alpha spectra requires good radiochemical procedures in order to obtain well diff... more The analysis of alpha spectra requires good radiochemical procedures in order to obtain well differentiated alpha peaks in the spectrum, and the easiest way to analyze them is by directly summing the counts obtained in the Regions of Interest (ROIs). However, the low-energy tails of the alpha peaks frequently make this simple approach unworkable because some peaks partially overlap. Many fitting procedures have been proposed to solve this problem, most of them based on semi-empirical mathematical functions that emulate the shape of a theoretical alpha peak. The main drawback of these methods is that the great number of fitting parameters used means that their physical meaning is obscure or completely lacking. We propose another approach—the application of an artificial neural network. Instead of fitting the experimental data to a mathematical function, the fit is carried out by an artificial neural network (ANN) that has previously been trained to model the shape of an alpha peak using as training patterns several polonium spectra obtained from actual samples analyzed in our laboratory. In this sense, the ANN is able to learn the shape of an actual alpha peak. We have designed such an ANN as a feed-forward multi-layer perceptron with supervised training based on a back-propagation algorithm. The fitting procedure is based on the experimental observables that are characteristic of alpha peaks—the number of counts of the maximum and several peak widths at different heights. Polonium isotope spectra were selected because the alpha peaks corresponding to 208Po, 209Po, and 210Po are monoenergetic and well separated. The uncertainties introduced by this fitting procedure were less than the counting uncertainties. This new approach was applied to the problem of resolving overlapping peaks. Firstly, a theoretical study was carried out by artificially overlapping alpha peaks from actual samples in order to test the ability of the ANN to resolve each peak. Then, the ANN procedure was checked by determining the activity levels of different spectra obtained from certified samples for which one knows a priori the radioactive content, and its results were compared with those of other methods.
This work is the result of a collaboration between Spanish and Portuguese laboratories. The speci... more This work is the result of a collaboration between Spanish and Portuguese laboratories. The specific objective was to quantify the time evolution during 1994, 1995 and 1996 of the radioecological impact of the liquid releases of 3H from the Almaraz Nuclear Power Plant (ANPP) in the section of the Tagus River corresponding to Cáceres province in Spain and the Alentejo region in Portugal. We found that the temporal evolution of the levels of tritium depends on the management of the water held in the cooling reservoir of the ANPP and the presence of the dams that exist along the river. This management regime has a 12-month period. Also the movement of the mass of tritiated water (HTO) downriver was much faster during 1996 than 1995 or 1994 due to the hydrological differences between those years and consequently to the different amounts of water transferred between the reservoirs of the dams. From the hypothesis that hydrodynamically it is impossible to differentiate tritiated water from non-tritiated water, a model was constructed that satisfactorily reproduces the temporal evolution of the 3H in the zone of the Tagus River in which the exchange of water takes place, with the cooling reservoir of the Almaraz Nuclear Power Plant.
A pilot scale installation 1.8 m long and 1.6 m wide was designed to simulate a surface treatment... more A pilot scale installation 1.8 m long and 1.6 m wide was designed to simulate a surface treatment tank incorporating a lateral capture system and a distribution network that permits the surface emission of tracer (SF6). The capture efficiency, ET, was determined as a function of the specific capture flow qc, m3/sm2, for three tank lengths, L, (1.2, 1.53, and 1.8 m) and several temperatures, T, from ambient to 95 degrees C, keeping the surrounding air velocity low (v < or = 0.1 m/sec). The data showed a satisfactory fit to a model that related capture efficiency with two exponential functions: the first dependent on the ratio capture velocity/air velocity in the vicinity of the tank, and the second on the ratio capture velocity/velocity of rising drafts provoked by the temperature of the tank.
The raw water used in Drinking Water Treatment Plants (DWTPs) can present high values of naturall... more The raw water used in Drinking Water Treatment Plants (DWTPs) can present high values of naturally occurring radionuclides. In order to reduce this content, the routine working conditions of DWTPs were successfully modified. This meant that those radionuclides were accumulated in the sludges generated, whose radioactive content was frequently above the exemption levels. It therefore becomes necessary to assess the association of naturally occurring radionuclides in the sludges for their potential use as agricultural fertilizers. Two approaches were studied: (a) the effect of different sequential extraction methods applied to a selected sludge; and (b) the effect of the different contents of inorganic complexes dissolved in the input water on the composition of the sludges generated by two DWTPs with different origins of their input water. Uranium and radium were mainly associated with the carbonated and reducible fractions, while (210)Po and (228)Th were associated with the residual fraction. There were differences between the two speciation methods, but the order of bioavailable radionuclides was roughly the same: (226)Ra≈(234,238)U>(228)Th>(210)Po. The major inorganic complexes content, mainly carbonate, in the raw water affected the radionuclide association. The greater the carbonate content in the raw water, the greater was the association of uranium and radium with the carbonated and easily reducible fractions.
