Tuning the Ising-type anisotropy in trigonal bipyramidal Co(II) complexes We can tune the Ising-t... more Tuning the Ising-type anisotropy in trigonal bipyramidal Co(II) complexes We can tune the Ising-type anisotropy in trigonal bipyramidal Co(II) complexes using simple ligand theory considerations. We used a sulfur containing ligand to synthesize a complex that had long equatorial Co–S bonds. This complex exhibits a larger anisotropy barrier and a longer relaxation time in comparison to the complex prepared with a nitrogen-containing ligand.
Tuning the Ising-type anisotropy in trigonal bipyramidal Co(II) complexes We can tune the Ising-t... more Tuning the Ising-type anisotropy in trigonal bipyramidal Co(II) complexes We can tune the Ising-type anisotropy in trigonal bipyramidal Co(II) complexes using simple ligand theory considerations. We used a sulfur containing ligand to synthesize a complex that had long equatorial Co–S bonds. This complex exhibits a larger anisotropy barrier and a longer relaxation time in comparison to the complex prepared with a nitrogen-containing ligand.
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