The surface of the g-C3N4 was altered by impregnating W6+ ions that transformed to homogeneously ... more The surface of the g-C3N4 was altered by impregnating W6+ ions that transformed to homogeneously coated oxide layer by a calcination process. An enhanced absorption and the suppressed de-excitation in the emission spectra, with the increasing W6+ loading, exposed the supporting role of the coated layer in extending the spectral response as well as the prolonged life span of excitons. The same was further supported by electrochemical impedance spectroscopy (EIS). The XRD and XPS analysis revealed the coated layer as highly crystalline pure phase monoclinic WO3 with the majority of impregnated tungsten ions in 6+ oxidation state respectively, whereas the FESEM and HRTEM analysis substantiated the uniformity of the coated layer with the interlayer spacing of the 0.369 nm. Additionally, the probable formation of individual WO3 nanoparticles or clusters was ruled out. The as-synthesized impregnated photocatalysts, in comparison to pure g-C3N4, were subjected to natural sunlight exposure for the photocatalytic removal of chlorophenol derivatives (2-CP, 3-CP, 4-CP, 2,3-DCP, 2,4-DCP, 2,4,6-TCP and PCP) that revealed the 5 wt% coating as the optimum level for significant removal. The progress of the photocatalytic process was monitored by periodic HPLC analysis whereas ion chromatography (IC) was used for the estimation of released ions. The mineralization capability of the as-synthesized W6+ coated catalysts was measured by the time scale TOC measurements. As the formation of intermediates was indicated in HPLC analysis, selected samples were subjected to GC-MS analysis for the identification of the nature of intermediates. The variable degree of removal of chlorophenol derivatives signified the role of the position and orientation of Cl group. The kinetics of the removal process was evaluated with the calculation of rate constants. The results extracted from the analytical tools and the associated band edge potentials were correlated to speculate the probable mechanism as well as the identification of major reactive oxygen species (ROS) involved in the removal process.
Particle size dependent anti-bacterial and anti-diabetic activities of green synthesized ZnO nano... more Particle size dependent anti-bacterial and anti-diabetic activities of green synthesized ZnO nanoparticles.
In terms of reduced toxicity, the biologically inspired green synthesis of nanoparticles has emer... more In terms of reduced toxicity, the biologically inspired green synthesis of nanoparticles has emerged as a promising alternative to chemically fabricated nanoparticles. The use of a highly stable, biocompatible, and environmentally friendly aqueous extract of Cynara cardunculus as a reducing and capping agent in this study demonstrated the possibility of green manufacturing of silver nanoparticles (CC-AgNPs). UV–visible spectroscopy validated the development of CC-AgNPs, indicating the surface plasmon resonance (SPR) λmax band at 438 nm. The band gap of CC-AgNPs was found to be 2.26 eV. SEM and TEM analysis examined the surface morphology of CC-AgNPs, and micrographs revealed that the nanoparticles were spherical. The crystallinity, crystallite size, and phase purity of as-prepared nanoparticles were confirmed using XRD analysis, and it was confirmed that the CC-AgNPs were a face-centered cubic (fcc) crystalline-structured material. Furthermore, the role of active functional groups i...
Background: Water contamination and its remediation are currently considered a major concern worl... more Background: Water contamination and its remediation are currently considered a major concern worldwide. Design of effective methods for water purification is highly demanded for the adsorption and removal of such pollutants. Objective: This study depicts the effectiveness of nickel oxide-copper oxide nanoparticles (NiO-CuO), which can extract and remediate ferric ions, Fe(III), from aqueous solutions. Methods: The NiO-CuO nanoparticles were simply prepared by the co-precipitation method and then used as adsorbent with respectable advantages of high uptake capacity and surface area. Results: Adsorption of Fe(III) onto NiO-CuO nanoparticles showed an uptake capacity of 85.86 mgg-1 at pH 5.0. The obtained data from the carried-out experiment of Fe(III) adsorption onto NiO-CuO nanoparticles were well suited to the Langmuir isotherm and pseudo-second-order kinetic models. Moreover, different coexisting ions did not influence the adsorption of Fe(III) onto NiO-CuO nanoparticles. The recommended methodology was implemented on the adsorption and removal of several environmental water samples with high efficiency. Conclusion: The designed method displayed that NiO-CuO nanoparticles can be used as a promising material for the adsorptive removal of heavy metals from water.
In this work, we have developed novel beads based on carboxymethyl cellulose (CMC) encapsulated c... more In this work, we have developed novel beads based on carboxymethyl cellulose (CMC) encapsulated copper oxide-titanium oxide (CuO-TiO2) nanocomposite (CMC/CuO-TiO2) via Al+3 cross-linking agent. The developed CMC/CuO-TiO2 beads were applied as a promising catalyst for the catalytic reduction of organic and inorganic contaminants; nitrophenols (NP), methyl orange (MO), eosin yellow (EY) and potassium hexacyanoferrate (K3[Fe(CN)6]) in the presence of reducing agent (NaBH4). CMC/CuO-TiO2 nanocatalyst beads exhibited excellent catalytic activity in the reduction of all selected pollutants (4-NP, 2-NP, 2,6-DNP, MO, EY and K3[Fe(CN)6]). Further, the catalytic activity of beads was optimized toward 4-nitrophenol with varying its concentrations and testing different concentrations of NaBH4. Beads stability, reusability, and loss in catalytic activity were investigated using the recyclability method, in which the CMC/CuO-TiO2 nanocomposite beads were tested several times for the reduction of ...
A highly effective approach was developed for the specific detection of 2,4-dichlorophenol (2,4-D... more A highly effective approach was developed for the specific detection of 2,4-dichlorophenol (2,4-DCP) in real samples, based on a cyclodextrin functionalized ionic liquid modified carbon paste electrode (β-CD-BIMOTs/CPE).
A series of binary oxide catalysts (ceria-ZnO) were prepared and doped with different amounts of ... more A series of binary oxide catalysts (ceria-ZnO) were prepared and doped with different amounts of palladium in the range of 0.5%-1.5%. The prepared catalysts were characterized by SEM, TEM, XRD and XPS, as well as by N2 sorptiometry study. The XPS results confirmed the structure of the Pd CeO2-x-ZnO. The photocatalytic activity of these catalysts was evaluated for degradation of MTBE in water. These photocatalyst efficiently degrade a 100ppm aqueous solution of MTBE upon UV irradiation for 5h in the presence of 100mg of each of these photocatalysts. The removal of 99.6% of the MTBE was achieved with the ceria-ZnO catalyst doped with 1% Pd. In addition to the Pd loading, the N2 sorptiometry study introduced other factors that might affect the catalytic efficiency is the catalyst average pore sizes. The photoreaction was determined to be a first order reaction.
Abstract The high optical gain of InGaAs/GaAsSb/InAlAs nano-scale heterostructure has motivated u... more Abstract The high optical gain of InGaAs/GaAsSb/InAlAs nano-scale heterostructure has motivated us for its further study under variable temperature and electric field. The presented work is devoted to show the impact of variable temperature and electric field on optical gain characteristics of InGaAs/GaAsSb/InAlAs nano-scale heterostructure which has been assumed to grow on lattice matched GaAs substrate. A six band k.p approach has been utilized to optimize the heterostructure in terms of carrier's wavefunctions, local carriers' density in conduction and valence band and dispersion curves followed by calculating momentum matrix elements and the optical gain spectra. According to the calculation results, the increasing range of temperature (having range of 100–300 K at the interval of 50 K) can control the peak gain significantly (6070 cm−1 to 4470 cm−1) with the red shift in wavelength; while enhanced order of electric field at room temperature can control the gain slightly (4470 cm−1 to ~4150 cm−1) with fine red shift in wavelength. The results achieved in this work will definitely prove the method of controlling the gain characteristics as excellent; and the heterostructure studied will be suitable in design of tunable NIR (near infrared) light sources.
The removal of dyes from industrial effluents is one of the most important industrial processes t... more The removal of dyes from industrial effluents is one of the most important industrial processes that is currently on academic demand. In this project, for the first time, Trachycarpus fortunei seeds are used as biosources for the synthesis of activated carbon (AC) using physical as well as acid–base chemical methods. The synthesized AC was initially characterized by different instrumental techniques, such as FTIR, BET isotherm, SEM, EDX and XRD. Then, the prepared activated carbon was used as an economical adsorbent for the removal of xylenol orange and thymol blue from an aqueous solution. Furthermore, the effect of different parameters, i.e., concentration of dye, contact time, pH, adsorbent amount, temperature, adsorbent size and agitation speed, were investigated in batch experiments at room temperature. The analysis of different techniques concluded that the pyrolysis method created a significant change in the chemical composition of the prepared AC and the acid-treated AC offe...
The surface of the g-C3N4 was altered by impregnating W6+ ions that transformed to homogeneously ... more The surface of the g-C3N4 was altered by impregnating W6+ ions that transformed to homogeneously coated oxide layer by a calcination process. An enhanced absorption and the suppressed de-excitation in the emission spectra, with the increasing W6+ loading, exposed the supporting role of the coated layer in extending the spectral response as well as the prolonged life span of excitons. The same was further supported by electrochemical impedance spectroscopy (EIS). The XRD and XPS analysis revealed the coated layer as highly crystalline pure phase monoclinic WO3 with the majority of impregnated tungsten ions in 6+ oxidation state respectively, whereas the FESEM and HRTEM analysis substantiated the uniformity of the coated layer with the interlayer spacing of the 0.369 nm. Additionally, the probable formation of individual WO3 nanoparticles or clusters was ruled out. The as-synthesized impregnated photocatalysts, in comparison to pure g-C3N4, were subjected to natural sunlight exposure for the photocatalytic removal of chlorophenol derivatives (2-CP, 3-CP, 4-CP, 2,3-DCP, 2,4-DCP, 2,4,6-TCP and PCP) that revealed the 5 wt% coating as the optimum level for significant removal. The progress of the photocatalytic process was monitored by periodic HPLC analysis whereas ion chromatography (IC) was used for the estimation of released ions. The mineralization capability of the as-synthesized W6+ coated catalysts was measured by the time scale TOC measurements. As the formation of intermediates was indicated in HPLC analysis, selected samples were subjected to GC-MS analysis for the identification of the nature of intermediates. The variable degree of removal of chlorophenol derivatives signified the role of the position and orientation of Cl group. The kinetics of the removal process was evaluated with the calculation of rate constants. The results extracted from the analytical tools and the associated band edge potentials were correlated to speculate the probable mechanism as well as the identification of major reactive oxygen species (ROS) involved in the removal process.
Particle size dependent anti-bacterial and anti-diabetic activities of green synthesized ZnO nano... more Particle size dependent anti-bacterial and anti-diabetic activities of green synthesized ZnO nanoparticles.
In terms of reduced toxicity, the biologically inspired green synthesis of nanoparticles has emer... more In terms of reduced toxicity, the biologically inspired green synthesis of nanoparticles has emerged as a promising alternative to chemically fabricated nanoparticles. The use of a highly stable, biocompatible, and environmentally friendly aqueous extract of Cynara cardunculus as a reducing and capping agent in this study demonstrated the possibility of green manufacturing of silver nanoparticles (CC-AgNPs). UV–visible spectroscopy validated the development of CC-AgNPs, indicating the surface plasmon resonance (SPR) λmax band at 438 nm. The band gap of CC-AgNPs was found to be 2.26 eV. SEM and TEM analysis examined the surface morphology of CC-AgNPs, and micrographs revealed that the nanoparticles were spherical. The crystallinity, crystallite size, and phase purity of as-prepared nanoparticles were confirmed using XRD analysis, and it was confirmed that the CC-AgNPs were a face-centered cubic (fcc) crystalline-structured material. Furthermore, the role of active functional groups i...
Background: Water contamination and its remediation are currently considered a major concern worl... more Background: Water contamination and its remediation are currently considered a major concern worldwide. Design of effective methods for water purification is highly demanded for the adsorption and removal of such pollutants. Objective: This study depicts the effectiveness of nickel oxide-copper oxide nanoparticles (NiO-CuO), which can extract and remediate ferric ions, Fe(III), from aqueous solutions. Methods: The NiO-CuO nanoparticles were simply prepared by the co-precipitation method and then used as adsorbent with respectable advantages of high uptake capacity and surface area. Results: Adsorption of Fe(III) onto NiO-CuO nanoparticles showed an uptake capacity of 85.86 mgg-1 at pH 5.0. The obtained data from the carried-out experiment of Fe(III) adsorption onto NiO-CuO nanoparticles were well suited to the Langmuir isotherm and pseudo-second-order kinetic models. Moreover, different coexisting ions did not influence the adsorption of Fe(III) onto NiO-CuO nanoparticles. The recommended methodology was implemented on the adsorption and removal of several environmental water samples with high efficiency. Conclusion: The designed method displayed that NiO-CuO nanoparticles can be used as a promising material for the adsorptive removal of heavy metals from water.
