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Marcelo Cilla
  • Rua Professor Aristídes Novis, 02 - Federação - Zip Code: 41210-630 - Salvador - BA - Brazil
  • +55 71 997040099
O processo de fundição mais rápido, econômico e convencional é o de moldagem em areia a verde, onde o ligante principal é uma argila umedecida (bentonita). Entretanto, devido a exigências tecnológicas, são utilizados também ligantes... more
O processo de fundição mais rápido, econômico e convencional é o de moldagem em areia a verde, onde o ligante principal é uma argila umedecida (bentonita). Entretanto, devido a exigências tecnológicas, são utilizados também ligantes tóxicos como resinas furânicas, fenólicas ou uretânicas. Novas tecnologias vêm sendo desenvolvidas para a recuperação e inertização das areias, porém as resinas disponíveis atualmente têm como limitação "ecológica" sua origem química. Após sua utilização estes moldes são descartados, e assim, os ligantes tóxicos tornam-se um problema ambiental. Desta maneira, a substituição destes ligantes por compostos orgânicos derivados de fontes renováveis como a resina poliuretana derivada do óleo de mamona minimiza os impactos ambientais, conduzindo o processo de fundição rumo à sustentabilidade, necessária devido ao aumento do rigor da legislação ambiental. Devido ao comportamento térmico do poliuretano vegetal, que se decompõem de maneira mais acentuada...
The geopolymers (inorganic polymers formed basically of silicates) have attracted increasing attention from academia for several reasons, particularly because it is considered a sustainable material where industrial by-products (fly ash... more
The geopolymers (inorganic polymers formed basically of silicates) have attracted increasing attention from academia for several reasons, particularly because it is considered a sustainable material where industrial by-products (fly ash and blast furnace slag) can be used as raw material, and is based on a low energy cost process. Such materials find applications in virtually all industrial sectors, depending on the molar ratio Si:Al, responsible for its properties. Currently the application of large volumes of geopolymers is focused on replacement of Portland cement, a material with an extremely aggressive process of obtaining to the environment. However, due to their similar properties to the ceramic material and increase search for new applications, studies of porous geopolymers are also of great interest. Processing routes currently used to obtain porous geopolymers are based on the civil construction for the production of aerated concrete with closed porosity, limiting their ap...
Effect of mixing speed and surfactant content on total porosity With the aim of evaluate the effect the rotation speed and of the surfactant content on total porosity, two amounts of surfactant were used. Figure 3.A (left) is for samples... more
Effect of mixing speed and surfactant content on total porosity With the aim of evaluate the effect the rotation speed and of the surfactant content on total porosity, two amounts of surfactant were used. Figure 3.A (left) is for samples containing 2 wt% of surfactant (Tween 80) and Figure 3.B (right) shows how porosity changed with the addition of 4 wt% of surfactant. For both surfactant contents, the total porosity produced was measured for three different speed rotation, as 800, 1500 and 2000 rpm. After these preliminary experiments, all studies were conducted on samples with 68 wt% solid content. Fig. 3 also shows the morphology of samples produced using either 2 (left) or 4 (right) wt% of Tween 80 surfactant (mixing speed = 1500 rpm). Highly porous foams possessing fully interconnected pores were produced by this method.
ABSTRACT Open cell geopolymer foams with a total porosity as high as 80 vol% were produced by gelcasting, and the effect of processing (mixing speed, amount and type of surfactant) on some physical properties of the components was... more
ABSTRACT Open cell geopolymer foams with a total porosity as high as 80 vol% were produced by gelcasting, and the effect of processing (mixing speed, amount and type of surfactant) on some physical properties of the components was investigated. The data show that, as expected, the permeability increased while the compression strength decreased with increasing the amount of open porosity. No great statistically significant difference could be observed when using either one of the surfactants, but we can suggest that the use of Tween 80 as a surfactant is more amenable to the formation of interconnected cell structures and high levels of total porosity. The gas permeability data indicate that these foams perform similarly to granular filters and other ceramic foams produced by gelcasting. Heating the geopolymer foams to intermediate (700 degrees C) or high (1200 degrees C) temperature reduced the specific surface area, the total and the open porosity, due to the crystallization of leucite and partial viscous sintering.
ABSTRACT Using a novel saponification/peroxide/gelcasting combined route it was possible to produce geopolymer foams with a total porosity of similar to 85 vol%, open porosity as high as similar to 70 vol%, average cell size (D50) of 318... more
ABSTRACT Using a novel saponification/peroxide/gelcasting combined route it was possible to produce geopolymer foams with a total porosity of similar to 85 vol%, open porosity as high as similar to 70 vol%, average cell size (D50) of 318 mu m, and possessing a specific surface area of 50 m(2)/g. The in situ formation of surfactants by the saponification reaction of oil in the geopolymer alkaline environment led to increased total and open porosity in comparison to alternative methods for the fabrication of geopolymer foams.