Indoor and outdoor elemental carbon (EC) and organic carbon (OC) concentrations were measured fro... more Indoor and outdoor elemental carbon (EC) and organic carbon (OC) concentrations were measured from September 2001 through January 2002 at 20 residential sites and a local high school in western Riverside County, CA. The correlation (R 2 ) between indoor vs. outdoor EC and indoor vs. outdoor OC were 0.63 and 0.47, respectively, while the correlation of EC to OC outdoors and indoors was 0.58 and 0.23, respectively. The average OC content of PM 2.5 was 0.25 and 0.55 for outdoor and indoor PM 2.5 , respectively. It was concluded that there were no significant indoor sources of EC while indoor OC sources contributed significantly to indoor PM 2.5 . Home with smokers had significantly higher TC and OC than homes without. Schoolrooms generally had less EC and OC due to the schools HVAC system. r
In order to demonstrate the performance of a retrofitted selective catalytic reduction (SCR) syst... more In order to demonstrate the performance of a retrofitted selective catalytic reduction (SCR) system while also addressing the issues associated with greater use of biodiesel, a 2005 International 9200i tractor owned by the City of Santa Monica was retrofitted with a titania-vanadia-tungsten catalyst and a urea dosing system supplied by Extengine Systems, Inc. This tractor was operated under normal service conditions within the City of Santa Monica refuse collection and transportation fleet. An on-board emissions measurement system supplied by Engine, Fuel, and Emissions Engineering, Inc., was installed on the vehicle; it measured the emissions and fuel use of the vehicle while it operated on ultra-low-sulfur diesel (ULSD), 20 % biodiesel (B20), and 99 % biodiesel (B99) on consecutive days. The vehicle, with a similar aftertreatment system, was then tested at the California Air Resources Board (CARB) Los Angeles Heavy-Duty Emissions Lab and tested on the Urban Dynamometer Driving Sch...
This study examines the influence of ammonia (NH3) on secondary organic aerosol (SOA) formation f... more This study examines the influence of ammonia (NH3) on secondary organic aerosol (SOA) formation from the alpha-pinene/ozone oxidation system for dry and humid conditions. Aerosol yield differed depending on which OH scavenger was used, with the highest yield noted for CO, followed by cyclohexane and 2-butanol. Number and volume concentrations were quickly increased within the reactor by 15 and 8%, respectively, when NH3 was added after the reaction ceased. The increase in number concentration indicated the formation of new particles resulting from gas-to-particle conversion. Moreover, average particle size increased from 242 to 248 nm. The resulting aerosol growth was attributed to ammonium salts formed by the reaction between organic acids and NH3. When NH3 was added to aerosolized cis-pinonic acid in the environmental reactor, a dramatic increase in both number and volume concentrations of cis-pinonic acid was observed. This provides further evidence that NH3 can interact with gas-phase organic acids forming condensable salts and thereby enhancing SOA formation. Initially present NH3 significantly enhanced aerosol yield in alpha-pinene-ozone reactions, regardless of the presence of water vapor. The role of NH3 on SOA formation in the dry and humid conditions is discussed in terms of a theoretical modeling study.
... program used was as follows: initial tem-pera~-e 0 ~ for 7 rain, rising at 15 ~ I'[lin -... more ... program used was as follows: initial tem-pera~-e 0 ~ for 7 rain, rising at 15 ~ I'[lin -1 up to 170 ~ where it re-ma~s for 6 rain. ... Dumg the winter,he (from Novem-berto March), 5 to 30wt% of prolmne is added to tile butane fuel which is used for the some types of vehicles such as ...
This study describes the methodology used to obtain the volatile organic compound (VOC) source si... more This study describes the methodology used to obtain the volatile organic compound (VOC) source signature of vehicle exhaust. To accomplish this, C(2)-C(9) VOCs were measured in a traffic tunnel located in Seoul, South Korea. The effect of VOC concentrations from the outside ambient air was considered in the determination of the source signature. To examine the effects of ambient air on VOC concentrations inside the tunnel, the ratio of propane to the total VOC concentrations was compared between the entrance and middle sites in the tunnel. Propane was used as a standard not only because of its insignificant contribution to vehicle exhaust gas, but also the fact that propane is the most abundant VOC in the atmosphere of Seoul. The ratio of propane to the total VOC concentrations was higher at the entrance site than at the middle location by, on average, 60%. This suggests that ambient air affects the inside tunnel air to a greater extent at the entrance site as compared to the middle site. The contribution of ambient air to the air inside the tunnel at the entrance location varied from 30% to 67%, with an average of 55%. This is 1.5 times higher than the value measured at the middle location, which ranged from 20% to 48%, with an average of 36%. This shows that ambient air substantially affects the inside air of the tunnel. Excluding the effects of ambient air on the air inside the tunnel can provide an improved chemical composition for vehicle exhaust using tunnel measurements. We believe that the concentration difference between the two sites within the tunnel provides a more accurate chemical composition of vehicle exhaust as compared to that obtained from a measurement taken at only one point inside the tunnel.