In this work, we have developed novel beads based on carboxymethyl cellulose (CMC) encapsulated c... more In this work, we have developed novel beads based on carboxymethyl cellulose (CMC) encapsulated copper oxide-titanium oxide (CuO-TiO2) nanocomposite (CMC/CuO-TiO2) via Al+3 cross-linking agent. The developed CMC/CuO-TiO2 beads were applied as a promising catalyst for the catalytic reduction of organic and inorganic contaminants; nitrophenols (NP), methyl orange (MO), eosin yellow (EY) and potassium hexacyanoferrate (K3[Fe(CN)6]) in the presence of reducing agent (NaBH4). CMC/CuO-TiO2 nanocatalyst beads exhibited excellent catalytic activity in the reduction of all selected pollutants (4-NP, 2-NP, 2,6-DNP, MO, EY and K3[Fe(CN)6]). Further, the catalytic activity of beads was optimized toward 4-nitrophenol with varying its concentrations and testing different concentrations of NaBH4. Beads stability, reusability, and loss in catalytic activity were investigated using the recyclability method, in which the CMC/CuO-TiO2 nanocomposite beads were tested several times for the reduction of ...
A highly effective approach was developed for the specific detection of 2,4-dichlorophenol (2,4-D... more A highly effective approach was developed for the specific detection of 2,4-dichlorophenol (2,4-DCP) in real samples, based on a cyclodextrin functionalized ionic liquid modified carbon paste electrode (β-CD-BIMOTs/CPE).
A series of binary oxide catalysts (ceria-ZnO) were prepared and doped with different amounts of ... more A series of binary oxide catalysts (ceria-ZnO) were prepared and doped with different amounts of palladium in the range of 0.5%-1.5%. The prepared catalysts were characterized by SEM, TEM, XRD and XPS, as well as by N2 sorptiometry study. The XPS results confirmed the structure of the Pd CeO2-x-ZnO. The photocatalytic activity of these catalysts was evaluated for degradation of MTBE in water. These photocatalyst efficiently degrade a 100ppm aqueous solution of MTBE upon UV irradiation for 5h in the presence of 100mg of each of these photocatalysts. The removal of 99.6% of the MTBE was achieved with the ceria-ZnO catalyst doped with 1% Pd. In addition to the Pd loading, the N2 sorptiometry study introduced other factors that might affect the catalytic efficiency is the catalyst average pore sizes. The photoreaction was determined to be a first order reaction.
Abstract The high optical gain of InGaAs/GaAsSb/InAlAs nano-scale heterostructure has motivated u... more Abstract The high optical gain of InGaAs/GaAsSb/InAlAs nano-scale heterostructure has motivated us for its further study under variable temperature and electric field. The presented work is devoted to show the impact of variable temperature and electric field on optical gain characteristics of InGaAs/GaAsSb/InAlAs nano-scale heterostructure which has been assumed to grow on lattice matched GaAs substrate. A six band k.p approach has been utilized to optimize the heterostructure in terms of carrier's wavefunctions, local carriers' density in conduction and valence band and dispersion curves followed by calculating momentum matrix elements and the optical gain spectra. According to the calculation results, the increasing range of temperature (having range of 100–300 K at the interval of 50 K) can control the peak gain significantly (6070 cm−1 to 4470 cm−1) with the red shift in wavelength; while enhanced order of electric field at room temperature can control the gain slightly (4470 cm−1 to ~4150 cm−1) with fine red shift in wavelength. The results achieved in this work will definitely prove the method of controlling the gain characteristics as excellent; and the heterostructure studied will be suitable in design of tunable NIR (near infrared) light sources.
The removal of dyes from industrial effluents is one of the most important industrial processes t... more The removal of dyes from industrial effluents is one of the most important industrial processes that is currently on academic demand. In this project, for the first time, Trachycarpus fortunei seeds are used as biosources for the synthesis of activated carbon (AC) using physical as well as acid–base chemical methods. The synthesized AC was initially characterized by different instrumental techniques, such as FTIR, BET isotherm, SEM, EDX and XRD. Then, the prepared activated carbon was used as an economical adsorbent for the removal of xylenol orange and thymol blue from an aqueous solution. Furthermore, the effect of different parameters, i.e., concentration of dye, contact time, pH, adsorbent amount, temperature, adsorbent size and agitation speed, were investigated in batch experiments at room temperature. The analysis of different techniques concluded that the pyrolysis method created a significant change in the chemical composition of the prepared AC and the acid-treated AC offe...
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