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Light-scattering spectra of fast relaxation in glasses

N. V. Surovtsev, J. A. H. Wiedersich, V. N. Novikov, E. Rössler, and A. P. Sokolov
Phys. Rev. B 58, 14888 – Published 1 December 1998
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Abstract

Light-scattering spectra of the glasses polystyrene (PS), polycarbonate (PC), and Ca0.4K0.6(NO3)1.4 (CKN) are measured in the frequency interval 310000GHz covering a broad temperature range. The low frequency wing of the fast relaxation spectrum is found to show a power-law behavior with an exponent α=0.20.6. The exponent depends on system and temperature. No indication of a crossover to a white noise spectrum, as previously reported and discussed within mode-coupling analyses is found. It is shown that the Gilroy-Phillips model of thermally activated transitions in asymmetric double-well potentials well describes the power-law part of fast relaxation spectra in PS and CKN but fails in the case of PC. The distribution of barrier heights is extracted from the spectra.

  • Received 16 July 1998

DOI:https://doi.org/10.1103/PhysRevB.58.14888

©1998 American Physical Society

Authors & Affiliations

N. V. Surovtsev*, J. A. H. Wiedersich, V. N. Novikov*, and E. Rössler

  • Physikalisches Institut, Universität Bayreuth, D-95440 Bayreuth, Germany

A. P. Sokolov

  • Institut für Festkörperforschung, Forschungszentrum Jülich, D-52425 Jülich, Germany

  • *On leave from Institute of Automation & Electrometry, Russian Academy of Sciences, Novosibirsk, 630090, Russia.

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Vol. 58, Iss. 22 — 1 December 1998

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