Indoor and outdoor elemental carbon (EC) and organic carbon (OC) concentrations were measured fro... more Indoor and outdoor elemental carbon (EC) and organic carbon (OC) concentrations were measured from September 2001 through January 2002 at 20 residential sites and a local high school in western Riverside County, CA. The correlation (R 2 ) between indoor vs. outdoor EC and indoor vs. outdoor OC were 0.63 and 0.47, respectively, while the correlation of EC to OC outdoors and indoors was 0.58 and 0.23, respectively. The average OC content of PM 2.5 was 0.25 and 0.55 for outdoor and indoor PM 2.5 , respectively. It was concluded that there were no significant indoor sources of EC while indoor OC sources contributed significantly to indoor PM 2.5 . Home with smokers had significantly higher TC and OC than homes without. Schoolrooms generally had less EC and OC due to the schools HVAC system. r
In order to demonstrate the performance of a retrofitted selective catalytic reduction (SCR) syst... more In order to demonstrate the performance of a retrofitted selective catalytic reduction (SCR) system while also addressing the issues associated with greater use of biodiesel, a 2005 International 9200i tractor owned by the City of Santa Monica was retrofitted with a titania-vanadia-tungsten catalyst and a urea dosing system supplied by Extengine Systems, Inc. This tractor was operated under normal service conditions within the City of Santa Monica refuse collection and transportation fleet. An on-board emissions measurement system supplied by Engine, Fuel, and Emissions Engineering, Inc., was installed on the vehicle; it measured the emissions and fuel use of the vehicle while it operated on ultra-low-sulfur diesel (ULSD), 20 % biodiesel (B20), and 99 % biodiesel (B99) on consecutive days. The vehicle, with a similar aftertreatment system, was then tested at the California Air Resources Board (CARB) Los Angeles Heavy-Duty Emissions Lab and tested on the Urban Dynamometer Driving Sch...
This study examines the influence of ammonia (NH3) on secondary organic aerosol (SOA) formation f... more This study examines the influence of ammonia (NH3) on secondary organic aerosol (SOA) formation from the alpha-pinene/ozone oxidation system for dry and humid conditions. Aerosol yield differed depending on which OH scavenger was used, with the highest yield noted for CO, followed by cyclohexane and 2-butanol. Number and volume concentrations were quickly increased within the reactor by 15 and 8%, respectively, when NH3 was added after the reaction ceased. The increase in number concentration indicated the formation of new particles resulting from gas-to-particle conversion. Moreover, average particle size increased from 242 to 248 nm. The resulting aerosol growth was attributed to ammonium salts formed by the reaction between organic acids and NH3. When NH3 was added to aerosolized cis-pinonic acid in the environmental reactor, a dramatic increase in both number and volume concentrations of cis-pinonic acid was observed. This provides further evidence that NH3 can interact with gas-phase organic acids forming condensable salts and thereby enhancing SOA formation. Initially present NH3 significantly enhanced aerosol yield in alpha-pinene-ozone reactions, regardless of the presence of water vapor. The role of NH3 on SOA formation in the dry and humid conditions is discussed in terms of a theoretical modeling study.
... program used was as follows: initial tem-pera~-e 0 ~ for 7 rain, rising at 15 ~ I'[lin -... more ... program used was as follows: initial tem-pera~-e 0 ~ for 7 rain, rising at 15 ~ I'[lin -1 up to 170 ~ where it re-ma~s for 6 rain. ... Dumg the winter,he (from Novem-berto March), 5 to 30wt% of prolmne is added to tile butane fuel which is used for the some types of vehicles such as ...
This study describes the methodology used to obtain the volatile organic compound (VOC) source si... more This study describes the methodology used to obtain the volatile organic compound (VOC) source signature of vehicle exhaust. To accomplish this, C(2)-C(9) VOCs were measured in a traffic tunnel located in Seoul, South Korea. The effect of VOC concentrations from the outside ambient air was considered in the determination of the source signature. To examine the effects of ambient air on VOC concentrations inside the tunnel, the ratio of propane to the total VOC concentrations was compared between the entrance and middle sites in the tunnel. Propane was used as a standard not only because of its insignificant contribution to vehicle exhaust gas, but also the fact that propane is the most abundant VOC in the atmosphere of Seoul. The ratio of propane to the total VOC concentrations was higher at the entrance site than at the middle location by, on average, 60%. This suggests that ambient air affects the inside tunnel air to a greater extent at the entrance site as compared to the middle site. The contribution of ambient air to the air inside the tunnel at the entrance location varied from 30% to 67%, with an average of 55%. This is 1.5 times higher than the value measured at the middle location, which ranged from 20% to 48%, with an average of 36%. This shows that ambient air substantially affects the inside air of the tunnel. Excluding the effects of ambient air on the air inside the tunnel can provide an improved chemical composition for vehicle exhaust using tunnel measurements. We believe that the concentration difference between the two sites within the tunnel provides a more accurate chemical composition of vehicle exhaust as compared to that obtained from a measurement taken at only one point inside the tunnel.
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