Unraveling the nature of magnetism of the 5 double perovskite BaYIrO

S Fuchs, T Dey, G Aslan-Cansever, A Maljuk… - arXiv preprint arXiv …, 2018 - arxiv.org
S Fuchs, T Dey, G Aslan-Cansever, A Maljuk, S Wurmehl, B Büchner, V Kataev
arXiv preprint arXiv:1805.05243, 2018arxiv.org
We report electron spin resonance (ESR) spectroscopy results on the double perovskite Ba
$ _2 $ YIrO $ _6 $. On general grounds, this material is expected to be nonmagnetic due to
the strong coupling of the spin and orbital momenta of Ir $^{5+} $(5$ d^ 4$) ions. However,
controversial experimental reports on either strong antiferromagnetism with static order at
low temperatures or just a weakly paramagnetic behavior have triggered a discussion on the
breakdown of the generally accepted scenario of the strongly spin-orbit coupled ground …
We report electron spin resonance (ESR) spectroscopy results on the double perovskite BaYIrO. On general grounds, this material is expected to be nonmagnetic due to the strong coupling of the spin and orbital momenta of Ir (5) ions. However, controversial experimental reports on either strong antiferromagnetism with static order at low temperatures or just a weakly paramagnetic behavior have triggered a discussion on the breakdown of the generally accepted scenario of the strongly spin-orbit coupled ground states in the 5 iridates and the emergence of a novel exotic magnetic state. Our data evidence that the magnetism of the studied material is solely due to a few percent of Ir and Ir magnetic defects while the regular Ir sites remain nonmagnetic. Remarkably, the defect Ir species manifest magnetic correlations in the ESR spectra at K suggesting a long-range character of superexchange in the double prevoskites as proposed by recent theories.
arxiv.org