A real-scale pilot installation simulating an open surface treatment tank with a push-pull ventil... more A real-scale pilot installation simulating an open surface treatment tank with a push-pull ventilation system has been designed. From experiments carried out, typical representations of the total and transversal linear efficiencies show that when total efficiency is related to push flow rate, taking as a parameter the pull flow rate, a parabolic profile is obtained with a maximum point or plateau that increases as the pull flow increases. When the transversal linear efficiency is analysed, three general zones where losses occur to the exterior can be detected: (i) when the push flow rate is low, any distortion in the wall jet, whether external (e.g. in the air flow inside the workshop) or internal (e.g. thermal effects), provokes an escape from contaminant; (ii) in the impact zone, where the push flow impacts on the tank surface, distortion increases as the push flow rate increases; (iii) when the push/pull flow rate ratio increases and preferential currents are produced inside the exhaust hood, these escape and cause substantial losses in efficiency.
Elastic scattering of 35Cl and 37Cl on 24Mg was measured at two c.m. energies. Optical model anal... more Elastic scattering of 35Cl and 37Cl on 24Mg was measured at two c.m. energies. Optical model analysis with different potentials are compared. Isotopics effects on absorption are observed. The closure approximation model is found to give a good reproduction of experimental data.
Nuclear Instruments & Methods in Physics Research Section a-Accelerators Spectrometers Detectors and Associated Equipment, 2011
The analysis of alpha spectra requires good radiochemical procedures in order to obtain well diff... more The analysis of alpha spectra requires good radiochemical procedures in order to obtain well differentiated alpha peaks in the spectrum, and the easiest way to analyze them is by directly summing the counts obtained in the Regions of Interest (ROIs). However, the low-energy tails of the alpha peaks frequently make this simple approach unworkable because some peaks partially overlap. Many fitting procedures have been proposed to solve this problem, most of them based on semi-empirical mathematical functions that emulate the shape of a theoretical alpha peak. The main drawback of these methods is that the great number of fitting parameters used means that their physical meaning is obscure or completely lacking. We propose another approach—the application of an artificial neural network. Instead of fitting the experimental data to a mathematical function, the fit is carried out by an artificial neural network (ANN) that has previously been trained to model the shape of an alpha peak using as training patterns several polonium spectra obtained from actual samples analyzed in our laboratory. In this sense, the ANN is able to learn the shape of an actual alpha peak. We have designed such an ANN as a feed-forward multi-layer perceptron with supervised training based on a back-propagation algorithm. The fitting procedure is based on the experimental observables that are characteristic of alpha peaks—the number of counts of the maximum and several peak widths at different heights. Polonium isotope spectra were selected because the alpha peaks corresponding to 208Po, 209Po, and 210Po are monoenergetic and well separated. The uncertainties introduced by this fitting procedure were less than the counting uncertainties. This new approach was applied to the problem of resolving overlapping peaks. Firstly, a theoretical study was carried out by artificially overlapping alpha peaks from actual samples in order to test the ability of the ANN to resolve each peak. Then, the ANN procedure was checked by determining the activity levels of different spectra obtained from certified samples for which one knows a priori the radioactive content, and its results were compared with those of other methods.
This work is the result of a collaboration between Spanish and Portuguese laboratories. The speci... more This work is the result of a collaboration between Spanish and Portuguese laboratories. The specific objective was to quantify the time evolution during 1994, 1995 and 1996 of the radioecological impact of the liquid releases of 3H from the Almaraz Nuclear Power Plant (ANPP) in the section of the Tagus River corresponding to Cáceres province in Spain and the Alentejo region in Portugal. We found that the temporal evolution of the levels of tritium depends on the management of the water held in the cooling reservoir of the ANPP and the presence of the dams that exist along the river. This management regime has a 12-month period. Also the movement of the mass of tritiated water (HTO) downriver was much faster during 1996 than 1995 or 1994 due to the hydrological differences between those years and consequently to the different amounts of water transferred between the reservoirs of the dams. From the hypothesis that hydrodynamically it is impossible to differentiate tritiated water from non-tritiated water, a model was constructed that satisfactorily reproduces the temporal evolution of the 3H in the zone of the Tagus River in which the exchange of water takes place, with the cooling reservoir of the Almaraz Nuclear Power Plant.
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