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    Donal Keane

    A novel class of photocatalytic coating capable of degrading bacterial and chemical contaminants in the presence of visible sunlight wavelengths was produced by depositing a stable photocatalytic TiO2 film on the internal lumen of glass... more
    A novel class of photocatalytic coating capable of degrading bacterial and chemical contaminants in the
    presence of visible sunlight wavelengths was produced by depositing a stable photocatalytic TiO2 film on
    the internal lumen of glass bottles via a sol–gel method. This coating was prepared in either undoped form
    or doped with nitrogen and/or copper to produce visible light-active TiO2 films which were annealed at
    600 ◦C and were characterized by Raman and X-ray photoelectron spectroscopy. The presence of doped
    and undoped TiO2 films was found to accelerate the degradation of methylene blue in the presence
    of natural sunlight, while copper-doped TiO2 films were found to accelerate bacterial inactivation (of
    Escherichia coli and Enterococcus faecalis) in the presence of natural sunlight.
    Research Interests:
    A combination of solar disinfection and photocatalysis technology offers real possibilities for removing lethal pathogenic microorganisms from drinking water. The time taken for the conventional SODIS process can be greatly reduced by... more
    A
    combination of solar disinfection and photocatalysis technology offers real possibilities for removing
    lethal pathogenic microorganisms from drinking water. The time taken for the conventional SODIS
    process can be greatly reduced by semiconductor (e.g. TiO2, ZnO, nano-heterojunctions) based
    photocatalysis. This review addresses the fundamental reaction mechanism, advances in materials
    synthesis and selection and recent developments in the reactor design for solar energy driven photocatalysis
    using titanium dioxide. The major advantage of using photo-reactors is that they enhance disinfection by
    increasing photon flux into the photocatalyst. Other major factors affecting such efficiency of solarbased
    photocatalysis such as the illuminated volume/total volume ratio, catalyst load and flow rate, are
    discussed in detail. The significance of using immobilised catalysts over the catalyst powder in slurries is
    also highlighted. It is noted that, despite encouraging early field studies, the commercialisation and
    mass production of solar photocatalysis systems remains highly challenging. Recommendations for
    future directions for addressing issues such as mass transfer, requirement of a standard test method,
    photo-reactors design and visible light absorption by TiO2 coatings are also discussed
    Research Interests: