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Science Data Booklet

Science is a systematic enterprise that builds and organizes knowledge in the form of testable explanations and predictions about the nature. This booklet is designed to place less emphasis on factual material and greater emphasis on the understanding and application of scientific concepts and principles. This booklet has been designed in recognition of the need for students to develop skills that will be of long term value in an increasingly technological world rather than focusing on large quantities of factual material which may have only short term relevance.

Science Data Booklet "The only true wisdom is in knowing you know nothing." ― Socrates Manjunath.R #16/1, 8th Main Road, Shivanagar, Rajajinagar, Bangalore560010, Karnataka, India *Corresponding Author Email: manjunath5496@gmail.com *Website: http://www.myw3schools.com/ Science is a systematic enterprise that builds and organizes knowledge in the form of testable explanations and predictions about the nature. This booklet is designed to place less emphasis on factual material and greater emphasis on the understanding and application of scientific concepts and principles. This booklet has been designed in recognition of the need for students to develop skills that will be of long term value in an increasingly technological world rather than focusing on large quantities of factual material which may have only short term relevance. My brain is only a receiver, in the Universe there is a core from which we obtain knowledge, strength and inspiration. I have not penetrated into the secrets of this core, but I know that it exists. ― Nikola Tesla Laws of Exponents  1n = 1  0n = 0, for n > 0  x1 = x  x0 = 1  x ½ = √𝑥 n  x 1/n = √𝑥  x−1 = 1 𝑥  x m x n = xm+n  𝑥m = x m – n , if m > n  𝑥m = 1 , if m = n  𝑥m = 𝑥n 𝑥n 𝑥 n 1 𝑥n–m , if m < n; x ∈ R, x ≠ 0  (x m) n = x mn  (x y) n = x n y n 𝑥n  (x / y) n = 𝑦 n 1  x −n = 𝑥 n  x m / n = n√𝑥 m  (x m y n) p = x mp y np 1  (x m / y n) p = 𝑥 mp 𝑦 np  If n is even, (−1) n = 1  If n is odd, (−1) n = −1 Important Formulas in Algebra  (a + b) 2 = a2 + 2ab + b2  a2 + b2 = (a + b)2 − 2ab  (a − b)2 = a2 − 2ab + b2  a2 + b2 = (a − b)2 + 2ab  (a + b + c) 2 = a2 + b2 + c2 + 2(ab + bc + ca)  (a + b) 3 = a3 + b3 + 3ab (a + b)  a3 + b3 = (a + b) 3 − 3ab (a + b)  (a − b)3 = a3 − b3 − 3ab (a − b)  a3 − b3 = (a − b) 3 + 3ab (a − b)  a2 − b2 = (a + b) (a − b)  a3 − b3 = (a − b) (a2 + ab + b2)  a3 + b3 = (a + b) (a2 − ab + b2)  a4 – b4 = (a2 – b2) (a2 + b2) = (a + b) (a + b) (a2 + b2)  a4 + b4 = (a2 + b2) 2 – 2a2 b2 = (a2 + √2ab + b2) (a2 – √2ab + b2)  a5 + b5 = (a + b) (a4 – a3b + a2b2 – ab3 + b4 )  a5 – b5 = (a – b) (a4 + a3b + a2b2 + ab3 + b4)  an − bn = (a − b) (an−1 + an−2 b + an−3 b2 + ··· + bn−1n−1) 2  (a + b + c) 2 = a2 + b2 + c2 + 2 (ab + bc + ca)  a3 + b3 + c3 – 3abc = (a + b + c) (a2 + b2 + c2 – ab – bc – ca) If a + b + c = 0, then the above identity reduces to a3 + b3 + c3 = 3abc Roots of Quadratic Equation For a quadratic equation ax2 + bx + c where a ≠ 0, the roots will be given by the equation as: 𝑥= −b ± √b 2 − 4ac 2a  Δ = b2 − 4ac is called the discrimination  For real and distinct roots, Δ > 0  For real and coincident roots, Δ = 0  For non-real roots, Δ < 0  If α and β are the two roots of the equation ax2 + bx + c then, α+β= α×β=  −b 𝑎 c a If the roots of a quadratic equation are α and β, the equation will be (x − α) (x − β) = 0 TRIGONOMETRY FORMULAS cos 2 ( x)  sin 2 ( x)  1 1  tan 2 ( x)  sec 2 ( x) cos( x  y )  cos( x) cos( y ) sin( x) sin( y ) sin( x  y )  sin( x) cos( y )  cos( x) sin( y ) cot 2 ( x)  1  csc 2 ( x) tan( x  y )  3 tan( x)  tan( y) 1  tan( x) tan( y) sin( 2 x)  2 sin( x) cos( x) c 2  a 2  b 2  2ab cos(C ) sin( A) sin( B) sin(C )   a b c cos 2 ( x)  sin 2 ( x)  cos( 2 x)  2 cos 2 ( x)  1 1  2 sin 2 ( x)  tan( 2 x)  2 tan( x) 1  tan 2 ( x) 1  cos( x)  x cos    2 2 1  cos( 2 x) 2  1 cos( 2 x) cos 2 ( x)  2 1  cos( 2 x) tan 2 ( x)  1  cos( 2 x) sin 2 ( x)  1  cos( x)  x sin     2 2 1  cos( x)  x tan     1  cos( x) 2 sin( x) sin( y )  12 [cosx  y   cos( x  y )] cos( x) cos( y )  12 [cosx  y   cos( x  y )] sin( x) cos( y )  12 [sin x  y   sin( x  y )] cos( x) sin( y )  12 [sin x  y   sin( x  y )] x y x y sin( x)  sin( y )  2 sin    cos  2   2  x y x y sin( x)  sin( y )  2 sin    cos  2   2  x y x y cos( x)  cos( y )  2 cos   cos  2   2  x y x y cos( x)  cos( y )  2 sin    sin   2   2   sin(−x) = −sin(x)  csc(−x) = −csc(x)  cos(−x) = cos(x) 4  sec(−x) = sec(x)  tan(−x) = −tan(x)  cot(−x) = −cot(x) Pythagorean Theorem c a α b a2 + b2 = c2 c = √a2 + b 2 a  sin α = = c hypotenuse c hypotenuse b  cos α = = a  tan α = =  cot α = opposite b adjacent opposite 1 adjacent tan α 1  sec α =  cosec α =  The length of the longest side can never be greater than the sum of the two other sides. cos α 1 sin α 5  The length of the shortest side can never be less than the positive difference of the other two sides.  A "Pythagorean Triple" is a set of positive integers, a, b and c that fits the rule: a2 + b2 = c2 The smallest Pythagorean Triple is 3, 4 and 5. Hyperbolic Functions  sinh x = −sinh(−x)  sech x = sech(−x)  cosh x = cosh(−x)  cosech x = −cosech(−x)  tanh x = −tanh(−x)  coth x = −coth(−x)  cosh ix = cos x  cos ix = cosh x  sinh ix = i sin x  sin ix = i sinh x  tanh x =  coth x =  sech x =  cosech x =  cosh2 x − sinh2 x =1  cosh x = (ex + e−x) = 1 + sinh 𝑥 cosh 𝑥 cosh 𝑥 sinh 𝑥 1 cosh 𝑥 1 2 1 sinh 𝑥 𝑥2 2! + 𝑥4 4! + …. 6 valid for all x  1 sinh x = (ex − e−x) = x + 2 𝑥3 For large positive x: 3! cosh x ≈ sinh x → tanh x →1 + 𝑥5 5! + …. valid for all x 𝑒𝑥 2 For large negative x: 𝑒−𝑥 cosh x ≈ −sinh x → 2 tanh x → −1 Inverse functions 𝑥 = ln ( 𝑥 + √𝑥 2 + 𝑎2 ) for −∞ < x < ∞ 𝑥 = ln ( 𝑥 + √𝑥 2 − 𝑎2 ) for x ≥ a  sinh −1  cosh −1  tanh −1  coth −1  sech −1  cosech −1 𝑎 𝑎 𝑥 𝑎 𝑥 𝑎 𝑥 𝑎 = = 1 2 1 2 𝑎 ln ( ln ( 𝑎 𝑎 𝑎+𝑥 𝑎−𝑥 𝑥+𝑎 𝑥−𝑎 ) for x2 < a2 ) for x2 > a2 𝑎2 = ln ( + √ 𝑥 2 − 1 ) for 0 < x ≤ a 𝑥 𝑎 𝑥 𝑎 𝑎2 = ln ( + √ 𝑥 2 + 1 ) for x ≠ 0 𝑥 Natural Number s {1, 2, 3, 4 ...................} Whole numbers 7 {0, 1, 2, 3 .................... } 0 is neither positive nor negative Integers {.....–3, –2, –1, 0, 1, 2, 3….} Type of Integers  Non negative integers { 0, 1, 2, 3, ......... }  Negative integers {. .......... –3, –2, –1}  Non positive integers {. .......... –3, –2 –1, 0}  Positive integers {1, 2, 3 .......... } Rational Numbers A number is called rational if it can be expressed in the form Example: 4 3 p q where p and q are integers (q>0). = 1.3̅ = 1.333......... Irrational numbers A number is called irrational if it cannot be expressed in the form (q> 0). Example: √2 = 1.414.............. Real Numbers 8 p q where p and q are integers Real → Rational + Irrational Prime Numbers Numbers which are divisible by 1 or itself {2, 3, 5, 7, 11, 13 ..........} 1 is not a prime. 2 is the smallest prime and the only even prime. Composite Numbers Numbers which are multiples of prime are called composite numbers {4, 6, 8, 9 ...........} Coprime 21 and 22 are coprime:   The factors of 21 are 1, 3, 7 and 21 The factors of 22 are 1, 2, 11 and 22 (The only common factor is 1) But 21 and 24 are NOT coprime: • • The factors of 21 are 1, 3, 7 and 21 The factors of 24 are 1, 2, 3, 4, 6, 8, 12 and 24 (The common factors are 1 and 3) Twin primes The prime numbers which having the difference of 2 e.g. (5, 3), (7, 5), (13, 11)............ 1 is neither a prime nor a composite number Order of Operations: PEMDAS (Parentheses / Exponents / Multiply / Divide / Add / Subtract) 9 Euclid's Division Lemma: If two positive integers a and b, then there exists unique integers q and r such that which satisfies the condition a = bq + r where 0 ≤ r ≤ b. If r = 0, then b is divisor of a. Coordinate Geometry Any line can be represented by y = mx + b, where m is the slope and b is the y-intercept. This is called slope-intercept form. Distance between two points ( x1 , y1 ), ( x2 , y2 )   x1  x2    y1  y2  2 x x y y  Midpoint of two points ( x1 , y1 ), ( x2 , y2 )   1 2 , 1 2  2   2 y (x2, y2) (x1, y1) x The slope of the line passing through the points (x1, y1) and (x2, y2) is Differentiation Formulas 1. d n ( x )  nx n 1 dx 2. d (sin x)  cos x dx 10 𝑦2 −𝑦1 𝑥2 −𝑥1 2 3. d (cos x)   sin x dx 4. d (tan x)  sec 2 x dx 5. d (cot x)   csc 2 x dx 6. d (sec x)  sec x tan x dx 7. d (csc x)   csc x cot x dx 8. d x (e )  e x dx 9. d x (a )  a x ln a dx 10. d 1 (ln x )  dx x 11. d 1 ( Arc sin x)  dx 1 x2 12. 1 d ( Arc tan x)  dx 1 x2 13. d 1 ( Arc sec x)  dx | x | x2 1 14. dy dy du   dx dx dx 15. d c  0 dx 16. d cu   c du dx dx 11 17. d u  v  du  dv dx dx dx 18. d uv  u dv  v du dx dx dx dv du u d u   dx 2 dx 19.   dx  v  v v 20. d x   1 dx Integration Formulas 1.  a dx  ax  C 2. n  x dx  3.  x dx  ln 4. e 5. x  a dx  6.  ln x dx  x ln x  x  C 7.  sin x dx   cos x  C 8.  cos x dx  sin x  C 9.  tan x dx  ln sec x  C 1 x x n 1  C , n  1 n 1 x C dx  e x  C ax C ln a or  ln cos x  C 10.  cot x dx  ln sin x  C 12 11.  sec x dx  ln sec x  tan x  C 12.  csc x dx  ln csc x  cot x  C   ln csc x  cot x  C 13.  sec 2 x d x  tan x  C 14.  sec x tan x dx  sec x  C 15.  csc 2 x dx   cot x  C 16.  csc x cot x dx   csc x  C 17.  tan 18. a 2 19.   x  Arc sin    C a a2  x2 20. x 2 x dx  tan x  x  C 1 dx  x  Arc tan    C 2 a x a dx dx x2  a2  x a 1 1 Arc sec  C  Arc cos  C x a a a 21.  u dv  uv   v du HCF (Highest common factor)  HCF (a, b) =1. Then a and b are co primes  HCF (a, b) × LCM (a, b) = a × b Vector Algebra If i, j, k are orthonormal vectors and A = Axi + Ay j + Azk then |A|2 = Ax2 + Ay2 + Az2. 13  Scalar product A ∙ B = |A| |B| cosθ where θ is the angle between the vectors. Scalar multiplication is commutative: A ∙ B = B ∙ A.  Vector product A × B = n |A| |B| sinθ, where θ is the angle between the vectors and n is a unit vector normal to the plane containing A and B in the direction for which A, B, n form a righthanded set of axes. Vector multiplication is not commutative: A×B = −B×A.  Scalar triple product A × B ∙ C = A ∙B × C  Vector triple product A × (B × C) = (A ∙ C) B − (A ∙ B) C (A×B) × C = (A ∙ C) B − (B ∙ C) A  Angles on the inside of any triangle add up to 180◦  The length of one side of any triangle is always less than the sum and more than the difference of the lengths of the other two sides.  If two lines intersect, the sum of the resulting four angles equals 360. Average formula: 14 Let a1, a2, a3... an be a set of numbers, average = 𝑎1 + 𝑎2 + 𝑎3 + ….+ 𝑎n Fractions formulas:      a + a − a × b b b a b a b = c d = ad+bc c d = ad−bc c = ac d c c d d bd bd bd = a b × d c = → ad = bc ad bc Geometry formulas: Perimeter:  Perimeter of a square: s + s + s + s s: length of one side  Perimeter of a rectangle: l + w + l + w l: length w: width  Perimeter of a triangle: a + b + c  a, b, and c: lengths of the 3 sides Area: 15 n  Area of a square: s × s s: length of one side  Area of a rectangle: l × w l: length w: width  Area of a triangle: b: length of base b×h 2 h: length of height  Area of a trapezoid: (b1 + b2) × h 2 b1 and b2: parallel sides or the bases h: length of height Volume:  Volume of a cube: s × s × s s: length of one side  Volume of a box: l × w × h l: length w: width h: height  4 Volume of a sphere: × π × r3 3 π: 3.14159265359 r: radius of sphere 16  Volume of a triangular prism: area of triangle × height of the triangular prism  Volume of a cylinder: π × r2 × h r: radius of the circle of the base h: height of the cylinder Quadrilaterals  The diagonals of a square bisect one another, forming four 90 degree angles  The diagonals of a rhombus bisect one another, forming four 90 degree angles  The perimeter of a rectangle is twice its height plus twice its length (or, the sum of all its sides).  The area of a parallelogram can be found multiplying base × height (the base always forms a right angle with the height). Circles: Area = πr2 Circumference = 2πr A circle has 360 degrees. An arc is the portion of the circumference of a circle in x degrees of the circle. Arc length = 𝑥 360 Area of sector = × 2πr 𝑥 360 × πr2 Basic Identities 17  a+0=a  a + (−a) = 0  (a + b) + c = a + (b + c)  a+b=b+a  a − b = a + (−b)  a*1=a  a*  a*0=0  (a * b) * c = a * (b * c)  a*b=b*a  a (b + c) = ab + ac  a b 1 a =1 (a ≠ 0) 1 =a(b) Negative exponents: x −2 = 1 𝑥2 Negative bases: (−2) 4 = −2 × −2 × −2 × −2 = 16 (−2) 5 = −2 × −2 × −2 × −2 × −2 = 32 Perfect Squares: Perfect Square Factors 18 1 1 * 1 4 2 * 2 9 3 * 3 16 4 * 4 25 5 * 5 36 6 * 6 49 7 * 7 64 8 * 8 81 9 * 9 100 10 * 10 121 11 * 11 144 12 * 12 169 13 * 13 196 14 * 14 225 15 * 15 256 16 * 16 289 17 * 17 324 18 * 18 361 19 * 19 19 400 20 * 20 Inequalities:  If w < x and x < y, then w < y.  If a < b and c < d, then a + c < b + d. However, this does not hold for subtracting, multiplying, or dividing. Probabilities Probability is a representation of the odds of something happening. A probability of 1 is guaranteed to happen. A probability of 0 will never happen. 0.5 = there is a 50/50 chance the event will occur.  Probability of an outcome happening = number of desired outcomes total number of possible outcomes Probability of two independent outcomes both happening is Probability of event A * probability of event B e.g., Event A has a probability of events happening is: happening. 1 4 * 1 8 = 1 1 4 and event B has a probability of 1 . The probability of both 8 . There is a 1 in 32 chance of both events A and event B 32 Combinations 20  Possible combinations = number of element A * number of element B * number of element C…. e.g., In a cafeteria, there are 3 different dessert options, 2 different entree options, and 4 drink options. How many different lunch combinations are possible, using one drink, one, dessert, and one entree?  The total combinations possible = 3 * 2 * 4 = 24 Fundamental Counting Principle: If an event can happen in N ways, and another, independent event can happen in M ways, and then both events together can happen in N × M ways. Combinations: n 5 Cr = C3 = 𝑛! 𝑟!(𝑛−𝑟)! 5! 3! (2!) = 10 Permutations: n Pr = 𝑛! (𝑛−𝑟)! Probability that event A will happen: P (A) = Number of outcomes where A occurs Total number of outcomes P (event happens) + P (event does not happen) = 1 21 Mutually exclusive events: Two events are mutually exclusive if they can't happen together: P (A and B) = 0 Events A and B (if they are independent events): P (A and B) = P (A) × P (B) Events A or B: A happens, B happens, or both A and B happen. P (A or B) = P (A) + P (B) – P (A and B) Events A and B (if A and B are dependent events): P (A and B) = P (A) × P (B | A) P (B | A) is the probability that B occurs given that A occurs. Number of ways to follow a rule = number of ways to ignore the rule – number of ways to break the rule. Percents: part = percent 100 × whole  mode = value in the list that appears most often  median = middle value in the list median of {3, 9, 10, 27, 50} = 10 median of {3, 9, 10, 27} = 9 + 10 2 = 9.5 Range = Greatest value – least value Polygons 22  Total degrees = 180 (n −2) where n = number of sides  Average degrees per side = 180 (𝑛−2) 𝑛 Distance, Rate, and Time  Distance = Rate × Time  Rate =  Time =  Average speed = Distance Time Distance Rate Total Distance Traveled Total Time Standard deviation: If you're given a set of n numbers a, b, c … with a mean m: (a−m)2 + (b−m)2 + (c−m)2 + … SD = √ n Variance = SD2 Integer series 𝑛 (𝑛+1)  1 + 2 + 3 + ….. + n =  12 + 22 + 32 + ….. + n2 =  1 + 2 + 3 + ….. + n = 3 3 3 3 2 𝑛 (𝑛+1) (2𝑛+1) 6 𝑛2 (𝑛+1)2 4 23 𝑛(𝑛+1)(2𝑛+1)(3𝑛2 + 3𝑛−1)  14+ 24 + 34 + ….. + n4 =  1− 1 + − 1 1 + ….. = ln2  1− 1 + − 1 1 + ….. =  1− 1 + − 1 1  1.2.3 + 2.3.4+ … + n (n+1) (n+2) = 2 3 4 3 5 9 4 7 16 30 𝜋 4 + ….. = 𝜋2 6 𝑛 (𝑛+1) (𝑛+2) (𝑛+3) 4 Arithmetic and Geometric progressions A.P. Sn = a + (a + d) + (a + 2d) + … + [a + (n − 1) d] = G.P. Sn = a + ar + ar2 + … + ar n −1 = a 1−𝑟 𝑛 1−𝑟 𝑛 2 [2𝑎 + (𝑛 − 1)𝑑] 𝑎 , (S∞ = 1− 𝑟 for |r| < 1) Convergence of series: the ratio test Sn = u1 + u2 + u3 + …..+ un converges as n → ∞ if lim | 𝑛→∞ 𝑢𝑛+1 𝑢𝑛 |<1 Convergence of series: the comparison test If each term in a series of positive terms is less than the corresponding term in a series known to be convergent, then the given series is also convergent. Power series with real variables  ex = 1 + x + 𝑥2 2! + ….. + 𝑥𝑛 𝑛! + …… valid for all x 24 𝑥2 𝑥3  ln(1+x) =x −  cosx = 𝑒 𝑖𝑥 + 𝑒 −𝑖𝑥 = 1−  sinx = 𝑒 𝑖𝑥 − 𝑒 −𝑖𝑥 = x−  tanx = x + 2 2 2𝑖 1 3  tan −1x = x −  sin −1x = x + + 𝑥3 + 𝑥3 3 + 1 𝑥3 2 3 3 2 15 𝑥5 5 + + …. + (−1) n+1 𝑥2 2! 𝑥3 3! + + 𝑥4 4! 𝑥5 5! 𝑥 5 + …. − …. 1.3 𝑥 5 2.4 5 𝑥6 𝑥𝑛 𝑛! + …. valid for −1 < x ≤ 1 − 6! + …… valid for all values of x + …… valid for all values of x valid for − π 2 <x< valid for −1 ≤ x ≤ 1 + …. π 2 valid for −1 < x < 1 Complex numbers The complex number z = x + iy = r (cosθ + i sinθ) = r e arbitrary integer. , where i2 = −1 and n is an i (θ+2nπ) The complex conjugate of z is z* = x − iy = r (cosθ − i sinθ) = re−iθ; zz* = |z|2 = x2 + y2 De Moivre's theorem (cosθ + i sinθ) n = einθ = cos nθ + i sin nθ Power series for complex variables ez = 1 + z + sin z = z − 𝑧2 2! 𝑧3 cos z = 1 − 3! 𝑧2 2! + …… + + 𝑧5 + ln (1 + z) = z − 5! 𝑧4 4! 𝑧2 2 𝑧𝑛 𝑛! +… convergent for all finite z − …… convergent for all finite z − …… convergent for all finite z + 𝑧3 3 − …… principal value of ln(1 + z) 25  Sum of first n odd numbers = n²  Sum of first n even numbers = n (n + 1) Profit, Loss and Discount  Profit or Gain = Selling Price – Cost Price  Profit % =  Selling Price =  Cost Price =  Loss = Cost Price – Selling Price  Loss % =  Selling Price =  Cost Price =  Discount % =  Effective Discount after successive discount of a% and b% is (a + b − Profit Cost Price ×100 100 + Profit % 100 100 100 + Profit % Loss Cost Price × Cost Price × Selling Price × 100 100− loss % 100 100 100− loss % × Cost Price × Selling Price Marked Price−Selling Price Marked Price × 100 y buy x goods and get y goods free is x + y × 100 LCM and HCF  Product of two numbers = Their H. C. F. × Their L. C. M.  LCM of Co-prime Numbers = Product of the Numbers  HCF of Fractions =  LCM of Fractions = HCF of Numerator LCM of denominator LCM of Numerator HCF of denominator 26 ab 100 ). Effective Discount when you Percentages  To find what percentage of x is y:  Increase N by S % = N( 1+  Decrease N by S % = N (1− S 100 S ) 100 y x × 100 ) Time and Work    If A can do a piece of work in n days, then A's 1 day's work = 1 If A's 1 day's work = 𝑛, then A can finish the work in n days. 1 𝑛 If A is thrice as good a workman as B, then: Ratio of work done by A and B = 3 : 1 Ratio of times taken by A & B to finish a work = 1 : 3 Pipes and Cisterns  If a pipe can fill a tank in 'x' hours and another pipe can empty the full tank in 'y' hours (where y > x), then 1 1 on opening both the pipes, the net part of the tank filled in 1 hour is ( x − y ) Time and Distance  Suppose a man covers a distance at 'x' kmph and an equal distance at 'y' kmph, then average speed during his whole journey is [ 2xy x+y ] kmph Trains  Lengths of trains are 'x' km and 'y' km, moving at 'u' kmph and 'v' kmph (where u > v) in the same direction, then the time taken y the over-taker train to cross the slower train is [ 27 x+y u−v ] hrs x+y  Time taken to cross each other is [  If two trains start at the same time from two points A and B towards each other and after crossing they take u+ v ] hrs a and b hours in reaching B and A respectively. Then, A's speed : B's speed = (√b : √a). Boats and Streams  If the speed of a boat in still water is u km/hr and the speed of the stream is v km/hr, then: Speed downstream = (u + v) km/hr. Speed upstream = (u − v) km/hr.  If the speed downstream is a km/hr and the speed upstream is b km/hr, then: 1 Speed in still water = (a + b) km/hr. 1 2 Rate of stream = 2 (a −b) km/hr. Mixtures and Alligations  Alligation: It is the rule that enables us to find the ratio in which two or more ingredients at the given price must be mixed to produce a mixture of desired price.  Mean Price: The cost of a unit quantity of the mixture is called the mean price.  Rule of Alligation: If two ingredients are mixed, then Quantity of cheaper Quantity of dearer  Cost Price of dearer – Mean Price = Mean price – Cost Price of cheaper Where a is the original quantity, b is the quantity that is replaced and n is the number of times the replacement process is carried out, then Quantity of original entity after n operation Quantity of mixture Inequalities If a > b and c > 0, 28 =( a−b a )n  a+c>b+c  a−c>b−c  ac > bc  a c > b c If a, b ≥ 0, then an > bn and 1 an <  a < b and x > 0, then  a > b and x > 0, then 1 n, where n is positive. b a+x b+x a+x b+x > < a b a b 1. n (n+l)(2n+1) is always divisible by 6. 2. 32n leaves remainder = 1 when divided by 8 3. n3 + (n+1)3 + (n+2)3 is always divisible by 9 4. 102n+1 + 1 is always divisible by 11 5. n(n2-1) is always divisible by 6 6. n2+ n is always even 7. 23n-1 is always divisible by 7 8. 152n-1 +l is always divisible by 16 9. n3 + 2n is always divisible by 3 10. 34n – 43n is always divisible by 17 11. Product of n consecutive numbers is always divisible by n! 12. If n is a positive integer and p is a prime, then n p – n is divisible by p. 13. |x| = x if x ≥ 0 and |x| = – x if x ≤ 0. 14. Dividend = Quotient × Divisor + Remainder 15. A number is divisible by 2, if its unit’s place digit is 0, 2, 4, or 8 16. A number is divisible by 3, if the sum of its digits is divisible by 3 17. A number is divisible by 4, if the number formed by its last two digits is 29 divisible by 4 18. A number is divisible by 8, if the number formed by its last three digits is divisible by 8 19. A number is divisible by 9, if the sum of its digits is divisible by 9 20. If the population of a town is 'P' in a year, then its population after 'N' years is P(1+ R 100 )N 21. If the population of a town is 'P' in a year, then its population 'N' years ago is P /[(1+ R 100 )N] 22. The equality of two ratios is called a proportion. If a : b = c : d, we write a : b :: c : d and we say that a, b, c, d are in proportion. In a proportion, the first and fourth terms are known as extremes, while the second and third are known as means. 23. Product of extremes = Product of means 24. Mean proportion between a and b is √ab 25. The compounded ratio of the ratios (a : b), (c : d), (e : f) is (ace : bdf) 26. a2 : b2 is a duplicate ratio of a : b 27. √a : √b is a sub-duplicate ration of a : b 28. a3 : b3 is a triplicate ratio of a : b 29. a1/3 : b1/3 is a sub-triplicate ratio of a : b 30. If 31. If 32. If a = a = a = b b b c , then, (a + b) = (c + d) c , then, (a− b) = (c− d) d d c d , then, b b (a + b) (a − b) = d d (c + d) (c − d) , which is called the componendo. , which is called the dividendo. , which is called the componendo and dividendo. 33. Variation: We say that x is directly proportional to y if x = ky for some constant k and we write, x α y. Also, we say that x is inversely proportional to y if x = k y for some constant k and we write x α 1 y 34. The cost of articles is directly proportional to the number of articles. 35. The work done is directly proportional to the number of men working at it. 30 n = m × 10P If n = 12345: 12345 = 1.2345 × 104  Any single digit number written (P −1) times is divisible by P, where P is a prime number >5.  If log x = y, then antilog y = x.  Logarithms to the base 10 are known as common logarithms. Characteristic and Mantissa in Logarithms: log10 15 = 1.176 = 1 + 0.176 Characteristic Mantissa (Integral part) When the number is greater than 1 (Decimal part) When the number is less than 1 log10 x = y  log10 15 = 1.176 = 1 + 0.176  log10 250 = 2.397 = 2 + 0.397  log10 4000 = 3.602 = 3 + 0.602  log10 50000 = 4.698 = 4 + 0.698 log10 x = y  log10 0.5 = − 0.301 = −1 + 0.699  log10 0. 08 = − 1.096 = −2 + 0.904  log10 0.005 = − 2.3010 = −3 + 0.699 31 Fermat's Last Theorem: No 3 positive integers a, b and c satisfy the equation: an + bn = cn for any integer value of n > 2. Fermat's little theorem: If p is a prime number and a is any integer not divisible by p, then p divides ap−1 −1. Fraction Percentage Fraction Percentage 1 2 1 3 50% 1 9 1 10 11.11% 1 4 1 5 1 6 1 7 1 8 33.33% 1 11 1 12 1 13 1 14 1 15 25% 20% 16.66% 14.28% 12.5% 10% 9.09% 8.33% 7.69% 7.14% 6.66% If N = (2) a (y) b (z) c where x, y, z are prime factors  Number of even factors of N = (a) (b+1) (c+1)  Number of odd factors of N = (b+1) (c+1) Triangle inequality: The sum of the lengths of any two sides of a triangle is greater than the length of the third side. 32 c b a Properties of inequalities: a+b>c Let x, y, and z be real numbers a+c>b Addition property: b+c>a If x < y, then x + z < y + z Subtraction property: If x < y, then x − z < y – z For a triangle with the side lengths: Multiplication property: 7, 9, 13 If x < y and z > 0, then xz < yz If x < y and z < 0, then xz > yz  The sum of 7 and 9 is 16 and 16 is greater than 13  The sum of 9 and 13 is 21 and 21 is greater than 7  The sum of 7 and 13 is 20 and 20 is greater than 9 Division property: If x < y and z > 0, then x < If x < y and z < 0, then x > Modulus inequalities or Absolute value inequalities: Transitive property: z z x y x y If x < y and y < z, then x < z  If |x| < a, then – a < x < a  If |x| > a, then either x > a or x <−a  If |x – l| < a, then l – a < x < l + a  If |x – l| > a, then either x > l + a or x < l – a. Comparison property: If x = y + z and z > 0, then x > y 33 Segment Addition Postulate: AB A BC B C AC If AB + BC = AC, then B is between A and C Ceva's theorem: If AF BD CE × × = 1, then the line AD, CF, BE forms a concurrent point at O. FB DC EA  Decimal (Base 10) — Represent any number using 10 digits [0–9]  Binary (Base 2) — Represent any number using 2 digits [0–1]  Octal (Base 8) — Represent any number using 8 digits [0–7]  Hexadecimal (Base 16) — Represent any number using 10 digits and 6 characters [0–9, A, B, C, D, E, F] 34  Decimal, hexadecimal, octal, and binary values Decimal Hexadecimal Octal Binary 0 0 0 0 1 1 1 1 2 2 2 10 3 3 3 11 4 4 4 100 5 5 5 101 6 6 6 110 7 7 7 111 8 8 10 1000 9 9 11 1001 10 A 12 1010 11 B 13 1011 12 C 14 1100 13 D 15 1101 14 E 16 1110 15 F 17 1111 16 10 20 10000 17 11 21 10001 18 12 22 10010 19 13 23 10011 20 14 24 10100 21 15 25 10101 22 16 26 10110 23 17 27 10111 24 18 30 11000 25 19 31 11001 26 1A 32 11010 27 1B 33 11011 28 1C 34 11100 29 1D 35 11101 30 1E 36 11110 31 1F 37 11111 32 20 40 100000 33 21 41 100001 34 22 42 100010 35 23 43 100011 36 24 44 100100 35 33 37 25 45 100101 38 26 46 100110 39 27 47 100111 40 28 50 101000 41 29 51 101001 42 2A 52 101010 43 2B 53 101011 44 2C 54 101100 45 2D 55 101101 46 2E 56 101110 47 2F 57 101111 48 30 60 110000 49 31 61 110001 50 32 62 110010 51 33 63 110011 52 34 64 110100 53 35 65 110101 54 36 66 110110 55 37 67 110111 56 38 70 111000 57 39 71 111001 58 3A 72 111010 59 3B 73 111011 60 3C 74 111100 61 3D 75 111101 62 3E 76 111110 63 3F 77 111111 64 40 100 1000000 65 41 101 1000001 66 42 102 1000010 67 43 103 1000011 68 44 104 1000100 69 45 105 1000101 70 46 106 1000110 71 47 107 1000111 72 48 110 1001000 73 49 111 1001001 74 4A 112 1001010 75 4B 113 1001011 76 4C 114 1001100 36 34 77 4D 115 1001101 78 4E 116 1001110 79 4F 117 1001111 80 50 120 1010000 81 51 121 1010001 82 52 122 1010010 83 53 123 1010011 84 54 124 1010100 85 55 125 1010101 86 56 126 1010110 87 57 127 1010111 88 58 130 1011000 89 59 131 1011001 90 5A 132 1011010 91 5B 133 1011011 92 5C 134 1011100 93 5D 135 1011101 94 5E 136 1011110 95 5F 137 1011111 96 60 140 1100000 97 61 141 1100001 98 62 142 1100010 99 63 143 1100011 100 64 144 1100100 101 65 145 1100101 102 66 146 1100110 103 67 147 1100111 104 68 150 1101000 105 69 151 1101001 106 6A 152 1101010 107 6B 153 1101011 108 6C 154 1101100 109 6D 155 1101101 110 6E 156 1101110 111 6F 157 1101111 112 70 160 1110000 113 71 161 1110001 114 72 162 1110010 115 73 163 1110011 116 74 164 1110100 37 35 117 75 165 1110101 118 76 166 1110110 119 77 167 1110111 120 78 170 1111000 121 79 171 1111001 122 7A 172 1111010 123 7B 173 1111011 124 7C 174 1111100 125 7D 175 1111101 126 7E 176 1111110 127 7F 177 1111111 128 80 200 10000000 129 81 201 10000001 130 82 202 10000010 131 83 203 10000011 132 84 204 10000100 133 85 205 10000101 134 86 206 10000110 135 87 207 10000111 136 88 210 10001000 137 89 211 10001001 138 8A 212 10001010 139 8B 213 10001011 140 8C 214 10001100 141 8D 215 10001101 142 8E 216 10001110 143 8F 217 10001111 144 90 220 10010000 145 91 221 10010001 146 92 222 10010010 147 93 223 10010011 148 94 224 10010100 149 95 225 10010101 150 96 226 10010110 151 97 227 10010111 152 98 230 10011000 153 99 231 10011001 154 9A 232 10011010 155 9B 233 10011011 156 9C 234 10011100 38 36 157 9D 235 10011101 158 9E 236 10011110 159 9F 237 10011111 160 A0 240 10100000 161 A1 241 10100001 162 A2 242 10100010 163 A3 243 10100011 164 A4 244 10100100 165 A5 245 10100101 166 A6 246 10100110 167 A7 247 10100111 168 A8 250 10101000 169 A9 251 10101001 170 AA 252 10101010 171 AB 253 10101011 172 AC 254 10101100 173 AD 255 10101101 174 AE 256 10101110 175 AF 257 10101111 176 B0 260 10110000 177 B1 261 10110001 178 B2 262 10110010 179 B3 263 10110011 180 B4 264 10110100 181 B5 265 10110101 182 B6 266 10110110 183 B7 267 10110111 184 B8 270 10111000 185 B9 271 10111001 186 BA 272 10111010 187 BB 273 10111011 188 BC 274 10111100 189 BD 275 10111101 190 BE 276 10111110 191 BF 277 10111111 192 C0 300 11000000 193 C1 301 11000001 194 C2 302 11000010 195 C3 303 11000011 196 C4 304 11000100 39 37 197 C5 305 11000101 198 C6 306 11000110 199 C7 307 11000111 200 C8 310 11001000 201 C9 311 11001001 202 CA 312 11001010 203 CB 313 11001011 204 CC 314 11001100 205 CD 315 11001101 206 CE 316 11001110 207 CF 317 11001111 208 D0 320 11010000 209 D1 321 11010001 210 D2 322 11010010 211 D3 323 11010011 212 D4 324 11010100 213 D5 325 11010101 214 D6 326 11010110 215 D7 327 11010111 216 D8 330 11011000 217 D9 331 11011001 218 DA 332 11011010 219 DB 333 11011011 220 DC 334 11011100 221 DD 335 11011101 222 DE 336 11011110 223 DF 337 11011111 224 E0 340 11100000 225 E1 341 11100001 226 E2 342 11100010 227 E3 343 11100011 228 E4 344 11100100 229 E5 345 11100101 230 E6 346 11100110 231 E7 347 11100111 232 E8 350 11101000 233 E9 351 11101001 234 EA 352 11101010 235 EB 353 11101011 236 EC 354 11101100 40 38 237 ED 355 11101101 238 EE 356 11101110 239 EF 357 11101111 240 F0 360 11110000 241 F1 361 11110001 242 F2 362 11110010 243 F3 363 11110011 244 F4 364 11110100 245 F5 365 11110101 246 F6 366 11110110 247 F7 367 11110111 248 F8 370 11111000 249 F9 371 11111001 250 FA 372 11111010 251 FB 373 11111011 252 FC 374 11111100 253 FD 375 11111101 254 FE 376 11111110 255 FF 377 11111111  Any prime number greater than 3 can be written as 6k±1.  The product of 'n' consecutive natural numbers is always divisible by n!  Square of any natural number can be written in the form of 3n or 3n+1. Also, square of any natural number can be written in the form of 4n or 4n+1.  Any two digit number 'pq' can effectively be written as 10p + q and a three digit number 'pqr' can effectively be written as 100p + 10q + r.  Number of ways N can be written as product of two factors = P is even or odd respectively  P 2 or (P+1) 2 if The number of ways in which a composite number can be resolved into two co-prime factors is 2m-1, where m is the number of different prime factors of the number. 41 39  (x + a)(x + b) (x + c) = x3 + (a + b + c) x2 + (ab + bc + ac)x + abc  (x – a)(x – b) (x – c) = x3 – (a + b + c) x2 + (ab + bc + ac)x – abc  Arithmetic Mean = (a1 + a2 + a3 ….an) / n  Geometric Mean =  Harmonic Mean = n / (  For two numbers a and b n √a1 a2 … . . an 1 x1 + 1 + ...+ x2 AM = 1 xn ) (a + b) 2 GM = √ab HM =  2ab a+b AM ≥ GM ≥ HM is always true. They will be equal if all elements are equal to each other. If there are just two values then GM2 = AM × HM  Absolute Growth = Final Value – Initial Value  Growth rate for one year period =  Compound Annual Growth Rate =  Average Annual Growth Rate =  Linear Races ( Final Value – Initial Value Initial Value Final Value Initial Value ) 1 𝑛𝑜. 𝑜𝑓 𝑦𝑒𝑎𝑟𝑠 Final Value – Initial Value Number of years × 100 − 1 × 100 Winner's distance = Length of race Loser's distance = Winner's distance – (beat distance + start distance) Winner's time = Loser's time – (beat time + start time) Circular Races 42 40 Two people are running on a circular track of length L with speeds a and b in the same direction L Time for 1st meeting = a−b They meet at a – b distinct points (reduced ratio) L L Time for 1st meeting at the starting point = LCM ( a , b ) Two people are running on a circular track of length L with speeds a and b in the opposite direction Time for 1st meeting = L a+b They meet at a + b distinct points (reduced ratio) L L Time for 1st meeting at the starting point = LCM ( a , b ) Three people are running on a circular track of length L with speeds a, b and c in the same direction Time for 1st meeting = LCM ( L a−b , L a−c ) Time for 1st meeting at the starting point = LCM (  If a and b are positive quantities, then a+b 2  L L , a b ≥ √ab If a, b, c, d are positive quantities, then a b + b c + c d + d a ≥ 4 a4 + b4 + c4 +d4 ≥ 4abcd 43 41 , L ) c  For any positive integer n, 2 ≤  (n!)2 ≥ nn  am + bm 2 > (   Simple Interest Formula 2 n ≤ 3 a+b m ) [m ≤ 0 or m ≥ 1] 2 am + bm < ( 1 (1+ )n a+b m ) [0 < m 2 < 1] Simple interest = P × i × n where: P = principal amount i = interest rate n = term of the loan  Compound Interest Formula The formula for calculating compound interest in a year is: Compound interest = [P (1 + i) n] − P where: P = principal amount i = interest rate in percentage terms n = number of compounding periods for a year 44 42 Total value with compound interest = [P ( where: 1+ 𝑖 n ) nt] − P P = principal amount i = interest rate in percentage terms n = number of compounding periods per year t = total number of years for the investment or loan  The formulas for obtaining the future value (FV) and present value (PV) are as follows: FV = PV × ( PV = ( 1+ 𝑖 n ) nt FV 1+ 𝑖 nt ) n Theorems  Mid Point Theorem: The line joining the midpoint of any two sides is parallel to the third side and is half the length of the third side.  Apollonius' Theorem: A B C D AB2 + AC2 = 2 (AD2 + BD2)  Basic Proportionality Theorem: 45 43 A D E B If DE || BC, then  AD DB = C AE EC Interior Angle Bisector Theorem: A E D B AE ED  = BA BD Right Angled Triangle: A ∆ABC ≈ ∆ADB ≈ ∆BDC BD2 = AD × DC AB × BC = BD × AC D C B 46 44 Fundamental Theorem of Arithmetic: Every integer greater than 1 can be factored uniquely into a product of prime numbers For example: 4312 = 2 × 2 × 2 × 7 × 7 × 11 Euclid's lemma: If a prime number divides a product of two numbers, it must divide at least one of the numbers. Stewart's Theorem: If a, b and c are the lengths of the sides of a triangle. If d is the length of the cevian of the side of the length a. Suppose this cevian divides the side 'a' into 2 segments of the length m and n, where m is adjacent to the side c and whereas n is adjacent to the side b, then b2m + c2 n = a (d2 + mn) 47 The Square Root of 2 is Called "Pythagoras' Constant." 0 is the Only Number That Can't Be Represented In Roman Numerals 0 is an Even Number 6 is the Smallest Perfect Number The Number Pi (the ratio of the circumference to the diameter of a circle) is Irrational If we multiply a number by 9 and add all the digits of the new number together, the sum will always add up to 9. For example: 8 × 9 = 72 7+2=9 4 × 9 = 36 3+6=9 48 Number Square Cube Square Root Cubic Root 1 1 1 1.000 1.000 2 4 8 1.414 1.260 3 9 27 1.732 1.442 4 16 64 2.000 1.587 5 25 125 2.236 1.710 6 36 216 2.449 1.817 7 49 343 2.646 1.913 8 64 512 2.828 2.000 9 81 729 3.000 2.080 10 100 1000 3.162 2.154 11 121 1331 3.317 2.224 12 144 1728 3.464 2.289 13 169 2197 3.606 2.351 14 196 2744 3.742 2.410 15 225 3375 3.873 2.466 16 256 4096 4.000 2.520 17 289 4913 4.123 2.571 18 324 5832 4.243 2.621 19 361 6859 4.359 2.668 20 400 8000 4.472 2.714 21 441 9261 4.583 2.759 22 484 10648 4.690 2.802 23 529 12167 4.796 2.844 24 576 13824 4.899 2.884 25 625 15625 5.000 2.924 26 676 17576 5.099 2.962 49 27 729 19683 5.196 3.000 28 784 21952 5.292 3.037 29 841 24389 5.385 3.072 30 900 27000 5.477 3.107 31 961 29791 5.568 3.141 32 1024 32768 5.657 3.175 33 1089 35937 5.745 3.208 34 1156 39304 5.831 3.240 35 1225 42875 5.916 3.271 36 1296 46656 6.000 3.302 37 1369 50653 6.083 3.332 38 1444 54872 6.164 3.362 39 1521 59319 6.245 3.391 40 1600 64000 6.325 3.420 41 1681 68921 6.403 3.448 42 1764 74088 6.481 3.476 43 1849 79507 6.557 3.503 44 1936 85184 6.633 3.530 45 2025 91125 6.708 3.557 46 2116 97336 6.782 3.583 47 2209 103823 6.856 3.609 48 2304 110592 6.928 3.634 49 2401 117649 7.000 3.659 50 2500 125000 7.071 3.684 51 2601 132651 7.141 3.708 52 2704 140608 7.211 3.733 53 2809 148877 7.280 3.756 50 54 2916 157464 7.348 3.780 55 3025 166375 7.416 3.803 56 3136 175616 7.483 3.826 57 3249 185193 7.550 3.849 58 3364 195112 7.616 3.871 59 3481 205379 7.681 3.893 60 3600 216000 7.746 3.915 61 3721 226981 7.810 3.936 62 3844 238328 7.874 3.958 63 3969 250047 7.937 3.979 64 4096 262144 8.000 4.000 65 4225 274625 8.062 4.021 66 4356 287496 8.124 4.041 67 4489 300763 8.185 4.062 68 4624 314432 8.246 4.082 69 4761 328509 8.307 4.102 70 4900 343000 8.367 4.121 71 5041 357911 8.426 4.141 72 5184 373248 8.485 4.160 73 5329 389017 8.544 4.179 74 5476 405224 8.602 4.198 75 5625 421875 8.660 4.217 76 5776 438976 8.718 4.236 77 5929 456533 8.775 4.254 78 6084 474552 8.832 4.273 79 6241 493039 8.888 4.291 80 6400 512000 8.944 4.309 51 81 6561 531441 9.000 4.327 82 6724 551368 9.055 4.344 83 6889 571787 9.110 4.362 84 7056 592704 9.165 4.380 85 7225 614125 9.220 4.397 86 7396 636056 9.274 4.414 87 7569 658503 9.327 4.431 88 7744 681472 9.381 4.448 89 7921 704969 9.434 4.465 90 8100 729000 9.487 4.481 91 8281 753571 9.539 4.498 92 8464 778688 9.592 4.514 93 8649 804357 9.644 4.531 94 8836 830584 9.695 4.547 95 9025 857375 9.747 4.563 96 9216 884736 9.798 4.579 97 9409 912673 9.849 4.595 98 9604 941192 9.899 4.610 99 9801 970299 9.950 4.626 100 10000 1000000 10.000 4.642 Logarithm Table x log10 x log2 x loge x 0 undefined undefined undefined 52 0.0001 −4 −13.287712 −9.210340 0.001 −3 −9.965784 −6.907755 0.01 −2 −6.643856 −4.605170 0.1 −1 −3.321928 −2.302585 1 0 0 0 2 0.301030 1 0.693147 3 0.477121 4 0.602060 5 0.698970 2.321928 1.609438 6 0.778151 2.584963 1.791759 7 0.845098 2.807355 1.945910 8 0.903090 9 0.954243 3.169925 2.197225 10 1 3.321928 2.302585 20 1.301030 4.321928 2.995732 30 1.477121 4.906891 3.401197 40 1.602060 5.321928 3.688879 50 1.698970 5.643856 3.912023 1.584963 2 3 53 1.098612 1.386294 2.079442 60 1.778151 5.906991 4.094345 70 1.845098 6.129283 4.248495 80 1.903090 6.321928 4.382027 90 1.954243 6.491853 4.499810 100 2 6.643856 4.605170 200 2.301030 7.643856 5.298317 300 2.477121 8.228819 5.703782 400 2.602060 8.643856 5.991465 500 2.698970 8.965784 6.214608 600 2.778151 9.228819 6.396930 700 2.845098 9.451211 6.551080 800 2.903090 9.643856 6.684612 900 2.954243 9.813781 6.802395 1000 3 9.965784 6.907755 10000 4 13.287712 9.210340 1 is Not a Prime Number Six Weeks = 10! Seconds 10 × 9 × 8 × 7 × 6 × 5 × 4 × 3 × 2 × 1 = 3,628,800 seconds = 60,480 minutes = 1,008 hours = 42 days = 6 weeks 54 Multiplication Table × 0 1 2 3 4 5 6 7 8 9 10 11 12 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 1 2 3 4 5 6 7 8 9 10 11 12 2 0 2 4 6 8 10 12 14 16 18 20 22 24 3 0 3 6 9 12 15 18 21 24 27 30 33 36 4 0 4 8 12 16 20 24 28 32 36 40 44 48 5 0 5 10 15 20 25 30 35 40 45 50 55 60 6 0 6 12 18 24 30 36 42 48 54 60 66 72 7 0 7 14 21 28 35 42 49 56 63 70 77 84 8 0 8 16 24 32 40 48 56 64 72 80 88 96 9 0 9 18 27 36 45 54 63 72 81 90 99 108 10 0 10 20 30 40 50 60 70 80 90 100 110 120 11 0 11 22 33 44 55 66 77 88 99 110 121 132 12 0 12 24 36 48 60 72 84 96 108 120 132 144 13 + 53 +33 = 153 163 + 503 +333 = 165033 1663 + 5003 +3333 = 166500333 16663 + 50003 +33333 = 166650003333 55 1×8+1=9 12 × 8 + 2 = 98 123 × 8 + 3 = 987 1234 × 8 + 4 = 9876 12345 × 8 + 5 = 98765 123456 × 8 + 6 = 987654 1234567 × 8 + 7 = 9876543 12345678 × 8 + 8 = 98765432 123456789 × 8 + 9 = 987654321 Metric Units of Measurement Prefix Name Prefix Symbol Value yotta Y 1024 Septillion zetta Z 1021 Sextillion exa E 1018 Quintillion peta P 1015 Quadrillion tera T 1012 Trillion giga G 109 Billion mega M 106 Million kilo k 103 Thousand hecto h 102 Hundred deka da 101 Ten 100 One deci d 10−1 Tenth centi c 10−2 Hundredth milli m 10−3 Thousandth micro μ 10−6 Millionth 56 nano n 10−9 Billionth pico p 10−12 Trillionth femto f 10−15 Quadrillionth atto a 10−18 Quintillionth zepto z 10−21 Sextillionth yocto y 10−24 Septillionth From 0 to 1000, the only number that has the letter "a" in it is "one thousand". Units of Length 10 millimeter (mm) 1 centimeter (cm) 10 centimeter 1 decimeter (dm) = 100 millimeters 10 decimeter 1 meter (m) = 1000 millimeters 10 meter 1 decameter (dam) 10 decameter 1 hectometer (hm) = 100 meters 10 hectometer 1 kilometer (km) = 1000 meters The numbers on opposite sides of a dice always add up to seven Units of Area 100 square millimeter (mm2) 1 square centimeter (cm2) 100 square centimeter 1 square decimeter (dm2) 100 square decimeter 1 square meter (m2) 100 square meter 1 square decameter (dam2) = 1 are 100 square decameter 1 square hectometer (hm2) = 1 hectare (ha) 100 square hectometer 1 square kilometer (km2) 57 Units of Liquid Volume 10 milliliters (mL) 1 centiliter (cL) 10 centiliters 1 deciliter (dL) = 100 milliliters 10 deciliters 1 liter = 1000 milliliters 10 liters 1 decaliter (daL) 10 decaliter 1 hectoliter (hL) = 100 liters 10 hectoliters 1 kiloliter (kL) = 1000 liters The number 0.999999….. is exactly equal to 1 Units of Volume 1000 cubic millimeter (mm3) 1 cubic centimeter (cm3) 1000 cubic centimeter 1 cubic decimeter (dm3) 1 000 000 cubic millimeter 1000 cubic decimeter 1 cubic meter (m3) 1 000 000 cubic centimeter 1 000 000 000 cubic millimeter Dividing by zero once put a US Navy Warship out of action Units of Mass 10 milligrams (mg) 1 centigram (cg) 10 centigrams 1 decigram (dg) = 100 milligrams 10 decigrams 1 gram (g) = 1000 milligrams 10 grams 1 dekagram (dag) 10 decagrams 1 hectogram (hg) = 100 grams 10 hectograms 1 kilogram 1000 kilograms 1 megagram (Mg) or 1 metric ton (t) (kg) = 1000 grams 58 Physical constants Symbol Quantity Value c speed of light in vacuum 299792458 m⋅s−1 h Planck constant 6.62607015×10−34 J⋅Hz−1 ℏ reduced Planck constant 1.054571817...×10−34 J⋅s Newtonian constant of gravitation 6.67430(15)×10−11 m3⋅kg−1⋅s−2 G vacuum electric permittivity 8.8541878128(13)×10−12 F⋅m−1 μ0 vacuum magnetic permeability 1.25663706212(19)×10−6 N⋅A−2 Z0 = μ0c characteristic impedance of vacuum 376.730313668(57) Ω e elementary charge 1.602176634×10−19 C ΔυCs hyperfine transition frequency of 133Cs 9192631770 Hz NA Avogadro constant 6.02214076×1023 mol−1 kB Boltzmann constant 1.380649×10−23 J⋅K−1 conductance quantum 7.748091729...×10−5 S ε0 = 1 μ0 c2 G0 = 2e2 h 59 Josephson constant 483597.8484...×109 Hz⋅V−1 Coulomb constant 8.9875517923(14)×109 kg⋅m3⋅s−2⋅C−2 h von Klitzing constant 25812.80745... Ω h magnetic flux quantum 2.067833848...×10−15 Wb inverse conductance quantum 12906.40372... Ω eℏ Bohr magneton 9.2740100783(28)×10−24 J⋅T−1 eℏ nuclear magneton 5.0507837461(15)×10−27 J⋅T−1 e2 fine-structure constant 7.2973525693(11)×10−3 α−1 inverse fine-structure constant 137.035999084(21) me electron mass 9.1093837015(28)×10−31 kg mp proton mass 1.67262192369(51)×10−27 kg mn neutron mass 1.67492749804(95)×10−27 kg Bohr radius 5.29177210903(80)×10−11 m 2e KJ = h 1 4πε0 RK = e2 Φ0 = 2e 1 G0 μB = μN = α= 2me 2mp 4πε0 ℏc a0 = ℏ αme c 60 classical electron radius 2.8179403262(13)×10−15 m ge electron g-factor −2.00231930436256(35) GF / (ℏc)3 Fermi coupling constant 1.1663787(6)×10−5 GeV−2 Eh = 2R∞ hc Hartree energy 4.3597447222071(85)×10−18 J h quantum of circulation 3.6369475516(11)×10−4 m2⋅s−1 α2 me c Rydberg constant 10973731.568160(21) m−1 8πr2e Thomson cross section 6.6524587321(60)×10−29 m2 W-to-Z mass ratio 0.88153(17) weak mixing angle 0.22290(30) mu = 1Da atomic mass constant 1.66053906660(50)×10−27 kg F=NAe Faraday constant 96485.33212... C⋅mol−1 R = NAkB molar gas constant Mu = M (12C) /12 molar mass constant 8.314462618... J⋅mol−1⋅K−1 0.99999999965(30)×10−3 kg⋅mol−1 Stefan–Boltzmann constant 5.670374419...×10−8 W⋅m−2⋅K−4 re = e2 4πε0 me c2 2me R∞= 2h σe = 3 mW mZ sin2θW = 1 – ( σ= mW 2 ) mZ π2 k4B 60ℏ3 c2 61 c1 = 2πhc2 first radiation constant 3.741771852...×10−16 W⋅m2 first radiation constant for spectral radiance 1.191042972...×10−16 W⋅m2⋅sr−1 M (12C) = NA m (12C) molar mass of carbon-12 11.9999999958(36)×10−3 kg⋅mol−1 NAh molar Planck constant 3.990312712...×10−10 J⋅Hz−1⋅mol−1 c1L = c2 = c1 π hc kB second radiation constant 1.438776877...×10−2 m⋅K Wien wavelength displacement law constant 2.897771955...×10−3 m⋅K b' Wien frequency displacement law constant 5.878925757...×1010 Hz⋅K−1 bentropy Wien entropy displacement law constant 3.002916077...×10−3 m⋅K b 111111111 × 111111111 = 12345678987654321 Euler's identity: eiπ +1 = 0 i = √−1 Euler's number − the base of natural logarithms 62 Planetary Fact Sheet Data about the planets of our solar system (Planetary facts taken from NASA's Planetary Fact Sheet−Metric). Distance Name Mercury Terrestrial planets Gas Mass Diameter Density Gravity (1024 kg) (km) (kg/m3 ) (m/s2 ) Length from Mean of day Sun te mp e ra t ure of (hours) (106 km) (°C) moons 0.330 4,879 5427 3.7 4222.6 57.9 167 0 Venus 4.87 12,104 5243 8.9 2802.0 108.2 464 0 Earth 5.97 12,756 5514 9.8 24.0 149.6 15 1 Mars 0.642 6,792 3933 3.7 24.7 227.9 −65 2 Jupiter 1898 142,984 1326 23.1 9.9 778.6 −110 67 568 120,536 687 9.0 10.7 1433.5 −140 62 Uranus 86.8 51,118 1271 8.7 17.2 2872.5 −195 27 Neptune 102 49,528 1638 11.0 16.1 4495.1 −200 14 0.0146 2,370 2095 0.7 153.3 5906.4 −225 5 Saturn giants Jovian planets Ice giants Dwarf planets Number Pluto Sun Reference Data Diameter: 1.4 million km Age: 4.5 billion years (870,000 miles) Mass: 330,000 × Earth Distance from Earth: 149.6 million km (93 million miles) Density: 1.41 (water =1) Distance to Nearest Star: 4.3 light years Solar Wind Speed: 3 million km/hr. Luminosity: 390 billion billion megawatts Solar Cycle: 8 - 11 years Temperature at surface: 5,500 oC (9,932 oF) Temperature at Core: 14 million oC Temperature of Sunspots: 4,000 oC (7,232 oF) Rotation Period at Poles: 35 Earth days (22.5 million oF) Rotation Period at Equator: 25 Earth days 63 Mercury and Venus are the only 2 planets in our solar system that have no moons. The hottest planet in our solar system is Venus. Enceladus − one of Saturn's smaller moons, reflects 90% of the Solar radiation. A light-year is the distance covered by light in a single year. The Milky Way galaxy is 105,700 light-years wide. The Sun weighs about 330,000 times more than Earth. Footprints left on the Moon won't disappear as there is no wind. The Sun makes a full rotation once every 25 – 35 days. Earth is the only planet not named after a God. Pluto is smaller than the United States. 64 He is like the fox, who effaces his tracks in the sand with his tail. {Describing the writing style of famous mathematician Carl Friedrich Gauss} ― Niels Henrik Abel There are more volcanoes on Venus than any other planet in our solar system. Neptune's moon [Triton] orbits the planet backwards. 65 There are more stars in space than there are grains of sand in the world. Neptune takes nearly 165 Earth years to make one orbit of the Sun. Pluto's largest moon [Charon] is half the size of Pluto. A day on Pluto is lasts for 153.6 hours long. Any free-moving liquid in outer space will shape itself into a sphere. Only 5% of the universe is visible from Earth. Light travels from the Sun to the Earth in less than 10 minutes. The Earth's rotation is slowing slightly as time goes on. There are three main types of galaxies:  elliptical  spiral  irregular There are approximately 100 thousand million stars in the Milky Way. 66 Essential Amino Acids Nonessential Amino Acids These cannot be synthesized or produced by These are produced or synthesized by our the body and are required from food bodies and are not taken up as food supplements supplements  Leucine  Arginine  Isoleucine  Alanine  Histidine  Aspartic acid  Lysine  Asparagine  Methionine  Cysteine  Threonine  Glutamine  Phenylalanine  Glutamic acid  Tryptophan  Proline  Valine  Glycine  Serine  Tyrosine Conditional Amino Acids These are usually not essential but in times of illness and stress − may become essential  Cysteine  Arginine  Tyrosine  Glutamine  Ornithine  Glycine  Serine  Proline 67 Common Amino Acids Name Abbr. Molecular Weight Molecular Formula Alanine Ala A 89.10 C3H7NO2 Arginine Arg R 174.20 C6H14N4O2 Asparagine Asn N 132.12 C4H8N2O3 Aspartic acid Asp D 133.11 C4H7NO4 Cysteine Cys C 121.16 C3H7NO2S Glutamic acid Glu E 147.13 C5H9NO4 Glutamine Gln Q 146.15 C5H10N2O3 Glycine Gly G 75.07 C2H5NO2 Histidine His H 155.16 C6H9N3O2 Hydroxyproline Hyp O 131.13 C5H9NO3 Isoleucine Ile I 131.18 C6H13NO2 Leucine Leu L 131.18 C6H13NO2 Lysine Lys K 146.19 C6H14N2O2 Methionine Met M 149.21 C5H11NO2S Phenylalanine Phe F 165.19 C9H11NO2 Proline Pro P 115.13 C5H9NO2 Pyroglutamatic Glp U 139.11 C5H7NO3 Serine Ser S 105.09 C3H7NO3 Threonine Thr T 119.12 C4H9NO3 Tryptophan Trp W 204.23 C11H12N2O2 Tyrosine Tyr Y 181.19 C9H11NO3 Valine Val V 117.15 C5H11NO2 68 82 With our naked eye, we can see 3 – 7 different galaxies from Earth. The closest galaxy to us is the Andromeda Galaxy – it's estimated at 2.5 million light-years away. The distance between the Sun and Earth is defined as an Astronomical Unit. On Venus, it snows metal and rains sulfuric acid. Space is completely silent. Astronauts can grow approximately two inches in height when in space. The first artificial satellite in space was called Sputnik Exoplanets are planets that orbit around other stars. The center of the Milky Way smells like rum and tastes like raspberries. 69 Particles and their Properties Particle name Mass (MeV/c2) Average lifetime (s) Leptons Electron 0.511 Stable Electron neutrino ≈0 Stable Muon 105.7 2.20×10−6 Muon neutrino ≈0 Stable Tau 1784 <4×10−13 Tau neutrino ≈0 Stable Proton 938.3 Stable Neutron 939.6 920 Lambda 1115.6 2.6×10−10 Sigma 1189.4 0.80×10−10 Xi 1315 2.9×10−10 Omega 1672 0.82×10−10 Pion 139.6 2.60×10−8 π-Zero 135.0 0.83×10−16 Kaon 493.7 1.24×10−8 k-Short 497.6 0.89×10−10 k-Long 497.6 5.2×10−8 J/ψ 3100 7.1×10−21 Upsilon 9460 1.2×10−20 Hadrons 70 83 Composition of Earth's Atmosphere Nitrogen 78.1% Oxygen 20.9% Argon 0.9% Carbon dioxide, Methane, Rare (inert) gases 0.1% Base Planck units Name Planck length Planck mass Dimension Expression Length (L) 𝑙𝑃 = √ 1.616255(18)×10−35 m ћ𝐺 𝑐3 Mass (M) ћ𝑐 𝑚𝑃 = √ Planck time Planck temperature Time (T) 𝑡𝑃 = √ Temperature (θ) Value (SI units) 2.176435(24)×10−8 kg 𝐺 5.391247(60)×10−44 s ћ𝐺 𝑐5 ћ𝑐 5 1.416785(16)×1032 K 𝑇𝑃 = √ 2 𝐺𝑘 𝐵 Planck charge Electric charge (Q) 71 84 −18 𝑞𝑃 = √4𝜋𝜀0 ћ𝑐 1.875545956(41)×10 C Abundances of the Elements in the Earth's Crust Element Appro×imate % by weight O×ygen 46.6 Silicon 27.7 Aluminum 8.1 Iron 5.0 Calcium 3.6 Sodium 2.8 Potassium 2.6 Magnesium 2.1 All others 1.5 Element Abundance in the Solar System Element Symbol Mass Number A Mass fraction in Atom fraction in parts per million parts per million Hydrogen-1 H 1 705700 909964 Helium-4 He 4 275200 88714 O×ygen-16 O 16 5920 477 Carbon-12 C 12 3032 326 Nitrogen-14 N 14 1105 102 Neon-20 Ne 20 1548 100 Silicon-28 Si 28 653 30 Magnesium-24 Mg 24 513 28 Iron-56 Fe 56 1169 27 Sulfur-32 S 32 396 16 72 85 Helium-3 He 3 35 15 Hydrogen-2 H 2 23 15 Neon-22 Ne 22 208 12 Magnesium-26 Mg 26 79 4 Carbon-13 C 13 37 4 Magnesium-25 Mg 25 69 4 Aluminum-27 Al 27 58 3 Argon-36 Ar 36 77 3 Calcium-40 Ca 40 60 2 Sodium-23 Na 23 33 2 Iron-54 Fe 54 72 2 Silicon-29 Si 29 34 2 Nickel-58 Ni 58 49 1 Silicon-30 Si 30 23 1 Iron-57 Fe 57 28 1 Composition of the Sun Element Abundance Abundance (percentage of total number of atoms) (percentage of total mass) Hydrogen 91.2 71.0 Helium 8.7 27.1 O×ygen 0.078 0.97 Carbon 0.043 0.40 Nitrogen 0.0088 0.096 Silicon 0.0045 0.099 Magnesium 0.0038 0.076 Neon 0.0035 0.058 73 86 Iron 0.0030 0.14 Sulfur 0.0015 0.040 Speed of Sound Gases Material v (m/s) Hydrogen (0°C) 1286 Helium (0°C) 972 Air (20°C) 343 Air (0°C) 331 Liquids at 25°C Material v (m/s) Glycerol 1904 Sea water 1533 Water 1493 Mercury 1450 Kerosene 1324 Methyl alcohol 1143 Carbon tetrachloride 926 Solids Material v (m/s) Diamond 12000 Pyre× glass 5640 Iron 5130 Aluminum 5100 Brass 4700 Copper 3560 Gold 3240 Lucite 2680 Lead 1322 Rubber 1600 74 87 Our moon is moving away from Earth at a rate of 4 cm per year. Pluto is named after the Roman god of the underworld. The first living mammal to go into space was a dog named "Laika" from Russia. Saturn is the only planet that could float in water. A sunset on Mars is blue. Astronauts can grow approximately two inches in height when in space. The Earth weighs about 81 times more than the Moon Asteroids are the byproducts of formations in the solar system, more than 4 billion years ago. 75 Molecule Bond Energy (kJ/mol) H—H 432 H—F 565 H—Cl 427 H—Br 363 H—I 295 C—H 413 C—C 347 C—N 305 C—O 358 C—F 485 C—Cl 339 C—Br 276 C—I 240. C—S 259 N—H 391 N—N 160. N—F 272 N—Cl 200. N—Br 243 N—O 201 O—H 467 O—O 146 O—F 190. O—Cl 203 76 88 O—I 234 F—F 154 F—Cl 253 F—Br 237 Cl—Cl 239 Cl—Br 218 Br—Br 193 I—I 149 I—Cl 208 I—Br 175 S—H 347 S—F 327 S—Cl 253 S—Br 218 S—S 266 Si—Si 340 Si—H 393 Si—C 360 Si—O 452 C=C 614 C≡C 839 O=O 495 C=O 799 C≡O 1072 N=O 607 77 89 N=N 418 N≡N 941 C≡N 891 C=N 615 Electron Affinities of the Main-Group Elements Electron Affinities in kJ/mole IA Period 1 IIIA IVA VA VIA VIIA Li B C N O F -60 -27 -122 0 -141 -328 Na Al Si P S Cl -53 -44 -134 -72 -200 -349 K Ga Ge As Se Br -48 -30 -120 -77 -195 -325 Rb In Sn Sb Te I -47 -30 -121 -101 -190 -295 Cs Tl Pb Bi Po At -45 -30 -110 -110 -180 -270 H -73 Period 2 Period 3 Period 4 Period 5 Period 6 Work function of elements (eV) Ag 4.26 – 4.74 Al 4.06 – 4.26 78 90 As 3.75 Au 5.10 – 5.47 B ~4.45 Ba 2.52 – 2.70 Be 4.98 Bi 4.31 C ~5 Ca 2.87 Cd 4.08 Ce 2.9 Co 5 Cr 4.5 Cs 1.95 Cu 4.53 – 5.10 Eu 2.5 Fe: 4.67 – 4.81 Ga 4.32 Gd 2.90 Hf 3.90 Hg 4.475 In 4.09 Ir 5.00 – 5.67 K 2.29 La 3.5 Li 2.9 Lu ~3.3 Mg 3.66 Mn 4.1 Mo 4.36 – 4.95 Na 2.36 Nb 3.95 – 4.87 Nd 3.2 Ni 5.04 – 5.35 Os 5.93 Pb 4.25 Pd 5.22 – 5.60 Pt 5.12 – 5.93 Rb 2.261 Re 4.72 Rh 4.98 79 91 Ru 4.71 Sb 4.55 – 4.70 Sc 3.5 Se 5.9 Si 4.60 – 4.85 Sm 2.7 Sn 4.42 Sr ~2.59 Ta 4.00 – 4.80 Tb 3.00 Te 4.95 Th 3.4 Ti 4.33 Tl ~3.84 U 3.63 – 3.90 W 4.32 – 5.22 Y 3.1 Zn 3.63 – 4.9 Zr 4.05 V Yb 4.3 2.60 Fermi Energies, Fermi Temperatures, and Fermi Velocities Element Fermi Energy Fermi Temperature Fermi Velocity eV 104 K 106 m/s Li 4.74 5.51 1.29 Na 3.24 3.77 1.07 K 2.12 2.46 0.86 Rb 1.85 2.15 0.81 Cs 1.59 1.84 0.75 Cu 7.00 8.16 1.57 Ag 5.49 6.38 1.39 Au 5.53 6.42 1.40 Be 14.3 16.6 2.25 Mg 7.08 8.23 1.58 80 92 Ca 4.69 5.44 1.28 Sr 3.93 4.57 1.18 Ba 3.64 4.23 1.13 Nb 5.32 6.18 1.37 Fe 11.1 13.0 1.98 Mn 10.9 12.7 1.96 Zn 9.47 11.0 1.83 Cd 7.47 8.68 1.62 Hg 7.13 8.29 1.58 Al 11.7 13.6 2.03 Ga 10.4 12.1 1.92 In 8.63 10.0 1.74 Tl 8.15 9.46 1.69 Sn 10.2 11.8 1.90 Pb 9.47 11.0 1.83 Bi 9.90 11.5 1.87 Sb 10.9 12.7 1.96 Radioactive Nuclide Half-Life (years) V 6.0×1015 Nd 2.4×1015 Hf 2.0×1015 Pt 1×1015 In 6.0×1014 Gd 1.08×1014 Te 1.2×1013 Pt 6.9×1011 50 144 174 192 115 152 123 190 81 93 La 1.12×1011 Sm 1.06×1011 Rb 4.88×1010 Re 4.3×1010 Lu 3.5×1010 Th 1.40×1010 U 4.47×109 K 1.25×109 U 7.04×810 Pu 8.2×107 Sm 7.0×107 Pb 3.0×107 U 2.39×107 I 1.7×107 Cm 1.60×107 Hf 9.0×106 Pd 7×106 Mn 3.7×106 Cs 3.0×106 Tc 2.6×106 Np 2.14×106 Gd 2.1×106 Be 1.6×106 Zr 1.5.0×106 Tc 1.5×106 138 147 87 187 176 232 238 40 235 244 146 205 236 129 247 182 107 53 135 97 237 150 10 93 98 82 94 1×106 153Dy  Standard Electrode Potentials in Aqueous Solution at 25°C Cathode (Reduction) Standard Potential Half-Reaction E° (volts) Li+(aq) + e- → Li(s) -3.04 K+(aq) + e- → K(s) -2.92 Ca2+(aq) + 2e- → Ca(s) -2.76 Na+(aq) + e- → Na(s) -2.71 Mg2+(aq) + 2e- → Mg(s) -2.38 Al3+(aq) + 3e- → Al(s) -1.66 2H2O(l) + 2e- → H2(g) + 2OH-(aq) -0.83 Zn2+(aq) + 2e- → Zn(s) -0.76 Cr3+(aq) + 3e- → Cr(s) -0.74 Fe2+(aq) + 2e- → Fe(s) -0.41 Cd2+(aq) + 2e- → Cd(s) -0.40 Ni2+(aq) + 2e- → Ni(s) -0.23 Sn2+(aq) + 2e- → Sn(s) -0.14 Pb2+(aq) + 2e- → Pb(s) -0.13 Fe3+(aq) + 3e- → Fe(s) -0.04 2H+(aq) + 2e- → H2(g) 0.00 Sn4+(aq) + 2e- → Sn2+(aq) 0.15 Cu2+(aq) + e- → Cu+(aq) 0.16 ClO4-(aq) + H2O(l) + 2e- → ClO3-(aq) + 2OH-(aq) 0.17 AgCl(s) + e- → Ag(s) + Cl-(aq) 0.22 Cu2+(aq) + 2e- → Cu(s) 0.34 ClO3-(aq) + H2O(l) + 2e- → ClO2-(aq) + 2OH-(aq) 0.35 IO-(aq) + H2O(l) + 2e- → I-(aq) + 2OH-(aq) 0.49 83 95 Cu+(aq) + e- → Cu(s) 0.52 I2(s) + 2e- → 2I-(aq) 0.54 ClO2-(aq) + H2O(l) + 2e- → ClO-(aq) + 2OH-(aq) 0.59 Fe3+(aq) + e- → Fe2+(aq) 0.77 Hg22+(aq) + 2e- → 2Hg(l) 0.80 Ag+(aq) + e- → Ag(s) 0.80 Hg2+(aq) + 2e- → Hg(l) 0.85 ClO-(aq) + H2O(l) + 2e- → Cl-(aq) + 2OH-(aq) 0.90 2Hg2+(aq) + 2e- → Hg22+(aq) 0.90 NO3-(aq) + 4H+(aq) + 3e- → NO(g) + 2H2O(l) 0.96 Br2(l) + 2e- → 2Br-(aq) 1.07 O2(g) + 4H+(aq) + 4e- → 2H2O(l) 1.23 Cr2O72-(aq) + 14H+(aq) + 6e- → 2Cr3+(aq) + 7H2O(l) 1.33 Cl2(g) + 2e- → 2Cl-(aq) 1.36 Ce4+(aq) + e- → Ce3+(aq) 1.44 MnO4-(aq) + 8H+(aq) + 5e- → Mn2+(aq) + 4H2O(l) 1.49 H2O2(aq) + 2H+(aq) + 2e- → 2H2O(l) 1.78 Co3+(aq) + e- → Co2+(aq) 1.82 S2O82-(aq) + 2e- → 2SO42-(aq) 2.01 O3(g) + 2H+(aq) + 2e- → O2(g) + H2O(l) 2.07 F2(g) + 2e- → 2F-(aq) 2.87  Astronomy Data 1 light-year = 9.47 × 1015 m 1 AU (astronomical unit) = 1.50 × 1011 m 84 96    Distilled Water at Room Temperature (25°C) and Standard Pressure (101.325 kPa) Volume Mass Density 1.0 mL or 1.0 cm3 1.0 g 1.0 g/cm3 1.0 L or 1.0 dm3 1.0 kg 1.0 kg/dm3 Melting and Boiling points of Selected Compounds Compound Formula Boiling Point Melting Point pentane CH3(CH2)3CH3 36ºC –130ºC hexane CH3(CH2)4CH3 69ºC –95ºC heptane CH3(CH2)5CH3 98ºC –91ºC octane CH3(CH2)6CH3 126ºC –57ºC nonane CH3(CH2)7CH3 151ºC –54ºC decane CH3(CH2)8CH3 174ºC –30ºC tetramethylbutane (CH3)3C-C(CH3)3 106ºC +100ºC Flame Colour of Elements Element Symbol Colour barium Ba yellowish-green calcium Ca yellowish red cesium Cs violet copper Cu blue to green lead Pb blue-white lithium Li red potassium K violet rubidium Rb violet sodium Na yellow 85 97 strontium   Sr scarlet red Prefixes for Molecular Compounds 1 = mono- 6 = hexa- 2 = di- 7 = hepta- 3 = tri- 8 = octa- 4 = tetra- 9 = ennea- (nona-) 5 = penta- 10 = deca- Properties of alkanes Alkane Formula Boiling point [°C] Melting point [°C] Density [kg/m3] (at 20 °C) Methane CH4 -162 −182 0.656 (gas) Ethane C2H6 −89 −183 1.26 (gas) Propane C3H8 −42 −188 2.01 (gas) Butane C4H10 0 −138 2.48 (gas) Pentane C5H12 36 −130 626 (liquid) Hexane C6H14 69 −95 659 (liquid) Heptane C7H16 98 −91 684 (liquid) Octane C8H18 126 −57 703 (liquid) 86 98 Nonane C9H20 151 −54 718 (liquid) Decane C10H22 174 −30 730 (liquid) Undecane C11H24 196 −26 740 (liquid) Dodecane C12H26 216 −10 749 (liquid) Tridecane C13H28 235 -5.4 756 (liquid) Tetradecane C14H30 253 5.9 763 (liquid) Pentadecane C15H32 270 10 769 (liquid) Hexadecane C16H34 287 18 773 (liquid) Heptadecane C17H36 303 22 777 (solid) Octadecane C18H38 317 28 781 (solid) Nonadecane C19H40 330 32 785 (solid) Icosane C20H42 343 37 789 (solid) Triacontane C30H62 450 66 810 (solid) Tetracontane C40H82 525 82 817 (solid) Pentacontane C50H102 575 91 824 (solid) Hexacontane C60H122 625 100 829 (solid) Heptacontane C70H142 653 109 869 (solid) 87 99 Quantity Time  Unit Name Symbol minute min 1min = 60s hour h 1h = 3,600s day d 1d = 86,400s year (annum) a 1a = 31,557,600s Area hectare ha 1ha = 10,000 m2 Volume litre L 1L = 1,000 cm3 Mass metric ton or tonne t 1t = 1,000 kg = 1 Mg Pressure standard atmosphere atm 1atm = 101.325 kPa Color of Transition Metal Ions in Aqueous Solution Transition Metal Ion  Definition Color Co2+ pink Cu2+ blue-green Fe2+ olive green Ni2+ bright green Fe3+ brown to yellow CrO42- orange Cr2O72- yellow Ti3+ purple Cr3+ violet Mn2+ pale pink Zn2+ colorless DNA Nitrogen Bases Nitrogen Base Abbreviation adenine A 100 88  cytosine C guanine G thymine T Acid–Base Indicators at 25°C Colour Change as Indicator pH Range methyl violet 0.0 – 1.6 yellow to blue thymol blue 1.2 – 2.8 red to yellow thymol blue 8.0 – 9.6 yellow to blue orange IV 1.4 – 2.8 red to yellow methyl orange 3.2 – 4.4 red to yellow bromocresol green 3.8 – 5.4 yellow to blue litmus 4.5 – 8.3 red to blue methyl red 4.8 – 6.0 red to yellow chlorophenol red 5.2 – 6.8 yellow to red bromothymol blue 6.0 – 7.6 yellow to blue phenol red 6.6 – 8.0 yellow to red phenolphthalein 8.2 – 10.0 colourless to pink thymolphthalein 9.4 – 10.6 colourless to blue pH Increases alizarin yellow R 10.1 – 12.0 yellow to red indigo carmine 11.4 – 13.0 blue to yellow 1,3,5–trinitrobenzene 12.0 – 14.0 colourless to orange 101 89  Activity Series for 1.0 mol/L Solution at 25 °C and 101.325 kPa Reduction Half-Reaction Au (aq) + 3 e–  Au(s) 3+ Hg2+(aq) + 2 e–  Hg(l) Ag+(aq) + e–  Ag(s) – Cu (aq) + 2 e  Cu(s) 2+ 2 H+(aq) + 2 e–  H2(g) Pb2+(aq) + 2 e–  Pb(s) Increasing strength of reactant as an oxidizing agent Sn2+(aq) + 2 e–  Sn(s) Ni2+(aq) + 2 e–  Ni(s) Cd2+(aq) + 2 e–  Cd(s) Fe2+(aq) + 2 e– 2+ Zn (aq) + 2 e – Cr2+(aq) + 2 e–  Fe(s)  Mg (aq) + 2 e Na+(aq) + 2+ e– Ca (aq) + 2 e – – Zn(s)  Cr(s) Al3+(aq) + 3 e–  2+ Increasing strength of reactant as a reducing agent Al(s)  Mg(s)  Na(s)  Ca(s) – Li (aq) + e  Li(s) +  Symbol Symbols in Chemical Equations Meaning + used to separate one reactant or product from another → used to separate the reactants from the products - it is pronounced "yields" or "produces" when the equation is read ↔ used when the reaction can proceed in both directions - this is called an equilibrium arrow and will be used later in the course (g) ↑ (s) indicates that the substance is in a gaseous state an alternative way of representing a substance in a gaseous state indicates that the substance is in a solid state 102 90 ↓ an alternative way of representing a substance in a solid state (aq) indicates that the substance is dissolved in water - the aq comes from aqueous ∆ → indicates that heat is applied to make the reaction proceed ℎ𝑣 The reaction undergoes photolysis (catalyzed with light/radiation) indicates that the substance is in a liquid state (l) → 𝐹𝑒(𝑠) Catalyzed by iron (solid). 4𝑜 𝐶 The reaction occurs at 4°C → →  Geological time scale Era Period Epoch Plant and Animal Development Cenozoic Quaternary Holocene (.01) Humans develop Pleistocene (1.8) Tertiary Pliocene (5.3) Miocene (23.8) Oligocene (33.7) "Age of mammals" Eocene (54.8) Paleocene (65.0) Extinction of dinosaurs and many other species. Mesozoic Cretaceous (144) "Age of Reptiles" First flowering plants Jurassic (206) Triassic (248) First birds Dinosaurs dominant. Paleozoic Permian (290) "Age of Extinction of trilobites and many Carboniferous: Amphibians" other marine animals Pennyslvanian (323) Carboniferous: 103 91 Mississippian (354) First reptiles Large coal swamps Large Amphibians abundant. Devonian (417) "Age of Fishes" First insect fossils Silurian (443) Fishes dominant First land plants Ordovician (490) "Age of Cambrian (540) Invertebrates" First fishes Trilobites dominant First organisms with shells Precambrian - comprises about 88% of geologic time (4500) First multicelled organisms First one-celled organisms Origin of Earth prefix number of carbons alkyl group meth- 1 methyl eth- 2 ethyl 104 92  prop- 3 propyl but- 4 butyl pent- 5 pentyl hex- 6 hexyl hept- 7 heptyl oct- 8 octyl non- 9 nonyl dec- 10 decyl The suffix associated with various functional groups Functional group suffix alkane -ane alkene -ene alkyne -yne alcohol -ol aldehyde -al ketone -one 105 93  carboxylic acid -oic acid ester -oate Heat Capacities of Selected Substances at 1 atm and 25°C Specific Heat Capacity (J/g°C) Substance air 1.012 aluminum 0.89 argon 0.5203 copper 0.385 granite 0.790 graphite 0.710 helium 5.1932 iron 0.450 lead 0.129 lithium 3.58 mercury 0.14 methanol 2.14 sodium 1.228 steel 0.466 titanium 0.523 water (ice, O°C) 2.09 water 4.184 water (steam, 100°C) 2.03 106 94  Thermodynamic Properties of Selected Compounds Compound Melting Point Boiling Point Heat of Fusion Heat of (°C) (°C) (kJ/mol) Vaporization (kJ/mol) water 0.00 100.00 6.01 40.66 hexane –95.35 68.73 13.08 28.85 ethanol –114.14 78.29 4.93 38.56 methanol –97.53 64.6 3.22 35.21 toluene –94.95 110.63 6.64 33.18  Standard Heats of Formation of Selected Compounds at 25°C Compound Standard heat of formation (kJ/mol) ammonia –45.9 benzene +49.1 butane –125.7 calcium carbonate –1207.6 calcium hydroxide –985.2 carbon dioxide –393.5 carbon monoxide –110.5 ethane –84.0 ethanoic acid (acetic acid) –484.3 ethanol –277.6 ethene (ethylene) +52.4 ethyne (acetylene) +227.4 glucose –1273.3 hydrogen sulfide –20.6 methane –74.6 107 95 methanol –239.2 nitrogen dioxide +33.2 nitrogen monoxide +91.3 octane –250.1 pentane –173.5 propane –103.8 sucrose –2226.1 sulfur dioxide –296.8 sulfur trioxide –395.7 water (liquid) –285.8 water (gas) –241.8 Note: Negative sign (–) denotes exothermic change. Positive sign (+) denotes endothermic change. 1.00 kilowatt hour = 1.00 kW.h = 3.60 × 106 J  Elements for Radioactive Dating Radioisotope Final Decay Nuclide Approximate Half-Life (annum—a) (Parent Nuclide) carbon-14 nitrogen-14 5.73 × 103 potassium-40 argon-40 1.26 × 109 rubidium-87 strontium-87 4.88 × 1010 uranium-235 lead-207 7.04 × 108 uranium-238 lead-206 4.47 × 109 108 96  Types of Reactions Formation (Synthesis) element + element → compound Decomposition compound → element + element Single Replacement compound + element → new compound + new element Double Replacement compound + compound → new compound + new compound Complete Hydrocarbon Combustion hydrocarbon + oxygen → carbon dioxide + water Addition alkene or alkyne + excess hydrogen → alkane alkene or alkyne + halogen → halogenated hydrocarbon Cracking large hydrocarbon → small hydrocarbons Polymerization monomer + monomer → polymer Esterification alcohol + carboxylic acid → ester + water 109 97  Table of Polyatomic Ions Name Formula ammonium NH4+ nitrite NO2− nitrate NO3− sulfite SO32− sulfate SO42− hydrogen sulfate HSO4− (bisulfate) thiosulfate S2O32− oxalate C2O42− hydroxide OH− phosphite PO33− phosphate PO43− hydrogen phosphate HPO42− dihydrogen H2PO4− phosphate perchlorate ClO4− chlorate ClO3− 110 98 chlorite ClO2− hypochlorite ClO− bromate BrO3− iodate IO3− acetate CH3COO− acetate C2H3O2− carbonate CO32− hydrogen carbonate HCO3− (bicarbonate)  chromate CrO42− dichromate Cr2O72− permanganate MnO4− peroxide O22− cyanide CN− cyanate OCN− thiocyanate SCN− Standard index of refraction measurements taken at the "yellow doublet" sodium D line with a wavelength of 589 nm 111 99 MATERIAL INDEX OF REFRACTION STATE Vacuum 1 (by definition) Helium 1.000036 Gas (0°C and 1 atm) Hydrogen 1.000132 Gas (0°C and 1 atm) Air 1.000277 Gas (at STP*) Air 1.000293 Gas (0°C and 1 atm) Carbon Dioxide 1.001 Gas (0°C and 1 atm) Liquid Helium 1.025 Liquid (at -270°C) Water Ice 1.31 Solid (at 0°C) Water 1.330 Liquid (at 20°C) Acetone 1.36 Liquid (at 20°C) Ethanol 1.361 Liquid (at 20°C) Kerosene 1.39 Liquid (at 20°C) Corn Oil 1.47 Liquid (at 20°C) Glycerol 1.4729 Liquid (at 20°C) Acrylic Glass 1.490–1.492 Solid (at 20°C) Benzene 1.501 Liquid (at 20°C) Crown Glass (pure) 1.50–1.54 Solid (at 20°C) Plate Glass (window glass) 1.52 Solid (at 20°C) Sodium Chloride (table salt) 1.544 Solid (at 20°C) Amber 1.55 Solid (at 20°C) Polycabonate 1.60 Solid (at 20°C) Flint Glass (pure) 1.60–1.62 Solid (at 20°C) Bromine 1.661 Liquid (at 20°C) Sapphire 1.762–1.778 Solid (at 20°C) Cubic Zirconia 2.15–2.18 Solid (at 20°C) Diamond 2.417 Solid (at 20°C) Silicon 3.42–3.48 Solid (at 20°C) Germanium 4.05–4.01 Solid (at 20°C) 100 112  STP is defined as a temperature of 273.15 K (0 °C, 32 °F) and an absolute pressure of exactly 105 Pa (100 kPa, 1 bar).  Solubility Products for Selected Ionic Substances at 25°C Solid Color Ksp Solid Acetates Ca(O2CCH3)2·3H2O white Hg2Br2 4 × 10−3 Hg2I2 yellow 5.2 × 10−29 PbI2 yellow off-white 5.35 × 10−13 yellow Ksp Iodides Bromides AgBr Color 6.40 × 10−23 Carbonates Oxalates Ag2C2O4 white 5.40 × 10−12 MgC2O4·2H2O white CaCO3 white 3.36 × 10−9 PbCO3 white 7.40 × 10−14 Chlorides PbC2O4 4.83 × 10−6 4.8 × 10−10 white Phosphates Ag3PO4 AgCl white 1.77 × 10−10 Hg2Cl2 white 1.43 × 10−18 FePO4·2H2O PbCl2 white 1.70 × 10−5 Chromates 9.8 × 10−9 Sr3(PO4)2 white 8.89 × 10−17 white 4.0 × 10−28 pink 9.91 × 10−16 Sulfates Ag2SO4 white 1.20 × 10−5 CaCrO4 yellow 7.1 × 10−4 BaSO4 white 1.08 × 10−10 PbCrO4 yellow 2.8 × 10−13 PbSO4 white Fluorides 2.53 × 10−8 Sulfides BaF2 white 1.84 × 10−7 Ag2S black PbF2 white 3.3 × 10−8 CdS yellow 8.0 × 10−27 PbS black 8.0 × 10−28 ZnS white 1.6 × 10−24 Hydroxides Ca(OH)2 white 5.02 × 10−6 Cu(OH)2 pale blue 1 × 10−14 Mn(OH)2 light pink 1.9 × 10−13 Cr(OH)3 gray-green 6.3 × 10−31 Fe(OH)3 rust red 2.79 × 10−39 101 113 6.3 × 10−50 20 Amino Acids In Human Protein: Table of DNA Base Triplets, RNA Codons and Anticodons Amino Acid DNA Base Triplets M-RNA Codons T-RNA Anticodons alanine CGA, CGG, CGT, CGC GCU, GCC, GCA, GCG CGA, CGG, CGU, CGC arginine GCA, GCG, GCT, GCC CGU, CGC, CGA, CGG GCA, GCG, GCU, GCC TCT, TCC AGA, AGG UCU, UCC asparagine TTA, TTG AAU, AAC UUA, UUG aspartate CTA, CTG GAU, GAC CUA, CUG cysteine ACA, ACG UGU, UGC ACA, ACG glutamate CTT, CTC GAA, GAG CUU, CUC glutamine GTT, GTC CAA, CAG GUU, GUC glycine CCA, CCG, CCT, CCC GGU, GGC, GGA, GGG CCA, CCG, CCU, CCC histidine GTA, GTG CAU, CAC GUA, GUG isoleucine TAA, TAG, TAT AUU, AUC, AUA UAA, UAG, UAU leucine AAT, AAC, GAA, GAG UUA, UUG, CUU, CUC AAU, AAC, GAA, GAG GAT, GAC CUA, CUG GAU, GAC lysine TTT, TTC AAA, AAG UUU, UUC methionine TAC AUG UAC phenylalanine AAA, AAG UUU, UUC AAA, AAG proline GGA, GGG, GGT, GGC CCU, CCC, CCA, CCG GGA, GGG, GGU, GGC serine AGA, AGG, AGT, AGC UCU, UCC, UCA, UCG AGA, AGG, AGU, AGC TCA, TCG AGU, AGC UCA, UCG Stop ATG, ATT, ACT UAA, UAG, UGA AUG, AUU, ACU threonine TGA, TGG, TGT, TGC ACU, ACC, ACA, ACG UGA, UGG, UGU, UGC tryptophan ACC UGG ACC tyrosine ATA, ATG UAU, UAC AUA, AUG valine CAA, CAG, CAT, CAC GUU, GUC, GUA, GUG CAA, CAG, CAU, CAC 102 114 Element Symbol Relative atomic mass Density (g / cm3) Date of Discovery Actinium Ac 227 10·1 1899 Aluminium Al 27 2·70 1825 Americium Am 243 13·7 1944 Antimony Sb 122 6·68 Ancient Argon Ar 40 0·0018 1894 Arsenic As 75 5·78 ~1250 Astatine At 210 unknown 1940 Barium Ba 137·5 3·62 1808 Berkelium Bk 247 14·8 1949 Beryllium Be 9 1·85 1798 Bismuth Bi 209 9·79 1753 Boron B 11 2·47 1808 Bromine Br 80 3·12 1826 Cadmium Cd 112·5 8·69 1817 Calcium Ca 40 1·54 1808 Californium Cf 251 unknown 1950 Carbon C 12 * Prehistoric Cerium Ce 140 6·77 1803 Caesium Cs 133 1·93 1860 Chlorine Cl 35·5 0·0032 1774 Chromium Cr 52 7·15 1797 Cobalt Co 59 8·86 1739 Copper Cu 63·5 8·96 Ancient Curium Cm 247 13·3 1944 Dysprosium Dy 162·5 8·55 1886 Einsteinium Es 252 unknown 1952 Erbium Er 167·5 9·07 1843 Europium Eu 152 5·24 1896 Fluorine F 19 0·0017 1886 Francium Fr 223 unknown 1939 Gadolinium Gd 157 7·90 1880 Gallium Ga 69·5 5·91 1875 Germanium Ge 72·5 5·32 1886 Gold Au 197 19·3 Ancient Hafnium Hf 178·5 13·3 1923 Helium He 4 0·0002 1868 Holmium Ho 165 8·80 1879 Hydrogen H 1 0·00009 1766 Indium In 115 7·31 1863 Iodine I 127 4·95 1811 Iridium Ir 192 22·5 1803 Iron Fe 56 7·87 Ancient Krypton Kr 84 0·0037 1898 Lanthanum La 139 6·15 1839 Lead Pb 207 11·3 Ancient Lithium Li 7 0·53 1817 103 115 Lutetium Lu 175 9·84 1907 Magnesium Mg 24·5 1·74 1808 Manganese Mn 55 7·47 1774 Mercury Hg 200·5 13·5 Ancient Molybdenum Mo 96 10·2 1778 Neodymium Nd 144 7·01 1885 Neon Ne 20 0·0009 1898 Neptunium Np 237 20·2 1940 Nickel Ni 58·5 8·90 1751 Niobium Nb 93 8·57 1801 Nitrogen N 14 0.0013 1772 Osmium Os 190 22·6 1803 Oxygen O 16 0·0014 1774 Palladium Pd 106·5 12·0 1803 Phosphorus P 31 1·82 1669 Platinum Pt 195 21·5 1735 Plutonium Pu 244 19·7 1941 Polonium Po 209 9·20 1898 Potassium K 39 0·89 1807 Praseodymium Pr 141 6·77 1885 Promethium Pm 145 7·26 1944 Protactinium Pa 231 15·4 1913 Radium Ra 226 5·00 1898 Radon Rn 222 0·0097 1900 Rhenium Re 186 20·8 1925 Rhodium Rh 103 12·4 1803 Rubidium Rb 85·5 1·53 1861 Ruthenium Ru 101 12·1 1844 Samarium Sm 150·5 7·52 1853 Scandium Sc 45 2·99 1879 Selenium Se 79 4·81 1817 Silicon Si 28 2·33 1824 Silver Ag 108 10·5 Ancient Sodium Na 23 0·97 1807 Strontium Sr 87·5 2·64 1790 Sulfur S 32 2·09 Ancient Tantalum Ta 181 16·4 1802 Technetium Tc 98 11 1937 Tellurium Te 127·5 6·25 1782 Terbium Tb 159 8·23 1843 Thallium Tl 204·5 11·8 1861 Thorium Th 232 11·7 1828 Thulium Tm 169 9·32 1879 Tin Sn 118·5 7·26 Ancient Titanium Ti 48 4·51 1791 Tungsten W 184 19·3 1783 Uranium U 238 19·1 1789 Vanadium V 51 6·00 1801 104 116  Xenon Xe 131·5 0·0059 1898 Ytterbium Yb 173 6·90 1878 Yttrium Y 89 4·47 1789 Zinc Zn 65·5 7·14 Ancient Zirconium Zr 91 6·52 1789 Solubilities of Selected Compounds in Water vs means very soluble (a solubility greater than 10 gl−1) s means soluble (a solubility of between 1 and 10 gl−1) i means insoluble (a solubility of less than 1 gl−1) − no data bromide carbonate chloride iodide nitrate phosphate sulfate oxide hydroxide aluminium vs − vs vs vs i vs i i ammonium vs vs vs vs vs vs vs − − barium vs i vs vs vs i i vs vs calcium vs i vs vs vs i s s s copper(II) vs i vs − vs i vs i i iron(II) vs i vs vs vs i vs i i iron(III) vs − vs − vs i vs i i lead(II) s i s i vs i i i i lithium vs vs vs vs vs i vs vs vs magnesium vs i vs vs vs i vs i i nickel vs i vs vs vs i vs i i potassium vs vs vs vs vs vs vs vs vs i i i i vs i s i − sodium vs vs vs vs vs vs vs vs vs tin(II) vs i vs s − i vs i i zinc vs i vs vs vs i vs i i silver 105 117 Bond Bond length (pm) Bond energy (kJ/mol) H−H 74 436 C−C 154 348 N−N 145 170 O−O 148 145 F−F 142 158 Cl−Cl 199 243 Br−Br 228 193 I−I 267 151 C−C 154 348 C−N 147 308 C−O 143 360 C−S 182 272 C−F 135 488 C−Cl 177 330 C−Br 194 288 C−I 214 216 H−C 109 413 H−N 101 391 H−O 96 366 H−F 92 568 H−Cl 127 432 H−Br 141 366 H−I 161 298 C−C 154 348 C=C 134 614 C≡C 120 839 O−O 148 145 O=O 121 498 N−N 145 170 N≡N 110 945 106 118 We cannot taste anything without saliva.  Blue is the color of liquid oxygen.  Every hydrogen atom in our body is likely 13.5 billion years old because they were created at the birth of the universe. Gallium has a melting point of 29.76 degrees centigrade and can melt on the palm of our hand. If we pour a handful of salt into a glass of water, the water level will go down When we freeze seawater or saltwater, we get freshwater ice. More than 78% of human brain consists of water. The rarest naturally-occurring element in the Earth's crust is astatine 107  Spectrochemical series Ligands can be arranged in a spectrochemical series according to the energy difference they produce between the two sets of d-orbitals in an octahedral complex. 2− I − < Br− < S < Cl− < F− < OH− < H2O < SCN− < NH3 < CN− ≈ CO  Values of the ionization constant of water Temperature (oC) Kw value 0 0.113 × 10−14 5 0.185 × 10−14 10 0.292 × 10−14 15 0.453 × 10−14 20 0.684 × 10−14 25 1.00 × 10−14 30 1.47 × 10−14 35 2.09 × 10−14 40 2.92 × 10−14 45 4.02 × 10−14 50 5.43 × 10−14 55 7.24 × 10−14 60 9.55 × 10−14 65 12.4 × 10−14 70 15.9 × 10−14 75 20.1 × 10−14 80 25.2 × 10−14 85 31.3 × 10−14 90 38.3 × 10−14 95 46.6 × 10−14 100 56.0 × 10−14 108 119  Specific Gravity of Liquids Liquid Temperature kg/m3 1,1,2-Trichlorotrifluoroethane 25 °C 1564.00 1,2,4-Trichlorobenzene 20 °C 1454.00 1,4-Dioxane 20 °C 1033.60 2-Methoxyethanol 20 °C 964.60 Acetic Acid 25 °C 1049.10 Acetone 25 °C 784.58 Acetonitrile 20 °C 782.20 Alcohol, ethyl 25 °C 785.06 Alcohol, methyl 25 °C 786.51 Alcohol, propyl 25 °C 799.96 Ammonia (aqua) 25 °C 823.35 Analine 25 °C 1018.93 Automobile oils 15 °C 880 - 940 Beer (varies) 10 °C 1010 Benzene 25 °C 873.81 Benzil 25 °C 1079.64 Brine 15 °C 1230 Bromine 25 °C 3120.40 Butyric Acid 20 °C 959 Butane 25 °C 599.09 n-Butyl Acetate 20 °C 879.60 n-Butyl Alcohol 20 °C 809.70 n-Butyl Chloride 20 °C 886.20 Caproic acid 25 °C 921.06 Carbolic acid 15 °C 956.30 Carbon disulfide 25 °C 1260.97 Carbon tetrachloride 25 °C 1584.39 Carene 25 °C 856.99 Castor oil 25 °C 956.14 Chloride 25 °C 1559.88 Chlorobenzene 20 °C 1105.80 Chloroform 20 °C 1489.20 Chloroform 25 °C 1464.73 Citric acid 25 °C 1659.51 Coconut oil 15 °C 924.27 Cotton seed oil 15 °C 925.87 Cresol 25 °C 1023.58 Creosote 15 °C 1066.83 109 120 Crude oil, 48° API 60 °F 790 Crude oil, 40° API 60 °F 825 Crude oil, 35.6° API 60 °F 847 Crude oil, 32.6° API 60 °F 862 Crude oil, California 60 °F 915 Crude oil, Mexican 60 °F 973 Crude oil, Texas 60 °F 873 Cumene 25 °C 860.19 Cyclohexane 20 °C 778.50 Cyclopentane 20 °C 745.40 Decane 25 °C 726.28 Diesel fuel oil 20 to 60 15 °C 820 - 950 Diethyl ether 20 °C 714 o-Dichlorobenzene 20 °C 1305.80 Dichloromethane 20 °C 1326.00 Diethylene glycol 15 °C 1120 Dichloromethane 20 °C 1326.00 Dimethyl Acetamide 20 °C 941.50 N,N-Dimethylformamide 20 °C 948.70 Dimethyl Sulfoxide 20 °C 1100.40 Dodecane 25 °C 754.63 Ethane -89 °C 570.26 Ether 25 °C 72.72 Ethylamine 16 °C 680.78 Ethyl Acetate 20 °C 900.60 Ethyl Alcohol 20 °C 789.20 Ethyl Ether 20 °C 713.30 Ethylene Dichloride 20 °C 1253.00 Ethylene glycol 25 °C 1096.78 Fluorine refrigerant R-12 25 °C 1310.95 Formaldehyde 45 °C 812.14 Formic acid 10% concentration 20 °C 1025 Formic acid 80% concentration 20 °C 1221 Freon - 11 21 °C 1490 Freon - 21 21 °C 1370 Fuel oil 60 °F 890.13 Furan 25 °C 1416.03 Furforol 25 °C 1154.93 Gasoline, natural 60 °F 711.22 Gasoline, Vehicle 60 °F 737.22 110 121 Gas oils 60 °F 890 Glucose 60 °F 1350 - 1440 Glycerin 25 °C 1259.37 Glyme 20 °C 869.10 Glycerol 25 °C 1126.10 Heptane 25 °C 679.50 Hexane 25 °C 654.83 Hexanol 25 °C 810.53 Hexene 25 °C 671.17 Hydrazine 25 °C 794.52 Iodine 25 °C 4927.28 Ionene 25 °C 932.27 Isobutyl Alcohol 20 °C 801.60 Iso-Octane 20 °C 691.90 Isopropyl Alcohol 20 °C 785.40 Isopropyl Myristate 20 °C 853.20 Kerosene 60 °F 817.15 Linolenic Acid 25 °C 898.64 Linseed oil 25 °C 929.07 Methane -164 °C 464.54 Methanol 20 °C 791.30 Methyl Isoamyl Ketone 20 °C 888.00 Methyl Isobutyl Ketone 20 °C 800.80 Methyl n-Propyl Ketone 20 °C 808.20 Methyl t-Butyl Ether 20 °C 740.50 N-Methylpyrrolidone 20 °C 1030.40 Methyl Ethyl Ketone (MEK) 20 °C 804.90 MEK 25 °C 802.52 Milk 15 °C 1020 - 1050 Naphtha 15 °C 664.77 Naphtha, wood 25 °C 959.51 Napthalene 25 °C 820.15 Ocimene 25 °C 797.72 Octane 15 °C 917.86 Olive oil 20 °C 800 - 920 Oxygen (liquid) -183 °C 1140 Palmitic Acid 25 °C 850.58 Pentane 20 °C 626.20 Pentane 25 °C 624.82 Petroleum Ether 20 °C 640.00 111 122 Petrol, natural 60 °F 711.22 Petrol, Vehicle 60 °F 737.22 Phenol 25 °C 1072.28 Phosgene 0 °C 1377.59 Phytadiene 25 °C 823.35 Pinene 25 °C 856.99 Propane -40 °C 583.07 Propane, R-290 25 °C 493.53 Propanol 25 °C 804.13 Propylene Carbonate 20 °C 1200.60 Propylene 25 °C 514.35 n-Propyl Alcohol 20 °C 803.70 Propylene glycol 25 °C 965.27 Pyridine 25 °C 978.73 Pyrrole 25 °C 965.91 Rape seed oil 20 °C 920 Resorcinol 25 °C 1268.66 Rosin oil 15 °C 980 Sabiname 25 °C 812.14 Sea water 25 °C 1025.18 Silane 25 °C 717.63 Sodium Hydroxide (caustic soda) 15 °C 1250 Sorbaldehyde 25 °C 895.43 Soya bean oil 15 °C 924 - 928 Stearic Acid 25 °C 890.63 Sulphuric Acid 95% conc. 20 °C 1839 Sugar solution 68 brix 15 °C 1338 Sunflower oil 20 °C 920 Styrene 25 °C 903.44 Terpinene 25 °C 847.38 Tetrahydrofuran 20 °C 888.00 Toluene 20 °C 866.90 Toluene 25 °C 862.27 Triethylamine 20 °C 727.60 Trifluoroacetic Acid 20 °C 1489.00 Turpentine 25 °C 868.20 Water, pure 4 °C 1000.00 Water, sea 77 °F 1021.98 Whale oil 15 °C 925 o-Xylene 20 °C 880.20 112 123 Bromine and mercury are the only elements that can stay liquid at room temperature.  DNA is a flame retardant  There is about 250 g of table salt (NaCl) in an average adult human body. Air becomes liquid at −190°C Frogs don't drink water because they can absorb it through their skin Helium and Hydrogen account for 98% of all matter. The chemical elements are organized in order of their increasing atomic numbers. Mars is red because of iron oxide 113 Molecular formula Compound name Ac2O3 Actinium(III) oxide AgBF4 Silver tetrafluoroborate AgBr silver bromide AgBrO silver hypobromite AgBrO2 silver bromite AgBrO3 silver bromate AgBrO4 silver perbromate AgCl silver chloride AgCl3Cu2 dicopper silver trichloride AgClO3 silver chlorate AgClO4 silver perchlorate AgCN silver cyanide AgCNO silver fulminate AgF silver fluoride AgF2 silver(II) fluoride AgI silver iodide AgIO silver hypoiodite AgIO2 silver iodite AgIO3 silver iodate AgIO4 silver periodate AgMnO4 silver permanganate AgN3 silver azide AgNO3 silver nitrate AgO silver monoxide AgONC silver cyanate AgPF6 silver hexafluorophosphate AgSNC silver thiocyanate Ag2C2 silver acetylide Ag2CO3 silver(I) carbonate Ag2C2O4 silver oxalate Ag2Cl2 silver(II) dichloride Ag2CrO4 silver chromate Ag2Cr2O7 silver dichromate Ag2F silver subfluoride Ag2MoO4 silver molybdate Ag2O silver(I) oxide Ag2S silver sulfide Ag2SO4 silver sulfate Ag2Se silver selenide 114 124 Ag2SeO3 silver selenite Ag2SeO4 silver selenate Ag2Te silver(I) telluride Ag3Br2 silver dibromide Ag3Br3 silver tribromide Ag3Cl3 silver(III) trichloride Ag3I3 silver(III) triiodide Ag3PO4 silver phosphate AlBO aluminium boron oxide AlBO3 aluminium borate AlBr aluminium monobromide AlBr3 aluminium tribromide AlCl aluminium monochloride AlClF aluminium chloride fluoride AlCl2<F aluminium chloride fluoride AlClO aluminium chloride oxide AlCl2H Dichloroalumane AlCl3 aluminium chloride AlCl2F aluminium chloride fluoride AlCl3 aluminium trichloride AlCl4Cs aluminium caesium tetrachloride AlCl4K potassium tetrachloroaluminate AlCl4Na sodium tetrachloroaluminate AlCl4Rb aluminium rubidium tetrachloride AlCl6K3 potassium hexachloroaluminate AlCl6Na3 sodium hexachloroaluminate AlF aluminium monofluoride AlFO aluminium monofluoride monoxide AlF2 aluminium difluoride AlF2O aluminium difluoride oxide AlF3 aluminium trifluoride AlF4K potassium tetrafluoroaluminate AlF4Li lithium tetrafluoroaluminate AlF6K3 potassium hexafluoraluminate AlF6Li3 lithium hexafluoroaluminate AlF6Na3 cryolite AlGaInP aluminium-gallium-indium phosphide Al(OH)3 aluminium hydroxide AlI aluminium monoiodide AlI3 aluminium triiodide 115 125 AlLiO2 lithium aluminate AlN aluminium nitride Al(NO2)3 aluminium nitrite Al(NO3)3 aluminium nitrate AlNaO2 sodium aluminate AlO aluminium monoxide AlOSi aluminium silicon monoxide AlO2 Aluminium(IV) oxide AlP aluminium monophosphide AlPO4 aluminium phosphate AlTe aluminium monotelluride AlTe2 monoaluminium ditelluride Al2BeO4 beryllium aluminium oxide Al2Br6 dialuminium hexabromide Al2(CO3)3 aluminium carbonate Al2Cl9K3 potassium aluminium chloride Al2CoO4 cobalt blue Al2F6 aluminium fluoride Al2I6 aluminium iodide Al2MgO4 magnesium aluminium oxide Al2O dialuminium monoxide Al2O2 dialuminium dioxide Al2O3 aluminium oxide Al2O5Si aluminium silicate Al2O5Si aluminium silicate Al2O5Si andalusite Al2O7Si2 aluminium silicate Al2S dialuminium monosulfide Al2S3 aluminium sulfide Al2(SO4)3 aluminium sulphate Al2Se dialuminium selenide Al2Si2O5(OH)4 kaolin Al2Te dialuminium telluride Al3F14Na5 chiolite Al4C3 aluminium carbide Al6BeO10 beryllium aluminium oxide Al6O13Si2 mullite ArClF argon chloride fluoride ArClH argon chloride hydride ArFH argon fluoride hydride 116 126 AsBrO arsenic oxybromide AsBr3 arsenic tribromide AsClO arsenic monoxide monochloride AsCl3 arsenic trichloride AsCl3O arsenic oxychloride AsCl4F arsenic tetrachloride fluoride AsF3 arsenic trifluoride AsF5 arsenic pentafluoride AsH3 arsine AsI3 arsenic triiodide AsO arsenic monoxide AsO2 arsenic dioxide AsP arsenic monophosphide AsP3 arsenic triphosphide AsTl thallium arsenide As2I4 arsenic diiodide As2O3 arsenic trioxide As2P2 arsenic diphosphide As2O5 arsenic pentoxide As2S4 arsenic tetrasulfide As2S5 arsenic pentasulfide As2Se arsenic hemiselenide As2Se3 arsenic triselenide As2Se5 arsenic pentaselenide As3O4 arsenic tetraoxide As3P arsenic(III) phosphide As4O3 tetraarsenic trioxide As4O5 tetraarsenic pentaoxide As4S3 tetraarsenic trisulfide As4S4 tetraarsenic tetrasulfide AuBO gold monoboride monoxide AuBr gold bromide AuBr3 gold tribromide AuCN gold cyanide AuCl gold chloride AuCl3 gold trichloride AuF3 gold trifluoride AuI gold iodide AuI3 gold(III) iodide Au(OH)3 gold hydroxide 117 127 AuTe gold telluride Au2O3 gold trioxide Au2S gold sulfide Au2S3 gold trisulfide Au2(SeO4)3 gold triselenate Au2Se3 gold triselenide BAs boron arsenide BAsO4 boron(III) arsenate BBr3 boron tribromide BCl3 boron trichloride BF3 boron trifluoride BI3 boron iodide BN boron nitride c(NO2)3 boron nitrite B(NO3)3 boron nitrate B(OH)3 boric acid BP boron(III) phosphide BPO4 boron(III) orthophosphate B2Cl4 boron chloride B 2F 4 Diboron tetrafluoride B 2H 6 boron hydride B 2O 3 boron(III) oxide B 2S 3 boron sulfide B2Se3 boron selenide B3N3H6 borazine B 4C boron carbide Ba(AlO2)2 barium aluminate Ba(AsO3)2 barium arsenite Ba(AsO4)2 barium arsenate BaB6 barium hexaboride Ba(BrO3)2·H2O barium bromate monohydrate Ba(BrO3)2·2H2O barium bromate dihydrate BaBr2 barium bromide Ba(BrO)2 barium hypobromite Ba(BrO2)2 barium bromite Ba(BrO3)2 barium bromate Ba(BrO4)2 barium perbromate Ba(CHO2)2 barium formate Ba(C2H3O2)2 barium acetate Ba(CN)2 barium cyanide 118 128 BaHfO3 barium hafnate BaHgI4 barium tetraiodomercurate(II) Ba(HS)2 barium hydrosulfide BaI2 barium iodide Ba(IO)2 barium hypoiodite Ba(IO2)2 barium iodite Ba(IO3)2 barium iodate Ba(IO4)2 barium periodate BaK2(CrO4)2 barium potassium chromate BaMnO4 barium manganate Ba(MnO4)2 barium permanganate BaMoO4 barium molybdate BaN6 barium azide Ba(NO2)2 barium nitrite Ba(NO3)2 barium nitrate Ba(NbO3)2 barium niobate BaNb2O6 barium metaniobate BaO barium oxide Ba(OH)2 barium hydroxide baryta BaO2 barium peroxide Ba(PO3)2 barium metaphosphate BaS barium sulfide Ba(SCN)2 barium thiocyanate BaS2O3 barium thiosulfate BaSiF6 barium hexafluorosilicate BaSO3 barium sulfite BaSO4 barium sulfate barite BaSe barium selenide Ba(SeCN)2 barium selenocyanate BaSeO3 barium selenite BaSeO4 barium selenate BaSiO3 barium metasilicate BaSi2 barium silicide BaSi2O5 barium disilicate BaSnO3 barium stannate BaTeO3 barium tellurite BaTeO4·3H2O barium tellurate trihydrate BaTiO3 barium titanate barium metatitanate 119 129 BaU2O7 barium uranium oxide BaWO4 barium tungstate BaZrO3 barium zirconate Ba2Na(NbO3)5 barium sodium niobate Ba2P2O7 barium pyrophosphate Ba2V2O7 barium pyrovanadate Ba2XeO6 barium perxenate Ba3(CrO4)2 barium chromate(V) Ba3N2 barium nitride Ba3(PO4)2 barium orthophosphate Ba3(VO4)2 barium orthovandate BeB2 beryllium boride Be(BH4)2 beryllium borohydride BeBr2 beryllium bromide Be(CHO2)2 beryllium formate BeCO3 beryllium carbonate Be(C2H3O2)2 beryllium acetate Be(C5H7O2)2 beryllium acetylacetonate BeCl2 beryllium chloride Be(ClO)2 beryllium hypochlorite Be(ClO3)2 beryllium chlorate Be(ClO4)2 beryllium perchlorate BeF2 beryllium fluoride BeI2 beryllium iodide Be(NO2)2 beryllium nitrite Be(NO3)2 beryllium nitrate BeO beryllium oxide bromellite Be(OH)2 beryllium hydroxide BeS beryllium sulfide BeSO3 beryllium sulfite BeSO4 beryllium sulfate Be2C beryllium carbide Be3Al2(SiO3)6 beryl Be3N2 beryllium nitride BiBO3 bismuth(III) orthoborate BiBr3 bismuth(III) bromide Bi(C2H3O2)3 bismuth(III) acetate BiC6H5O7 bismuth(III) citrate BiCl3 bismuth(III) chloride BiF3 bismuth(III) fluoride 120 130 BiI3 bismuth(III) iodide Bi(NO3)3·5H2O bismuth(III) nitrate pentahydrate BiOCl bismuth(III) oxychloride BiOI bismuth(III) oxyiodide (BiO)2CO3 bismuth oxycarbonate BiPO4 bismuth(III) orthophosphate Bi(VO3)5 bismuth(III) metavanadate Bi2Se3 bismuth(III) selenide bismuth selenide Bi2(MoO4)3 bismuth(III) molybdate Bi2O3 bismuth(III) oxide Bi2S3 bismuth(III) sulfide bismuthinite Bi2Se3 bismuth(III) selenide BrCl bromine chloride BrCl3 bromine trichloride BrCl5 bromine pentachloride BrF bromine monofluoride bromine fluoride BrF3 bromine trifluoride BrF5 bromine pentafluoride BrO3− bromate ion Br2 bromine Br2O5 dibromine pentoxide CCl2F2 dichlorodifluoromethane freon-12 CCl4 carbon tetrachloride tetrachloromethane C(CN)4 tetracyanomethane CFCl3 freon-11 CFCl2CF2Cl freon-13 CHCl3 chloroform trichloromethane methyl trichloride CHClF2 chlorodifluoromethane CH(CN)3 cyanoform CHO2− formate ion CH2CHCHCH2 1,3-butadiene CH2CO ketene CH2CHOH ethenol CH2ClCOOH chloroacetic acid 121 131 CH2Cl2 dichloromethane CH2ClF chlorofluoromethane CH2(CN)2 malononitrile CH2O formaldehyde CH2(OH)2 methanediol CH2OHCH2OH ethylene glycol CH3CCH propyne CH3CdCH3 dimethylcadmium CH3CHCHCH3 2-butene CH3CHCH2 propene CH3CHO acetaldehyde CH3CH2Br bromoethane CH3CH2CH2CH2OH butan-1-ol CH3CH2CH2OH 1-propanol propan-1-ol CH3CH2CONH2 propanamide CH3CH2COOH propionic acid CH3CH2OCH2CH3 diethyl ether ethoxyethane CH3CH2OH ethanol CH3(CH2)16COOH stearic acid CH3CN acetonitrile CH3COCH3 acetone CH3COOCH3 methyl acetate CH3COCl acetyl chloride CH3CONH2 acetamide ethanamide CH3COO− acetate ion CH3COOCHCH2 vinyl acetate CH3COOCH2C6H5 benzyl acetate CH3COO(CH2)2CH(CH3)2 isoamyl acetate CH3COOH acetic acid ethanoic acid CH3COONa sodium acetate CH3COOK potassium acetate CH3COORb rubidium acetate CH3COOCs caesium acetate (CH3CO)2O acetic anhydride CH3Cl chloromethane methyl chloride CH3HgCH3 dimethylmercury 122 132 CH3I iodomethane methyl iodide CH3OCH3 dimethyl ether CH3NH2 methylamine CH3NO oxaziridine CH3OCs caesium methoxide CH3OH methanol CH3OK potassium methoxide CH3OLi lithium methoxide CH3ONa sodium methoxide CH3ORb rubidium methoxide CH3SCH3 dimethyl sulfide DMS CH3SH methanethiol (CH3)2CHOH isopropyl alcohol 2-propanol propan-2-ol isopropanol (CH3)2CO acetone (CH3)2C2O4 dimethyl oxalate (CH3)2NNH2 dimethyl hydrazine (CH3)2NH dimethylamine (CH3)2S+CH2CH2COO− dimethylsulfoniopropionate DMSP (CH3)3CCl t-butyl chloride (CH)3COH t-butyl alcohol (CH3)3COOC(CH3)3 di-t-butyl peroxide DTBP (CH3)3N trimethylamine CH4 methane natural gas CH4N2O2 hydroxycarbamide CH5N3 Guanidine CN− cyanide ion (CN)2 cyanogen C(NH2)3NO3 guanidine nitrate CNO− cyanate ion CO carbon monoxide COCl2 phosgene CO2 carbon dioxide CO3 carbon trioxide 123 133 CO32− carbonate ion CS2 carbon disulfide C 2F 4 tetrafluoroethylene C 2H 2 acetylene C2H2O2 glyoxal C2H3Cl vinyl chloride C2H3NO glycolonitrile C2H3O2− acetate ion C 2H 4 ethylene C2H4Cl2 ethylene dichloride C2H4N4 3-amino-1,2,4-triazole C2H4O ethylene oxide C2H4O2 acetic acid C2H5Br bromoethane C2H5NH2 ethylamine C2H5NO2 glycine Gly C2H5O− ethoxide ion C2H5OH ethanol ethyl alcohol (C2H5)2NH diethylamine C2H5OCs caesium ethoxide C2H5OK potassium ethoxide C2H5ONa sodium ethoxide C2H5ORb rubidium ethoxide C 2H 6 ethane C2H6OS dimethyl sulfoxide DMSO C2H7NO ethanolamine C2H7NO2 ammonium acetate C2H7NO3S taurine C2O42− oxalate ion C3H3O4− malonate ion C3HN cyanopolyyne C3H3N azete C3H4N2 imidazole C3H4N2S aminothiazole C3H4O3 pyruvic acid C3H4O4 malonic acid C3H5NO acrylamide C3H5N3 3-amino-1H-pyrazole 124 134 C3H5N3O9 nitroglycerine C 3H 6 cyclopropane propylene C3H6O2 ethyl formate C3H6O2S 2-Mercaptopropionic acid C3H6O2S 3-Mercaptopropionic acid C3H7N azetidine C3H7NO2 α-alanine β-alanine C3H7NO2S cysteine Cys C3H7NO3 serine Ser C 3H 8 propane C3H8NO5P glyphosate C3H8O propanol 1-propanol 2-propanol C3H8O2 propylene glycol C3H8O2 1,3-propanediol C3H8O3 glycerol C3H9N3 1,3,5-triazinane C3N3(OH)3 cyanuric acid C3N12 cyanuric triazide C4HCl2FN2 2,6-dichloro-5-fluoroacil C 4H 2 diacetylene C 4I 2 diiodobutadiyne C4H2BrClN2 5-bromo-2-chloropyrimidine C4H2Cl2N2 2,4-dichloropyrimidine 4,6-dichloropyrimidine C4H3Cl2N3 2-amino-4,6-dichloropyrimidine C4H3FN2O2 fluorouracil C 4H 4 vinylacetylene C4H4FN3O flucytosine C4H4N2O2 uracil C4H4N4 diaminomaleonitrile C4H4N4 3-aminopyrazole-4-carbonitrile C4H4N4 1,3,5,7-tetrazocine C4H4O furan C4H5N3O cytosine C4H6N2 fomepizole 125 135 C4H6N2 1-methylimidazole C4H6N2 4-methylimidazole C4H6N2S methimazole 2-amino-4-methylthiazole C4H6N4O 2,4-diamino-6-hydroxypyrimidine C4H6O2 1,4-Butynediol C4H6O2 gamma-Butyrolactone C4H6O2 crotonic acid C4H6O2 diacetyl C4H6O2 diepoxybutane C4H6O2 1,4-Dioxene C4H6O2 isocrotonic acid C4H6O2 methacrylic acid C4H6O2 methyl acrylate C4H6O2 succinaldehyde C4H6O2 vinyl acetate C4H6O4 succinic acid C4H7BrO2 2-bromobutyric acid 4-bromobutyric acid α-bromoisobutyric acid ethyl bromoacetate C4H7KO3 potassium oxybate C4H7NaO3 sodium oxybate C4H7NO2 1-Aminocyclopropanecarboxylic acid C4H7NO3 aceturic acid C4H7NO4 aspartic acid Asp C 4H 8 cyclobutane C4H8N2O3 asparagine Asn C4H8O tetrahydrofuran THF C4H8O2 ethyl acetate C4H8O3 gamma-Hydroxybutyric acid C4H9Li n-butyllithium C4H9NO2 γ-aminobutyric acid C4H9NO3 threonine Thr C4H9OH butyl alcohol C4H10 butane 2-methylpropane 126 136 C4H10O diethyl ether C4H10O2 1,2-Butanediol C4H10O2 1,3-Butanediol C4H10O2 1,4-Butanediol C4H10O2 2,3-Butanediol C4H10O2 tert-Butyl hydroperoxide C4H10O2 Dimethoxyethane C4H10O2 2-Ethoxyethanol C4H10O2 1-Methoxy-2-propanol C4H10O3 diethylene glycol C4H11NO2 diethanolamine C5H3BrN2O2 2-bromo-5-nitropyridine C5H3Br2N 3,5-dibromopyridine C5H3ClN2O2 2-chloro-5-nitropyridine C5H3ClN4 6-chloropurine C5H4NCOOH niacin C5H4N2O2 pyrazinoic acid C5H4N2O4 orotic acid C5H4N4O allopurinol hypoxanthine C5H4N4O2 xanthine C5H4N4S mercaptopurine C5H4O cyclopentadienone C5H4O2 furfural C5H4O2S b-thiophenic acid C5H5− cyclopentadienyl anion C5H5BrN2 2-amino-5-bromopyridine C5H5ClN2 2-amino-4-chloropyridine 2-amino-5-chloropyridine 4-amino-2-chloropyridine C5H5IN2 2-amino-5-iodopyridine C5H5N pyridine C5H5NO 2-pyridone 3-pyridinol C5H5N3O pyrazinamide C5H5N3O2 2-amino-nitropyridine C5H5N5 adenine C5H5N5O guanine C5H6BNO2 3-pyridinylboronic acid C5H6N2 1,2-diazepine 127 137 1,3-diazepine 1,4-diazepine 1-vinylimidazole 2-aminopyridine 3-aminopyridine 4-aminopyridine glutaronitrile C5H6N2OS methylthiouracil C5H6N2O2 thymine C5H6O cyclopentenone C5H6O5 α-Ketoglutaric acid C5H7N3 3,4-diaminopyridine C5H8O2 gamma-Valerolactone C5H9NO2 allylglycine C5H9NO2 proline Pro C5H9NO4 glutamic acid Glu C5H10 cyclopentane C5H10N2O3 glutamine Gln C5H10O2 pivalic acid C5H10O2 valeric acid C5H10O2 3-Methylbutanoic acid C5H10O4 deoxyribose C5H11NO2 valine Val C5H11NO2S methionine Met C5H12 pentane C5H12O2 neopentyl glycol C5H12O4 pentaerythritol C5H12O5 xylitol C6F5COOH pentafluorobenzoic acid C6H3Br3O 2,4,6-Tribromophenol C6H3Cl3O 2,4,6-Trichlorophenol C6H4BrNO2 5-bromonicotinic acid C6H4ClNO2 2-chloronicotinic acid C6H4ClN3 6-chloro-7-dezapurine C6H4ClNO2 6-chloro-2-pyridinecarboxylic acid 6-chloronicotinic acid 128 138 C6H4N4 tricyanoaminopropene C6H4O2 orthobenzoquinone parabenzoquinone quinone C6H5Br bromobenzene C6H5CHO benzaldehyde C6H5CH2OH benzyl alcohol C6H5Cl chlorobenzene C6H5COCl benzoyl chloride C6H5COO− benzoate ion C6H5COOH benzoic acid C6H5F fluorobenzene C6H5I iodobenzene C6H5NO2 picolinic acid C6H5NO3 4-nitrophenol 6-hydroxyniacin C6H5OH phenol C6H5O73− citrate ion (C6H5)4Ge tetraphenylgermane (C6H5)2O diphenyl ether (C6H5)3N triphenylamine (C6H5)3P triphenylphosphine C 6H 6 benzene C6H6BClO2 4-chlorophenylboronic acid C6H6BFO2 4-fluorophenylboronic acid C6H6IN 4-iodoaniline C6H6N2O nicotinamide C6H6N2O2 6-aminonicotinic acid C6H6O phenol C6H6O2 catechol hydroquinone resorcinol C6H6O3 hydroxymethylfurfural C6H7BO2 phenylboronic acid C6H7CsO6 caesium ascorbate C6H7KO6 potassium ascorbate C6H7LiO6 lithium ascorbate C6H7N3O isoniazid C6H7NaO6 sodium ascorbate C6H7RbO6 rubidium ascorbate C6H8N2 2-amino-3-methylpyridine 129 139 2-amino-4-methylpyridine 2-amino-5-methylpyridine 2-amino-6-methylpyridine C6H8N2O2S ethyl 2-aminothiazole-4-carboxylate sulfanilamide C6H8O7 citric acid C6H9N3O2 histidine His ethyl 5-amino-1H-pyrazole-4-carboxylate C6H9N3O3 metronidazole C6H10O3 4-acetylbutyric acid butyl glyoxylate ethyl acetoacetate 2-hydroxypropyl acrylate pantolactone propyl pyruvate C6H10O4 aceburic acid C6H10O4 adipic acid C6H10O4 conduritol C6H10O4 dianhydrohexitol C6H10O4 ethylidene diacetate C6H10O4 glucal C6H11NO2 cycloleucine pipecolic acid C6H12 cyclohexane C6H12O3 4-Hydroxy-4-methylpentanoic acid C6H12O6 fructose glucose C6H13NO N-ethylmorpholine C6H13NO2 aminocaproic acid isoleucine Ile leucine Leu C6H14 hexane C6H14N2O2 lysine Lys C6H14N4O2 arginine Arg C6H14O2 1,6-hexanediol C6H14O3 dipropylene glycol 130 140 C6H14O3 trimethylolpropane C6H14O4 triethylene glycol C6H15NO3 triethanolamine C 6N 4 tetracyanoethylene C7H5Br3O 2,4,6-tribromoanisole C7H5Cl3O 2,4,6-trichloroanisole C7H5F3O 2,4,6-trifluoroanisole C7H5FO2 2-fluorobenzoic acid C7H5FO2 3-Fluorobenzoic acid C7H5FO2 4-fluorobenzoic acid C7H5NO4 quinolinic acid dipicolinic acid C7H5NS2 2-mercaptobenzothiazole C7H5N3O2 7-nitroindazole C7H6N2 7-azaindole C7H6N2 Benzimidazole C7H6O tropone C7H6O2 benzoic acid 4-hydroxybenzaldehyde C7H6O3 salicylic acid 4-hydroxybenzoic acid C7H6O4 protocatechuic acid 2,3-dihydroxybenzoic acid C7H6O5 gallic acid C7H7BO4 4-carboxyphenylboronic acid C7H7NO2 4-aminobenzoic acid C7H7NO3 mesalazine C7H7N3 benomyl metabolite C 7H 8 toluene C7H8ClN3O4S2 hydrochlorothiazide C7H8N4O2 theophylline C7H8N4O2 theobromine C7H9BO2 4-methylphenylboronic acid C7H9BO3 4-boronoanisole C7H10N2 4-dimethylaminopyridine C7H11NO5 N-Acetylglutamic acid C7H12O4 diethyl malonate C7H12N2O4 aceglutamide C7H14O6 bornesitol C7H16 heptane 131 141 C8H5F3N2OS riluzole C8H5NO2 isatin C8H6BrN 5-bromoindole 6-bromoindole C8H6ClN 4-chloroindole C8H6Cl2O3 2,4-dichlorophenoxyacetic acid C8H6N2O 4-quinazolinol C8H6N2O2 indazolium-3-carboxylate C8H7N indole C8H7NO indol-4-ol oxindole 5-hydroxyindole C 8H 8 cubane C8H8N2OS 2-amino-6-methoxybenzothiazole C8H8O3 4-hydroxyphenylacetic acid isovanillin C8H8O4 vanillic acid C8H9NO2 acetaminophen C8H9NO2 aminomethylbenzoic acid C8H9NO2 hydroxydanaidal C8H9NO2 methyl anthranilate C8H10N4O2 caffeine C8H11NO tyramine C8H11N5O3 aciclovir C8H16O2 cyclohexanedimethanol C8H16O6 pinpollitol C8H16O6 viscumitol C8H16O6 Eleutheroside C ethyl galactoside C8H18 octane C9H6BrN 4-bromoisoquinoline C9H6N2 5-cyanoindole C9H6O3 umbelliferone C9H6OS thiochromone C9H7NO 8-hydroxyquinoline indole-3-carboxaldehyde C9H7NO2 indole-2-carboxylic acid indole-3-carboxylic acid C9H8N2 5-aminoisoquinoline 5-aminoquinoline 6-aminoquinoline 132 142 8-aminoquinoline C9H8O2 cinnamic acid C9H8O3 o-coumaric acid m-coumaric acid p-coumaric acid C9H8O4 aspirin acetylsalicylic acid caffeic acid C9H9N methylketol skatole C9H9NO 4-methoxyindole 5-methoxyindole 6-methoxyindole indole-3-carbinol C9H9NO3 hippuric acid C9H10O chavicol C9H10O3 paeonol C9H11NO2 phenylanine LPA phenylanine DLPA C9H10O cinnamyl alcohol C9H11NO3 tyrosine Tyr C9H11NO4 L-DOPA C9H17NO2 gabapentin C9H18N2O2 1-boc-piperazine C9H20 nonane C10H7NO2 quinaldic acid C10H7N3S tiabendazole C10H8 azulene C10H8 naphthalene C10H8O3 hymecromone C10H9NO2 indole-3-acetic acid C10H9N5O kinetin C10H9NO2 5-methoxyindole-3-carboxaldehyde C10H10N2O edaravone C10H10O2 safrole C10H10O4 ferulic acid C10H11N3O3S sulfamethoxazole C10H12N2 tryptamine 133 143 C10H12O anethole C10H12O estragole C10H12O2 hinokitiol C10H12O2 eugenol C10H12O2 isoeugenol C10H12O2 pseudoisoeugenol C10H12O3 coniferyl alcohol C10H13N5O4 adenosine C10H14O mentha spicata herb oil C10H15ON ephedrine C10H16 limonene C10H16O camphor C10H17NO3 boc-4-piperidone C10H19NO3 1-boc-4-piperidinol C10H20N2O2 boc-4-aminopiperidine C10H22 decane C11H8O2 menadione C11H11NO2 3-indolepropionic acid C11H12N2O2 tryptophan Trp C11H12O3 myristicin C11H14N2O 5-methoxytryptamine C11H14O2 methyl eugenol C11H14O2 methyl isoeugenol C11H19NO4 boc-isonipecotic acid C11H24 undecane C12H4N4 tetracyanoquinodimethane C12H8O4 methoxsalen C12H10 biphenyl C12H10ClN2O5S furosemide C12H11N5 6-benzylaminopurine C12H11N7 triamterene C12H13NO2 indole-3-butyric acid (C12H14CaO12)n calcium alginate C12H14O4 apiole C12H14O4 dillapiole C12H15NO 1-benzyl-4-piperidone C12H16N2 N,N-Dimethyltryptamine C12H16O3 asarone C12H16O3 elemicin C12H16O3 isoelemicin 134 144 C12H16O3 oudenone C12H16O4 2,4,5-Trimethoxypropiophenone C12H16O7 arbutin C12H18O propofol C12H22O11 maltose sucrose C12H26 dodecane C13H10O benzophenone C13H12F2N6O fluconazole C13H12O β-ionone C13H12O2 monobenzone C13H14N2O harmaline C13H16N2O2 melatonin C13H18O2 ibuprofen C13H28 tridecane C14H10 anthracene C14H10 phenanthrene C14H10O14 benzoyl peroxide C14H12O3 resveratrol C14H14Cl2N2O enilconazole C14H18N2O5 aspartame C14H18N4O3 trimethoprim C14H30 tetradecane C15H10O4 daidzein C15H10O5 apigenin emodin genistein C15H10O6 luteolin C15H10O7 quercetin C15H12N2O carbamazepine C15H12N2O2 phenytoin C15H32 pentadecane C16H14O3 ketoprofen C16H28N2O6Zn zinc acexamate C16H34 hexadecane C17H13ClN4 alprazolam C17H14F3N3O2S celecoxib C17H18N2O6 nifedipine C17H19N3O3S omeprazole C17H21NO4 cocaine 135 145 C17H22O2 cicutoxin C17H22O2 oenanthotoxin C17H24O falcarinol C17H24O9 Eleutheroside B syringin C17H36 heptadecane C18H22O2 estrone C18H24O2 estradiol C18H24O3 estriol C18H24O4 estetrol C18H27NO3 capsaicin C18H32O2 linoleic acid C18H36O2 stearic acid C18H38 octadecane C19H16ClNO4 indometacin C19H26O2 androstenedione C19H28O2 dehydroepiandrosterone C19H28O2 testosterone C19H30O2 androstenediol C19H30O2 dihydrotestosterone C19H40 nonadecane C20H24O2N2 quinine C20H27NO11 amygdalin C20H28O2 tretinoin C20H32O5 prostacyclin C20H32O5 prostaglandin E2 C20H34O5 dinoprost C20H42 eicosane C21H20O6 curcumin C21H30O2 progesterone C21H36N7O16P3S Coenzyme A C21H30O2 tetrahydrocannabinol C22H23ClN2O2 loratadine C23H19ClF3NO3 cyhalothrin C30H19NO9 Dynemicin A C34H46O18 Eleutheroside D C35H60O6 Eleutheroside A C40H56 lycopene C44H69N15O9S adrenorphin C55H74IN3O21S4 calicheamicin C59H80N4O22S4 esperamicin 136 146 C62H89CoN13O15P hydroxocobalamin C63H88CoN14O14P Vitamin B12 C63H88CoN14O14P cyanocobalamin C63H91CoN13O14P methylcobalamin C72H100CoN18O17P adenosylcobalamin C77H120N18O26S alpha-Endorphin C83H131N19O27S gamma-Endorphin C131H200N30O43S2 amidorphin C158H251N39O46S beta-Endorphin C161H236N42O48 leumorphin C164H256Na2O68S2 maitotoxin CaAl2O4 calcium aluminate CaB6 calcium boride CaBr2 calcium bromide Ca(BrO)2 calcium hypobromite Ca(BrO2)2 calcium bromite Ca(BrO3)2 calcium bromate Ca(BrO4)2 calcium perbromate Ca(CN)2 calcium cyanide CaCO3 calcium carbonate spent lime calcite limestone marble CaC2 calcium carbide Ca(CHO2)2 calcium formate Ca(C2H3O2)2 calcium acetate CaC2O4 calcium oxalate CaCN2 calcium cyanamide CaCl2 calcium chloride Ca(ClO)2 calcium hypochlorite Ca(ClO2)2 calcium chlorite Ca(ClO3)2 calcium chlorate Ca(ClO4)2 calcium perchlorate CaF2 calcium fluoride fluorite CaH2 calcium hydride CaHPO4 dicalcium phosphate Ca(H2PO2)2 calcium hypophosphite Ca(HS)2 calcium hydrosulfide CaI2 calcium iodide 137 147 Ca(IO)2 calcium hypoiodite Ca(IO2)2 calcium iodite Ca(IO3)2 calcium iodate Ca(IO4)2 calcium periodate CaMoO4 calcium molybdate Ca(NO2)2 calcium nitrite Ca(NO3)2 calcium nitrate Ca(NO3)2 · 4H2O Calcium nitrate tetrahydrate Ca(NbO3)2 calcium metaniobate CaO quicklime calcium oxide burnt lime Ca(OH)2 calcium hydroxide slaked lime CaO2 calcium peroxide CaP calcium monophosphide CaS calcium sulfide hepar calcies sulfurated lime oldhamite CaSO3 calcium sulfite CaSO4 calcium sulfate CaSO4 · 0.5H2O plaster of paris calcium sulfate hemihydrate CaSe calcium selenide CaSeO3 calcium selenite CaSeO4 calcium selenate CaSiO3 calcium metasilicate wollastonite CaTe calcium telluride CaTeO3 calcium tellurite CaTeO4 calcium tellurate CaTiO3 calcium titanate Ca(VO3)2 calcium metavanadate Ca(VO4)2 calcium orthovanadate CaWO4 calcium tungstate Ca3(AsO4)2 calcium arsenate Ca3N2 calcium nitride Ca3P2 calcium phosphide Ca3(PO4)2 tricalcium phosphate Ca4(PO4)2O tetracalcium phosphate 138 148 Ca5(PO4)3F calcium fluorophosphate Ca5(PO4)3(OH) hydroxyapatite CdBr2 cadmium bromide Cd(CN)2 cadmium cyanide CdCO3 cadmium carbonate Cd(C2H3O2)2 cadmium acetate CdC2O4 cadmium oxalate CdCl2 cadmium chloride CdCrO4 cadmium chromate CdF2 cadmium fluoride CdI2 cadmium iodide Cd(IO3)2 cadmium iodate CdMoO4 cadmium molybdate Cd(NO3)2 cadmium nitrate Cd(N3)2 cadmium azide CdO cadmium oxide Cd(OH)2 cadmium hydroxide CdS cadmium sulfide greenockite CdSO3 cadmium sulfite CdSO4 cadmium sulfate CdSb cadmium antimonide CdSe cadmium selenide cadmoselite CdSeO3 cadmium selenite CdSiO3 cadmium metasilicate Cd(TaO3)2 cadmium metatantalate CdTe cadmium telluride CdTeO4 cadmium tellurate CdTiO3 cadmium titanate CdWO4 cadmium tungstate CdZrO3 cadmium metazirconate Cd2Nb2O7 cadmium niobate Cd3As2 cadmium arsenide Cd3P2 cadmium phosphide Cd3(PO4)2 cadmium phosphate CeB6 cerium boride CeBr3 cerium(III) bromide CeC cerium carbide CeCl3 cerium(III) chloride CeF3 cerium(III) fluoride 139 149 CeF4 cerium(IV) fluoride CeI2 cerium(II) iodide CeI3 cerium(III) iodide CeN cerium nitride CeO2 cerium(IV) oxide cerianite CeS cerium(II) sulfide Ce(SO4)2 cerium(IV) sulfate CeSi2 cerium silicide Ce2C3 cerium(III) carbide Ce2O3 cerium(III) oxide Ce2S3 cerium(III) sulfide CF3Cl chlorotrifluoromethane CF4 tetrafluoromethane ClF chlorine fluoride ClF3 chlorine trifluoride ClF5 chlorine pentafluoride ClOClO3 chlorine perchlorate ClO2 chlorine dioxide ClO3F chlorine trioxide fluoride Cl2 chlorine Cl2O3 chlorine trioxide Cl2O6 chlorine hexoxide Cl2O7 chlorine heptoxide Cl2O8 Chlorine octaoxide CoAl2O4 cobalt(II) aluminate CoAs cobalt arsenide CoAs2 cobalt(II) arsenide CoB cobalt(II) boride CoBr2 cobalt(II) bromide Co(CN)2 cobalt(II) cyanide Co(C2H3O2)2 cobalt(II) acetate Co(C2H3O2)3 cobalt(III) acetate CoC2O4 cobalt(II) oxalate Co(ClO4)2 cobalt(II) perchlorate CoCl2 cobalt(II) chloride CoCrO4 cobalt(II) chromate CoCr2O4 cobalt(II) chromite CoF2 cobalt(II) fluoride CoF3 cobalt(III) fluoride Co(IO3)2 cobalt(II) iodate 140 150 CoI2 cobalt(II) iodide CoMoO4 cobalt(II) molybdate Co(NO3)2 cobalt(II) nitrate Co(NO3)3 cobalt(III) nitrate CoO cobalt(II) oxide Co(OH)2 cobalt(II) hydroxide Co(OH)3 cobalt(III) hydroxide CoS cobalt(II) sulfide CoS2 cobalt disulfide CoSb cobalt antimonide CoSe cobalt(II) selenide CoSeO3 cobalt(II) selenite CoTe cobalt(II) telluride CoTiO3 cobalt(II) titanate CoWO4 cobalt(II) tungstate Co2B cobalt boride Co2SO4 cobalt(II) sulfate Co2S3 cobalt(III) sulfide Co2SiO4 cobalt(II) orthosilicate Co2SnO4 cobalt(II) stannate Co2TiO4 cobalt(II) titanite Co3(AsO4)2 cobalt arsenate Co3(Fe(CN)6)2 cobalt(II) ferricyanide CrBr2 chromium(II) bromide CrBr3 chromium(III) bromide CrCl2 chromium(II) chloride CrCl3 chromium(III) chloride CrCl4 chromium(IV) chloride CrF2 chromium(II) fluoride CrF3 chromium(III) fluoride CrF4 chromium(IV) fluoride CrF5 chromium(V) fluoride CrF6 chromium(VI) fluoride CrI2 chromium(II) iodide CrI3 chromium(III) iodide Cr(NO3)3 chromium(III) nitrate Cr(NO2)3 chromium(III) nitrite Cr(OH)3 chromium(III) hydroxide CrO2 chromium(IV) oxide CrO3 chromium(VI) oxide 141 151 CrO42− chromate ion CrO2Cl2 chromium(VI) oxychloride CrPO4 chromium(III) phosphate CrSb chromium antimonide CrSe chromium(II) selenide CrSi2 chromium(II) silicide CrVO4 chromium(III) orthovanadate Cr2O3 chromium(III) oxide eskolaite Cr2(SO4)3 chromium(III) sulfate Cr2S3 chromium(III) sulfide Cr2Se3 chromium(III) selenide Cr2(TeO4)3 chromium(III) tellurate Cr2Te3 chromium(III) telluride Cr3As2 chromium(II) arsenide Cr3C2 chromium(II) carbide Cr3Sb2 chromium(II) antimonide CsBO2 caesium borate CsBr caesium bromide CsBrO caesium hypobromite CsBrO2 caesium bromite CsBrO3 caesium bromate CsBrO4 caesium perbromate CsBr3 caesium tribromide CsCN caesium cyanide CsCNO caesium cyanate CsCNO caesium fulminate CsC2H3O2 caesium acetate CsCl caesium chloride CsClO caesium hypochlorite CsClO2 caesium chlorite CsClO3 caesium chlorate CsClO4 caesium perchlorate CsF caesium fluoride CsH caesium hydride CsHS caesium hydrosulfide CsI caesium iodide CsIO caesium hypoiodite CsIO2 caesium iodite CsIO3 caesium iodate CsIO4 caesium periodate 142 152 CsI3 caesium triiodide CsNH2 caesium amide CsNO2 caesium nitrite CsNO3 caesium nitrate CsN3 caesium azide CsNbO3 caesium niobate Cs2NbO3 caesium metaniobate CsOH caesium hydroxide CsO2 caesium superoxide Cs2O2 caesium peroxide Cs2S caesium sulfide CsSCN caesium thiocyanate CsSeO4 caesium selenate CsTaO3 caesium metatantalate Cs2CO3 caesium carbonate CsHCO3 caesium bicarbonate CsH2PO3 monocaesium phosphite CsH2PO4 monocaesium phosphate CsHSO3 caesium bisulfite CsHSO4 caesium hydrogen sulfate Cs2C2O4 caesium oxalate Cs2CrO4 caesium chromate Cs2Cr2O7 caesium dichromate Cs2HPO4 caesium hydrogen orthophosphate Cs2MoO4 caesium molybdate Cs2O caesium oxide Cs2SO3 caesium sulfite Cs2SO4 caesium sulfate Cs2SiO3 caesium metasilicate Cs2TeO4 caesium tellurate Cs2TiO3 caesium titanate caesium metatitanate Cs2WO4 caesium orthotungstate Cs2HPO3 dicaesium phosphite Cs2HPO4 dicaesium phosphate Cs3PO3 tricaesium phosphite Cs3PO4 caesium orthophosphate Cs3VO4 caesium orthovanadate CuBr copper(I) bromide Cu(BrO3)2 · 6H2O copper(II) bromate hexahydrate CuBr2 copper(II) bromide 143 153 CuC2O4 copper oxalate Cu(CH3COO) copper(I) acetate Cu(CH3COO)2 copper(II) acetate CuCl copper(I) chloride Cu(ClO3)2 · 6H2O copper(II) chlorate hexahydrate CuCl2 copper(II) chloride CuF copper(I) fluoride CuF2 copper(II) fluoride CuFeS2 copper iron sulfide chalcopyrite CuFe2O4 copper(II) iron(II) oxide CuFe2S3 copper iron sulfide cubanite [Cu(H2O)4]SO4 · H2O blue vitriol CuI copper(I) iodide CuIO3 copper(I) iodate Cu(IO3)2 copper(II) iodate CuMoO4 copper(II) orthomolybdate Cu(NO3)2 copper(II) nitrate Cu(NO3)2 · 3H2O copper(II) nitrate trihydrate Cu(NO3)2 · 6H2O copper(II) nitrate hexahydrate Cu(NbO3)2 copper(II) orthoniobate CuO copper(II) oxide Cu2O copper(I) oxide Cu(OH)2 copper(II) hydroxide Cu2(OH)2CO3 basic copper carbonate CuS copper(II) sulfide covellite CuSCN copper(I) thiocyanate CuSO4 copper(II) sulfate CuSO4 · 5H2O copper(II) sulfate pentahydrate CuSe copper(II) selenide CuSeO3 · 2H2O copper(II) selenite dihydrate CuSeO4 · 5H2O copper(II) selenate pentahydrate CuSiO3 copper(II) metasilicate CuTe copper(II) telluride CuTeO3 copper(II) tellurite CuTiO3 copper(II) metatitanate Cu(VO3)2 copper(II) metavanadate CuWO4 copper(II) orthotungstate Cu2CO3(OH)2 malachite 144 154 Cu2S copper(I) sulfide chalcocite Cu2Se copper(I) selenide Cu2Te copper(I) telluride Cu3As copper(I) arsenide Cu3P copper(I) phosphide Cu3(PO4)2 copper(II) phosphate Cu3Sb copper(III) antimonide Cu9S5 copper sulfide digenite DBr deuterium bromide DI deuterium iodide DLi lithium deuteride DNa sodium deuteride D 2O deuterium oxide heavy water D 3O + trideuterium oxide cation DyBr3 dysprosium(III) bromide DyCl2 dysprosium(II) chloride DyCl3 dysprosium(III) chloride DySi2 dysprosium(II) silicide Dy2O3 dysprosium(III) oxide Dy2S3 dysprosium(III) sulfide ErCl3 erbium(III) chloride ErF erbium monofluoride ErF2 erbium difluoride ErF3 erbium trifluoride ErI3 erbium triiodide ErI4Na erbium sodium tetraiodide ErO erbium monoxide EuCl2 europium(II) chloride EuCl3 europium(III) chloride EuF europium monofluoride EuF3 europium trifluoride EuI2 europium diiodide EuNbO2 europium niobium dioxide EuNb2O6 europium diniobium hexaoxide EuO europium monoxide EuO2V monoeuropium monovandium dioxide EuO3Ti europium titanium trioxide EuO3V europium metavanadate 145 155 EuO4W europium tungsten tetraoxide EuS europium monosulfide EuSO4 europium(II) sulfate EuS2 europium disulfide Eu2O dieuropium monoxide Eu2O2 dieuropium dioxide Eu2O3 europium(III) oxide Eu2S dieuropium monosulfide Eu2S2 dieuropium disulfide Eu2(SO4)3 europium(III) sulfate FGa gallium monofluoride FGaO gallium monofluoride monoxide FGd gadolinium monofluoride FGe germanium monofluoride FHo holmium monofluoride FI iodine monofluoride FI2 monofluorodiiodine FIn indium monofluoride FLa lanthanum monofluoride FLi lithium fluoride FLiO lithium hypofluorite FLi2 dilithium monofluoride FMg magnesium monofluoride FMn monomanganese monofluoride FMnO3 manganese fluoride trioxide FMo molybdenum monofluoride FN fluoroimidogen FNO nitrosyl fluoride FNO2 nitryl fluoride FNO3 fluorine nitrate FNS thiazyl fluoride FNa sodium fluoride FNa2 disodium monofluoride FNd neodymium monofluoride FO oxygen monofluoride FOTh thorium monofluoride monoxide FOTi titanium fluoride oxide FO2 dioxygen monofluoride FO3S fluorosulfate radical FP phosphorus monofluoride 146 156 FPS phosphenothious fluoride FPS2 phosphenodithioic fluoride FPb lead monofluoride FPu plutonium monofluoride FRb rubidium fluoride FS monosulfur monofluoride FSc scandium monofluoride FSm samarium monofluoride FSn tin monofluoride FSr strontium monofluoride FTh thorium monofluoride FTi titanium fluoride FTl thallium monofluoride FW tungsten monofluoride FXe xenon monofluoride FY yttrium monofluoride FZr zirconium fluoride F2 fluorine F2Fe ferrous fluoride F2Ga gallium difluoride F2Gd gadolinium difluoride F2Ge germanium difluoride F2GeO difluorogermanone F2Hg mercury fluoride F2Hg2 mercury fluoride F2Ho holmium difluoride F2IP difluoroiodophosphine F 2K 2 dipotassium difluoride F2Kr krypton difluoride F2La lanthanum difluoride F2Li2 lithium fluoride F2Mg magnesium fluoride F2Mn manganese difluoride F2Mo molybdenum difluoride F2MoO2 molybdenum difluoride dioxide F 2N difluoroamino radical F2N2O nitrosodifluoroamine F2Na2 disodium difluoride F2Nd neodymium difluoride F2Ni nickel difluoride 147 157 F 2O oxygen difluoride F2OS thionyl fluoride F2OSi difluorooxosilane F2OTi titanium fluoride oxide F 2O 2 perfluoroperoxide F2O2S sulfuryl fluoride F2O2W tungsten difluoride dioxide F2O5S3 peroxydisulfuryl difluoride F 2P phosphorus difluoride F2Pb lead difluoride F2Pt platinum difluoride F2Pu plutonium difluoride F 2S sulfur difluoride F2SW tungsten difluoride monosulfide F 2S 2 difluorodisulfane F 2S 2 thiothionyl fluoride F 2S 2 thiothionyl fluoride F2S2W tungsten difluoride disulfide F2Sc scandium difluoride F2Se selenium difluoride F2Si difluorosilylene F2Sn tin difluoride F2Sr strontium fluoride F2Th thorium difluoride F2Ti titanium difluoride F2Tl2 dithallium difluoride F 2W tungsten difluoride F2Xe xenon difluoride F 2Y yttrium difluoride F2Zn zinc difluoride F2Zr zirconium fluoride F3Fe iron trifluoride F3Ga gallium trifluoride F3Gd gadolinium trifluoride F3Ho holmium trifluoride F3La lanthanum trifluoride F3Li3 trilithium trifluoride F3Lu lutetium trifluoride F3Mn manganese trifluoride F3Mo molybdenum trifluoride 148 158 F3MoO molybdenum trifluoride oxide F3MoS molybdenum trifluoride sulfide F 3N nitrogen trifluoride F3NO nitrogen trifluoride oxide F3NO2S difluoroaminosulfonyl fluoride F3NO3S difluoraminooxysulfonyl fluoride F3NS thiazyl trifluoride F3NaSn sodium trifluorostannate F3Nd neodymium trifluoride F3OP phosphoryl fluoride F3OTa tantalum monoxide trifluoride F3OV vanadium trifluoride oxide F 3P phosphorus trifluoride F3PS thiophosphoryl fluoride F3Pr praseodymium trifluoride F3Pu plutonium trifluoride F3Rh rhodium fluoride F 3S sulfur trifluoride F3SW tungsten trifluoride monosulfide F3Sb antimony trifluoride F3Sc scandium fluoride F3Si trifluorosilyl radical F3Sm samarium trifluoride F3Tb terbium trifluoride F3Th thorium trifluoride F3Ti titanium trifluoride F3Tl thallium trifluoride F3Tm thulium trifluoride F 3W tungsten trifluoride F 3Y yttrium trifluoride F3Yb ytterbium trifluoride F3Zr zirconium trifluoride F4Ge germanium tetrafluoride F4Ge2 digermanium tetrafluoride F4Hf hafnium fluoride F4Mg2 dimagnesium tetrafluoride F4Mg2 magnesium fluoride F4Mo molybdenum tetrafluoride F4MoO molybdenum tetrafluoride oxide F4MoS molybdenum tetrafluoride monosulfide 149 159 F 4N 2 tetrafluorohydrazine F4Na2Sn disodium tetrafluorostannate F4OOs osmium oxide tetrafluoride F4OP2 diphosphorus tetrafluoride oxide F4ORe rhenium tetrafluoride oxide F4OS sulfur tetrafluoride oxide F4OW tungsten tetrafluoride oxide F4OXe xenon tetrafluoride oxide F 4P 2 diphosphorus tetrafluoride F4Pb lead tetrafluoride F4Pt platinum tetrafluoride F4Pu plutonium tetrafluoride F 4S sulfur tetrafluoride F4SW tungsten tetrafluoride monosulfide F4Se selenium tetrafluoride F4Si silicon tetrafluoride F4Sn2 ditin tetrafluoride F4Ti titanium fluoride F 4U uranium tetrafluoride F 4W tungsten tetrafluoride F4Xe xenon tetrafluoride F4Zr zirconium tetrafluoride F 5I iodine pentafluoride F5Mo molybdenum pentafluoride F5ORe rhenium monoxide pentafluoride F 5P phosphorus pentafluoride F5Pu plutonium pentafluoride F 5S disulfur decafluoride F5Sb antimony pentafluoride F5Ta tantalum pentafluoride F 5U uranium pentafluoride F 5W tungsten pentafluoride F6Fe2 diiron hexafluoride F6La2 lanthanum trifluoride dimer F6Mo molybdenum hexafluoride F6NP3 nitridotriphosphorous hexafluoride F6Os osmium hexafluoride F6Pu plutonium hexafluoride F6Re rhenium hexafluoride F 6S sulfur hexafluoride 150 160 F6Se selenium hexafluoride F6Si2 hexafluorodisilane F6Sn3 tritin hexafluoride F6Te tellurium hexafluoride F 6U uranium hexafluoride F 6W tungsten hexafluoride F6Xe xenon hexafluoride F 7I iodine fluoride F7NS pentafluorosulfanyldifluoroamine F7Re rhenium heptafluoride F8Si3 octafluorotrisilane F10Mo2 molybdenum fluoride F10S2 sulfur fluoride F15Mo3 molybdenum fluoride FeAsS iron arsenic sulfide arsenopyrite FeBr2 iron(II) bromide FeBr3 iron(III) bromide FeBr3 · 6H2O iron(III) bromide hexahydrate FeCO3 siderite FeC2O4 iron oxalate FeC5O5 iron pentacarbonyl pentacarbonyl iron FeC10H10 ferrocene FeCl2 iron(II) chloride FeCl3 iron(III) chloride FeCr2O4 chromite (ore) FeF2 iron fluoride FeF2 · 4H2O iron(II) fluoride tetrahydrate FeI iron monoiodide FeI2 iron diiodide iron(II) iodide FeI2 · 4H2O iron(II) iodide tetrahydrate FeI3 iron(III) iodide FeMoO4 iron(II) orthomolybdate FeO iron monoxide iron(II) oxide wüstite FeO2 iron dioxide FeO2H goethite FeO2H · nH2O limonite 151 161 Fe(OH)2 iron(II) hydroxide Fe(OH)3 iron(III) hydroxide Fe(SCN)3 iron(III) Thiocyanate FeO4S ferrous sulfate FeO4Se iron(II) selenate ferrous selenate FeO8H4P2 iron(II) dihydrogen phosphate FeP iron(III) phosphide FePO4 iron(III) phosphate FeS iron sulfide iron(II) sulfide FeS2 pyrite fool's gold iron(IV) sulfide marcasite FeSe iron(II) selenide FeTe iron(II) telluride FeTiO3 iron(II) metatitanate ilmenite FeVO4 iron(III) orthovanadate FeWO4 iron(II) orthotungstate FeZrO3 iron(II) metazirconate Fe2I2 diiron diiodide Fe2I4 diiron tetraiodide Fe2O3 iron oxide iron(III) oxide hematite Fe2O3 venetian red Fe2O12S3 ferric sulfate iron(III) sulfate Fe2O12W3 iron(III) orthotungstate Fe2P diiron phosphide Fe2SiO4 fayalite Fe3H2Na2O45Si chrysotile white asbestos Fe3O4 iron(II,III) oxide magnetite triiron(II, III) tetraoxide Fe3P iron(tri) phosphide Fe4(P2O7)3 iron(III) pyrophosphate Fe7Si8O24H2 amosite 152 162 brown asbestos grunerite GaAs gallium(III) arsenide GaAsO4 gallium(III) orthoarsenate GaBr3 gallium(III) bromide Ga(C2H3O2)3 gallium(III) acetate GaCl2 gallium(II) chloride GaCl3</ gallium trichloride Ga(ClO4)3 gallium(III) perchlorate GaI2 gallium(II) iodide GaI3 gallium(III) iodide GaN gallium(III) nitride Ga(OH)3 gallium(III) hydroxide GaPO4 gallium(III) orthophosphate GaSb gallium(III) antimonide GaTe gallium(II) telluride Ga2O3 gallium(III) oxide Ga2(SO4)3·18H2O gallium(III) sulfate octadecahydrate Ga2S3 gallium(III) sulfide Ga2Te3 gallium(III) telluride GeBr4 germanium(IV) bromide GeH3COOH 2-germaacetic acid GeI2 germanium(II) iodide GeI4 germanium(IV) iodide GeO germanium(II) oxide HArF argon fluorohydride HAt hydrogen astatide HBr hydrogen bromide hydrobromic acid HBrO hypobromous acid HBrO2 bromous acid HBrO3 bromic acid HBrO4 perbromic acid HCCH acetylene ethyne HCN hydrocyanic acid hydrogen cyanide HCNO fulminic acid HCONH2 formamide methanamide HCOO− formate ion 153 163 HCOOH formic acid methanoic acid HCOONH4 ammonium formate HCO3− hydrogen carbonate ion HC3H5O3 lactic acid HC5H5N+ pyridinium ion HC6H7O6 ascorbic acid HC9H7O4 acetylsalicylic acid HC12H17ON4SCl2 thiamine hydrochloride vitamin B1 hydrochloride HCl hydrochloric acid hydrogen chloride HClO hypochlorous acid HClO2 chlorous acid HClO3 chloric acid HClO4 perchloric acid HDO semiheavy water water-d1 HF hydrofluoric acid HI hydroiodic acid HIO hypoiodous acid HIO2 iodous acid HIO3 iodic acid HIO4 periodic acid HNCO isocyanic acid HNO nitroxyl HNO2 nitrous acid HNO3 nitric acid hydrogen nitrate HN3 hydrazoic acid HOBr hypobromous acid HOCl hypochlorous acid HOF hypofluorous acid HOOCCOOH oxalic acid HPO42− hydrogen phosphate ion HSO3− hydrogen sulfite ion HSO4− hydrogen sulfate HTO partially tritiated water water-t H2 hydrogen H2C(CH)CN acrylonitrile 154 164 H2CO formaldehyde H2CO3 carbonic acid H2CSO sulfine H2C2O4 oxalic acid H2C4H4O6 tartaric acid H2C8H4O4 phthalic acid H2Ph H2CrO4 chromic acid H2NCH2COOH glycine H2N2O2 hyponitrous acid H2NNH2 hydrazine H 2O water H 2O 2 hydrogen peroxide H2PO4− dihydrogen phosphate ion H 2S hydrogen sulfide hydrosulfuric acid H2SO3 sulfurous acid H2SO4 sulfuric acid hydrogen sulfate H2S2O2 thiosulfurous acid H2S2O3 thiosulfuric acid H2S2O4 dithionous acid H2S2O5 disulfurous acid H2S2O6 dithionic acid H2S2O7 disulfuric acid H2S2O8 peroxydisulfuric acid H2SeO3 selenous acid H2SeO4 selenic acid H2SiO3 silicic acid H2TeO3 tellurous acid H2TiO3 titanic acid H3AsO4 arsenic acid H3CCH2CH3 propane H3N+CH2COO− zwitterion H 3O + hydronium ion H3PO2 hypophosphorous acid H3PO3 phosphorous acid H3PO4 phosphoric acid H4XeO6 perxenic acid H6TeO6 telluric acid HfBr4 hafnium(IV) bromide 155 165 HfF4 hafnium(IV) fluoride HfOCl2 · 8H2O hafnium(IV) oxychloride octahydrate HfOH(C2H3O2)3 hafnium(IV) acetate, basic Hf(SO4)2 hafnium(IV) sulfate Hg(BrO3)2 · 2H2O mercury(II) bromate dihydrate Hg2Br2 mercury(I) bromide HgBr2 mercury(II) bromide Hg(C2H3O2)2 mercury(II) acetate Hg(C7H5O2)2 · H2O mercury(II) benzoate monohydrate HgClO4 · 4H2O mercury(I) perchlorate tetrahydrate Hg(ClO4)2 · 3H2O mercury(II) perchlorate trihydrate HgCl2 mercury(II) chloride Hg(IO3)2 mercury(II) iodate HgI2 mercury(II) iodide Hg(NO3)2 · H2O mercury(II) nitrate monohydrate Hg(CNO)2 mercury(II) fulminate HgO mercury(II) oxide Hg(OH)2 mercury(II) hydroxide HgS mercury(II) sulfide cinnabar Hg(SCN)2 mercury(II) thiocyanate HgSe mercury(II) selenide HgSeO3 mercury(II) selenite HgTe mercury(II) telluride HgTeO3 mercury(II) tellurite HgWO4 mercury(II) tungstate Hg2Br2 mercury(I) bromide Hg2Cl2 mercury(I) chloride Hg2I2 mercury(I) iodide Hg3(AsO4)2 mercury(II) orthoarsenate Hg3(PO4)2 mercury(II) phosphate IBr iodine(I) bromide IBr3 iodine(III) bromide ICl Iodine monochloride ICl3 iodine(III) chloride IO3− iodate ion I2 iodine I 2O 5 iodine pentoxide I 3− triiodide ion InAs indium(III) arsenide InBr indium(I) bromide 156 166 InBrI2 indium(III) bromodiiodide InBr2I indium(III) dibromoiodide InBr3 indium(III) bromide InCl indium(I) chloride InCl2 indium(II) chloride InCl3 indium(III) chloride InCl3·4H2O indium(III) chloride tetrahydrate InI indium(I) iodide In(IO3)3 indium(III) iodate InI2 indium(II) iodide InI3 indium(III) iodide In(NO3)3·4.5H2O indium(III) nitrate tetrahemihydrate In(OH)3 indium(III) hydroxide InP indium(III) phosphide InPO4 indium(III) orthophosphate InS indium(II) sulfide InSb indium(III) antimonide InTe indium(II) telluride In2O3 indium(III) oxide In2(SO4)3·H2O indium(III) sulfate monohydrate In2S3 indium(III) sulfide In2Se3 indium(III) selenide In2Te3 indium(III) telluride IrBr3 iridium(III) bromide KAl(SO4)2 potassium alum KAsO2 potassium arsenite KH2AsO4 potassium dihydrogen arsenate KBr potassium bromide KBrO potassium hypobromite KBrO2 potassium bromite KBrO3 potassium bromate KBrO4 potassium perbromate KCN potassium cyanide KCNO potassium cyanate KCNO potassium fulminate KCNS potassium thiocyanate KCl potassium chloride KClO potassium hypochlorite KClO2 potassium chlorite KClO3 potassium chlorate 157 167 KClO4 potassium perchlorate K2CrO4 potassium chromate K2Cr2O7 potassium dichromate K2HAsO4 dipotassium hydrogen arsenate K2HPO3 dipotassium phosphite K2HPO4 dipotassium phosphate K3AsO4 potassium arsenate K3C6H5O7 potassium citrate K3PO3 tripotassium phosphite K3PO4 tripotassium phosphate KF potassium fluoride KOF potassium hypofluorite KH potassium hydride KHCO3 potassium bicarbonate KHS potassium hydrosulfide KHSO3 potassium bisulfite KHSO4 potassium bisulfate KH2PO3 monopotassium phosphite KH2PO4 monopotassium phosphate KI potassium iodide KIO potassium hypoiodite KIO2 potassium iodite KIO3 potassium iodate KIO4 potassium periodate KMnO4 potassium permanganate KNO3 potassium nitrate KNO2 potassium nitrite K2CO3 potassium carbonate K2MnO4 potassium manganate K2N2O2 potassium hyponitrite KNbO3 potassium niobate K 2O potassium oxide K 2O 2 potassium peroxide K 2S potassium sulfide K2S2O3 potassium thiosulfate K2S2O5 potassium metabisulfite K2S2O8 potassium persulfate K2SO3 potassium sulfite K2SO4 potassium sulfate KOH potassium hydroxide/custic potash 158 168 LaBr3 lanthanum(III) bromide LaCl3 lanthanum(III) chloride LaI3 lanthanum(III) iodide La2O3 lanthanum(III) oxide La(OH)3 lanthanum hydroxide LaPO4 lanthanum(III) phosphate LaPO4·0.5H2O lanthanum(III) phosphate crystal hemihydrate LiAlH4 lithium aluminium hydride Li(AlSi2O6) keatite LiBH4 lithium borohydride LiBr lithium bromide LiBr·2H2O lithium bromide dihydrate LiBrO lithium hypobromite LiBrO2 lithium bromite LiBrO3 lithium bromate LiBrO4 lithium perbromate LiCl lithium chloride LiClO lithium hypochlorite LiClO2 lithium chlorite LiClO3 lithium chlorate LiClO4 lithium perchlorate LiCN lithium cyanide LiCNO lithium cyanate LiC2H5O lithium ethoxide LiF lithium fluoride LiH lithium hydride LiHCO3 lithium bicarbonate LiHS lithium hydrosulfide LiHSO3 lithium bisulfite LiHSO4 lithium hydrogen sulfate LiH2AsO4 lithium dihydrogen arsenate LiH2PO3 monolithium phosphite LiH2PO4 monolithium phosphate LiI lithium iodide LiIO lithium hypoiodite LiIO2 lithium iodite LiIO3 lithium iodate LiIO4 lithium periodate LiNa sodium lithium LiNbO3 lithium niobate 159 169 LiNO2 lithium nitrite LiNO3 lithium nitrate LiNO3·H2O lithium nitrate monohydrate LiOH lithium hydroxide LiTaO3 lithium tantalate lithium metatantalate LiVO3·2H2O lithium metavanadate dihydrate Li2HAsO4 dilithium hydrogen arsenate Li2B4O7·5H2O lithium tetraborate pentahydrate Li2CO3 lithium carbonate Li2CrO4 lithium chromate Li2CrO4·2H2O lithium chromate dihydrate Li2Cr2O7 lithium dichromate Li2HPO3 dilithium phosphite Li2HPO4 dilithium phosphate Li2MoO4 lithium orthomolybdate Li2NbO3 lithium metaniobate Li2N2O2 lithium hyponitrite Li2O lithium oxide Li2O2 lithium peroxide Li2S lithium sulfide Li2SO3 lithium sulfite Li2SO4 lithium sulfate Li2SeO3 lithium selenite Li2SeO4 lithium selenate Li2SiO3 lithium metasilicate lithium orthosilicate Li2TeO3 lithium tellurite Li2TeO4 lithium tellurate Li2TiO3 lithium metatitanate Li2WO4 lithium orthotungstate Li2ZrO3 lithium metazirconate Li3AsO4 trilithium arsenate Li3PO3 trilithium phosphite Li3PO4 trilithium phosphate MgBr2 magnesium bromide Mg(BrO)2 magnesium hypobromite Mg(BrO2)2 magnesium bromite Mg(BrO3)2 magnesium bromate Mg(BrO4)2 magnesium perbromate Mg(AlO2)2 magnesium aluminate 160 170 As2Mg3 magnesium arsenide MgCO3 magnesium carbonate magnesite MgC2O4 magnesium oxalate Mg(ClO)2 magnesium hypochlorite Mg(ClO2)2 magnesium chlorite Mg(ClO3)2 magnesium chlorate Mg(ClO3)2·xH2O magnesium chlorate hydrate Mg(ClO4)2 magnesium perchlorate MgCl2 magnesium chloride MgCrO4 magnesium chromate MgCrO4·5H2O magnesium chromate pentahydrate MgF2 magnesium fluoride MgHPO4 dimagnesium phosphate MgI2 magnesium iodide Mg(IO)2 magnesium hypoiodite Mg(IO2)2 magnesium iodite Mg(IO3)2 magnesium iodate Mg(IO4)2 magnesium periodate MgMoO4 magnesium molybdate MgNH4PO4·6H2O magnesium ammonium phosphate hexahydrate Mg(NO2)2 magnesium nitrite Mg(NO3)2 magnesium nitrate Mg(NO3)2·6H2O magnesium nitrate hexahydrate MgNaAl5(Si4O10)3(OH)6 montmorillonite (clay) MgO magnesium oxide magnesia periclase Mg(OH)2 magnesium hydroxide milk of magnesia MgPo magnesium polonide MgS magnesium sulfide MgSO3 magnesium sulfite MgSO4 magnesium sulfate MgSe magnesium selenide MgSeO3 magnesium selenite MgSeO4 magnesium selenate MgSiO3 magnesium metasilicate enstatite MgTiO3 magnesium metatitanate 161 171 Mg(VO3)2 magnesium metavanadate MgWO4 magnesium tungstate Mg2Al(AlSiO5)(OH)4 amesite Mg2P2O7 magnesium pyrophosphate Mg2SiO4 forsterite Mg3As2 magnesium arsenide Mg3Bi2 magnesium bismuthide Mg3P2 magnesium phosphide Mg3(Si2O5)(OH)4 chrysotile Mg3(Si4O10)(OH)2 talc Mg3(VO4)2 magnesium orthovanadate MnAs manganese(III) arsenide MnBi manganese(III) bismuthide MnBr2 manganese(II) bromide MnBr2·4H2O manganese(II) bromide tetrahydrate Mn(CHO2)2 manganese(II) formate Mn(CHO2)2·2H2O manganese(II) formate dihydrate MnCO3 manganese(II) carbonate MnCl2 manganese(II) chloride MnF2 manganese(II) fluoride MnI2 manganese(II) iodide MnMoO4 manganese(II) orthomolybdate Mn(NO3)2 manganese(II) nitrate Mn(NO3)2·4H2O manganese(II) nitrate tetrahydrate MnO manganese(II) oxide Mn(OH)2 manganese hydroxide MnOOH manganite MnO2 manganese dioxide pyrolusite MnO4− permanganate ion MnPb8(Si2O7)3 barysilate MnS manganese sulfide MnTe manganese(II) telluride MnZrO3 manganese(II) metazirconate Mn2O3 manganese(III) oxide Mn3As2 manganese(II) arsenide Mn3O4 manganese(II,III) oxide trimanganese tetroxide hausmannite Mn3P2 manganese(II) phosphide Mn3Sb2 manganese(II) antimonide 162 172 MoBr2 molybdenum(II) bromide MoBr3 molybdenum(III) bromide MoCl2 molybdenum(II) chloride MoCl3 molybdenum(III) chloride MoCl5 molybdenum(V) chloride MoO2 molybdenum(IV) oxide MoO3 Molybdenum trioxide MoO42− molybdate ion MoSe2 molybdenum(IV) selenide MoS2 molybdenum sulfide molybdenum disulfide molybdenite NCl3 nitrogen trichloride NHCl2 dichloramine NH2Cl monochloramine NH2− amide ion NH2CH2CH2NH2 ethylenediamine NH2CH2CN aminoacetonitrile NH2COOH carbamic acid NH2CONH2 urea NH2C6H4SO3H sulfanilic Acid NH2OH hydroxylamine (NH2)2CO urea NH3 ammonia NH4+ ammonium ion (NH4)3N ammonium nitride NH4Br ammonium bromide NH4CO2NH2 ammonium carbamate (NH4)2CO3 ammonium carbonate NH4Cl ammonium chloride NH4ClO4 Ammonium perchlorate NH4HS ammonium hydrosulfide (NH4)H2AsO4 ammonium dihydrogen arsenate NH4NO3 ammonium nitrate NH4OCONH2 ammonium carbamate NH4OH ammonium hydroxide (NH4)2Ce(NO3)6 ammonium cerium(IV) nitrate ceric ammonium nitrate CAN (NH4)3PO4 ammonium phosphate (NH4)2CrO4 ammonium chromate 163 173 (NH4)2Hg(SCN)4 mercury(II) ammonium thiocyanate (NH4)2[PtCl6] ammonium hexachloroplatinate(IV) (NH4)2[Pt(SCN)6] ammonium hexathiocyanoplatinate(IV) (NH4)2SO4 ammonium sulfate NI3 nitrogen triiodide NO nitric oxide nitrogen oxide nitrogen(II) oxide NOCl nitrosyl chloride NOBr nitrosyl bromide NOI nitrosyl iodide NO2 nitrogen dioxide nitrogen(IV) oxide NO2− nitrite ion NO2Cl nitryl chloride NO3− nitrate ion N2 nitrogen N 2H 2 diazene N 2H 4 hydrazine N 2O nitrous oxide dinitrogen oxide nitrogen(I) oxide N 2O 3 dinitrogen trioxide nitrogen(III) oxide N 2O 4 dinitrogen tetroxide nitrogen(IV) oxide N 2O 5 dinitrogen pentaoxide nitrogen(V) oxide N 4H 4 trans-tetrazene NaAlSi3O3 albite NaAsO2 sodium metaarsenite NaH2AsO4 sodium dihydrogen arsenate NaAu(CN)2 sodium dicyanoaurate(I) Na2Cr2O7 · 2H2O Sodium dichromate dihydrate Na[B(NO3)4] sodium tetranitratoborate(III) NaBr sodium bromide NaBrO sodium hypobromite NaBrO2 sodium bromite NaBrO3 sodium bromate NaBrO4 sodium perbromate NaCN sodium cyanide 164 174 NaCNO sodium cyanate NaCNO sodium fulminate NaC6F5COO pentafluorobenzoate NaC6H5COO sodium benzoate NaC6H7O7 monosodium citrate NaCa2(Al5Si5O20) · 6H2O thomsonite NaCl sodium chloride rock-salt halite NaClO2 sodium chlorite NaClO3 sodium chlorate NaClO4 sodium perchlorate NaF sodium fluoride NaOF sodium hypofluorite NaH sodium hydride NaHCOO sodium formate NaHCO3 sodium bicarbonate baking soda NaHS sodium hydrosulfide NaHSO3 sodium bisulfite NaHSO4 sodium bisulfate NaH2PO3 monosodium phosphite NaH2PO4 monosodium phosphate NaI sodium iodide NaIO sodium hypoiodite NaIO2 sodium iodite NaIO3 sodium iodate NaIO4 sodium periodate NaNH2C6H4SO3 sodium sulfanilate NaNO2 sodium nitrite NaNO3 sodium nitrate NaNbO3 sodium metaniobate NaNbO3 · 7H2O sodium metaniobate heptahydrate NaOCl sodium hypochlorite NaOH sodium hydroxide NaO2As(CH3)2 · 3H2O sodium salt of cacodylic acid NaSeO3 sodium selenite NaTaO3 sodium metatantalate NaVO3 sodium metavanadate Na2CO3 sodium carbonate soda ash 165 175 Na2C2O4 sodium oxalate Na2C6H6O7 disodium citrate Na2HAsO4 disodium hydrogen arsenate Na2HPO3 disodium phosphite Na2HPO4 disodium phosphate Na2MoS4 sodium thiomolybdate Na2N2O2 sodium hyponitrite Na2O2 sodium peroxide Na2O sodium oxide Na2S sodium monosulfide Na2SO3 sodium sulfite Na2SO4 sodium sulfate salt cake Na2S2O3 sodium thiosulfate Na2S2O5 sodium disulfite Na2S2O8 sodium persulfate Na2S4 sodium tetrasulfide Na2SeO3 sodium selenite Na2SeO4 sodium selenate Na2TeO3 sodium tellurite Na2TeO4 sodium tellurate Na2TiO3 sodium metatitanate Na2Zn(OH)4 sodium zincate Na2ZnO2 sodium zincate Na2ZrO3 sodium metazirconate Na3AlF6 cryolite Na3AsO4 sodium arsenate Na3[Co(CO3)3] sodium tricarbonatocobaltate(III) Na3VO4 sodium orthovanadate Na3C6H5O7 trisodium citrate Na3PO3 trisodium phosphite Na3PO4 trisodium phosphate Na4V2O7 sodium pyrovanadate NbBr5 niobium(V) bromide NbCl3 niobium(III) chloride NbCl5 niobium(V) chloride NbI5 niobium(V) iodide Nb2O3 niobium(III) oxide NdCl2 neodymium(II) chloride neodymium dichloride NdI2 neodymium(III) iodide 166 176 neodymium diiodide Nd(OH)3 neodymium hydroxide Nd2O3 neodymium(III) oxide dineodymium trioxide NiAs nickel(III) arsenide NiAsS nickel arsenic sulfide gersdorffite NiBr2 nickel(II) bromide NiBr2 · 3H2O nickel(II) bromide trihydrate NiBr2 · 6H2O nickel(II) bromide hexahydrate Ni(CO)3 nickel(II) carbonate Ni(CO)4 nickel tetracarbonyl NiC2O4 · 2H2O nickel(II) oxalate dihydrate NiCl2 nickel(II) chloride NiFe2O4 nickel(II) iron(III) oxide NiI2 nickel(II) iodide Ni(H2PO)2 · 6H2O nickel(II) hypophosphite hexahydrate NiMoO4 nickel(II) orthomolybdate Ni(NO3)2 · 6H2O nickel(II) nitrate hexahydrate NiOOH nickel oxo-hydroxide NiO nickel(II) oxide Ni(OH)2 nickel(II) hydroxide NiS nickel(II) sulfide millerite NiSO4 nickel sulfate NiS2 nickel sulfide NiSb nickel antimonide NiSe nickel(II) selenide NiTiO3 nickel(II) metatitanate Ni(VO3)2 nickel(II) metavanadate NiWO4 nickel(II) orthotungstate Ni2SiO4 nickel(II) orthosilicate Ni3(PO4)2 nickel(II) orthophosphate Ni3Sb2 nickel(II) antimonide O oxygen O2 dioxygen O 2− superoxide ion O22− peroxide ion OF2 oxygen difluoride O 2F 2 dioxygen difluoride OH− hydroxide ion 167 177 O3 ozone O 3− ozonide ion PCl3 phosphorus trichloride PCl5 phosphorus pentachloride POCl3 phosphoryl chloride P 2I 4 diphosphorus tetraiodide P 2O 5 phosphorus pentoxide P 2S 3 diphosphorus trisulfide P2Se3 diphosphorus triselenide P 3N 5 triphosphorus pentanitride PH3 phosphine POCl3 phosphoryl chloride PbCl2 lead(II) chloride PbCl4 lead(IV) chloride PbHAsO4 lead hydrogen arsenate PbI2 lead(II) iodide Pb(IO3)2 lead(II) iodate Pb(N3)2 lead(II) nitride Pb(NO3)2 lead(II) nitrate Pb(OH)2 lead(II) hydroxide Pb(OH)4 lead(IV) hydroxide PbC2O4 lead oxalate PbCO3 lead carbonate PbCrO4 lead chromate PbF2 lead(II) fluoride PbO lead(II) oxide PbO2 lead dioxide PbS lead(II) sulfide PbSO4 lead(II) sulfate PoBr2 polonium dibromide PoCl2 polonium dichloride PoCl4 polonium tetrachloride PoF6 polonium hexafluoride PoH2 polonium hydride PoO polonium monoxide PoO2 polonium dioxide PoO3 polonium trioxide RaCl2 radium chloride RbBr rubidium bromide RbBrO rubidium hypobromite 168 178 RbBrO2 rubidium bromite RbBrO3 rubidium bromate RbBrO4 rubidium perbromate RbCl rubidium chloride RbClO rubidium hypochlorite RbClO2 rubidium chlorite RbClO3 rubidium chlorate RbClO4 rubidium perchlorate RbCN rubidium cyanide RbCNO rubidium cyanate RbCNO rubidium fulminate RbF rubidium fluoride RbH rubidium hydride RbH2PO3 monorubidium phosphite RbH2PO4 monorubidium phosphate RbHS rubidium hydrosulfide RbI rubidium iodide RbIO rubidium hypoiodite RbIO2 rubidium iodite RbIO3 rubidium iodate RbIO4 rubidium periodate RbOH rubidium hydroxide Rb2O rubidium oxide Rb2O2 rubidium peroxide Rb2CO3 rubidium carbonate Rb2S rubidium sulfide Rb2SO3 rubidium sulfite Rb2SO4 rubidium sulfate Rb2HPO3 dirubidium phosphite Rb2HPO4 dirubidium phosphate Rb3PO3 trirubidium phosphite Rb3PO4 trirubidium phosphate RbHCO3 rubidium bicarbonate RbHSO3 rubidium bisulfite RbHSO4 rubidium bisulfate RbNbO3 rubidium niobate RbNO2 rubidium nitrite RbNO3 rubidium nitrate RnF2 radon difluoride RuCl3 ruthenium(III) chloride 169 179 RuF6 ruthenium hexafluoride RuO4 ruthenium tetroxide SCN− thiocyanate SF4 sulfur tetrafluoride SF6 sulfur hexafluoride SOF2 thionyl difluoride SO2 sulfur dioxide SO2Cl2 sulfuryl chloride SO2F2 sulfuryl difluoride SO2OOH− peroxymonosulfurous acid (aqueous) SO3 sulfur trioxide SO32− sulfite ion SO42− sulfate ion S2Br2 sulfur(II) bromide S2O32− thiosulfate ion S2O72− disulfate ion SbBr3 antimony(III) bromide SbCl3 antimony(III) chloride SbCl5 antimony(V) chloride SbI3 antimony(III) iodide SbPO4 antimony(III) phosphate Sb2OS2 antimony oxysulfide kermesite Sb2O3 antimony(III) oxide Sb2O5 antimony(V) oxide Sb2S3 antimony(III) sulfide Sb2Se3 antimony(III) selenide Sb2Se5 antimony(V) selenide Sb2Te3 antimony(III) telluride Sc2O3 scandium oxide scandia SeBr4 selenium(IV) bromide SeCl selenium(I) chloride SeCl4 selenium(IV) chloride SeOCl2 selenium(IV) oxychloride SeOF2 selenyl difluoride SeO2 selenium(IV) oxide SeO42− selenate ion SeTe selenium(IV) telluride SiBr4 silicon(IV) bromide SiC silicon carbide 170 180 SiCl4 silicon(IV) chloride SiH4 silane SiI4 silicon(IV) iodide SiO2 silicon(IV) dioxide silica quartz SiO44− silicate ion Si2O76− disilicate ion Si3N4 silicon nitride Si6O1812− cyclosilicate ion SnBrCl3 tin(IV) bromotrichloride SnBr2 tin(II) bromide SnBr2Cl2 tin(IV) dibromodichloride SnBr3Cl tin(IV) tribromochloride SnBr4 tin(IV) bromide Sn(CH3COO)2 tin(II) acetate Sn(CH3COO)4 tin(IV) acetate SnCl2 tin(II) chloride SnCl2I2 tin(IV) dichlorodiiodide SnCl4 tin(IV) chloride Sn(CrO4)2 tin(IV) chromate SnI4 tin(IV) iodide Sn(OH)2 tin(II) hydroxide Sn(OH)4 tin(IV) hydroxide SnO tin(II) oxide SnO2 tin(IV) oxide SnO32− stannate ion SnS tin(II) sulfide SnS2 tin(IV) sulfide Sn(SO4)2·2H2O tin(IV) sulfate dihydrate SnSe tin(II) selenide SnSe2 tin(IV) selenide SnTe tin(II) telluride SnTe4 tin(IV) telluride Sn(VO3)2 tin(II) metavanadate Sn3Sb4 tin(IV) antimonide SrBr2 strontium bromide SrBr2·6H2O strontium bromide hexahydrate SrCO3 strontium carbonate SrCl2 strontium chloride Sr(ClO)2 strontium hypochlorite 171 181 Sr(ClO2)2 strontium chlorite Sr(ClO3)2 strontium chlorate Sr(ClO4)2 strontium perchlorate SrC2O4 strontium oxalate SrF2 strontium fluoride SrHfO3 strontium hafnate Sr(HS)2 strontium hydrosulfide SrI2 strontium iodide SrI2·6H2O strontium iodide hexahydrate Sr(IO)2 strontium hypoiodite Sr(IO2)2 strontium iodite Sr(IO3)2 strontium iodate Sr(IO4)2 strontium periodate Sr(MnO4)2 strontium permanganate SrMoO4 strontium orthomolybdate Sr(NbO3)2 strontium metaniobate SrO strontium oxide Sr(OH)2 strontium hydroxide Sr2RuO4 strontium ruthenate SrS strontium sulfide SrSeO3 strontium selenite SrSeO4 strontium selenate SrTeO3 strontium tellurite SrTeO4 strontium tellurate SrTiO3 strontium metatitanate T 2O tritium oxide tritiated water TaBr3 tantalum(III) bromide TaBr5 tantalum(V) bromide TaCl5 tantalum(V) chloride TaI5 tantalum(V) iodide TaO3− tantalate ion TcO4− pertechnetate ion TeBr2 tellurium(II) bromide TeBr4 tellurium(IV) bromide TeCl2 tellurium(II) chloride TeCl4 tellurium(IV) chloride TeI2 tellurium(II) iodide TeI4 tellurium(IV) iodide TeO2 tellurium(IV) oxide TeO4− tellurate ion 172 182 TeY yttrium telluride Th(CO3)2 thorium carbonate Th(NO3)4 thorium nitrate ThO2 thorium(IV) oxide Th(SO4)2 thorium(IV) sulfate TiBr4 titanium(IV) bromide TiCl2I2 titanium(IV) dichlorodiiodide TiCl3I titanium(IV) trichloroiodide TiCl4 titanium tetrachloride TiH2 titanium hydride TiO2 titanium dioxide rutile TiO32− titanate ion TlBr thallium(I) bromide TlBr3 thallium(III) bromide Tl(CHO2) thallium(I) formate TlC2H3O2 thallium(I) acetate Tl(C3H3O4) thalliium(I) malonate TlCl thallium(I) chloride TlCl3 thallium(III) chloride TlF thallium(I) fluoride TlI thallium(I) iodide TlIO3 thallium(I) iodate TlI3 thallium(III) iodide TiI4 titanium(IV) iodide TiO(NO3)2 · xH2O titanium(IV) oxynitrate hydrate TlNO3 thallium(I) nitrate TlOH thallium(I) hydroxide TlPF6 thallium(I) hexafluorophosphate TlSCN thallium thiocyanate Tl2MoO4 thallium(I) orthomolybdate Tl2SeO3 thallium(I) selenite Tl2TeO3 thallium(I) tellurite Tl2WO4 thallium(I) orthotungstate Tl3As thallium(I) arsenide TmCl3 thulium(III) chloride Tm(NO3)3 thulium(III) nitrate Tm2(SO4)3 thullium(III) sulfate UBr2 uranium dibromide UBr3 uranium tribromide UBr5 uranium pentabromide 173 183 UC2 uranium carbide UCl3 uranium trichloride UCl4 uranium tetrachloride UF4 uranium(IV) fluoride UF6 uranium(VI) fluoride UI3 uranium(III) iodide UN uranium nitride UO2 uranium dioxide UO2(CH3COO)2 uranyl acetate UO2Cl2 uranyl chloride UO2(HCOO)2 uranyl formate UO2(NO3)2 uranyl nitrate UO2SO4 uranyl sulfate UO3 uranium trioxide U 3O 8 triuranium octoxide USe2 uranium diselenide US2 uranium sulfide UTe2 uranium ditelluride VBr2 vanadium(II) bromide VBr3 vanadium(III) bromide VCl2 vanadium(II) chloride VCl3 vanadium(III) chloride VI3 vanadium(III) iodide VN vanadium nitride VOC2O4 vanadyl oxalate VOSO4 vanadium oxysulfate V 2O 3 vanadium(III) oxide V 2O 5 vanadium pentoxide V2O74− divanadate ion pyrovanadate ion WBr2 tungsten(II) bromide WBr3 tungsten(III) bromide WBr4 tungsten(IV) bromide WBr5 tungsten(V) bromide WBr6 tungsten(VI) bromide W(CO)6 tungsten(VI) carbonyl WCl2 tungsten(II) chloride WCl3 tungsten(III) chloride WCl4 tungsten(IV) chloride WCl5 tungsten(V) chloride WCl6 tungsten(VI) chloride 174 184 WF4 tungsten(IV) fluoride WF5 tungsten(V) fluoride WF6 tungsten(VI) fluoride WI2 tungsten(II) iodide WI4 tungsten(IV) iodide WOBr3 tungsten(V) oxytribromide WOBr4 tungsten(VI) oxytetrabromide WOCl3 tungsten(V) oxytrichloride WOCl4 tungsten(VI) oxytetrachloride WOF4 tungsten(VI) oxytetrafluoride WO2 tungsten(IV) oxide WO2Br2 tungsten(VI) dioxydibromide WO2Cl2 tungsten(VI) dioxydichloride WO2I2 tungsten(VI) dioxydiiodide WO3 tungsten(VI) oxide WO42− tungstate ion WS2 tungsten(IV) sulfide WS3 tungsten(VI) sulfide WSe2 tungsten(IV) selenide WTe2 tungsten(IV) telluride WC tungsten carbide YAs yttrium arsenide YB6 yttrium boride YBr3 yttrium bromide YC2 yttrium carbide YCl3 yttrium chloride YF3 yttrium fluoride YP yttrium phosphide YSb yttrium antimonide YVO4 yttrium vanadate Y 2O 3 yttria yttrium oxide Y 2S 3 yttrium sulfide YbBr2 ytterbium(II) bromide YbBr3 ytterbium(III) bromide YbCl2 ytterbium(II)chloride YbCl3 ytterbium(III) chloride YbCl3·6H2O ytterbium(III) chloride hexahydrate Yb(ClO4)3 ytterbium(III) perchlorate YbF2 ytterbium(II) fluoride YbF3 ytterbium(III) fluoride 175 185 YbI2 ytterbium(II) iodide YbI3 ytterbium(III) iodide YbPO4 ytterbium(III) phosphate YbSe ytterbium(II) selenide YbSi2 ytterbium(II) silicide Yb2O3 ytterbium(III) oxide Yb2S3 ytterbium(III) sulfide Yb2Se3 ytterbium(III) selenide YbTe ytterbium(II) telluride Zn(AlO2)2 zinc aluminate Zn(AsO2)2 zinc arsenite ZnBr2 zinc bromide Zn(CN)2 zinc cyanide ZnCO3 zinc carbonate Zn(C8H15O2)2 zinc caprylate Zn(ClO3)2 zinc chlorate ZnCl2 zinc chloride ZnCr2O4 zinc chromite ZnF2 zinc fluoride Zn(IO3)2 zinc iodate ZnI2 zinc iodide ZnMoO4 zinc orthomolybdate Zn(NO2)2 zinc nitrite Zn(NO3)2 zinc nitrate Zn(NbO3)2 zinc metaniobate ZnO zinc(II) oxide zinc oxide ZnO2 zinc peroxide Zn(OH)2 zinc hydroxide Zn(OH)42− zincate ion ZnS zinc sulfide sphalerite Zn(SCN)2 zinc thiocyanate Zn(SeCN)2 zinc selenocyanate ZnSO3 zinc sulfite ZnS2O3 zinc thiosulfate ZnSO4 zinc sulfate ZnSb zinc antimonide ZnSe zinc selenide ZnSeO3 zinc selenite ZnSeO4 zinc selenate 176 186 ZnSnO3 zinc stannate Zn(TaO3)2 zinc metatantalate ZnTe zinc telluride ZnTeO3 zinc tellurite ZnTeO4 zinc tellurate ZnTiO3 zinc metatitanate Zn(VO3)2 zinc metavanadate ZnWO4 zinc orthotungstate ZnZrO3 zinc metazirconate Zn2P2O7 zinc pyrophosphate Zn2SiO4 zinc orthosilicate Zn3(AsO4)2 zinc arsenate Zn3As2 zinc arsenide Zn3N2 zinc nitride Zn3P2 zinc phosphide Zn3(PO4)2 zinc phosphate Zn3Sb2 zinc antimonide ZrB2 zirconium boride ZrBr4 zirconium bromide ZrC zirconium carbide ZrCl4 zirconium tetrachloride ZrF4 zirconium fluoride ZrI4 zirconium iodide ZrN zirconium nitride Zr(NO3)4 zirconium(IV) nitrate Zr(OH)4 zirconium hydroxide ZrO2 zirconium dioxide baddeleyite ZrO32− zirconate ion ZrP2 zirconium phosphide ZrS2 zirconium sulfide ZrSi2 zirconium silicide ZrSiO4 zirconium(IV) silicate Zr(SO4)2 zirconium(IV) sulfate Zr3(PO4)4 zirconium phosphate Ten most common elements in the Milky Way Galaxy estimated spectroscopically 177 187 Atomic no Element Mass fraction (ppm) 1 Hydrogen 739,000 2 Helium 240,000 8 Oxygen 10,400 6 Carbon 4,600 10 Neon 1,340 26 Iron 1,090 7 Nitrogen 960 14 Silicon 650 12 Magnesium 580 16 Sulfur 440 Total 999,500 Most abundant nuclides in the Solar System Nuclide Atomic mass Mass fraction in parts Atom fraction in parts per million per million 178 188 Sulfur-32 32 396 16 Sodium-23 23 33 2 Silicon-30 30 23 1 Silicon-29 29 34 2 Silicon-28 28 653 30 Oxygen-16 16 9,592 477 Nitrogen-14 14 1,105 102 Nickel-58 58 49 1 Neon-22 22 208 12 Neon-20 20 1,548 100 Magnesium-26 26 79 4 Magnesium-25 25 69 4 Magnesium-24 24 513 28 Iron-57 57 28 1 Iron-56 56 1,169 27 Iron-54 54 72 2 179 189 Hydrogen-2 2 23 15 Hydrogen-1 1 705,700 909,964 Helium-4 4 275,200 88,714 Helium-3 3 35 15 Carbon-13 13 37 4 Carbon-12 12 3,032 326 Calcium-40 40 60 2 Argon-36 36 77 3 Aluminium-27 27 58 3 Electron configurations of the elements 1 H hydrogen: 1s1 2 He helium: 1s2 3 Li lithium: [He] 2s1 4 Be beryllium: [He] 2s2 5 B boron: [He] 2s2 2p1 180 190 6 C carbon: [He] 2s2 2p2 7 N nitrogen: [He] 2s2 2p3 8 O oxygen: [He] 2s2 2p4 9 F fluorine: [He] 2s2 2p5 10 Ne neon: [He] 2s2 2p6 11 Na sodium: [Ne] 3s1 12 Mg magnesium: [Ne] 3s2 13 Al aluminium: [Ne] 3s2 3p1 14 Si silicon: [Ne] 3s2 3p2 15 P phosphorus: [Ne] 3s2 3p3 16 S sulfur: [Ne] 3s2 3p4 17 Cl chlorine: [Ne] 3s2 3p5 18 Ar argon: [Ne] 3s2 3p6 19 K potassium: [Ar] 4s1 20 Ca calcium: [Ar] 4s2 181 191 21 Sc scandium: [Ar] 3d1 4s2 22 Ti titanium: [Ar] 3d2 4s2 23 V vanadium: [Ar] 3d3 4s2 24 Cr chromium: [Ar] 3d5 4s1 25 Mn manganese: [Ar] 3d5 4s2 26 Fe iron: [Ar] 3d6 4s2 27 Co cobalt: [Ar] 3d7 4s2 28 Ni nickel: [Ar] 3d8 4s2 or [Ar] 3d9 4s1 29 Cu copper: [Ar] 3d10 4s1 30 Zn zinc: [Ar] 3d10 4s2 31 Ga gallium: [Ar] 3d10 4s2 4p1 32 Ge germanium: [Ar] 3d10 4s2 4p2 33 As arsenic: [Ar] 3d10 4s2 4p3 34 Se selenium: [Ar] 3d10 4s2 4p4 35 Br bromine: [Ar] 3d10 4s2 4p5 182 192 36 Kr krypton: [Ar] 3d10 4s2 4p6 37 Rb rubidium: [Kr] 5s1 38 Sr strontium: [Kr] 5s2 39 Y yttrium: [Kr] 4d1 5s2 40 Zr zirconium: [Kr] 4d2 5s2 41 Nb niobium: [Kr] 4d4 5s1 42 Mo molybdenum: [Kr] 4d5 5s1 43 Tc technetium: [Kr] 4d5 5s2 44 Ru ruthenium: [Kr] 4d7 5s1 45 Rh rhodium: [Kr] 4d8 5s1 46 Pd palladium: [Kr] 4d10 47 Ag silver: [Kr] 4d10 5s1 48 Cd cadmium: [Kr] 4d10 5s2 49 In indium: [Kr] 4d10 5s2 5p1 50 Sn tin: [Kr] 4d10 5s2 5p2 183 193 51 Sb antimony: [Kr] 4d10 5s2 5p3 52 Te tellurium: [Kr] 4d10 5s2 5p4 53 I iodine: [Kr] 4d10 5s2 5p5 54 Xe xenon: [Kr] 4d10 5s2 5p6 55 Cs caesium: [Xe] 6s1 56 Ba barium: [Xe] 6s2 57 La lanthanum: [Xe] 5d1 6s2 58 Ce cerium: [Xe] 4f1 5d1 6s2 59 Pr praseodymium: [Xe] 4f3 6s2 60 Nd neodymium: [Xe] 4f4 6s2 61 Pm promethium: [Xe] 4f5 6s2 62 Sm samarium: [Xe] 4f6 6s2 63 Eu europium: [Xe] 4f7 6s2 64 Gd gadolinium: [Xe] 4f7 5d1 6s2 65 Tb terbium: [Xe] 4f9 6s2 184 194 66 Dy dysprosium: [Xe] 4f10 6s2 67 Ho holmium: [Xe] 4f11 6s2 68 Er erbium: [Xe] 4f12 6s2 69 Tm thulium: [Xe] 4f13 6s2 70 Yb ytterbium: [Xe] 4f14 6s2 71 Lu lutetium: [Xe] 4f14 5d1 6s2 72 Hf hafnium: [Xe] 4f14 5d2 6s2 73 Ta tantalum: [Xe] 4f14 5d3 6s2 74 W tungsten: [Xe] 4f14 5d4 6s2 75 Re rhenium: [Xe] 4f14 5d5 6s2 76 Os osmium: [Xe] 4f14 5d6 6s2 77 Ir iridium: [Xe] 4f14 5d7 6s2 78 Pt platinum: [Xe] 4f14 5d9 6s1 79 Au gold: [Xe] 4f14 5d10 6s1 80 Hg mercury: [Xe] 4f14 5d10 6s2 185 195 81 Tl thallium: [Xe] 4f14 5d10 6s2 6p1 82 Pb lead: [Xe] 4f14 5d10 6s2 6p2 83 Bi bismuth: [Xe] 4f14 5d10 6s2 6p3 84 Po polonium: [Xe] 4f14 5d10 6s2 6p4 85 At astatine: [Xe] 4f14 5d10 6s2 6p5 86 Rn radon: [Xe] 4f14 5d10 6s2 6p6 87 Fr francium: [Rn] 7s1 88 Ra radium: [Rn] 7s2 89 Ac actinium: [Rn] 6d1 7s2 90 Th thorium: [Rn] 6d2 7s2 91 Pa protactinium: [Rn] 5f2 6d1 7s2 92 U uranium: [Rn] 5f3 6d1 7s2 93 Np neptunium: [Rn] 5f4 6d1 7s2 94 Pu plutonium: [Rn] 5f6 7s2 95 Am americium: [Rn] 5f7 7s2 186 196 96 Cm curium: [Rn] 5f7 6d1 7s2 97 Bk berkelium: [Rn] 5f9 7s2 98 Cf californium: [Rn] 5f10 7s2 99 Es einsteinium: [Rn] 5f11 7s2 100 Fm fermium: [Rn] 5f12 7s2 101 Md mendelevium: [Rn] 5f13 7s2 102 No nobelium: [Rn] 5f14 7s2 103 Lr lawrencium: [Rn] 5f14 7s2 7p1 104 Rf rutherfordium: [Rn] 5f14 6d2 7s2 105 Db dubnium: [Rn] 5f14 6d3 7s2 106 Sg seaborgium: [Rn] 5f14 6d4 7s2 107 Bh bohrium: [Rn] 5f14 6d5 7s2 108 Hs hassium: [Rn] 5f14 6d6 7s2 109 Mt meitnerium: [Rn] 5f14 6d7 7s2 110 Ds darmstadtium: [Rn] 5f14 6d8 7s2 187 197 111 Rg roentgenium: [Rn] 5f14 6d9 7s2 112 Cn copernicium: [Rn] 5f14 6d10 7s2 113 Nh nihonium: [Rn] 5f14 6d10 7s2 7p1 114 Fl flerovium: [Rn] 5f14 6d10 7s2 7p2 115 Mc moscovium: [Rn] 5f14 6d10 7s2 7p3 116 Lv livermorium: [Rn] 5f14 6d10 7s2 7p4 117 Ts tennessine: [Rn] 5f14 6d10 7s2 7p5 118 Og oganesson: [Rn] 5f14 6d10 7s2 7p6 119 Uue ununennium: [Og] 8s1 120 Ubn unbinilium: [Og] 8s2 121 Ubu unbiunium: [Og] 8s2 8p1 122 Ubb unbibium: [Og] 7d1 8s2 8p1 123 Ubt unbitrium: [Og] 6f1 7d1 8s2 8p1 124 Ubq unbiquadium: [Og] 6f3 8s2 8p1 125 Ubp unbipentium: [Og] 5g1 6f3 8s2 8p1 188 198 126 Ubh unbihexium: [Og] 5g2 6f2 7d1 8s2 8p1 127 Ubs unbiseptium: [Og] 5g3 6f2 8s2 8p2 128 Ubo unbioctium: [Og] 5g4 6f2 8s2 8p2 129 Ube unbiennium: [Og] 5g5 6f2 8s2 8p2 130 Utn untrinilium: [Og] 5g6 6f2 8s2 8p2 131 Utu untriunium: [Og] 5g7 6f2 8s2 8p2 132 Utb untribium: [Og] 5g8 6f2 8s2 8p2 133 Utt untritrium: [Og] 5g8 6f3 8s2 8p2 134 Utq untriquadium: [Og] 5g8 6f4 8s2 8p2 135 Utp untripentium: [Og] 5g9 6f4 8s2 8p2 136 Uth untrihexium: [Og] 5g10 6f4 8s2 8p2 137 Uts untriseptium: [Og] 5g11 6f3 7d1 8s2 8p2 138 Uto untrioctium: [Og] 5g12 6f3 7d1 8s2 8p2 139 Ute untriennium: [Og] 5g13 6f2 7d2 8s2 8p2 140 Uqn unquadnilium: [Og] 5g14 6f3 7d1 8s2 8p2 189 199 141 Uqu unquadunium: [Og] 5g15 6f2 7d2 8s2 8p2 142 Uqb unquadbium: [Og] 5g16 6f2 7d2 8s2 8p2 143 Uqt unquadtrium: [Og] 5g17 6f2 7d2 8s2 8p2 144 Uqq unquadquadium: [Og] 5g18 6f1 7d3 8s2 8p2 145 Uqp unquadpentium: [Og] 5g18 6f3 7d2 8s2 8p2 146 Uqh unquadhexium: [Og] 5g18 6f4 7d2 8s2 8p2 147 Uqs unquadseptium: [Og] 5g18 6f5 7d2 8s2 8p2 148 Uqo unquadoctium: [Og] 5g18 6f6 7d2 8s2 8p2 149 Uqe unquadennium: [Og] 5g18 6f6 7d3 8s2 8p2 150 Upn unpentnilium: [Og] 5g18 6f6 7d4 8s2 8p2 151 Upu unpentunium: [Og] 5g18 6f8 7d3 8s2 8p2 152 Upb unpentbium: [Og] 5g18 6f9 7d3 8s2 8p2 153 Upt unpenttrium: [Og] 5g18 6f11 7d2 8s2 8p2 154 Upq unpentquadium: [Og] 5g18 6f12 7d2 8s2 8p2 155 Upp unpentpentium: [Og] 5g18 6f13 7d2 8s2 8p2 190 200 156 Uph unpenthexium: [Og] 5g18 6f14 7d2 8s2 8p2 157 Ups unpentseptium: [Og] 5g18 6f14 7d3 8s2 8p2 158 Upo unpentoctium: [Og] 5g18 6f14 7d4 8s2 8p2 159 Upe unpentennium: [Og] 5g18 6f14 7d4 8s2 8p2 9s1 160 Uhn unhexnilium: [Og] 5g18 6f14 7d5 8s2 8p2 9s1 161 Uhu unhexunium: [Og] 5g18 6f14 7d6 8s2 8p2 9s1 162 Uhb unhexbium: [Og] 5g18 6f14 7d8 8s2 8p2 163 Uht unhextrium: [Og] 5g18 6f14 7d9 8s2 8p2 164 Uhq unhexquadium: [Og] 5g18 6f14 7d10 8s2 8p2 165 Uhp unhexpentium: [Og] 5g18 6f14 7d10 8s2 8p2 9s1 166 Uhh unhexhexium: [Og] 5g18 6f14 7d10 8s2 8p2 9s2 167 Uhs unhexseptium: [Og] 5g18 6f14 7d10 8s2 8p2 9s2 9p1 168 Uho unhexoctium: [Og] 5g18 6f14 7d10 8s2 8p2 9s2 9p2 169 Uhe unhexennium: [Og] 5g18 6f14 7d10 8s2 8p3 9s2 9p2 170 Usn unseptnilium: [Og] 5g18 6f14 7d10 8s2 8p4 9s2 9p2 191 201 171 Usu unseptunium: [Og] 5g18 6f14 7d10 8s2 8p5 9s2 9p2 172 Usb unseptbium: [Og] 5g18 6f14 7d10 8s2 8p6 9s2 9p2 173 Ust unsepttrium: [Usb] 6g1 Reactivity series Metal Ion Caesium Cs Cs+ Francium Fr Fr+ Rubidium Rb Rb+ Potassium K K+ Sodium Na Na+ Lithium Li Li+ Barium Ba Ba2+ Radium Ra Ra2+ Strontium Sr Sr2+ Calcium Ca Ca2+ Magnesium Mg Mg2+ Reactivity Extraction reacts with cold water electrolysis reacts very slowly with cold water, but rapidly 192 202 in boiling water, and very vigorously with acids Beryllium Be Be2+ reacts with acids and steam Aluminium Al Al3+ Titanium Ti Ti4+ reacts with concentrated mineral acids pyrometallurgical extraction using magnesium, or less commonly other alkali metals, hydrogen or calcium in the Kroll process Manganese Mn Mn2+ reacts with acids; very poor reaction with steam smelting with coke Zinc Zn Zn2+ Chromium Cr Cr3+ aluminothermic reaction Iron Fe Fe2+ smelting with coke Cadmium Cd Cd2+ Cobalt Co Co2+ Nickel Ni Ni2+ Tin Sn Sn2+ Lead Pb Pb2+ Antimony Sb Sb3+ Bismuth Bi Bi3+ Copper Cu Cu2+ may react with some strong oxidizing acids reacts slowly with air 193 203 heat or physical extraction Tungsten W W3+ may react with some strong oxidizing acids Mercury Hg Hg2+ Silver Ag Ag+ Gold Au Au3+[5][6] Platinum Pt Pt4+ The four fundamental interactions of nature Property/ Interaction Mediating particles Gravitation Electroweak Strong Weak Electromagnetic Fundamental Residual Not yet observed W+, W− and γ (photon) Gluons π, ρ and ω (Graviton Z0 mesons hypothesized) Affected particles All particles Left- handed Electrically charged Quarks, gluons Hadrons fermions Acts on Mass, energy Flavor Electric charge Color charge Bound states formed Planets, stars, n/a Atoms, molecules Hadrons Atomic nuclei galaxies, galaxy groups Strength at the scale 10−41 10−4 1 194 204 60 Not of quarks (predicted) applicable (relative to to quarks electromagnetism) Strength at the scale 10−36 (predicted) 10−7 1 of Not applicable to hadrons protons/neutrons (relative to electromagnetism) Formulas in Chemistry  Ideal Gas Law The ideal gas law is given by: PV = nRT where: P: the absolute pressure of the gas V: volume of the gas n: number of moles, which is the ratio of mass and molar mass R: universal gas constant, which is R = 8.3145 J mol−1 K−1 T: the absolute temperature  Henry's Law Henry's law is given by: p=K· x where: p: partial pressure of the solute K: Henry's constant  Raoult's Law 195 205 20 Raoult's law is given by: pi = xi ∙ pi* where: pi : pressure of component i xi : mole fraction in the solution pi *: vapor pressure of the pure substance i In a solution with two liquids A and B, if no gas are present, the total vapor pressure is given by: Ptot = PA + PB where: PA: vapor pressure of liquid A PB: vapor pressure of liquid B For an ideal solution of liquids A and B, which obeys Raoult's law over the full range of composition. The total pressure is given by: ptot = xA pA* + xB pB* which is equal to: ptot = (1− xB) pA* + xB pB* or ptot = pA* + xB (pB*− pA*)  Hess' Law Hess' Law can be expressed in 3 ways and they are: For enthalpy we have: ∆H = ∑ ∆Hproducts − ∑ ∆Hreactants For entropy we have: ∆S = ∑ ∆Sproducts − ∑ ∆Sreactants 196 206 For Gibbs' free energy we have: ∆G = ∑ ∆GOproducts − ∑ ∆GOreactants  Acid and Base For a chemical reaction: A + H2O ↔ H3O+ + B where: A: acid B: base To determine the strength of the acid, we use the acid dissociation constant, which is given by: KA = For a chemical reaction: [H3 O+ ][B] [A] B + H2O ↔ A + HO− where: A: acid B: base To determine the strength of the base, we use the base dissociation constant, which is given by: KB =  [OH− ][A] [B] pH pH = −log10[H+] H2O ↔ H+ + OH− 197 207 The dissociation constant: K= [H+ ][OH− ] Here [H2O] is constant, So, K [H2O] = [H+] [OH−] = Kw [H2 O] Kw is an ionic product of water and its value is 1×10−14 at 25°C. [H+] [OH−] = 1×10−14 Pure water dissociates completely and has equal concentration. Thus [H+] = [OH−] [H+] [H+] = 1×10−14 [H+] = 10−7 pH = 7 Thus, pure water is a neutral solution having pH equal to 7.0. Acidic soution pH < 7 Basic solution pH > 7  Types of Chemical Reaction Synthesis In a synthesis reaction, two or more simple substances combine to form a more complex substance. A+B → AB "Two or more reactants giving one product" is another way to identify a synthesis reaction. One example of a synthesis reaction is the combination of iron and sulfur to form iron (II) sulfide: 8Fe + S8→ 8FeS 198 208 Another example is simple hydrogen gas combined with simple oxygen gas to produce a more complex substance, such as water. Decomposition A decomposition reaction is when a more complex substance breaks down into its more simple parts. It is thus the opposite of a synthesis reaction, and can be written as: AB → A+B One example of a decomposition reaction is the electrolysis of water to make oxygen and hydrogen gas: 2H2O → 2H2 +O2 Single replacement In a single replacement reaction, a single uncombined element replaces another in a compound; in other words, one element trades places with another element in a compound. These reactions come in the general form of: A+BC → AC+B One example of a single displacement reaction is when magnesium replaces hydrogen in water to make magnesium hydroxide and hydrogen gas: Mg+2H2O →Mg (OH) 2 +H2 Double replacement In a double replacement reaction, the anions and cations of two compounds switch places and form two entirely different compounds. These reactions are in the general form: AB + CD → AD + CB For example, when barium chloride (BaCl2) and magnesium sulfate (MgSO4) react, the SO4 2− anion switches places with the 2Cl− anion, giving the compounds BaSO4 and MgCl2. Another example of a double displacement reaction is the reaction of lead(II) nitrate with potassium iodide to form lead(II) iodide and potassium nitrate: Pb (NO3) 2 + 2KI → PbI2 +2KNO3 199 209 experimental value – theoretical value  Percent difference from theoretical value =  magnification = power of ocular lens × power of objective lens  molar concentration =  number of moles =  percent by volume concentration =  parts per million = theoretical value × 100% number of moles (mol) volume (L) mass (g) molar mass ( 𝑚𝑠𝑜𝑙𝑢𝑡𝑒 𝑚𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛 g ) mol 𝑉𝑠𝑜𝑙𝑢𝑡𝑒 × 100% 𝑉𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛 × 106 ppm 1 amu = 1.66054 × 10−27 kg = 931.494 MeV/c2 1 MeV = 1.60 × 10−13 J Particle Electric Atomic Charge (C) Charge Protons +1.6022 × 10-19 +1 1.6726 × 10-24 1.0073 1/2 Neutrons 0 0 1.6740 × 10-24 1.0078 1/2 Electrons -1.6022 × 10-19 -1 9.1094 × 10-28 0.00054858 1/2 200 210 Mass (g) Atomic Mass Spin (Au)  Enthalpy Formula Enthalpy is a thermodynamic function that is equal to the total internal energy of the system plus the product of pressure and volume. The equation is as follows: H = E + PV where H is the enthalpy, E is the energy and PV is the pressure multiplied by the volume.  Molality Formula Molality (m) =  Molar Mass Formula moles of solute kilograms of solvent Molar mass =  mass (grams) Molarity Formula Molarity (M) =  moles moles of solute Liters of solution Structural Formula Substance Chemical Formula Structural Formula Methane CH4 H | H−C–H | H Carbon Dioxide  CO2 O=C=O Chemical Equilibrium Formula Equilibrium Constant (K): K= rate constant of forward reaction rate constant of backward reaction 201 211 = 𝑘1 𝑘2 Equilibrium constant in terms of concentration (KC) is given by KC = 𝑘1 𝑘2 = [𝐶]𝑐 [𝐷]𝑑 [𝐴]𝑎 [𝐵]𝑏 Equilibrium constant in the terms of partial pressure (KP) is given by KP = 𝑘1 𝑘2 = [𝑃𝐶 ]𝑐 [𝑃𝐷 ]𝑑 [𝑃𝐴 ]𝑎 [𝑃𝐵 ]𝑏 The equilibrium constant is in terms of mole fraction (Kx) is given by Kx = 𝑘1 𝑘2 = [𝑥𝐶 ]𝑐 [𝑥𝐷 ]𝑑 [𝑥𝐴 ]𝑎 [𝑥𝐵 ]𝑏 The Relation between KP and KC is given by KP = KC (RT) ∆n where: Δn = (c + d) − (a + b) Relation between equilibrium constant and standard free energy change ΔG° = −2.303 RT log K where: ΔG° = standard free energy change 202 212 T = Absolute temperature R = universal gas constant.  Normality Formula Normality (N) = gram equivalent weight liter of solution Normality (N) = Molarity (M) × number of equivalents  Photosynthesis Formula 6CO2 + 6H2O + light → C6H12O6 + 6O2  Boyle's Law Formula P1V1 = P2V2 where: P1 = Initial Pressure (atm or mmHg) V1 = Initial Volume (L or mL) P2 = Final Pressure (atm or mmHg) V2 = Final Volume (L or mL)  Titration Formula Macid × Vacid = Mbase × Vbase where: Macid = Molarity of the acid Vacid = Volume of the acid Mbase = Molarity of the base Vbase = Volume of the base  Charles' Law Formula 203 213 𝑉1 𝑉2 = 𝑇1 𝑇2 where: T1 = Initial Temperature (Kelvin - K) V1 = Initial Volume (L or mL) T2 = Final Temperature (Kelvin - K) V2 = Final Volume (L or mL)  Gay-Lussac's Law Formula 𝑃2 𝑃1 = 𝑇2 𝑇1 where: T1 = Initial Temperature (Kelvin - K) P1 = Initial Pressure (atm or mmHg) T2 = Final Temperature (Kelvin - K) P2 = Final Pressure (atm or mmHg)  Dilution Formula M1 × V1 = M2 × V2 where: M1 = the molarity of the original solution V1 = the volume of the original solution M2 = the molarity of the diluted solution V2 = the volume of the diluted solution  Heat of Fusion Formula Hf = 𝑞 𝑚 where: 204 214 Hf = heat of fusion q = heat m = mass  Heat of Vaporization Formula 𝑞 Hv = 𝑚 where: Hv = heat of vaporization q = heat m = mass  Lattice Energy Formula LE = 𝑘𝑄1 𝑄2 𝑟 LE = lattice energy k = 2.31 × 10−19 J ∙ nm Q1 and Q2 = numerical ion charges r = the distance between the ion centers  Mass Percent Formula Mass percent =  𝑔𝑟𝑎𝑚𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒 𝑔𝑟𝑎𝑚𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛 × 100 Mole Fraction Formula Mole fraction (xa) = 205 215 moles of a total moles a = the component that is being identified for mole fraction  Osmotic Pressure Formula Osmotic pressure (π) = MRT M = the molar concentration of the solution R = the gas laws constant (0.0821 T = the Kelvin temperature  L∙atm ) K∙mol Electric Potential Energy Formula Eel = 𝑘𝑄1 𝑄2 𝑑 Eel = electrostatic potential energy k = 8.99 × 109 J−m C2 Q1 and Q2 = electrical charges on the two particles d = the distance between the charges  Percent Composition Formula % composition =  𝑔𝑟𝑎𝑚𝑠 𝑜𝑓 𝑒𝑙𝑒𝑚𝑒𝑛𝑡 𝑔𝑟𝑎𝑚𝑠 𝑜𝑓 𝑐𝑜𝑚𝑝𝑢𝑛𝑑 Rate of Decay Formula Nt = N0 e−λt 206 216 × 100 Nt = the amount of radioactive particles at time (t) N0 = the amount of radioactive particles at time = 0 λ = rate of decay constant t = time  Specific Heat Capacity Formula s= s = specific heat capacity 𝑞 𝑚 × ∆𝑇 q = heat m = mass Δ T = change in temperature  Vapor Pressure Formula Psolution = xsolvent × Posolvent Psolution = the vapor pressure of the solution xsolvent = the mole fraction of the solvent in the solution Posolvent = the vapor pressure of the pure solvent at standard conditions  Degree of unsaturation Formula Degrees of unsaturation = (2 × #𝐶) + 2 + #𝑁 −#𝐻 −#𝑋 2 where #C, #N, #H, #X mean the number of carbon, nitrogen, hydrogen and halogen atoms present in the molecular formula.  Arrhenius equation 207 217 −𝐸𝑎 k = A 𝑒 𝑅𝑇 where: A is the pre-exponential factor for the reaction (that is nearly a constant that depends on the temperature), Ea is the activation energy, R is the gas constant, T is the temperature and k is the reaction rate constant.  Boiling point Formula ΔHvap = Hvapor − Hliquid where: ΔHvap is the change of enthalpy of vaporization, H vapor is the enthalpy or heat of the gas state of a compound and Hliquid is the enthalpy of the liquid state of a compound.  Avogadro's law Formula V=k×n where: V is the gas volume, n is the number of moles of gas and k is a constant, which is defined as 𝑅𝑇 𝑃 , where R is a constant called the constant of the gases (8.314 JK−1 mol−1), T is the temperature in Kelvin and P is the pressure.  Dalton's law Formula For a mixture of n gases, the total pressure is: Ptotal =P1 + P2 + P3 + ... + Pn where P1, P2, P3 ... Pn represent the partial pressure of each gas in the mixture.  Ionic strength formula 208 218 Ionic strength (I) = where: 1 2 ∑𝑛1 𝐶𝑖 𝑧𝑖2 Ci – ionic concentration Zi – ion charges Calculate the ionic strength of KCl if its concentration is 2 M. Ions Z C Z2 K+ 1 2 1 Cl– 1 2 1 The ionic strength is given by I=  1 2 [(2 × 1) + (2 × 1)] = 2 Percent by volume Formula % volume =  𝑣𝑜𝑙𝑢𝑚𝑒𝑠𝑜𝑙𝑢𝑡𝑒 𝑣𝑜𝑙𝑢𝑚𝑒𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛 × 100% pOH pOH = − log [OH−] For any aqueous solution at 25oC: pH + pOH = 14  Complete List of Inorganic Acids Acid Name Formula Acetic Acid CH3COOH 209 219 Antimonic Acid HSbO3 Antimonous Acid H3SbO3 Arsenic Acid H3AsO4 Boric Acid H3BO3 Bromic Acid HBrO3 Bromous Acid HBrO2 Carbonic Acid H2CO3 Carbonous Acid H2CO2 Chloric Acid HClO3 Chlorous Acid HClO2 Chromic Acid H2CrO4 Chromous Acid H2CrO3 Citric Acid C6H8O7 Cyanic Acid HCNO Dichromic Acid H2Cr2O7 Disulfurous Acid H2S2O5 Dithionous Acid H2S2O4 Diuranic Acid H2U2O7 Ferricyanic Acid H3[F3(CN)6] Fluoric Acid HFO3 Fluorous Acid HFO2 Formic Acid HCOOH Hydroarsenic Acid H3As Hydrobromic Acid HBr Hydrochloric Acid HCl Hydrocyanic Acid HCN Hydrofluoric Acid HF Hydroiodic Acid HI Hydronitric Acid HN3 Hydrophosphoric Acid H3P Hydroselenic Acid H2Se Hydrosulfuric Acid H2S Hypobromous Acid HBrO Hypocarbonous Acid H2CO Hypochlorous Acid HClO Hypochromous Acid H2CrO2 Hypofluorous Acid HFO 210 220 Hypoiodous Acid HIO Hyponitrous Acid HNO Hypooxalous Acid H2C2O2 Hypophosphoric Acid H4P2O6 Hypophosphous Acid H3PO2 Hyposulfurous Acid H2SO2 Iodic Acid HIO3 Iodous Acid HIO2 Manganic Acid H2MnO4 Metastannic Acid H2SnO3 Molybdic Acid H2MoO4 Nitric Acid HNO3 Nitrous Acid HNO2 Oxalic Acid H2C2O4 Percarbonic Acid H2CO4 Perchloric Acid HClO4 Perchromic Acid H2CrO5 Perfluoric Acid HFO4 Periodic Acid HIO4 Permanganic Acid HMnO4 Pernitric Acid HNO4 Peroxydisulfuric Acid H2S2O8 Perphosphoric Acid H3PO5 Persulfuric Acid H2SO5 Pertechnetic Acid HTcO4 Perxenic Acid H4XeO6 Phosphoric Acid H3PO4 Phosphorous Acid H3PO3 Pyroantimonic Acid H4Sb2O7 Pyrophosphoric Acid H4P2O7 Pyrosulfuric Acid H2S2O7 Selenic Acid H2SeO4 Selenous Acid H2SeO3 Silicic Acid H2SiO3 Silicofluoric Acid H2SiF6 Silicous Acid H2SiO2 Sulfuric Acid H2SO4 211 221  Sulfurous Acid H2SO3 Telluric Acid H6TeO6 Tellurous Acid H2TeO3 Tetraboric Acid H2B4O7 Tetrathionic Acid H2S4O6 Thiocyanic Acid HSCN Thiosulfurous Acid H2S2O2 Titanic Acid H2TiO3 Tungstic Acid H2WO4 Uranic Acid H2UO4 Xenic Acid H2XeO4 Complete List of Organic Acids Acid Name Formula Acetylsalicylic Acid HC9H7O4 Ascorbic Acid HC6H7O6 Azelaic Acid H2C9H14O4 Barbituric Acid HC4H3N2O3 Benzilic Acid HC14H11O3 Cinnamic Acid C9H8O2 Citric Acid H2C6H6O7 Folic Acid C19H19N7O6 Fumaric Acid C4H4O4 Gallic Acid HC7H5O5 Gluconic Acid C6H12O7 Glutamic Acid HC5H8NO4 Glutaric Acid C5H8O4 Hexanoic Acid C5H11COOH Lactic Acid HC3H5O3 Malic Acid H2C4H4O5 Malonic Acid CH2(COOH)2 Oleic Acid HC18H33O2 Phthalic Acid H2C8H4O4 Propiolic Acid HC2COOH 212 222 Propionic Acid CH3CH2COOH Rosolic Acid C19H14O3 Stearic Acid C17H35COOH Tannic Acid C76H52O46 Tartartic Acid H2C4H4O6 Trifluoroacetic Acid C2HF3O2 Uric Acid H2C5H2N4O3 Physics Formulas  Acceleration Formula a= 𝑣𝑓 − 𝑣𝑖 𝑡 a = acceleration (m/s2) = ∆𝑣 𝑡 vf = the final velocity (m/s) vi = the initial velocity (m/s) t = the time in which the change occurs (s) Δv = short form for "the change in" velocity (m/s)  Force Formula Force = mass × acceleration F=m×a  Frequency Formula Frequency, the cycles in a unit of time = Frequency =  𝟏 period, the time required for one cycle number of cycles 𝑡𝑖𝑚𝑒 Velocity Formula Velocity = 𝑓𝑖𝑛𝑎𝑙 𝑝𝑜𝑠𝑖𝑡𝑖𝑜𝑛−𝑖𝑛𝑖𝑡𝑖𝑎𝑙 𝑝𝑜𝑠𝑖𝑡𝑖𝑜𝑛 𝑡𝑖𝑚𝑒 213 223 = 𝑐ℎ𝑎𝑛𝑔𝑒 𝑖𝑛 𝑡ℎ𝑒 𝑝𝑜𝑠𝑖𝑡𝑖𝑜𝑛 𝑡𝑖𝑚𝑒  Wavelength Formula Wavelength =  frequency Angular Velocity Formula Angular velocity =  wave velocity 𝑓𝑖𝑛𝑎𝑙 𝑎𝑛𝑔𝑙𝑒 − 𝑖𝑛𝑖𝑡𝑖𝑎𝑙 𝑎𝑛𝑔𝑙𝑒 𝑡𝑖𝑚𝑒 = 𝑐ℎ𝑎𝑛𝑔𝑒 𝑖𝑛 𝑝𝑜𝑠𝑖𝑡𝑖𝑜𝑛 𝑡𝑖𝑚𝑒 Displacement Formula Displacement = (final position) − (initial position) = change in position  Density Formula Density =  mass volume Kinematic Equations Formula 1 D = vi t + at2 2 vf 2 = vi 2 + 2aD vf = vi + at D = displacement a = acceleration t = time vf = final velocity vi = initial velocity 214 224 The heaviest element is a hard, brittle, bluish-white transition metal in the platinum group (osmium) Approximately 20% of our body is carbon. Lightning can reach temperature greater than 30,000 degrees Celsius. The hardest substance in the human body is enamel (made mostly of an extremely hard mineral called calcium phosphate) Rotten eggs float in water Glass is an amorphous solid that lacks an ordered internal structure Water is blue because it absorbs colors in the red part of the light spectrum Dry ice is the solid form of carbon dioxide (CO2) If we were to urinate in space, it would vaporize and turn into a gas immediately 215  Tangential Velocity Formula Vt = ω r Vt = tangential velocity ω = angular velocity r = radius of wheel  Kinetic Energy Formula 1 Ek = mv2 2 Ek = Kinetic energy m = mass v = velocity  Buoyancy Formula Fb = ρgV = ρghA Fb = buoyant force of a liquid acting on an object (N) ρ = density of the liquid (kg/m3) g = gravitational acceleration (9.8 m/s2) V = volume of liquid displaced (m3 or liters, where 1 m3 = 1000 L) h = height of water displaced by a floating object (m) A = surface area of a floating object (m2)  Efficiency Formula Efficiency =  Static Friction Formula 𝑒𝑛𝑒𝑟𝑔𝑦 𝑜𝑢𝑡𝑝𝑢𝑡 𝑒𝑛𝑒𝑟𝑔𝑦 𝑖𝑛𝑝𝑢𝑡 Fs ≤ μs η Fsmax = μs η 216 225 × 100% Fs = force of static friction μs = coefficient of static friction η = normal force Fsmax = maximum force of static friction  Potential Energy: Elastic Formula 1 U = kx2 2 U = potential energy of a spring at a certain position k = the spring constant, specific to the spring, with units N/m. x = distance the spring is stretched or compressed away from equilibrium  Tangential Acceleration Formula Tangential acceleration = radius of the rotation × angular acceleration  Potential Energy: Earth's Gravity Formula Potential energy = mass of the object × acceleration due to gravity × height  Potential Energy: Electric Potential Formula Potential energy = charge of particle × electric potential  Potential Energy: Two-Body Gravitation Formula U=− 𝐺𝑚1 𝑚2 217 226 𝑟 U = potential energy of gravity between two objects G = the universal gravitational constant, G = 6.673 × 10−11 (Nm2) / kg2 m1 = mass of one of the objects m2 = mass of the second object r = the distance between the centers of mass of the two objects  Potential Energy: Electrostatic Point Particles Formula U=−k 𝑞1 𝑞2 𝑟 U = potential energy of electrostatic point particles k = the Coulomb constant, k = 8.99 × 109 Nm2/C2 = 1 4𝜋𝜀0 ϵ0 = the permittivity of free space, ϵ0 = 8.854 x 10−12 C2/ (Nm2) q1 = charge of one of the point particles q2 = charge of the other point particle r = distance between the two point charges  Doppler Shift Formula f= f = frequency heard by listener 𝑓𝑠 (𝑣+ 𝑣𝐿 ) (𝑣 − 𝑣𝐿 ) for sound fs = frequency of the source v = velocity of sound vs = velocity of the source (positive if moving towards listener, negative if moving away from listener) vL = velocity of listener (positive if moving toward the source, negative if moving away from the source)  Current Density Formula J= I A 218 227 J = current density in amperes/m2 I = current through a conductor (in amperes) A = cross-sectional area of the conductor (m2)  Heat Transfer Formula Heat transfer = mass × specific heat × temperature change  Centripetal Force Formula Fc = 𝑚𝑣 2 𝑟 Fc = centripetal force m = mass v = velocity r = radius of circular path  Kelvin to Celsius Formula K = °C + 273.15 K = temperature, Kelvin °C = temperature, degrees Celsius (Centigrade)  Acceleration Due to Gravity Formula g= 𝐺𝑚 𝑟2 g = acceleration due to gravity (units m/s2) G = the universal gravitational constant, G = 6.673 ×10−11 (Nm2) / kg2 219 228 m = mass of a large body (for example, Earth) r = the distance from the center of mass of the large body  Momentum Formula Momentum = mass × velocity  Power Formula Power =  𝑡𝑖𝑚𝑒 𝑖𝑛𝑡𝑒𝑟𝑣𝑎𝑙 Specific Gravity Formula Specific gravity =  𝑤𝑜𝑟𝑘 𝑑𝑜𝑛𝑒 density of the substance density of water at 4.0°C Torque Formula (Moment of Inertia and Angular Acceleration) Torque = moment of inertia × angular acceleration  Spring Constant Formula F = −kx F = restoring force of the spring (directed toward equilibrium) k = spring constant (units N/m) x = displacement of the spring from its equilibrium position  Amplitude Formula x = A sin (ωt + ϕ) 220 229 x = displacement (m) A = amplitude (m) ω = angular frequency (radians/s) t = time (s) ϕ = phase shift (radians)  Torque Formula (Force at a Distance) Torque = (distance between a center of rotation and a force) × force  Tension Formula T = mg + ma T = tension, N, kg-m/s2 m = mass, kg g = gravitational force, 9.8 m/s2 a = acceleration, m/s2  Centripetal Acceleration Formula ac = 𝑣2 𝑟 ac = centripetal acceleration v = velocity r = radius of circular path  Impulse Formula Impulse = Force × time  Capacitance Formula 221 230 C= Q V C = capacitance (Farads, F) Q = the charge built up on the capacitor (Coulombs, C) V = voltage difference between two sides of a capacitor (Volts, V)  Distance Speed Time Formula Distance = speed × time  Orbital Velocity Formula vorbit = √ GM R G = gravitational constant, M = mass of the body at centre, R = radius of the orbit.  Resistance Formula R= V I R = resistance (Ohms, Ω) V = voltage difference between the two ends of a resistor (Volts, V) I = the current flowing through a resistor (Amperes, A) 222 231  Reynold's Number Formula Reynold's Number = Reynold's Number =  inertial force viscous force density × velocity ×diameter viscosity Angular Momentum Formula Angular momentum = (distance from the center of rotation) × linear momentum  Unit Vector Formula Unit vector =  vector magnitude of the vector Work Formula W = Fd cosθ W = work (units J) F = force (units N) d = distance (m) θ = the angle between the force direction and movement direction  Air Resistance Formula F = kv2 = 𝜌 𝐶𝐷 𝐴 223 232 2 v2 F = force due to air resistance, or drag (N) k = a constant that collects the effects of density, drag, and area (kg/m) v = the velocity of the moving object (m/s) ρ = the density of the air the object moves through (kg/m3) CD = the drag coefficient, includes hard-to-measure effects (unitless) A = the area of the object the air presses on (m2)  Angular Momentum Formula (Moment of Inertia and Angular Velocity) Angular Momentum = moment of inertia × angular velocity  Center of Mass Formula Center of Mass =  sum of all (position × mass) sum of all masses Flow Rate Formula Q = Av Q = liquid flow rate (m3/s or L/s) A = area of the pipe or channel (m2) v = velocity of the liquid (m/s)  Stopping Distance Formula d= 𝑣2 2𝜇𝑔 d = stopping distance (m) v = velocity of the car (m/s) μ = coefficient of friction (unitless) g = acceleration due to gravity (9.8 m/s2) 224 233  Escape Velocity Formula G = universal gravitational constant escape velocity = √ 2𝐺𝑀 𝑅 M = mass of the planet (kg) R = radius of the planet (m)  Inelastic Collision Formula (mass of object 1) (initial velocity 1) + (mass of object 2) (initial velocity 2) = (mass of object 1 + mass of object 2) (final velocity of combined objects)  Newton's Law of Cooling Formula T(t) = Ts + (T0 - Ts) e−kt T(t) = temperature of an object at a certain time (Kelvin, K) t = time (s) Ts = temperature of the surroundings (Kelvin, K) T0 = starting temperature of the object (Kelvin, K) k = a cooling constant, specific to the object (1/s)  Pressure Formula 𝐹 Pressure = , where F is a force, and A is the area it acts on. 𝐴 P = ρgh P = pressure (Pa) ρ = density of a gas or fluid (kg/m3) g = acceleration due to gravity (9.8 m/s2) h = the height of a column of gas or fluid (m) 225 234  De Broglie Wavelength Formula de Broglie wavelength =  The Planck constant momentum = The Planck constant mass × velocity Horizontal Range Formula R= v20 sin2θ g R = horizontal range (m) v0 = initial velocity (m/s) g = acceleration due to gravity (9.8 m/s2) θ = angle of the initial velocity from the horizontal plane (radians or degrees)  Maximum Height Formula H= v20 sin2 θ 2g H = maximum height (m) v0 = initial velocity (m/s) g = acceleration due to gravity (9.8 m/s2) θ = angle of the initial velocity from the horizontal plane (radians or degrees)  Rotational Kinetic Energy Formula rotational kinetic energy =  1 2 (moment of inertia) × (angular velocity) 2 Strain Formula (general form) 226 235 strain =  𝑐ℎ𝑎𝑛𝑔𝑒 𝑖𝑛 𝑑𝑖𝑚𝑒𝑛𝑠𝑖𝑜𝑛 𝑜𝑟𝑖𝑔𝑖𝑛𝑎𝑙 𝑣𝑎𝑙𝑢𝑒 𝑜𝑓 𝑑𝑖𝑚𝑒𝑛𝑠𝑖𝑜𝑛 Time of Flight Formula t= 2v0 sinθ g t = time of flight (s) v0 = initial velocity (m/s) g = acceleration due to gravity (9.8 m/s2) θ = angle of the initial velocity from the horizontal plane (radians or degrees)  Trajectory Formula y = x tanθ − g𝑥 2 2v20 cos2 θ y = vertical position (m) x = horizontal position (m) v0 = initial velocity (combined components, m/s) g = acceleration due to gravity (9.8 m/s2) θ = angle of the initial velocity from the horizontal plane (radians or degrees)  Capacitors in Parallel Formula Ceq = C1 + C2 + C3 + … Ceq = equivalent capacitance (F) C1 = capacitance of first capacitor (F) C2 = capacitance of second capacitor (F) C3 = capacitance of third capacitor (F) 227 236  Capacitors in Series Formula 1 = Ceq 1 C1 + 1 C2 + 1 C3 + …. Ceq = equivalent capacitance (F) C1 = capacitance of first capacitor (F) C2 = capacitance of second capacitor (F) C3 = capacitance of third capacitor (F)  Electric Power Formula electric power = voltage difference × current  Resistors in Parallel Formula 1 Req = 1 R1 + 1 R2 + 1 R3 + …. Req = equivalent resistance (Ω) R1 = resistance of first resistor (Ω) R2 = resistance of second resistor (Ω) R3 = resistance of third resistor (Ω)  Resistors in Series Formula Req = R1 + R2 + R3 + … Req = equivalent resistance (Ω) R1 = resistance of first resistor (Ω) 228 237 R2 = resistance of second resistor (Ω) R3 = resistance of third resistor (Ω)  Length Contraction Formula observed length = proper length √1 −  velocity 2 speed of light 2 Snell's Law Formula sin i sin r where: = constant = n i is the angle of incidence and r is the angle of refraction. This constant value is called the refractive index of the second medium with respect to the first. n1 sinθ1 = n2 sinθ2 n1 and n2 are the two different mediums that will impact the refraction.θ1 is the angle of incidence; θ2 is the angle of refraction.  Time Dilation Formula observer time = proper time √1−  velocity 2 speed of light 2 Kirchhoff's Junction Rule Formula sum of the currents in and out of a circuit junction = 0 ∑I=0 I = current, (Amperes, A)  Kirchhoff's Loop Rule Formula 229 238 sum of voltage differences around a circuit loop = 0 ∑V=0 V = voltage difference, (Volts, V)  Decibel Formula β = 10 decibels × log I I0 β = sound intensity, in decibels (dB) I = sound intensity (W/m2) I0 = reference sound intensity (10 −12 W/m2)  Einstein's Mass-Energy Equivalence Formula Energy = mass × (speed of light) 2  Kinetic Energy of Gas Formula 3 <KE> = kBT 2 <KE> = average kinetic energy per molecule of gas (J) kB = Boltzmann's constant (1.38 × 10−23 J/K) T = temperature (K)  Impulse-Momentum Theorem Formula Impulse = final momentum − initial momentum 230 239  Magnetic Field Formula B= B = magnetic field magnitude (Tesla, T) μ0 I 2πr μ0 = permeability of free space (4π × 10−7 Tm/A) I = magnitude of the electric current (Amperes, A) r = distance (m)  Parallel Axis Theorem Formula IP = Icm + Md2 IP = moment of inertia for rotation around a parallel axis (kg∙m2) Icm = moment of inertia for rotation around an axis through the center of mass (kg∙m2) M = total mass of the object (kg) d = distance between the two rotation axes (m)  Bernoulli's Equation Formula 1 P + ρ v2 + ρ g h = constant 2 P is the pressure exerted by the fluid v is the velocity of the fluid ρ is the density of the fluid h is the height of the container g is the acceleration due to gravity  Drag Formula 1 FD = ρ v2 CD A 2 FD: Drag force 231 240 ρ: fluid density v: Relative velocity between the fluid and the object CD: Drag coefficient A: Transversal area or cross sectional area  Dynamic Viscosity Formula Dynamic viscosity =  Shear rate Kinematic Viscosity Formula Kinematic viscosity =  Shearing stress Dynamic viscosity Fluid mass density Mass Flow Rate Formula m=ρvA ρ: Density of the fluid v: Velocity of the fluid A: Area of the cross section  Volume Flow Rate Formula Volume Flow Rate =  variation of volume variation of time Pressure in a Fluid Formula P=ρgh 232 241 ρ: Density of the fluid g: Acceleration of gravity h: Depth of the fluid  Bulk modulus Formula Bulk modulus =  change in volume / original volume Froude number Formula Froude number =  change in pressure Velocity of the fluid √gravitational acceleration × depth of flow Latent Heat Formula Q=mL Q: Latent heat m: Mass of the body L: Specific latent heat coefficient of the material  Liquid Expansion Formula ΔL= L α ΔT ΔL: Expansion of the liquid L: Length of the liquid before the change of temperature ΔT: Change of the temperature α: Coefficient of expansion of the liquid  Shear modulus Formula 233 242 Shear modulus =  shear stress Entropy Formula strain S= kB ln Ω S: Entropy kB: Boltzmann constant. (1.38 ×10 −23 J/ K) Ω: number of microstates.  Surface tension Formula γ= γ: Surface tension F d F: Force applied on the liquid d: length along which the force acts  Heat Flow Rate Formula Heat flow = −  heat transfer coefficient × area of the emitting body × variation of the temperature length of the material Maxwell-Boltzmann Distribution Formula f= 1 exp(−𝐸 /𝑘𝐵 𝑇) f: Energy distribution E: energy of the system kB: Boltzmann constant T: Absolute Temperature in Kelvin. 234 243  Molecular Speed Formula v=√ 3RT m v: molecular speed R: Ideal gas constant T: Absolute Temperature in Kelvin. m: molar mass  Stephan-Boltzmann Law Formula P = є σ T4 A P: total power radiated σ: The Stefan-Boltzmann Constant T: absolute temperature in Kelvin є: Emissivity of the material. A: Area of the emitting body  Thermodynamic Work Formula Thermodynamic work = number of moles × ideal gas constant × change of temperature  Wien Displacement Law Formula λmax= λmax: The peak of the wavelength b T b: Wien's displacement constant (2.9 × 10−3 m K) T: Absolute Temperature in Kelvin  Capacitor potential energy Formula 235 244 U= 1 2 C V2 C: Capacitance V: Voltage U: Energy stored in the capacitor  Period of a Pendulum Formula T = 2π √ L g where L represents the length of the pendulum and g is the value of the acceleration of gravity.  Work done by gravity Formula W=m×g×h W = work done by gravity m = mass g = gravitational acceleration h = height  Weight Formula Weight = mass × gravitational acceleration  Inductance Formula L= ΦN I 236 245 L = Inductance Φ = Magnetic flux N = Number of coil turns I = current intensity  Resonant Frequency Formula fr = 1 2𝜋√LC fr: resonant frequency L: Inductance. C: capacitance.  Intensity Formula I= P S I = Intensity P = power S = surface perpendicular to the direction of propagation  Voltage divider Formula Vout = 𝑍𝑖 𝑛 ∑𝑖=1 𝑍𝑖 Vin Vout = output voltage. Zi = generic impedance. ∑𝑛𝑖=1 𝑍𝑖 = the sum from the first to the nth impedance of the circuit. Vin = input voltage. 237 246  Transformer Formula Vp × Ip = Vs × Is Vp Vs = np ns Vp = input voltage on the primary coil. Vs = input voltage on the secondary coil. Ip = input current on the primary coil. Is = input current on the secondary coil. np = number of turns of wire on the primary coil. ns = number of turns of wire on the secondary coil.  Speed of sound Formula γP v=√ v = speed of sound. ρ γ = the coefficient of adiabatic expansion. P = the pressure of the gas. ρ = the density of the medium.  Sound intensity Formula sound intensity =  acoustic power normal area to the direction of propagation Friction loss Formula Q 2 L FL = C × [ ] × 100 100 238 247 FL = friction loss. C = friction loss coefficient. Q = flow rate. L = hose length.  Archimedes Principle Formula push = density of fluid × gravitational acceleration × volume of object  Uncertainty Principle Formula Δx Δp ≤≥ ℏ ΔE Δt ≤≥ ℏ 2 2 ℏ: reduced Planck's constant Δx: Position uncertainty Δp: Momentum uncertainty ΔE: Energy uncertainty Δt: Time uncertainty  Rydberg Formula 1 λ =R[ 1 𝑛12 R: Rydberg's constant (R=1.097 × 107 m−1) λ: Wavelength of the emitted photon n1 and n2 are integers and n2 is always greater than n1 248 239 − 1 𝑛22 ]  Half-Life Formula ln(2) t1/2 = λ λ: disintegration constant of the system t1/2: Half life time  Relativistic Momentum Formula Relativistic momentum =  velocity 2 speed of light 2 rest mass √1− velocity 2 speed of light 2 Relativistic Energy Formula Relativistic energy =  √1− Relativistic Mass Formula Relativistic mass =  rest mass × velocity rest mass × speed of light squared √1− velocity 2 speed of light 2 Relativistic Doppler Effect Formula 𝑣 1+ 𝑐 frequency observed = frequency emitted × √ 𝑣 1− 𝑐 c: speed of light v: velocity of the observer respect to the source 240 249  Relative Velocity Formula vAB = vA – vB vAB: relative velocity of the body A respect body B vA: velocity of the body A vB: velocity of the body B  Photon Energy Formula E= hc λ E: photon's energy h: Plank's constant λ: photon's wavelength c: speed of light  Photoelectric Effect Formula photon energy = work function + electron kinetic energy  Energy momentum Formula E = √p 2 c 2 + (m0 c 2 )2 E: Energy p: momentum c: speed of light m0: rest mass  Ampere's Law Formula ∫B∙dl = μ0I 241 250 B: magnetic field dl: infinitesimal segment of the integration path μ0: vacuum permeability I: enclosed electric current by the path  Motional Electromotive Force Formula EMF = v × B × L EMF: Electromotive force v: Velocity of the charge B: Magnetic field L: Length of the wire where the charge is moving  Magnetic Flux Formula Magnetic flux = Magnetic field × Area × (angle between the planar area and the magnetic flux)  Induced Electromotive Force Formula EMF = − ΔΦ EMF: Electromotive force ΔΦ: Change of the magnetic flux Δt: change in time  Gauss's Law Φ= Q ε0 242 251 Δt Φ: Electric flux Q: Enclosed charge by the surface ϵ0: absolute permittivity  Electric Flux Formula Φ = E A cosθ Φ: Electric Flux A: Area E: Electric field θ: angle between a perpendicular vector to the area and the electric field  Spherical mirror Formula 1 object distance + image distance Focal length ≈  1 1 focal length curvature radius 2 Resistivity-Conductivity Formula Resistivity =  = 1 conductivity Image size Formula image height object height 243 252 =− image distance object distance  Electric resistance Formula R=ρ L A R: Electric Resistance ρ: Resistivity L: Length of the material A: cross sectional area of the material  Moment of Inertia Formula (common shapes) Object Type Formula Thin rod, axis through the center I= 1 12 ML2 1 Thin rod, axis through one end I = ML2 3 Rectangular plate, axis through center I= 1 12 M (a2 + b2) 1 Rectangular plate, axis along edge I = Ma2 3 Hollow cylinder, with a wall thickness 1 I = M (R12 + R22) 2 1 Solid cylinder I = MR2 2 244 253 Thin-walled hollow cylinder I = MR2 Solid sphere 2 I = MR2 5 2 Thin-walled hollow sphere I = MR2 3 I = moment of inertia (kg∙m2) M = total mass of the rotating object (kg) L = the total length of the rod (m) a = the length of two sides of the plate (m) b = the length of the other two sides of the plate (m) R1 = the inner radius of the cylinder (m) R2 = the outer radius of the cylinder (m) R = the radius of the cylinder or sphere (m)  Rotational Kinematics Formula ω = ω0 + αt 1 θ = θ0 + ω0t + 2 αt2 ω2 = ω02 + 2α (θ − θ0) 1 θ − θ0 = 2 (ω0 + ω)t θ0 is initial angle θ is final angle t is the time interval ω0 is initial angular velocity ω is final angular velocity α is angular acceleration 245 254  Electric Field E= 𝐹 𝑞 E = Electric field (N/C) F = Force (N) q = charge (C)  Kepler's Third Law 𝐺𝑀 𝑟3 = 2 4𝜋 2 𝑇 r = radius of motion (m) T = period of motion (s) G = universal gravitation constant (6.673 × 10-11 Nm2 kg−2) M = M1+M2 = total mass of system (kg)  Magnetic force on a current-carrying wire of length L in a magnetic field F=B×I×L F = force (N) B= Magnetic Field (T) I = current (A) L = length (m)  Force per unit length 246 255 II F k 1 2 d l F = force (N) l = length (m) per unit I1, I2 = two currents d = separation of the two currents (m) k = magnetic constant (2 × 10−7 NC−1m−1)  Torque on a coil immersed in a magnetic field  = n× B× I× A× cosθ  = torque (Nm) n = number of turns of coil B = magnetic field (T) I = current (A) A = area of coil immersed in magnetic field (m2) cosθ = angle between the coil and the magnetic field  Magnetic force on a charge in a magnetic field F = q × v × B × sinθ F = force (N) q = charge (C) v = velocity (m/s) B = magnetic field (T) sinθ = angle between the velocity and the magnetic field 247 256  Acoustic Impedance Z=ρ×v Z = Acoustic impedance ρ = acoustic density v = speed of sound in medium  Astronomical Distance M  m  5 log( d ) 10 M = absolute magnitude m = relative magnitude d = distance in parsecs  Amplifier Gain Amplifier Gain = Vout Vin Vout = output voltage (V) Vin = input voltage (V) Amplifier Gain = output voltage positive input voltage − negative input voltage 248 257 Water expands as it freezes due to the hydrogen bonding in the water. The taste cells in our taste buds live for only about two weeks. There are 10 times more bacterial cells in our body than human cells. The human brain (made up of more than 100 billion nerves that communicate in trillions of connections) uses just as much power as a 10-watt light bulb. An adult is made up of 7 octillion atoms. We spend about five years of our lives eating. Adult humans spend about 33% of their lives asleep. A python spends about 75% of their life, and a dog spends about 44%. We will eat approximately 35 tons of food in our lifetime. Emetophobia → The fear of vomiting Bromidrophobia → The fear of body odors On average, a person will blink approximately about 12,000 times a day. 249  Percentage uncertainty (%) = absolute uncertainty measurement ×100 Heating processes Latent heat of fusion for water Lf = 3.34 × 105 J kg −1 Latent heat of vaporization for water LV = 2.26 × 106 J kg −1 ci = 2.05 × 103 J kg −1 K −1 Specific heat capacity of ice Specific heat capacity of steam cs = 2.00 × 103 J kg −1 K −1 Specific heat capacity of water cw = 4.18 × 103 J kg −1 K −1 Electrical circuits Charge on an electron 𝑒 = −1.60 × 10−19 C Waves Speed of sound in air at 25 °C  ws = 346 m s−1 List of Phytochemicals Phytochemicals Carotenoids (beta‐carotene, lycopene, lutein, zeaxanthin) Plant Source Uses Red, orange and green fruits and May inhibit cancer cell vegetables including broccoli, growth, work as carrots, cooked tomatoes, leafy antioxidants and improve greens, sweet potatoes, winter immune response squash, apricots, cantaloupe, oranges and watermelon. Flavonoids (anthocyanins, quercetin) Apples, citrus fruits, onions, soybeans May inhibit inflammation and soy products (tofu, soy milk, and tumor growth; may edamame, etc.), coffee and tea aid immunity and boost production of detoxifying 250 258 enzymes in the body Indoles and Glucosinolates (sulforaphane) Cruciferous vegetables (broccoli, May induce detoxification of cabbage, collard greens, kale, carcinogens, limit cauliflower and Brussels sprouts) production of cancer‐related hormones, block carcinogens and prevent tumor growth Inositol (phytic acid) Bran from corn, oats, rice rye and May retard cell growth and wheat, nuts, soybeans and soy work as antioxidant products (tofu, soy milk, edamame, etc.) Isoflavones Soybeans and soy products (tofu, May inhibit tumor growth, soy milk, edamame, etc.) limit production of (daidzein, genistein) cancer‐related hormones and generally work as antioxidant Isothiocyanates Cruciferous vegetables (broccoli, May induce detoxification of cabbage, collard greens, kale, carcinogens, block tumor cauliflower and Brussels sprouts) growth and work as antioxidants Polyphenols (ellagic acid, resveratrol) Green tea, grapes, wine, berries, May prevent cancer citrus fruits, apples, whole grains formation, prevent and peanuts inflammation and work as antioxidants Terpenes Cherries, citrus fruit peel, rosemary May protect cells from becoming cancerous, slow (perillyl alcohol, limonene, cancer cell growth, carnosol) strengthen immune function, limit production of cancer‐related hormones, fight viruses, work as antioxidant 251 259  Refractive index = real depth apparent depth Conics Ellipse 𝑥2 Standard form 𝑎2 + Asymptotes 𝑦2 𝑏2 Parabola 𝑥2 y2 = 4ax =1 Hyperbola 𝑎2 none − 𝑥 none 𝑎 𝑦2 𝑏2 𝑦 |𝑎ℎ+𝑏𝑘+𝑐|  The acute angle between lines with gradients m1 and m2 is tan−1 |  The resolved part of a in the direction of b is  The point dividing AB in the ratio λ : μ is  1 atm =1.01×105 Nm−2 =101kPa = 760mmHg  1 radian (rad) =  1 parsec (pc) = 3.26 light year  If y = a ± b then Δy = Δa + Δb  If y = ab c then 180o π ∆𝑦 𝑦 = ∆𝑎 𝑎 + ∆𝑏 𝑏 + ∆𝑐 𝑐 252 260 λ+ μ x = 0, y = 0 =±𝑏 The perpendicular distance from (h, k) to ax + by + c = 0 is μa+λb xy = c2 =1  𝑎 ∙𝑏 |𝑏| Rectangular hyperbola √𝑎2 +𝑏2 𝑚1 −𝑚2 1+ 𝑚1 𝑚2 |  Star Colors and Corresponding Approximate Temperatures Star Color Approximate Temperature Example Blue 25,000 K Spica White 10,000 K Vega Yellow 6000 K Sun Orange 4000 K Aldebaran Red 3000 K Betelgeuse total scattered power  Albedo =  dose equivalent = absorbed dose × quality factor  For small angle θ, measured in radians: total incident power sinθ ≈ θ cosθ ≈ 1 – tanθ ≈ θ  θ2 2 Constructive interference: path difference = nλ  Destructive interference: 1  T = 2π √ 𝑚 path difference = ( n + 2 ) λ 𝑘 T is the time period of motion k is the spring constant m is the mass attached to the spring 253 261 Nitrogen Base Classification Abbreviation Adenine Purine A Guanine Purine G Pyrimidine C Cytosine Thymine Uracil Pyrimidine Pyrimidine Abbreviations for Some Hormones Hormone Abbreviation Adrenocorticotropic hormone ACTH Antidiuretic hormone ADH Follicle-stimulating hormone FSH Gonadotropin-releasing hormone GnRH Human chorionic gonadotropin hCG Human growth hormone hGH Luteinizing hormone LH Parathyroid hormone PTH Prolactin PRL Thyroid-stimulating hormone TSH 254 262 T U  Statistical Analysis 𝑥̅ = 1 𝑛 ∑𝑛𝑖=1 𝑥𝑖 s=√ ∑(𝑥𝑖 − 𝑥̅ 2 ) 𝑛−1 Standard Error of the Mean = SE = Chi-Square = χ = ∑ 2 s √n (𝑜−𝑒)2 𝑒 𝑥̅ = sample mean n = sample size s = sample standard deviation o = observed results e = expected results Σ = sum of all Hardy-Weinberg Equations p2 + 2pq + q2 = 1 p + q= l p = frequency of allele 1 in a population q = frequency of allele 2 in a population 255 263  Water Potential = pressure potential + solute potential  The Solute Potential of a Solution = − i CRT i = ionization constant (1.0 for sucrose because sucrose does not ionize in water) C = molar concentration R = pressure constant (R = 0.0831 liter bars / mole K) T = temperature in Kelvin (oC + 273) Simpson's Diversity Index Diversity Index = I – ∑  ( total number of organisms of a particular species total number of organisms of all species Rate and Growth Rate Rate = dY dt Population Growth dN dt =B–D Exponential Growth 256 264 )2 dN dt = rmax N Logistic Growth dN dt = rmax N ( K−N ) N dY = amount of change dt = change in time B =birthrate D = death rate N = population size K = carrying capacity r max = maximum per capita growth rate of population Shares and Dividends  Money invested = number of shares × market value of one share.  Annual income = number of shares × rate of dividend × face value of one share  Rate of return =  Number of shares purchased (or held) = annual income investment × 100 % = investment market value of one share annual income income on one share 257 265  Investment = No. of shares × Market value per share  Sales Proceeds = No. of shares × selling price of each share (Market Value of each share) Matrices  Size of Matrix = No. of rows × No. of columns.  Identity matrix = [   Null matrix = [ 0 0 1 0 0 ] 0 0 ] 1 Matrix A m × n can only be multiplied with matrix B p × q if n = p and the resultant matrix will have m rows and q columns i.e. R m × q  Matrix multiplication is not commutative. (i.e. AB ≠ BA)  Matrix multiplication is associative. A (BC) = (AB) C  A × I = I × A = A where I is a unit matrix of suitable order.  A (B + C) = AB + AC (distributive property)  If AB = AC then B ≠ C, A may or may not be zero.  Height of water risen =  Time taken to fill a tank =  Volume of Big Sphere = No. of lead shots × Volume of each lead shot Volume of solid immersed Area of base of container Volume of tank Volume of water given by pipe /sec 258 266  Volume = Area of cross section × length (height) 1m3 = 1000 ltrs = 106 cm3  Probability of certain event = 1  Probability of an impossible event = 0  All possible outcomes added = 1  Sample space denotes all possible outcomes.  Complementary event P (A) + P (A) = 1 P (A) = 1 – P (A)  BODMAS Rule: This Rule depicts the correct sequence in which the operations are to be executed, so as to find out the value of a given expression. B – Bracket O – Of D – Division M – Multiplications A – Addition S – Subtractions  Time taken to cross a stationary Engine =  Time taken to Cross a signal Post = (Length of the train + Length of engine) Length of the train Speed of the Train 259 267 Speed of the train  Acute angle = 0° – 90°  Right Angle = 90°  Obtuse angle = 90° – 180°  Straight Angle = 180°  Reflex Angle = 180° – 360°  Complete angle = 360°  Complementary Angle = sum of two angles = 90°  Supplementary angle = sum of two angles = 180°  Right Angle Triangle: One angle 90°  Obtuse Angle Triangle: One angle more than 90°  Acute Angle Triangle: All angles less than 90°  When AC2 < AB2 + BC2 (Acute angle triangle)  When AC2 > AB2 + BC2 (Obtuse angle triangle)  When AC2 = AB2 + BC2 (Right angle triangle)  A median divides triangle into 2 equal parts: 1  2 × ( median ) 2 + 2 × ( the third side ) 2 = Sum of the square of other sides 2  Each diagonal of a parallelogram divides it into triangles of the same area.  The diagonals of a rectangle are equal and bisect each other.  The diagonals of a square are equal and bisect each other at right angles.  The diagonals of a rhombus are unequal and bisect each other at right angles.  Class Width = The diagonals of a parallelogram bisect each other. highest value − lowest value number classes 260 268 upper limit + lower limit  Class Midpoint =  Midrange =  Range = Highest value − Lowest value  Sample variance = (Sample standard deviation) 2  Coefficient of Determination = 2 highest value + lowest value 2 explained variation total variation List of mathematically significant natural numbers  1, the multiplicative identity. Also the only natural number (not including 0) that isn't prime or composite.  2, the base of the binary number system, used in almost all modern computers and information systems.  3, 22-1, the first Mersenne prime. It is the first odd prime, and it is also the 2 bit integer maximum value.  4, the first composite number  6, the first of the series of perfect numbers, whose proper factors sum to the number itself.  9, the first odd number that is composite  11, the fifth prime and first palindromic multi-digit number in base 10.  12, the first sublime number.  17, the sum of the first 4 prime numbers, and the only prime which is the sum of 4 consecutive primes.  24, all Dirichlet characters mod n are real if and only if n is a divisor of 24.  25, the first centered square number besides 1 that is also a square number  27, the cube of 3, the value of 3 ↑↑ 2, where ↑ is Knuth's up-arrow notation. 261 269  28, the second perfect number.  30, the smallest sphenic number.  32, the smallest nontrivial fifth power.  36, the smallest number which is perfect power but not prime power.  72, the smallest Achilles number.  255, 28 − 1, the smallest perfect totient number that is neither a power of three nor thrice a prime; it is also the largest number that can be represented using an 8-bit unsigned integer  341, the smallest base 2 Fermat pseudoprime.  496, the third perfect number.  1729, the Hardy–Ramanujan number, also known as the second taxicab number; that is, the smallest positive integer that can be written as the sum of two positive cubes in two different ways.  8128, the fourth perfect number.  142857, the smallest base 10 cyclic number.  9814072356, the largest perfect power that contains no repeated digits in base ten. List of integers notable in computing  8, the number of bits in a byte  256, The number of possible combinations within 8 bits, or a byte.  1024, the number of bytes in a kibibyte. It's also the number of bits in a kibibit.  65535, 216 − 1, the maximum value of a 16-bit unsigned integer.  65536, 216, the number of possible 16-bit combinations.  65537, 216 + 1, the most popular RSA public key prime exponent in most SSL/TLS certificates on the Web/Internet.  16777216, 224, or 166; the hexadecimal "million" (0x1000000), and the total number of possible color combinations in 24/32-bit True Color computer graphics. 262 270  2147483647, 231 − 1, the maximum value of a 32-bit signed integer using two's complement representation.  9223372036854775807, 263 − 1, the maximum value of a 64-bit signed integer using two's complement representation. Properties of Water Heat energy gained during melting . . . . . . . . . . 334 J/g Heat energy released during freezing . . . . . . . . 334 J/g Heat energy gained during vaporization . . . . . 2260 J/g Heat energy released during condensation . . . 2260 J/g Density at 3.98°C . . . . . . . . . . . . . . . . . . . . . . . . 1.0 g/mL  Eccentricity =  Gradient = distance between foci length of major axis change in field value distance Average Chemical Composition of Earth's Crust, Hydrosphere, and Troposphere CRUST ELEMENT Percent by mass Oxygen (O) Silicon (Si) Aluminum (Al) Iron (Fe) Calcium (Ca) Sodium (Na) Magnesium (Mg) Potassium (K) Nitrogen (N) Hydrogen (H) Other 46.10 28.20 8.23 5.63 4.15 2.36 2.33 2.09 HYDROSPHERE Percent by volume 94.04 0.88 0.48 0.49 1.18 1.11 0.33 1.42 Percent by volume 33.0 TROPOSPHERE Percent by volume 21.0 78.0 0.91 66.0 1.0 0.07 263 271 1.0 Angle 0° 30° 45° 60° 90° sinθ 0 1 2 1 √3 2 1 √3 Undefined cosθ tanθ cotθ secθ cosecθ 1 0 √3 2 Undefined √3 √2 1 √2 1 1 1 √3 1 2 √2 2 √2 √3 Undefined 1 2 Mo = l + ( 𝑓1 −𝑓0 2𝑓1 − 𝑓0 −𝑓2 0 2 Undefined 2 1 √3 )h where: l = lower limit of the modal class, h = size of the class interval (assuming all class sizes to be equal), f1 = frequency of the modal class, f0 = frequency of the class preceding the modal class, f2 = frequency of the class succeeding in the modal class 264 272 1 √3 Mode is obtained using the modal class: 0 Approximate coefficients of friction Material Against Material Static Friction Dry contact Lubricated contact 0.61 Kinetic Friction Dry contact 0.47 Aluminium Steel Aluminum Aluminum Gold Gold Platinum Platinum 1.2 0.25 3.0 Silver Silver 1.4 0.55 1.5 Alumina ceramic Silicon Nitride ceramic BAM (Ceramic alloy AlMgB14) Titanium boride (TiB2) 0.04–0.05 0.02 Brass Steel 0.35-0.51 0.19 Cast iron Copper 1.05 0.29 Cast iron Zinc 0.85 0.21 Concrete Rubber Concrete Wood 0.62 Copper Glass 0.68 Copper Steel 0.53 1.05-1.35 Lubricated contact 0.3 1.4-1.5 2.5 0.004 (wet) 1.0 265 273 0.30 (wet) 0.44 0.6-0.85 0.36 0.45-0.75 (wet) 0.9-1.0 Glass Glass Human synovial fluid Cartilage Ice Ice Polyethene Steel PTFE (Teflon) 0.4 0.01 0.003 0.02-0.09 0.2 0.2 PTFE (Teflon) 0.04 0.04 0.04 Steel Ice 0.03 Steel PTFE (Teflon) 0.04-0.2 0.04 0.04 Steel Steel 0.74-0.80 0.16 Wood Metal 0.2–0.6 0.2 (wet) Wood Wood 0.25–0.5 0.2 (wet) 0.42-0.62 The Resistor Colour Code Table Colour Digit Multiplier Black 0 1 Brown 1 10 ± 1% Red 2 100 ± 2% Orange 3 1,000 266 274 Tolerance Yellow 4 10,000 Green 5 100,000 ± 0.5% Blue 6 1,000,000 ± 0.25% Violet 7 10,000,000 ± 0.1% Grey 8 White 9 ± 0.05% Gold 0.1 ± 5% Silver 0.01 ± 10% None ± 20% Resistivities at 20°C Element Resistivity at 20 °C (Ω m) Aluminum 2.82 × 10-8 Carbon (Graphite) 3.5 × 10-5 Constantan 4.9 × 10-7 Copper 1.7 × 10-8 Germanium 4.6 × 10-1 Glass 1010 to 1014 267 275 Gold 2.44 × 10-8 Iron 1.0 × 10-7 Lead 2.2 × 10-7 Manganin 4.82 × 10-7 Mercury 9.8 × 10-7 Platinum 1.1 × 10-7 Quartz (fused) 7.5 × 1017 Silicon 6.40 × 102 Silver 1.59 × 10-8 Tungsten 5.6 × 10-8 Properties of Minerals Property Description Example of Mineral Fluorescence Mineral glows under ultraviolet light Fluorite Magnetism Mineral is attracted to a magnet Magnetite Radioactivity Mineral gives off radiation that can be measured with Geiger counter Uraninite Reactivity Bubbles form when mineral is exposed to a weak acid Calcite Smell Some minerals have a distinctive smell Sulfur (smells like rotten eggs) Taste Some minerals taste salty Halite 268 276 Etymology of period names Period Started Siderian c.2500 Ma Greek sideros iron the banded iron formations Rhyacian c.2300 Ma Gk. rhyax lava flow much lava flowed Orosirian c.2050 Ma Gk. oroseira mountain much orogeny in this period's range latter half steady continents became Statherian c.1800 Ma Root word Gk. statheros Meaning Reason for name stable cratons Calymmian c.1600 Ma Gk. calymma cover platform covers developed or expanded Ectasian c.1400 Ma Gk. ectasis stretch platform covers expanded Stenian c.1200 Ma Gk. stenos narrow much orogeny, which survives as narrow metamorphic belts Tonian c.1000 Ma Gk. tonos stretch The continental crust stretched as Rodinia broke up Cryogenian Ediacaran c.720 Ma c.635 Ma Gk. cryogenicos Ediacara Hills cold- In this period all the Earth making froze over stony place in Australia where ground the Ediacaran biota fossils were found Cambrian c.541 Ma Latin Cambria Wales 269 277 the place in Great Britain where Cambrian rocks are best exposed Ordovician c.485.4 Celtic Ordovices Tribe in north Wales, where the rocks were first Ma identified Silurian c.443.8 Ctc. Silures Tribe in south Wales, where the rocks were first Ma identified Devonian c.419.2 Devon County in England in which rocks from this period were Ma first identified Carboniferous c.358.9 Lt. carbo coal Ma Permian c.298.9 Global coal beds were laid in this period Perm Krai Region in Russia where rocks from this period were first Ma identified Triassic c.251.902 Lt. trias triad Ma Jurassic c.201.3 In Germany this period forms three distinct layers Jura Mountains Mountain range in the Alps in which rocks from this period Ma were first identified Cretaceous c.145 Ma Lt. creta chalk More chalk formed in this period than any other Paleogene c.66 Ma Gk. palaiogenos "ancient born" 270 278 Neogene c.23.03 Gk. neogenos "new born" Lt. quaternarius "fourth" Ma Quaternary c.2.58 Ma This was initially deemed the "fourth" period after the now-obsolete "primary", "secondary" and "tertiary" periods. Abbreviations yr and ya Non-SI Short for... abbreviation SI- Comments and examples prefixed equivalent  Thousand years Ma  Million years Ga  Billion years (thousand kyr kilo years ka myr million years Myr Mega years byr billion years million years) kya kilo years ago ka ago  Appearance of Homo sapiens, circa 200 kya  Out-of-Africa migration, circa 60 kya mya million years ago Mya Mega years ago Ma ago 271 279  Last Glacial Maximum, circa 20 kya  Neolithic Revolution, circa 10 kya  Pliocene, 5.3 to 2.6 mya o The last geomagnetic reversal was 0.78 mya o The (Eemian Stage) Ice Age started 0.13 mya bya billion years ago Gya giga years ago Ga ago  The Holocene started 0.01 mya  oldest Eukaryotes, 2 bya  formation of the Earth, 4.5 bya  Big Bang, 13.8 bya Ionization Energies (1st, 2nd, 3rd and 4th) of Gaseous Atoms (kJ/mol) Atomic number First Second Third Fourth 1 H 1,312 2 He 2,372 5,251 3 Li 520.3 7,298 11,815 4 Be 899.5 1,757 14,849 21,007 5 B 800.7 2,427 3,660 25,026 6 C 1,086 2,353 4,621 6,223 7 N 1,402 2,856 7,475 9,445 8 O 1,314 3,388 5,301 7,469 9 F 1,681 3,374 6,051 8,408 10 Ne 2,081 3,952 6,122 9,370 11 Na 495.9 4,563 6,913 9,544 12 Mg 737.8 1,451 7,733 10,541 13 Al 577.6 1,817 2,745 11,578 14 Si 786.5 1,577 3,232 4,356 15 P 1,012 1,903 2,912 4,957 16 S 999.6 2,251 3,361 4,564 17 Cl 1,251 2,297 3,822 5,158 18 Ar 1,521 2,666 3,931 5,771 19 K 418.9 3,051 4,412 5,877 20 Ca 589.8 1,145 4,912 6,474 272 280 21 Sc 631 1,235 2,389 7,089 22 Ti 658 1,310 2,653 4,175 23 V 650 1,414 2,828 4,507 24 Cr 652.9 1,592 2,987 4,740 25 Mn 717.4 1,509 3,249 4,940 26 Fe 759.4 1,561 2,958 5,290 27 Co 758 1,646 3,232 4,950 28 Ni 736.7 1,753 3,394 5,300 29 Cu 745.5 1,958 3,554 5,330 30 Zn 906.4 1,733 3,833 5,730 31 Ga 578.8 1,979 2,963 6,200 32 Ge 762.2 1,537 3,302 4,411 33 As 947 1,798 2,736 4,837 34 Se 941 2,045 2,974 4,144 35 Br 1,140 2,100 3,500 4,560 36 Kr 1,351 2,368 3,565 5,070 37 Rb 403 2,632 3,900 5,080 38 Sr 549.5 1,064 4,210 5,500 39 Y 616 1,181 1,980 5,960 40 Zr 660 1,267 2,218 3,313 41 Nb 664 1,382 2,416 3,700 42 Mo 685 1,558 2,621 4,480 43 Tc 702 1,472 2,850 44 Ru 711 1,617 2,747 45 Rh 720 1,745 2,997 46 Pd 805 1,875 3,177 47 Ag 731 2,074 3,361 48 Cd 867.7 1,631 3,616 49 In 558.3 1,821 2,705 5,200 50 Sn 708.6 1,412 2,943 3,930 51 Sb 833.8 1,595 2,440 4,260 52 Te 869.3 1,790 2,698 3,610 53 I 1,008 1,846 3,200 54 Xe 1,170 2,047 3,100 55 Cs 375.7 2,420 56 Ba 502.9 965.3 57 La 538.1 1,067 273 281 1,850 4,820 58 Ce 527.4 1,047 1,949 3,547 59 Pr 523.2 1,018 2,086 3,761 60 Nd 529.6 1,035 2,130 3,899 61 Pm 535.9 1,052 2,150 3,970 62 Sm 543.3 1,068 2,260 3,990 63 Eu 546.7 1,085 2,405 4,110 64 Gd 592.6 1,167 1,991 4,250 65 Tb 564.7 1,112 2,114 3,839 66 Dy 571.9 1,126 2,200 4,001 67 Ho 580.7 1,139 2,204 4,100 68 Er 588.7 1,151 2,194 4,115 69 Tm 596.7 1,163 2,544 4,119 70 Yb 603.4 1,176 2,415 4,220 71 Lu 523.6 1,340 2,022 4,360 72 Hf 680 1,440 2,250 3,215 73 Ta 761 74 W 770 75 Re 760 76 Os 840 77 Ir 880 78 Pt 870 1,791 79 Au 890.1 1,980 80 Hg 1,007 1,810 3,300 81 Tl 589.4 1,971 2,878 82 Pb 715.6 1,450 3,082 4,083 83 Bi 703.3 1,610 2,466 4,370 84 Po 812 85 At 890 86 Rn 1,037 87 Fr 384 88 Ra 509.4 89 Ac 499 90 Th 587 91 Pa 568 92 U 584 93 Np 597 94 Pu 585 971.9 274 282 95 Am 578 96 Cm 581 97 Bk 601 98 Cf 608 99 Es 619 100 Fm 627 101 Md 635 102 No 642 Ionic radii Ionic Radius Name Symbol Atomic number 0.012 Å 1.2 pm Hydrogen H 1 0.13 Å 13 pm Nitrogen N 7 0.23 Å 23 pm Boron B 5 0.35 Å 35 pm Beryllium Be 4 0.38 Å 38 pm Phosphorus P 15 0.4 Å 40 pm Silicon Si 14 0.46 Å 46 pm Manganese Mn 25 0.5 Å 50 pm Selenium Se 34 0.52 Å 52 pm Uranium U 92 0.52 Å 52 pm Chromium Cr 24 0.53 Å 53 pm Germanium Ge 32 0.535 Å 53.5 pm Aluminum Al 13 0.56 Å 56 pm Rhenium Re 75 0.56 Å 56 pm Technetium Tc 43 0.58 Å 58 pm Arsenic As 33 0.59 Å 59 pm Vanadium V 23 0.605 Å 60.5 pm Titanium Ti 22 0.62 Å 62 pm Tungsten W 74 0.62 Å 62 pm Gallium Ga 31 0.625 Å 62.5 pm Platinum Pt 78 0.625 Å 62.5 pm Iridium Ir 77 0.63 Å 73 pm Osmium Os 76 0.64 Å 64 pm Tantalum Ta 73 275 283 0.645 Å 64.5 pm Iron Fe 26 0.65 Å 65 pm Molybdenum Mo 42 0.68 Å 68 pm Rhodium Rh 45 0.68 Å 68 pm Ruthenium Ru 44 0.69 Å 69 pm Nickel Ni 28 0.69 Å 69 pm Niobium Nb 41 0.69 Å 69 pm Tin Sn 50 0.71 Å 71 pm Hafnium Hf 72 0.72 Å 72 pm Zirconium Zr 40 0.72 Å 72 pm Magnesium Mg 12 0.73 Å 73 pm Copper Cu 29 0.74 Å 74 pm Zinc Zn 30 0.745 Å 74.5 pm Cobalt Co 27 0.745 Å 74.5 pm Scandium Sc 21 0.75 Å 75 pm Neptunium Np 93 0.76 Å 76 pm Lithium Li 3 0.76 Å 76 pm Antimony Sb 51 0.78 Å 78 pm Protactinium Pa 91 0.8 Å 80 pm Indium In 49 0.848 Å 84.8 pm Lutetium Lu 71 0.85 Å 85 pm Gold Au 79 0.858 Å 85.8 pm Ytterbium Yb 70 0.86 Å 86 pm Palladium Pd 46 0.869 Å 86.9 pm Thulium Tm 69 0.881 Å 88.1 pm Erbium Er 68 0.887 Å 88.7 pm Plutonium Pu 94 0.9 Å 90 pm Yttrium Y 39 0.901 Å 90.1 pm Holmium Ho 67 0.912 Å 91.2 pm Dysprosium Dy 66 0.923 Å 92.3 pm Terbium Tb 65 0.925 Å 92.5 pm Einsteinium Es 99 0.934 Å 93.4 pm Californium Cf 98 0.938 Å 93.8 pm Gadolinium Gd 64 0.947 Å 94.7 pm Europium Eu 63 0.949 Å 94.9 pm Berkelium Bk 97 0.964 Å 96.4 pm Samarium Sm 62 276 284 0.97 Å 97 pm Curium Cm 96 0.97 Å 97 pm Tellurium Te 52 0.97 Å 97 pm Cadmium Cd 48 0.972 Å 97.2 pm Thorium Th 90 0.979 Å 97.9 pm Promethium Pm 61 0.982 Å 98.2 pm Americium Am 95 0.99 Å 99 pm Calcium Ca 20 0.995 Å 99.5 pm Neodymium Nd 60 1.013 Å 101.3 pm Praseodymium Pr 59 1.02 Å 102 pm Mercury Hg 80 1.02 Å 102 pm Sodium Na 11 1.03 Å 103 pm Bismuth Bi 83 1.034 Å 103.4 pm Cerium Ce 58 1.061 Å 106.1 pm Lanthanum La 57 1.1 Å 110 pm Nobelium No 102 1.119 Å 111.9 pm Actinium Ac 89 1.12 Å 112 pm Strontium Sr 38 1.19 Å 119 pm Lead Pb 82 1.26 Å 126 pm Silver Ag 47 1.33 Å 133 pm Fluorine F 9 1.35 Å 135 pm Barium Ba 56 1.38 Å 138 pm Potassium K 19 1.4 Å 140 pm Oxygen O 8 1.43 Å 143 pm Radium Ra 88 1.5 Å 150 pm Thallium Tl 81 1.52 Å 152 pm Rubidium Rb 37 1.67 Å 167 pm Cesium Cs 55 1.8 Å 180 pm Francium Fr 87 1.81 Å 181 pm Chlorine Cl 17 1.84 Å 184 pm Sulfur S 16 1.96 Å 196 pm Bromine Br 35 2.2 Å 220 pm Iodine I 53 2.3 Å 230 pm Polonium Po 84 277 285 States of Matter and Appearance of Halogens at Room Temperature States of Matter Halogen Appearance Solid Iodine Violet Solid Astatine Black/Metallic [Assumed] Liquid Bromine Reddish-Brown Gas Fluorine Pale Yellow-Brown Gas Chlorine Pale Green (at Room Temperature) The gyromagnetic ratios for several common nuclei Nuclei 1 H 13 C 31 P 27 Al 23 Na 7 Li 29 Si 17 O Spin Gyromagetic Ratio Natural Abundance (MHz/T) (%) 1 2 42.576 99.9985 1 2 10.705 1.07 1 2 17.235 100 5 2 11.103 100 3 2 11.262 100 3 2 16.546 92.41 1 2 -8.465 4.68 5 2 5.772 0.038 278 286 1 2 15 N -4.361 0.368 COMMON ISOTOPE PAIRS CHART Isotope Half-life of Parent Effective Dating Range (years) (years) Parent Daughter Uranium-238 Lead-206 4.5 billion 1 million to 4.5 billion Potassium-40 Argon-40 1.3 billion 10 000 to 3 billion Carbon-14 Nitrogen-14 5730 up to 50 000 Measurement  Absolute error = indicated value – true value  Absolute correction = true value – indicated value  Relative error =  Relative correction = absolute error true value absolute correction true value Mechanical equations  axial stress =  axial strain = axial force cross sectional area change in length original length 279 287 shear force  shear stress =  Working or allowable stress =  Mechanical advantage (MA) =  Velocity ratio (VR) =  Velocity ratio =  Input speed × input size = output speed × output size  Gear systems  shear area ultimate stress Factor of Safety (FOS) output force (or torque) input force (or torque) velocity of output from a mechanism velocity of input to a mechanism speed of input speed of output MA = Number of teeth on output gear VR = Number of teeth on input gear Number of teeth on input gear Number of teeth on output gear Belt and pulley systems MA = Diameter of output pulley VR = Diameter of input pulley Diameter of input pulley Diameter of output pulley Fluid mechanics  Pressure due to a column of liquid = height of column × gravitational acceleration × density of liquid  Up-thrust force on a submerged body = volume of submerged body × gravitational acceleration × density of liquid 280 288 Energy equations  Non-flow energy equation U1 + Q = U2 + W where: Q = energy entering the system W = energy leaving the system U1 = initial energy in the system U2 = final energy in the system  Steady flow energy equation Q = (W2 – W1) + W where: Q = heat energy supplied to the system W1 = energy entering the system W2 = energy leaving the system W = work done by the system. Principle of moments Σ clockwise moments = Σ anti-clockwise moments 281 289 HYDRAULICS  Pressure loss due to Friction 𝑃𝑓 = 9000𝑓𝑙L2 d5 where: Pf = Pressure loss due to friction in bar f = Friction factor for the hose l = Length of the hose in meters L = Flow rate in liters per minute d = Diameter of the hose in millimeters  Flow through a Nozzle 2 L = d2 √P 3 where: L = Flow rate in liters per minute d = Diameter of the nozzle in millimeters P = Pressure in bar  Water power and Efficiency WP = 100LP 60 where: WP = Water Power in Watts L = Flow rate in liters per minute 282 290 P = Pressure in bar E= where: WP BP × 100 E = Efficiency of a pump (%) WP = Water Power in Watts BP = Brake Power of engine in Watts  Jet Reaction R = 0.157Pd2 where: R = Jet reaction in newtons P = Pressure in bar d = Diameter of the hose in millimeters  Effective Height of a Jet He = 2 3 (H – 0.113 H2 d ) where: He = Effective height of jet in meters H = Theoretical height to which water will rise when projected vertically from nozzle in meters d = Diameter of nozzle in millimeters 283 291 E◦net = E◦red + E◦ox E◦ net = net voltage of a cell (V) E◦ red = voltage of the reduction half reaction (V) E◦ ox = voltage of the oxidation half reaction (V) NEWTON'S LAWS OF MOTION  Newton's First Law: An object continues in its state of rest or of uniform motion in a straight line unless acted upon by an external force.  Newton's Second Law: A change in motion (acceleration) is proportional to the force acting and takes place in the direction of the straight line along which the force acts. Acting force = mass × acceleration caused  Newton's Third Law: To every action there is an equal and opposite reaction (or, if object A exerts a force on object B, then object B exerts an equal, but oppositely-directed, force on A). 284 292 The most abundant element in the universe is hydrogen. The most abundant element on the Earth is Oxygen. The idea of Friedrich August Kekule von Stradonitz's dream helped form the benzene structure. The density of ice is 10% lower than that of water. Hydrofluoric acid (a solution of hydrogen fluoride in water) is so corrosive that it can dissolve glass. Helium (a colorless, odorless, tasteless, non-toxic, inert, monatomic gas) can be frozen only through pressure; not by cooling. Graphene (an allotrope of carbon) is the best conductor of electricity and heat. Chalk is made of trillions of fossils of planktonic microscopic skeleton. 285 Systematic Procedure for Inorganic Qualitative Analysis Systematic Analysis of Anion S.No 1 2 3 4 Experiment Preliminary Reactions Observation Colourless Inference Absence of Fe2+, Fe3+, Ni2+, Co2+. Appearance Green May be Fe2+, Ni2+, Cu2+ Blue Cu2+ Brown May be Fe2+ Pink May be Co2+, Mn2+ A colourless gas with a May be NH4+ salt characteristic pungent odour turning moist red Action of heat litmus paper blue. Take a small amount of the given salt taken in a Reddish brown vapours May be dry test tube, heat it turning acidified ferrous gently; then strongly. sulphate paper brown, are obtained. Substance is white when May be (Zn)2+ cold and yellow when hot. Flame Test (i) Bluish green flame May be Cu2+ To a small amount of the (ii) Apple green May be Ba2+ given salt taken in a (iii) Brick red May be Ca2+ watch glass, add a drop (iv) Crimson red May be Sr2+ of Con. HCl and make it into a paste. Introduce the paste with the help of a glass rod to the base of the non-luminous bunsen burner. Identification of Anions from Volatile Products: Brisk effervescence of Anion is CO32colourless, odourless gas turning lime water, milky is obtained. Colourless gas with a smell Anion is sulphide. of rotten eggs, turning lead acetate paper black is obtained. Colourless gas with smell of Anion is SO32burning sulphur turning Action of dilute H2SO4: acidified dichromatic green To a small portion of the is obtained. given salt taken in a test Reddish brown gas with Anion is tube add 1 or 2ccs of fishy odour turning H2SO4 and gently warm acidified ferrous sulphate it. brown is obtained. Colourless gas with smell of Anion may be acetate. vinegar is obtained. No characteristic Absence of CO32-, , S2-, 2observation. SO3 , CH3COO 286 293 5 6 7 8 Reddish brown vapours turning moist fluorescent paper red. Colourless gas with pungent smell giving dense white fumes with a glass Action of Con.H2SO4 rod dipped in NH4OH To a small amount of given salt taken in a test solution. Violet coloured vapours tube, add 2-3 ccs of turning starch paper blue Con.H2SO4 and gently or violet. heat it. Reddish brown vapours turning acidified ferrous sulphate paper brown. No characteristic observation. Action of Con.H2SO4 with Copius evolution of reddish Cu turnings: brown gas turning acidified Mix a small amount of ferrous sulphate paper the given salt taken in a brown is observed. test tube with a few Cu bits, add 2 – 3 ccs of No reddish brown vapours. H2SO4 and heat it. A greenish yellow gas Action of Con.H2SO4 with turning starch iodide paper violet (or) blue is obtained. MnO2 To a small amount of the Reddish brown vapours given salt taken in a test turning moist fluorescent paper red is obtained. tube, add an equal amount of MnO2 and Violet vapours turning add a few ccs of starch paper blue (or) violet Con.H2SO4 and gently is obtained. heat. No characteristic coloured vapours are obtained. Action of NaOH A colourless gas with a To a pinch of the given pungent smell giving dense salt taken in a test tube, white fumes with glass rod add few ccs of 10% dipped in HCl is obtained. NaOH solution and gently warm it. No characteristic gas is Ammonium liberated. Anion may be bromide. Anion may be chloride. Anion may be Iodide. Anion may be nitrate. Absence of , , & Anion is nitrate. Absence of Anion may be chloride. Anion may be bromide. Anion may be iodide Absence of , , Cation is ammonium. Ammonium is absent. Sodium Carbonate Extract Identification of Anions in solution Preparation of Extract: Take about or of the given salt in a 50cc beaker. Mix it well with about thrice its amount of solid sodium carbonate. Add about 15 – 20ml of distilled water. Mix well with neat glass rod. Boil contents of the beaker over Bunsen flame. Cool and filter through filter assembly. Collect the clean filtrate in another beaker. The Filtrate is called soda extract. 287 294 S.No 9 10 11 12 13 Experiment Silver Nitrate Test: To a portion of extract add dilute HNO3 until effervescence ceases. Add few drops in excess, 2 – 3nos of AgNO3 solution. Observation Inference Curdy white precipitate Anion is Cl– soluble in NH4OH. – Pale yellow precipitate Anion is Br sparingly soluble in NH4OH. Yellow precipitate insoluble Anion is in NH4OH. Absence of Br–, Cl–, I– No precipitate is obtained. Barium Chloride Test: A white precipitate Anion is To about one or two ccs insoluble in HCl. of the extract, (after neutralizing with acetic A white precipitate soluble Anion is acid and boiling of CO2) in HCl. add BaCl2 solution. To a portion of the above No precipitate is obtained. Absence of ppt add dil. HCl. Lead Acetate Test: To about one or two ccs of the extract (after acidifying with acetic acid, boiling off CO2 and cooling) add lead acetate solution. Ferrous Sulphate Test: (Brown Ring Test) To about 1 or 2cc of extract add dilute H2SO4 in drops until the effervescence ceases. And few drops in excess add 2- 3 drops of freshly prepared FeSO4 solution. Keeping the test tube in a slanting position, add Con. H2SO4 without disturbing the solution. Ferric Chloride Test: Take about 1 or 2ccs of the extract in a test tube and add neutral FeCl3 solution. Filter, if required, and divide the solution or the filtrate in two parts: (i) To dil.HCl one part White ppt, soluble in excess of ammonium acetate solution. A brown ring is obtained at Anion is the junction of the liquid. No brown ring is observed. Deep red produced colouration add Red colouration disappears (ii) To the second part add water and boil confirmed. Reddish brown ppt. 288 295 Anion is absent. confirmed. confirmed. confirmed. 14 15 Calcium Chloride Test: white precipitate of Confirms Oxalate. To a portion of the A sodium carbonate calcium oxalate is obtained extract, taken in a test tube add dil. Acetic acid and boil off CO2. Then add a few drops of calcium chloride solution. Add dil. HNO3 to the The precipitate dissolves. white ppt and warm. Ethyl Acetate Test: To a pinch of given salt A pleasant fruity odor is taken in a test tube, add obtained. a few drops of ethanol followed by 1 or 2ccs of H2SO4. Gently heat and cool it. Pour into Na2CO3. The presence of anion acetate is confirmed. Diamond and graphite both are forms of pure carbon. The chemical name for water (H2O) is dihydrogen monoxide. The only 2 non-silvery metals are gold and copper. Our body contains enough carbon to provide graphite for 9,000 pencils. If we mix half a liter of alcohol and half a liter of water, the total volume of the resultant liquid will be less than one liter. 289 296 Systematic Analysis of Cations Preparation of Original solution: Check solubility of the given salt in: - Cold water (or) hot water (or) Dil HCl (or) Conc. HCl. original solution. Label this solution as Procedure for Separation of Basic Radicals into Groups To the original solution, add Dil. HCl. White ppt. Group I 2+ present (Pb and If no ppt. pass H2S through the given solution. If a coloured ppt. is formed, group 2 cations are present (Cu2+), Pb2+. If no ppt is obtained from the above, boil off H2s gas and add a few drops of conc. HNO3 to the remaining solution. Cool, add 2-3g of solid NH4Cl. Boil again and add NH4OH solution till it becomes alkaline. If a ppt is formed, Group III cations are present. Reddish brown ppt. Fe3+ Gelatinous white ppt. Al3+ If no ppt., pass H2S to the given solution. If a ppt is formed Group IV cations are present. Black ppt. (Co2+, Ni2+) Flesh coloured ppt. Mn2+ white ppt. Zn2+. If no ppt is formed, boil off H 2S gas add (NH4)2CO3 solution. If a white ppt is formed Group V cations are present (Ba2+, Sr2+, Ca2+) If no ppt. Group VI cation is present (Mg2+ If none of the cations are present, check for Group 0 ( ) Cation Analysis Group O (NH4+): To a pinch of given salt add Yellowish brown precipitate Cation is ammonium. some water and warm. is obtained. Then allow it to cool. Add Nessler’s reagent and No precipitate is obtained. Cation is not ammonium. excess of NaOH solution. 290 297 Group I (lead): Group I precipitate is dissolved by heating the precipitate with dil.HNO3 or distilled water. Divide the solution into 3 portions and carry out the following reactions. Experiment Observation Inference Pb2+ To one portion of the above A white precipitate solution add dilute H2SO4. PbSO4 is obtained. of To another portion, add A potassium chromate solution. of Presence confirmed. yellow precipitate is obtained. Golden Spangles Test: A yellow To the 3rd portion, add KI obtained. solution precipitate is present. of is The presence of confirmed. is is To above yellow precipitate, Precipitate dissolves and add some H2O, boil and reappears in the form of then cool. golden spangles. Group II ( : The group 2 precipitate is dissolved by heating with dilute HCl. Precipitate dissolves. Experiment Test for : To one portion of the above solution add drops of NH4OH, until it is in excess. Observation Inference A pale blue precipitate The presence of Cu2+ is which dissolves in excess confirmed. NH4OH to give any inky blue solution is obtained. To another portion, add dilute acetic acid and A chocolate brown ppt. potassium ferrocyanide [K4(Fe(CN6))] Confirms copper. Group III: Group III precipitate is heated with Con. HCl and water, cooled and filtered. Reddish brown precipitate indicates Fe2+ (or) Fe3+ Gelatinous white indicates Al3+ Experiment 1. Observation Inference To 1 cm3 OS, add a Formation of a deep Fe2+ confirmed. few drops of dilute blue colour or ppt. HCl and then add 291 298 2. 0.5 cm3 of potassium ferricyanide solution. White gelatinous precipitate dissolves in minimum quantity of dil. HCl. To this, add a few drops of blue litmus solution. Formation of a blue Al3+ confirmed. floating ppt. in colourless solution. (This is known as Lake test) Add NH4OH solution A blue ppt., suspended in excess. in a colourless medium (called a lake) 2B To one part of the White Precipitate soluble Al3+ confirmed above solution add in excess of NaOH NaOH solution solution 3. (i) (ii) Reddish brown ppt. (Shows the presence of Fe3+) Treat it with minimum quantity of dil. HCl solution to dissolve the ppt. and then heat. Divide the solution into two parts. To one part, add few drops of potassium ferrocyanide solution. A yellow produced. solution is may be present. A deep blue colour or ppt. is obtained. confirmed. To another portion A deep red colour is add few drops of obtained. potassium sulphocyanide solution. confirmed. Group IV : Group IV precipitate is warmed with dilute HCl centrifugate Black precipitate Ni2+ Ni is not soluble in dilute HCl. To residue A Red rosy precipitate add Con.HCl, boil, cool. Divide the presence of Ni2+ solution into two parts and boil of H2S. To one part add dimethyl glyoxime reagent. Con.NH4OH, till the solution becomes alikaline. 292 299 confirms the Sodium Hydroxide and Br2 – water test. A black precipitate confirms the To the second part of the above solution, of Ni2+. add NaOH and Br2 water and then boil Confirmation of Zn2+: Dissolve a part of white ppt in dil. HCl. Boil off H2S and divide the solution in two Bluish White ppt confirms Zinc. parts. (i) To one part of solution add Pot. ferrocyanide solution White ppt soluble in excess of (ii) To second part of solution add NaOH. obtained. Flesh (buff) colour precipitate indicates A white precipitate is formed. Mn2+. water to the white ppt it turns Dissolve the precipitate in Dil. HCl and brown. Mn2+ confirmed. boil off H2S then add NaOH solution. Lead peroxide test A pink colouration is produced. To the second part of the flesh coloured confirmed. ppt, add a little of PbO2 powder and conc. HNO3. Boil, cool and allow to stand. presence NaOH is Add Br black or Mn2+ is Group V : Take a small portion of Group V precipitate, carry out flame test. Take group V precipitate, add dilute CH3COOH, warm. Boil of CO2 and divide the solution into three parts. Barium, Ba2+ 1. Potassium chromate test. To one part of the above solution, add a few drops of K2CrO4 solution – Yellow ppt. Ba2+ confirmed. Stronium Sr2+ 1. Ammonium sulphate test. To the second part of the above solution add a few drops of ammonium sulphate solution – white ppt. Sr2+ confirmed. 2. Dil. H2SO4 Test Flame test To another portion of the above solution, add a few drops of dil. H2SO4 – white ppt. insoluble in HCl. Ba2+ confirmed. Calcium Ca2+ 1. Ammonium oxalate test. To the third portion of the above solution, add ammonium oxalate solution and then NH4OH solution to make it alkaline and scratch the sides of the test tube – white ppt. Ca2+ confirmed. Flame test 293 300 Test for Mg2+: 1. Ammonium phosphate test. White crystalline ppt. To the original salt solution, add solid NH4 Cl, warm to dissolve, cool and add NH4 OH solution in slight excess. Then add ammonium phosphate solution, shake well and allow to stand 2. To the original sat solution, add White crystalline ppt confirms Mg2+ disodium hydrogen phosphate. Additional Test: Ash test for Al3+, Zn2+, Mg2+ To a pinch of given salt Blue tinted ash is obtained. taken in a test tube, add a Green tinted ash is few drops of Con.H2SO4, obtained. Co(No3)2. Mix it well. Dip one filter paper bit in a Bunsen flame. After it burns Pink tinted ash is obtained. remove it from flame. After cooking observe the odor of the ash formed. The presence confirmed. of Al3+ is The presence of Zn2+ confirmed. is The presence of Mg2+ is confirmed. Sound travels 4.3 times faster in water than in air Urine glows under ultraviolet light Apples produce a gas called ethylene on ripening. We have lost about 1% of our body's water by the time we feel thirsty. Warm water freezes more quickly than cold water. 294 301 Known ice ages Name of ice age Years BP (Ma) Geological period Era Pongola 2900–2780 Huron 2400–2100 Siderian Rhyacian Paleoproterozoic Sturt Marino Gaskiers Baykonur 715–680 650–635 580 547 Cryogenian Neoproterozoic Andean-Saharan (incl. Hirnantian and Late Ordovician glaciation) 450–420 Late Ordovician Silurian Paleozoic Karoo 360–260 Carboniferous Permian Paleozoic Late Cenozoic Ice Age (incl. Quaternary glaciation) 34–present Late Paleogene Neogene Quaternary Cenozoic Ediacaran Binding Energy per nucleon = Element Mesoarchean Binding Energy Nucleon Number Mass of Nuclear mass Binding energy Binding energy nucleons (u) (u) (MeV) per nucleon (MeV) Deuterium 2.01594 2.01355 2.23 295 302 1.12 Helium 4 4.03188 4.00151 28.29 7.07 Lithium 7 7.05649 7.01336 40.15 5.74 Beryllium 9 9.07243 9.00999 58.13 6.46 Iron 56 56.44913 55.92069 492.24 8.79 Silver 107 107.86187 106.87934 915.23 8.55 Iodine 127 128.02684 126.87544 1072.53 8.45 Lead 206 207.67109 205.92952 1622.27 7.88 Polonium 210 211.70297 209.93683 1645.16 7.83 Uranium 235 236.90849 234.99351 1783.80 7.59 Uranium 238 239.93448 238.00037 1801.63 7.57 Viscosity of Water Temperature Dynamic Viscosity Kinematic Viscosity Density °C (centiPoise) (centiPoise) gm/cm3 2 1.6735 1.6736 0.9999 3 1.619 1.6191 1 4 1.5673 1.5674 1 5 1.5182 1.5182 1 6 1.4715 1.4716 0.9999 7 1.4271 1.4272 0.9999 8 1.3847 1.3849 0.9999 9 1.3444 1.3447 0.9998 10 1.3059 1.3063 0.9997 11 1.2692 1.2696 0.9996 12 1.234 1.2347 0.9995 13 1.2005 1.2012 0.9994 14 1.1683 1.1692 0.9992 296 303 15 1.1375 1.1386 0.9991 16 1.1081 1.1092 0.9989 17 1.0798 1.0811 0.9988 18 1.0526 1.0541 0.9986 19 1.0266 1.0282 0.9984 20 1.0016 1.0034 0.9982 21 0.9775 0.9795 0.998 22 0.9544 0.9565 0.9978 23 0.9321 0.9344 0.9975 24 0.9107 0.9131 0.9973 25 0.89 0.8926 0.997 26 0.8701 0.8729 0.9968 27 0.8509 0.8539 0.9965 28 0.8324 0.8355 0.9962 29 0.8145 0.8178 0.9959 30 0.7972 0.8007 0.9956 31 0.7805 0.7842 0.9953 32 0.7644 0.7682 0.995 33 0.7488 0.7528 0.9947 34 0.7337 0.7379 0.9944 35 0.7191 0.7234 0.994 36 0.705 0.7095 0.9937 37 0.6913 0.6959 0.9933 38 0.678 0.6828 0.993 39 0.6652 0.6702 0.9926 40 0.6527 0.6579 0.9922 45 0.5958 0.6017 0.9902 297 304  50 0.5465 0.5531 0.988 55 0.5036 0.5109 0.9857 60 0.466 0.474 0.9832 65 0.4329 0.4415 0.9806 70 0.4035 0.4127 0.9778 75 0.3774 0.3872 0.9748 80 0.354 0.3643 0.9718 Beer–Lambert law The absorbance of a material that has only one attenuating species also depends on the pathlength and the concentration of the species, according to the Beer–Lambert law: A=ε×C×L where: ε is the molar attenuation coefficient of that material C is the molar concentration of those species L is the pathlength  Profitability ratios (SL/HL) Gross profit margin = Net profit margin = gross profit sales revenue × 100 net profit before interest and tax sales revenue 298 305 × 100  Liquidity ratios (SL/HL) Current ratio = current assets current liabilities Acid test (quick) ratio =  × 100 current assets − stock current liabilities × 100 Efficiency ratios (SL/HL) Return on capital employed (ROCE) = net profit before interest and tax capital employed × 100 where: capital employed = loan capital (or long-term liabilities) + share capital + retained profit  Efficiency ratios (HL only) Stock turnover (number of times) = Stock turnover (number of days) = cost of goods sold average stock average stock cost of goods sold × 365 where: cost of goods sold is an approximation of total credit purchases and average stock = opening stock + closing stock 2 Debtor days ratio (number of days) = 299 306 debtors total sales revenue × 365 where total sales revenue is an approximation of total credit sales Creditor days ratio (number of days) = creditors cost of goods sold × 365 where cost of goods sold is an approximation of total credit purchases Gearing ratio = loan capital capital employed × 100 where capital employed = loan capital (or long-term liabilities) + share capital + retained profit  Investment appraisal (SL/HL) Average rate of return (ARR) =  (total returns− capital cost)/ years of use capital cost × 100 Investment appraisal (HL only) Net present value (NPV) = Σ present values of return − original cost  Capacity utilization and productivity (HL only) Capacity utilization rate = actual output productive capacity Productivity rate = total output total input 300 307 × 100 × 100 The Periodic Table of the Elements 1 2 H He Hydrogen Helium 1.00794 3 4.003 4 5 6 7 8 9 10 Li Be B C N O F Ne Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon 6.941 9.012182 10.811 12.0107 14.00674 11 12 13 14 15 15.9994 18.9984032 20.1797 16 17 18 Ar Na Mg Al Si P S Cl Sodium Magnesium Aluminum Silicon Phosphorus Sulfur Chlorine Argon 22.989770 24.3050 26.981538 28.0855 30.973761 32.066 35.4527 39.948 19 20 31 32 33 34 35 36 21 22 23 24 25 26 27 28 29 30 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton 39.0983 40.078 44.955910 47.867 50.9415 51.9961 54.938049 55.845 58.933200 58.6934 63.546 65.39 69.723 72.61 74.92160 78.96 79.904 83.80 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 Xe Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon 85.4678 87.62 88.90585 91.224 92.90638 95.94 (98) 101.07 102.90550 106.42 107.8682 112.411 114.818 118.710 121.760 127.60 126.90447 131.29 55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Rn Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Cesium Barium Lanthanum Hafnium Tantalum Tungsten 183.84 Rhenium 186.207 Osmium 190.23 Iridium 192.217 Platinum 195.078 Gold 196.96655 Mercury 200.59 Thallium 204.3833 Lead 207.2 Bismuth Polonium Astatine (210) (222) 106 107 108 109 110 111 112 113 114 66 67 68 69 70 71 132.90545 137.327 138.9055 178.49 180.9479 87 88 89 104 105 Fr Ra Ac Rf Db Sg Bh Hs Mt Francium Radium Actinium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium (223) (226) (227) (261) (262) (263) (262) (265) (266) (269) (272) (277) 58 59 60 61 62 63 64 65 208.98038 (209) Radon Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Cerium Praseodymium Neodymium Promethium Samarium 150.36 Europium 151.964 Gadolinium 157.25 Terbium 158.92534 Dysprosium 162.50 Holmium 164.93032 Erbium 167.26 Thulium 168.93421 Ytterbium 173.04 Lutetium 174.967 90 91 92 93 94 95 96 97 98 99 100 101 102 103 140.116 140.90765 144.24 (145) Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium 232.0381 231.03588 238.0289 (237) (244) (243) 301 308 (247) (247) (251) (252) (257) (258) (259) (262) Sources of antioxidants  allium sulphur compounds – leeks, onions and garlic  anthocyanins – eggplant, grapes and berries  beta-carotene – pumpkin, mangoes, apricots, carrots, spinach and parsley  catechins – red wine and tea  copper – seafood, lean meat, milk and nuts  cryptoxanthins – red capsicum, pumpkin and mangoes  flavonoids – tea, green tea, citrus fruits, red wine, onion and apples  indoles – cruciferous vegetables such as broccoli, cabbage and cauliflower  isoflavonoids – soybeans, tofu, lentils, peas and milk  lignans – sesame seeds, bran, whole grains and vegetables  lutein – green, leafy vegetables like spinach, and corn  lycopene – tomatoes, pink grapefruit and watermelon  manganese – seafood, lean meat, milk and nuts  polyphenols – thyme and oregano  selenium – seafood, offal, lean meat and whole grains  vitamin A – liver, sweet potatoes, carrots, milk, and egg yolks  vitamin C – oranges, blackcurrants, kiwifruit, mangoes, broccoli, spinach, capsicum and strawberries  vitamin E – vegetable oils (such as wheatgerm oil), avocados, nuts, seeds and whole grains  zinc – seafood, lean meat, milk and nuts  zoochemicals – red meat, offal and fish. 309 302 Oxidation states of the elements Element Negative states −5 −4 −3 −2 Positive states −1 0 +1 +2 +3 +4 +5 +6 Group +7 +8 +9 Z 1 hydrogen H 2 helium He 3 lithium Li 4 beryllium Be 5 boron B 6 carbon C 7 nitrogen N 8 oxygen O 9 fluorine F 10 neon Ne 11 sodium Na 12 magnesium Mg 13 aluminium Al 14 silicon Si 15 phosphorus P −1 1 +1 18 1 +1 −5 −4 0 +1 +2 −1 0 +1 +2 +3 0 +1 +2 +3 +4 +1 +2 +3 +4 +1 +2 −3 −2 −1 −3 −2 −1 −2 −1 0 2 13 14 +5 15 16 −1 17 18 −1 −4 1 +1 +1 +2 2 +1 +2 +3 −2 −1 −3 −2 −1 0 +1 +2 +3 +4 −3 −2 −1 0 +1 +2 +3 +4 310 303 13 14 +5 15 −2 16 sulfur S 17 chlorine Cl 18 argon Ar 19 potassium K 20 calcium Ca 21 scandium Sc 22 titanium Ti 23 vanadium V 24 chromium Cr 25 manganese Mn 26 iron Fe 27 cobalt Co 28 nickel Ni −2 29 copper Cu −2 30 zinc Zn −2 31 gallium Ga 32 germanium Ge 33 arsenic As 34 selenium Se −1 0 −1 +1 +2 +3 +4 +5 +6 +1 +2 +3 +4 +5 +6 16 +7 0 −1 −4 0 +1 +2 +3 −1 0 +1 +2 +3 +4 −1 0 +1 +2 +3 +4 +5 −2 −1 0 +1 +2 +3 +4 +5 +6 −2 −1 0 +1 +2 +3 +4 +5 +6 +7 7 −2 −1 0 +1 +2 +3 +4 +5 +6 +7 8 −1 0 +1 +2 +3 +4 +5 −1 0 +1 +2 +3 +4 10 0 +1 +2 +3 +4 11 +1 +2 +1 +2 +3 −3 −5 1 +1 +2 −3 −3 18 +1 −2 −4 17 2 3 4 −3 −2 −1 −4 −3 −2 −1 0 +1 +2 +3 +4 −3 −2 −1 0 +1 +2 +3 +4 +5 −2 −1 +1 +2 +3 +4 +5 304 6 9 12 −4 311 5 13 14 15 +6 16 −1 35 bromine Br 36 krypton Kr 37 rubidium Rb 38 strontium Sr 39 yttrium Y 40 zirconium Zr 41 niobium Nb 42 molybdenum Mo 43 technetium Tc 44 ruthenium Ru 45 rhodium Rh 46 palladium Pd 47 silver Ag −2 48 cadmium Cd −2 49 indium In 50 tin Sn 51 antimony Sb 52 tellurium Te 53 iodine I +1 0 −1 −2 −4 −1 −2 −3 −4 −5 −4 +7 +5 18 1 +1 +2 2 +1 +2 +3 +1 +2 +3 +4 +1 +2 +3 +4 +5 3 4 5 0 +1 +2 +3 +4 +5 +6 −1 0 +1 +2 +3 +4 +5 +6 +7 0 +1 +2 +3 +4 +5 +6 +7 0 +1 +2 +3 +4 +5 +6 0 +1 +2 +3 +4 +1 +2 +3 +1 +2 +1 +2 +3 −1 17 +2 −1 −2 −3 +4 +1 0 −3 +1 +3 −1 +8 8 9 11 12 −1 −3 −2 −1 0 +1 +2 +3 +4 −3 −2 −1 0 +1 +2 +3 +4 +5 −2 −1 +1 +2 +3 +4 +5 +6 −1 +1 +3 +4 +5 +6 305 7 10 −2 312 6 13 14 15 16 +7 17 54 xenon Xe 55 caesium Cs 56 barium Ba 57 lanthanum La 58 cerium Ce 59 praseodymium Pr 0 60 neodymium Nd 0 61 promethium Pm 62 samarium Sm 63 europium Eu 64 gadolinium Gd 0 65 terbium Tb 0 66 dysprosium Dy 67 holmium 68 0 −1 +1 +2 +4 +6 +8 18 1 +1 +1 +2 +1 +2 +3 +2 +3 +4 +2 +3 +4 +2 +3 +4 +2 +3 n/a +2 +3 n/a +2 +3 n/a +1 +2 +3 n/a +1 +2 +3 +4 n/a 0 +2 +3 +4 n/a Ho 0 +2 +3 n/a erbium Er 0 +2 +3 n/a 69 thulium Tm +2 +3 n/a 70 ytterbium Yb +2 +3 n/a 71 lutetium Lu +2 +3 n/a 72 hafnium Hf +2 +3 0 +1 0 0 −2 +1 313 306 2 3 +4 n/a +5 n/a n/a 4 −3 73 tantalum Ta 74 tungsten W 75 rhenium Re 76 osmium Os 77 iridium Ir −3 78 platinum Pt −3 79 gold Au −3 80 mercury Hg 81 thallium Tl 82 lead Pb 83 bismuth Bi 84 polonium Po 85 astatine At 86 radon Rn 87 francium Fr 88 radium Ra 89 actinium Ac 90 thorium Th 91 protactinium Pa −4 −1 −2 −3 +4 +5 5 +1 +2 +3 +4 +5 +6 −1 0 +1 +2 +3 +4 +5 +6 +7 −1 0 +1 +2 +3 +4 +5 +6 +7 +8 −1 0 +1 +2 +3 +4 +5 +6 +7 +8 −2 −1 0 +1 +2 +3 +4 +5 +6 −2 −1 0 +1 +2 +3 +1 +2 −2 −4 +3 0 −2 −5 +2 −1 −3 −4 +1 +1 +2 +3 −2 −1 +1 +2 +3 +4 −2 −1 +1 +2 +3 +4 +5 +4 +5 +2 15 +6 16 +7 +6 17 18 1 2 +2 3 +3 307 11 +5 +1 314 9 14 +2 +1 +9 13 +3 +1 8 12 −1 −1 7 10 +5 −2 −2 6 +2 +3 +4 +3 +4 n/a +5 n/a 92 uranium U 93 neptunium 94 +1 +2 +3 +4 +5 +6 n/a Np +2 +3 +4 +5 +6 +7 n/a plutonium Pu +2 +3 +4 +5 +6 +7 n/a 95 americium Am +2 +3 +4 +5 +6 +7 n/a 96 curium Cm +3 +4 +5 +6 97 berkelium Bk +2 +3 +4 +5 n/a 98 californium Cf +2 +3 +4 +5 n/a 99 einsteinium Es +2 +3 +4 100 fermium Fm +2 +3 n/a 101 mendelevium Md +2 +3 n/a 102 nobelium No +2 +3 n/a 103 lawrencium Lr +3 n/a 104 rutherfordium Rf 105 dubnium Db 106 seaborgium Sg 107 bohrium Bh 108 hassium Hs 109 meitnerium Mt 9 110 darmstadtium Ds 10 n/a n/a 4 +4 5 +5 0 6 +6 7 +7 +8 315 308 8 111 roentgenium Rg 11 112 copernicium Cn 113 nihonium Nh 13 114 flerovium Fl 14 115 moscovium Mc 15 116 livermorium Lv 16 117 tennessine Ts 17 118 oganesson Og 18 +2 Factorial table Number Factorial n n! 0 1 1 1 2 2 3 6 4 24 5 120 6 720 7 5040 316 309 12 8 40320 9 362880 10 3628800 11 3.991680 × 107 12 4.790016 × 108 13 6.227021 × 109 14 8.717829 × 1010 15 1.307674 × 1012 16 2.092279 × 1013 17 3.556874 × 1014 18 6.402374 × 1015 19 1.216451 × 1017 20 2.432902 × 1018 Rocket Equations: Thrust =     dM dt u M → mass of the rocket u → exhaust velocity in the rocket frame (v − u) → exhaust velocity in the observer frame v→ velocity of the rocket Under the influence of the rocket thrust in a gravity-free environment, the resulting velocity can be calculated from: 317 310 v = v0 + u ln m0 m velocity = initial velocity + exhaust velocity × ln original mass mass Under the influence of the rocket thrust in a gravity environment, the resulting velocity can be calculated from: v = v0 + u ln g→ gravitational acceleration m0 m − gt t→ time Power Table from 1 to 10 n 1 2 3 4 5 6 7 8 9 10 1n 1 1 1 1 1 1 1 1 1 1 2n 2 4 8 16 32 64 128 256 512 1024 3n 3 9 27 81 243 729 2187 6561 19683 59049 4n 4 16 64 256 1024 4096 16384 65536 262144 1048576 5n 5 25 125 625 3125 15625 78125 390625 1953125 9765625 318 311 6n 6 36 216 1296 7776 46656 279936 1679616 10077696 60466176 7n 7 49 343 2401 16807 117649 823543 5764801 40353607 282475249 8n 8 64 512 4096 32768 262144 2097152 16777216 134217728 1073741824 9n 9 81 729 6561 59049 531441 4782969 43046721 387420489 3486784401 10n 10 100 1000 10000 100000 1000000 10000000 100000000 1000000000 10000000000 Formulas of some saturated fatty acids Common name Chemical structure Caprylic acid CH3(CH2)6COOH Capric acid CH3(CH2)8COOH Lauric acid CH3(CH2)10COOH Myristic acid CH3(CH2)12COOH Palmitic acid CH3(CH2)14COOH Stearic acid CH3(CH2)16COOH Arachidic acid CH3(CH2)18COOH Behenic acid CH3(CH2)20COOH Lignoceric acid CH3(CH2)22COOH 319 312 Cerotic acid CH3(CH2)24COOH Formulas of some Unsaturated Fatty Acids Common name Chemical structure Myristoleic acid CH3(CH2)3CH=CH(CH2)7COOH Palmitoleic acid CH3(CH2)5CH=CH(CH2)7COOH Sapienic acid CH3(CH2)8CH=CH(CH2)4COOH Oleic acid CH3(CH2)7CH=CH(CH2)7COOH Elaidic acid CH3(CH2)7CH=CH(CH2)7COOH Vaccenic acid CH3(CH2)5CH=CH(CH2)9COOH Linoleic acid CH3(CH2)4CH=CHCH2CH=CH(CH2)7COOH Linoelaidic acid CH3(CH2)4CH=CHCH2CH=CH(CH2)7COOH α-Linolenic acid CH3CH2CH=CHCH2CH=CHCH2CH=CH(CH2)7COOH Arachidonic acid CH3(CH2)4CH=CHCH2CH=CHCH2CH=CHCH2CH=CH(CH2)3COOH Eicosapentaenoic acid CH3CH2CH=CHCH2CH=CHCH2CH=CHCH2CH=CHCH2CH=CH(CH2)3COOH Erucic acid CH3(CH2)7CH=CH(CH2)11COOH Docosahexaenoic acid CH3CH2CH=CHCH2CH=CHCH2CH=CHCH2CH=CHCH2CH=CHCH2CH=CH(CH2)2COOH 320 313 Qualitative Analysis of the Phytochemicals  Test for Carbohydrates: The presence of carbohydrates is confirmed when 2 ml of extract is treated with 1 ml of Molisch's reagent and few drops of concentrated sulphuric acid which results in the formation of purple or reddish color.  Test for Tannins: To 1 ml of extract, 2 ml of 5% ferric chloride is added. Formation of dark blue or greenish black indicates the presence of tannins.  Test for Saponins: 2 ml of extract, 2 ml of distilled water are added and shaken in a graduated cylinder for 15 min lengthwise. It results in the formation of 1 cm layer of foam that indicates the presence of saponins.  Test for Alkaloids: To 2 ml of extract, 2 ml of concentrated hydrochloric acid is added. Then few drops of Mayer's reagent are added. Presence of green color or white precipitate indicates the presence of alkaloids.  Test for Flavonoids: To 2 ml of extract, 1 ml of 2N sodium hydroxide is added. Presence of yellow color indicates the presence of flavonoids.  Test for Glycosides: To 2 ml of extract, 3ml of chloroform and 10% ammonia solution is added. Formation of pink color indicates presence of glycosides.  Test for Quinones: To 1 ml of extract, 1 ml of concentrated sulphuric acid is added. Formation of red color indicates presence of quinones.  Test for Phenols: 2 ml of distilled water followed by few drops of 10% ferric chloride is added to 1ml of the extract. Formation of blue or green color indicates presence of phenols. 321 314  Test for Terpenoids: 0.5 ml of the extract is treated with 2 ml of chloroform and conc. sulphuric acid. Formation of red brown colour at the interface indicates the presence of terpenoids.  Test for Cardiac Glycosides: To 0.5 ml of the extract, 2 ml of glacial acetic acid and few drops of ferric chloride are added. This is under layered with 1 ml of conc. sulphuric acid. Formation of brown ring at the interface indicates the presence of cardiac glycosides.  Ninhydrin Test: To 2 ml of the extract few drops of 0.2% ninhydrin reagent is added and heated for 5 min. Formation of blue colour indicates the presence of amino acids.  Test for Coumarins: 1 ml of 10% sodium hydroxide is added to 1ml of the extract. Formation of yellow colour indicates the presence of coumarins.  Anthraquinones: To 1 ml of extract few drops of 10% ammonia solution is added, appearance of pink color precipitate indicates the presence of anthraquinones  Steroids: To 1 ml of extract equal volume of chloroform is added and a few drops of concentrated sulphuric acid added appearance of brown ring indicates the presence of steroids and appearance of bluish brown ring indicates the presence of phytosteroids.  Test for Phlobatannins: Few drops of 2% hydrochloric acid are added to 1ml of the extract. Appearance of red colour precipitate indicates the presence of phlobatannins.  Anthracyanine: To 1 ml of the extract is added 1 mL 2N sodium hydroxide and heated for 5 min at 100 °C. Formation of bluish green color indicates the presence of anthocyanin. 322 315 Common names and IUPAC names of some carboxylic acids Carbon atoms Common name IUPAC name Chemical formula 1 Formic acid Methanoic acid HCOOH 2 Acetic acid Ethanoic acid CH3COOH 3 Propionic acid Propanoic acid CH3CH2COOH 4 Butyric acid Butanoic acid CH3(CH2)2COOH 5 Valeric acid Pentanoic acid CH3(CH2)3COOH 6 Caproic acid Hexanoic acid CH3(CH2)4COOH 7 Enanthic acid Heptanoic acid CH3(CH2)5COOH 8 Caprylic acid Octanoic acid CH3(CH2)6COOH 9 Pelargonic acid Nonanoic acid CH3(CH2)7COOH 10 Capric acid Decanoic acid CH3(CH2)8COOH 11 Undecylic acid Undecanoic acid CH3(CH2)9COOH 12 Lauric acid Dodecanoic acid CH3(CH2)10COOH 13 Tridecylic acid Tridecanoic acid CH3(CH2)11COOH 14 Myristic acid Tetradecanoic acid CH3(CH2)12COOH 15 Pentadecylic acid Pentadecanoic acid CH3(CH2)13COOH 323 316 16 Palmitic acid Hexadecanoic acid CH3(CH2)14COOH 17 Margaric acid Heptadecanoic acid CH3(CH2)15COOH 18 Stearic acid Octadecanoic acid CH3(CH2)16COOH 19 Nonadecylic acid Nonadecanoic acid CH3(CH2)17COOH 20 Arachidic acid Icosanoic acid CH3(CH2)18COOH Magnetic properties of common nuclei Isotope Occurrence Spin Magnetic Electric Operating Relative in nature number I moment μ quadrupole frequency at 7 T sensitivity (μN) moment (MHz) (%) (e × 10 1 H 99.984 2 H 0.016 10 B 18.8 11 B 81.2 12 C 98.9 13 C 1.1 14 N 99.64 15 N 0.37 16 O 99.76 17 O 0.0317 19 28 F 100 Si 92.28 −24 2 cm ) 1 2 2.79628 0 300.13 1 1 0.85739 0.0028 46.07 0.0964 3 1.8005 0.074 32.25 0.0199 3 2 2.6880 0.026 96.29 0.165 0 0 0 0 0 1 2 0.70220 0 75.47 0.0159 1 0.40358 0.071 21.68 0.00101 1 2 −0.28304 0 30.41 0.00104 0 0 0 0 0 5 2 1 2 −1.8930 −0.0040 40.69 0.0291 2.6273 0 282.40 0.834 0 0 0 0 0 324 317 29 Si 31 1 2 1 2 3 2 3 2 4.70 P 100 35 Cl 75.4 37 Cl 24.6 −0.5548 0 59.63 0.0785 1.1205 0 121.49 0.0664 0.92091 −0.079 29.41 0.0047 0.68330 −0.062 24.48 0.0027 List of plant hormones and their functions Hormone Function Ethylene Fruit ripening and abscission Gibberellins Break the dormancy of seeds and buds; promote growth Cytokinins Promote cell division; prevent senescence Abscisic Acid Close the stomata; maintain dormancy Auxins Involved in tropisms and apical dominance List of the Constellations Constellation Mythological Association First Genitive Form Brightest Star Ancient Andromedae Alpheratz 1756 Antliae α-Ant Appeared Andromeda The Princess Andromeda; in Greek mythology, the daughter of Cepheus and Cassiopeia and wife of Perseus. Antlia The air pump; a southern 325 318 constellation introduced by (Lacaille) Lacaille in 1756, originally the 'pneumatic machine'. Apus Apodis α-Aps Ancient Aquarii Sadalsuud Ancient Aquilae Altair Ancient Arae α-Ara Ancient Arietis Hamal Ancient Aurigae Capella Ancient Bootis Arcturus The chisel; a southern 1756 Caeli α-Cae constellation introduced by (Lacaille) The bird of paradise; a southern 1598 (Keyser constellation introduced by & de Houtman) Keyser & de Houtman in 1598. Aquarius The water bearer; in Greek mythology, Ganymede, wine-waiter to the Gods and lover of Zeus. Aquila The eagle; in Greek mythology, the bird of Zeus and the retriever of his thunderbolts. Ara The altar; in Greek mythology, used by the Gods to vow allegiance before their battle with the Titans. Aries The ram; in Greek mythology, the animal whose golden fleece was recovered by Jason and the Argonauts. Auriga The charioteer; in Greek mythology, Erichthonius, son of Vulcan, the first person to attach four horses to a chariot. Bootes The herdsman; in Greek mythology, Arcas, son of Zeus by Callisto. Caelum Lacaille in 1756. 326 319 Camelopardalis Camelopardalis β-Cam Ancient Cancri β-Cnc The hunting dogs; introduced by 1687 Canum Cor-Caroli Johannes Hevelius in 1687, and (Hevelius) Venaticorum Ancient Canis Majoris Sirius Ancient Canis Minoris Procyon Ancient Capricorni δ-Cap The keel; a sub-division of the 1756 Carinae Canopus ancient constellation Argo – in (Lacaille) Ancient Cassiopeiae γ-Cas Ancient Centauri Rigil- The giraffe; a large but faint 1612 northern constellation (Plancius) introduced by Plancius in 1612. Cancer The crab; in Greek mythology, a crab which bit Hercules's foot. Canes Venatici said to be held by the herdsman Bootes. Canis Major The greater dog; in Greek mythology, a hunting dog belonging to Orion, depicted pursuing the hare Lepus. Canis Minor The lesser dog; in Greek mythology, a hunting dog belonging to Orion, depicted pursuing the hare Lepus. Capricornus The sea goat; associated with Pan in Greek mythology, god of the countryside. Carina Greek mythology, the ship of the Argonauts. Cassiopeia Queen Cassiopeia; in Greek mythology, wife of Cepheus and mother of Andromeda. Centaurus The Centaur: half man and half horse; in Greek mythology, the wise centaur Chiron. 327 320 Kentaurus Cepheus King Cepheus of Ethiopeia; in Ancient Cephei Alderamin Ancient Ceti Diphda The chameleon; introduced by 1598 (Keyser Chamaeleontis α-Cha Keyser & de Houtman in 1598. & de Houtman) The pair of dividing compasses; 1756 Circini α-Cir a modern constellation (Lacaille) Columbae Phact Comae β-Com Greek mythology, the king of Ethiopia, descended from Zeus and Io. Cetus The sea monster, which in Greek mythology attacked Cepheus's territory and Andromeda, but which was slain by Perseus. Chamaeleon Circinus introduced by Lacaille in 1756. Columba The dove; introduced by Plancius 1592 in 1592. In Biblical history, (Plancius) said to be the dove of Noah. Coma Berenices The hair of Queen Berenice of 1536 (Vopel) Egypt; introduced as a Berenices constellation by Vopel in 1536. Corona The southern crown, lying at the Australis feet of Sagittarius, and known Ancient Coronae α-CrA Australis to the Greeks as a wreath. Corona The northern crown; in Greek Borealis mythology, worn by the Princess Ancient Coronae Alphecca Borealis Ariadne on her wedding day. Corvus The crow; in Greek mythology, Ancient Corvi Gienah Ancient Crateris δ-Crt sent by Apollo in search of water. Crater The cup; in Greek mythology, clutched by the crow Crater in 328 321 its search for water. Crux The southern cross; introduced 1598 Crucis Acrux as a constellation by Plancius (Plancius) Ancient Cygni Deneb Ancient Delphini Rotanev The goldfish; a constellation 1598 (Keyser Doradus α-Dor introduced by Keyser & de & de Houtman) Ancient Draconis Eltanin The little horse; a tiny yet Ancient Equulei Kitalpha ancient constellation with no (Ptolemy) Ancient Eridani Achernar The furnace; originally a 1756 Fornacis α-For chemist's distillation furnace, (Lacaille) Ancient Geminorum Pollux The crane; a constellation 1598 (Keyser Gruis Alnair introduced by Keyser & de & de Houtman) Herculis Kornephoros in 1598. Cygnus The swan; in Greek mythology, Zeus in disguise. Delphinus The dolphin; in Greek mythology, the messenger of Poseidon. Dorado Houtman in 1598. Draco The dragon; in Greek mythology, Ladon, guard of the tree on which golden apples grew, slain by Hercules. Equuleus mythological association. Eridanus The mythical river Eridanus; associated variously with the Nile or Po. Fornax introduced by Lacaille in 1756. Gemini The mythical twins Castor and Pollux. Grus Houtman in 1598. Hercules Hercules; a large yet dark 329 322 Ancient constellation representing the greatest hero of Greek mythology. Horologium Horologii α-Hor Ancient Hydrae Alphard The lesser water snake; 1598 (Keyser Hydri β-Hyi introduced as a constellation by & de Houtman) Indi α-Ind Lacertae α-Lac Ancient Leonis Regulus The lion cub; introduced as a 1687 Leonis Minoris 46-LMi constellation by Johannes (Hevelius) Ancient Leporis Arneb The balance; a zodiacal Ancient Librae Zubeneschamali constellation introduced by the (Roman) The pendulum clock; a modern 1756 constellation introduced by (Lacaille) Lacaille in 1756. Hydra The multi-headed water snake, slain by Hercules in Greek mythology. Hydrus Keyser & de Houtman in 1598. Indus The Indian; introduced as a 1598 (Keyser constellation by Keyser & de & de Houtman) Houtman in 1598. Lacerta The lizard; introduced as a 1690 constellation by Johannes (Hevelius) Hevelius in 1690. Leo The lion of Nemea; in Greek mythology, a monster slain by Hercules. Leo Minor Hevelius in 1687. Lepus The hare; often depicted being chased by Orion and his two dogs. Libra Romans. 330 323 Lupus Ancient Lupi α-Lup The lynx; a faint constellation 1687 Lyncis α-Lyn introduced by Johannes Hevelius (Hevelius) Ancient Lyrae Vega Table Mountain, South Africa; a 1756 Mensae α-Men modern constellation introduced (Lacaille) Microscopii γ-Mic Monocerotis α-Mon Muscae α-Mus Normae γ²-Nor Octantis ν-Oct Ophiuchi Rasalhague The wolf; an ancient constellation, but without mythological association. Lynx in 1687. Lyra The lyre; often said to be played by Orpheus, the greatest musician of his age. Mensa by Lacaille in 1756, celebrating his southern-hemisphere observing site. Microscopium The microscope; a modern 1756 constellation introduced by (Lacaille) Lacaille in 1756. Monoceros Musca The unicorn; a constellation 1612 introduced by Plancius in 1612. (Plancius) The fly; a constellation 1598 (Keyser introduced by Keyser & de & de Houtman) Houtman in 1598. Norma The set square; a modern 1756 constellation introduced by (Lacaille) Lacaille in 1756. Octans The octant, a navigational 1756 instrument invented in the (Lacaille) 1730s. A modern constellation introduced by Lacaille in 1756. Ophiuchus The serpent bearer; in Greek 331 324 Ancient mythology, Asclepius, the god of medicine, depicted in the sky holding the snake Serpens. Orion The hunter; associated in Greek Ancient Orionis Rigel The peacock; a constellation 1598 (Keyser Pavonis Peacock introduced by Keyser & de & de Houtman) Ancient Pegasi Enif Ancient Persei Mirfak The phoenix; a constellation 1598 (Keyser Phoenicis Ankaa introduced by Keyser & de & de Houtman) Pictoris α-Pic Ancient Piscium η-Psc Ancient Piscis Fomalhaut mythology with a son of Poseidon, but associated by the Sumerians with their great hero Gilgamesh. Pavo Houtman in 1598. Pegasus The winged horse; in Greek mythology, used by Zeus to carry thunder and lightning. Perseus Perseus; in Greek mythology, the husband of Andromeda, also known for slaying Medusa the Gorgon. Phoenix Houtman in 1598. Pictor The painter's easel; a modern 1756 constellation introduced by (Lacaille) Lacaille in 1756. Pisces Two fishes, swimming in opposite directions with their tails connected by a cord. Piscis The southern fish; the parent of Austrinus the two fish depicted by Pisces. Puppis The poop deck of the Argo Navis; 1756 a sub-division of the ancient (Lacaille) 332 325 Austrini Puppis Naos constellation Argo – in Greek mythology, the ship of the Argonauts. Pyxis Pyxidis α-Pyx Reticuli α-Ret Ancient Sagittae γ-Sge Ancient Sagittarii Kaus-Australis Ancient Scorpii Antares The sculptor – originally, the 1756 Sculptoris α-Scl sculptor's studio; a modern (Lacaille) Scuti α-Sct Serpentis Unukalhai The compass; a southern 1756 constellation introduced by (Lacaille) Lacaille in 1756. Reticulum The net; a southern 1756 constellation introduced by (Lacaille) Lacaille in 1756, commemorating the cross-hair in his telescope. Sagitta The arrow; in Greek mythology, perhaps the arrow that Apollo used to kill the Cyclopes. Sagittarius The archer; usually drawn as a centaur – half man, half horse Scorpius The scorpion; said to have stung the hunter Orion to death in Greek mythology. Sculptor constellation introduced by Lacaille in 1756. Scutum The shield; a constellation 1684 honouring King John III Sobieski (Hevelius) of Poland – the only politically inspired constellation still in use. Serpens Caput The serpent's head; held by Ophiuchus and part of the same constellation as Serpens Cauda. 333 326 Ancient Caput Serpens Cauda The serpent's tail; held by Ancient Ophiuchus and part of the same Serpentis η-Ser Cauda constellation as Serpens Caput. Sextans Sextantis α-Sex Ancient Tauri Aldebaran The telescope; a modern 1756 Telescopii α-Tel constellation introduced by (Lacaille) Ancient Trianguli β-Tri Atria The sextant; a constellation 1687 introduced by Johannes Hevelius (Hevelius) in 1687, celebrating an instrument used to measure star positions. Taurus The bull; said by the Sumerians to be charging at Orion the hunter, but in Greek mythology said to be Zeus in disguise. Telescopium Lacaille in 1756. Triangulum The triangle; appearing similar to a capital delta in the Greek alphabet. Triangulum The southern triangle; a 1598 (Keyser Trianguli Australe constellation introduced by & de Houtman) Australe The toucan; a constellation 1598 (Keyser Tucanae α-Tuc introduced by Keyser & de & de Houtman) Ancient Ursae Majoris Alioth Ancient Ursae Minoris Polaris Keyser & de Houtman in 1598. Tucana Houtman in 1598. Ursa Major The great bear, also known as the Big Dipper or the Plough. In Greek mythology, Callisto, lover of Zeus. Ursa Minor The lesser bear; in Greek mythology, one of the nymphs 334 327 that nursed Zeus as an infant. Vela Velorum γ²-Vel Ancient Virginis Spica The flying fish; a constellation 1598 (Keyser Volantis γ²-Vol introduced by Keyser & de & de Houtman) Vulpeculae α-Vul The sail; a sub-division of the 1756 ancient constellation Argo – in (Lacaille) Greek mythology, the ship of the Argonauts. Virgo The virgin; in Greek mythology, the goddess of justice. Volans Houtman in 1598, celebrating the family Exocoetidae. Vulpecula The fox; a constellation 1687 introduced by Johannes Hevelius (Hevelius) in 1687. List of superconductors Substance Al Class Element Transition Critical magnetic Type temperature (K) field (T) 1.20 0.01 I 5.3×10−4 5.2×10−6 I Bi Element Cd Element 0.52 0.0028 I Diamond:B Element 11.4 4 II Ga Element 1.083 0.0058 I Hf Element 0.165 α-Hg Element 4.15 335 328 I 0.04 I β-Hg Element 3.95 0.04 I In Element 3.4 0.03 I Ir Element 0.14 0.0016 I α-La Element 4.9 β-La Element 6.3 I I −4 Li Element 4×10 Mo Element 0.92 0.0096 I Nb Element 9.26 0.82 II Os Element 0.65 0.007 I Pa Element 1.4 Pb Element 7.19 Re Element 2.4 3.25×10 I I 0.08 I 0.03 −4 Rh Element Ru Element 0.49 0.005 I Si:B Element 0.4 0.4 II Sn Element 3.72 0.03 I Ta Element 4.48 0.09 I Tc Element 7.46–11.2 0.04 II α-Th Element 1.37 0.013 I Ti Element 0.39 0.01 I Tl Element 2.39 0.02 I α-U Element 0.68 I β-U Element 1.8 I V Element 5.03 1 II α-W Element 0.015 0.00012 I β-W Element 1–4 Zn Element 0.855 0.005 I Zr Element 0.55 0.014 I Ba8Si46 Compound 8.07 0.008 II C6Ca Compound 11.5 0.95 II C6Li3Ca2 Compound 11.15 II C8K Compound 0.14 II C8KHg Compound 1.4 II 336 329 4.9×10 I −6 I C6K Compound 1.5 II C3K Compound 3.0 II C3Li Compound <0.35 II C2Li Compound 1.9 II C3Na Compound 2.3–3.8 II C2Na Compound 5.0 II C8Rb Compound 0.025 II C6Sr Compound 1.65 II C6Yb Compound 6.5 II C60Cs2Rb Compound 33 II C60K3 Compound 19.8 C60RbX Compound 28 II FeB4 Compound 2.9 II InN Compound 3 II In2O3 Compound 3.3 LaB6 Compound 0.45 MgB2 Compound 39 Nb3Al Compound 18 NbC1-xNx Compound 17.8 12 II Nb3Ge Compound 23.2 37 II NbO Compound 1.38 II NbN Compound 16 II Nb3Sn Compound 18.3 30 II NbTi Compound 10 15 II SiC:B Compound 1.4 0.008 I SiC:Al Compound 1.5 0.04 II TiN Compound 5.6 5 I V3Si Compound 17 YB6 Compound 8.4 ZrN Compound 10 ZrB12 Compound 6.0 YBCO Cuprate 95 GdBCO Cuprate 91 337 330 0.013 II ~3 II 74 II II II II 120–250 II II BSCCO Cuprate 104 HBCCO Cuprate 135 SmFeAs(O,F) Iron-based 55 CeFeAs(O,F) Iron-based 41 LaFeAs(O,F)) Iron-based 26 LaFePO Iron-based 4 FeSe Iron-based 65 (Ba,K)Fe2As2 Iron-based 38 NaFeAs Iron-based 20 List of vitamins and their functions Water-soluble vitamins Vitamin Function Sources Thiamine Part of an enzyme needed for energy Found in all nutritious foods in moderate (vitamin B1) metabolism; important to nerve function amounts: pork, whole-grain or enriched breads and cereals, legumes, nuts and seeds Riboflavin Part of an enzyme needed for energy Milk and milk products; leafy green vegetables; (vitamin B2) metabolism; important for normal vision whole-grain, enriched breads and cereals and skin health Niacin (vitamin B3) Part of an enzyme needed for energy Meat, poultry, fish, whole-grain or enriched metabolism; important for nervous breads and cereals, vegetables (especially mushrooms, asparagus, and leafy green 338 331 system, digestive system, and skin health vegetables), peanut butter Pantothenic Part of an enzyme needed for energy Widespread in foods acid metabolism Biotin Part of an enzyme needed for energy Widespread in foods; also produced in intestinal metabolism tract by bacteria Part of an enzyme needed for protein Meat, fish, poultry, vegetables, fruits Pyridoxine (vitamin B6) Folic acid metabolism; helps make red blood cells Part of an enzyme needed for Leafy green vegetables and legumes, seeds, making DNA and new cells, especially orange juice, and liver; now added to most refined red blood cells grains Part of an enzyme needed for making Meat, poultry, fish, seafood, eggs, milk and milk new cells; important to nerve function products; not found in plant foods Ascorbic acid Antioxidant; part of an enzyme needed Found only in fruits and vegetables, especially (vitamin C) for protein metabolism; important for citrus fruits, vegetables in the cabbage family, immune system health; aids in iron cantaloupe, strawberries, peppers, tomatoes, absorption potatoes, lettuce, papayas, mangoes, kiwifruit Cobalamin (vitamin B12) 339 332 Fat-soluble vitamins Vitamin Function Sources Vitamin A (and its Needed for vision, healthy skin Vitamin A from animal sources (retinol): fortified precursor*, beta- and mucous membranes, bone milk, cheese, cream, butter, fortified margarine, carotene) and tooth growth, immune eggs, liver *A precursor is system health Beta-carotene (from plant sources): Leafy, dark converted by the green vegetables; dark orange fruits (apricots, body to the vitamin. cantaloupe) and vegetables (carrots, winter squash, sweet potatoes, pumpkin) Vitamin D Needed for proper absorption Egg yolks, liver, fatty fish, fortified milk, fortified of calcium; stored in bones margarine. When exposed to sunlight, the skin can make vitamin D. Vitamin E Antioxidant; protects cell walls Polyunsaturated plant oils (soybean, corn, cottonseed, safflower); leafy green vegetables; wheat germ; whole-grain products; liver; egg yolks; nuts and seeds Vitamin K Needed for proper blood clotting Leafy green vegetables such as kale, collard greens, and spinach; green vegetables such as broccoli, Brussels sprouts, and asparagus; also produced in intestinal tract by bacteria 340 333 Surface tension for some interfaces Interface Temperature Surface tension (mN/m) Water–air 20 °C 72.86 ± 0.05 Water–air 21.5 °C 72.75 Water–air 25 °C 71.99±0.05 Methylene iodide–air 20 °C 67.00 Methylene iodide–air 21.5 °C 63.11 Ethylene glycol–air 25 °C 47.3 Ethylene glycol–air 40 °C 46.3 Dimethyl sulfoxide–air 20 °C 43.54 Propylene carbonate–air 20 °C 41.1 Benzene–air 20 °C 28.88 Benzene–air 30 °C 27.56 341 334 Toluene–air 20 °C 28.52 Chloroform–air 25 °C 26.67 Propionic acid–air 20 °C 26.69 Butyric acid–air 20 °C 26.51 Carbon tetrachloride–air 25 °C 26.43 Butyl acetate–air 20 °C 25.09 Diethylene glycol–air 20 °C 30.09 Nonane–air 20 °C 22.85 Methanol–air 20 °C 22.50 Ethanol–air 20 °C 22.39 Ethanol–air 30 °C 21.55 Octane–air 20 °C 21.61 Heptane–air 20 °C 20.14 Ether–air 25 °C 20.14 342 335 Mercury–air 20 °C 486.5 Mercury–air 25 °C 485.5 Mercury–air 30 °C 484.5 NaCl–air 1073 °C 115 KClO3–air 20 °C 81 Water–1-Butanol 20 °C 1.8 Water–Ethyl acetate 20 °C 6.8 Water–Heptanoic acid 20 °C 7.0 Water–Benzaldehyde 20 °C 15.5 Water–transformer oil 20 °C 37.2 Water–Mercury 20 °C 415 Ethanol–Mercury 20 °C 389 Water–1,2-Dichloroethane 20 °C 30.5 ± 0.3 Water–α,α,α-trifluorotoluene 20 °C 38.0 ± 0.5 343 336 Water–nitrobenzene 20 °C 24.4 ± 0.2 Water–nitromethane 20 °C 16.0 ± 0.2 Water–propylene carbonate 20 °C 2.9 ± 0.1 List of inorganic and organic reagents commonly used in chemistry Name General Description Acetic acid an organic acid; is one of the simplest carboxylic acids Acetone an organic compound; simplest example of the ketones Acetylene a hydrocarbon and the simplest alkyne; widely used as a fuel and chemical building block Ammonia inorganic; the precursor to most nitrogen-containing compounds; used to make fertilizer Ammonium hydroxide aqueous ammonia; used in traditional qualitative inorganic analysis Azobisisobutyronitrile organic compound; often used as a foamer in plastics and rubber and as a radical initiator 344 337 Baeyer's reagent is an alkaline solution of potassium permanganate; used in organic chemistry as a qualitative test for the presence of unsaturation, such as double bonds; N-Bromosuccinimide used in radical substitution and electrophilic addition reactions in organic chemistry Butanone (methyl ethyl ketone) organic compound; similar solvent properties to acetone but has a significantly slower evaporation rate Butylated hydroxytoluene a fat-soluble organic compound that is primarily used as an antioxidant food additive n-Butyllithium an organolithium reagent; used as a polymerization initiator in the production of elastomers such as polybutadiene or styrenebutadiene-styrene (SBS) Carbon disulfide a non-polar solvent; used frequently as a building block in organic chemistry Carbon tetrachloride toxic, and its dissolving power is low; consequently, it has been largely superseded by deuterated solvents Carbonyldiimidazole often used for the coupling of amino acids for peptide synthesis and as a reagent in organic synthesis Ceric ammonium nitrate an inorganic compound; used as an oxidising agent in organic synthesis and as a standard oxidant in 345 338 quantitative analysis Chloridotris(triphenylphosphine) rhodium (I) Coordination complex; used in homogeneous catalysis of alkenes to alkanes Chloroform organic compound; often used as CHCl3 (deuterated chloroform) as a solvent for NMR spectroscopy and as a general solvent. Chromic acid a strong and corrosive oxidising agent; an intermediate in chromium plating Chromium trioxide the acidic anhydride of chromic acid; mainly used in chrome-plating Collins reagent used to selectively oxidize primary alcohols to an aldehyde Copper(I) iodide useful in a variety of applications ranging from organic synthesis to cloud seeding Dess–Martin periodinane chemical reagent used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones Diborane the central organic synthesis reagent for hydroboration Dicyclohexylcarbodiimide an organic compound; primary use is to couple amino acids during artificial peptide synthesis Diethyl azodicarboxylate a valuable reagent but also quite dangerous and explodes 346 339 upon heating Diethyl ether organic compound; a common laboratory solvent Dihydropyran a heterocyclic compound; used as a protecting group for alcohols in organic synthesis. Diisobutylaluminium hydride an organoaluminium compound ; a reducing agent; converts esters and nitriles to aldehydes Diisopropyl azodicarboxylate the diisopropyl ester of azodicarboxylic acid; a reagent in the production of many organic compounds Dimethyl ether the simplest ether; a useful precursor to other organic compounds and an aerosol propellant Dimethylformamide organic compound; a common solvent for chemical reactions Dimethylsulfide organosulfur compound; used in petroleum refining and in petrochemical production processes; a reducing agent in ozonolysis reactions Dimethyl sulfoxide an organosulfur compound; an important polar aprotic solvent that dissolves both polar and nonpolar compounds Dioxane a heterocyclic organic compound; classified as an ether Ethanol a powerful psychoactive drug; used in alcoholic 347 340 beverages, in thermometers, as a solvent, and as a fuel Fehling's reagent used to differentiate between water-soluble aldehyde and ketone functional groups Fenton's reagent a solution of hydrogen peroxide and an iron catalyst that is used to oxidize contaminants or waste waters Formaldehyde the simplest aldehyde; an important precursor to many other chemical compounds, such as polymers and polyfunctional alcohols Formic acid the simplest carboxylic acid; often used as a source of the hydride ion Grignard reagents the most common application is for alkylation of aldehydes and ketones Hexamethylphosphoramide a phosphoramide; useful polar aprotic solvent and additive in organic synthesis Hydrazine It's a good reducing agent and is used in the WolffKishner reaction for reducing carbonyls to its corresponding alkanes. used as a foaming agent in preparing polymer foams; also a precursor to polymerization catalysts and pharmaceuticals; also as an Oxygen scavenger in Power Plants Hydrazoic acid used primarily for preservation of stock solutions, and as a reagent 348 341 Hydrochloric acid a highly corrosive, strong mineral acid with many industrial uses Hydrofluoric acid valued source of fluorine, precursor to numerous pharmaceuticals; highly corrosive Hydrogen peroxide an oxidizer commonly used as a bleach Imidazole an organic compound; this aromatic heterocyclic is a diazole and is classified as an alkaloid Isopropyl alcohol simplest example of a secondary alcohol; dissolves a wide range of non-polar compounds Lime used in Flue Gas Desulphurisation in Power Plants Limestone used in Flue Gas Desulphurisation in Power Plants Lithium aluminium hydride a reducing agent in organic synthesis; used to prepare main group and transition metal hydrides from the corresponding metal halides Lithium diisopropylamide strong base used in organic chemistry for the deprotonation of weakly acidic compounds Manganese dioxide used as a pigment and as a precursor to other manganese compounds; used as a reagent in organic synthesis for the oxidation of allylic alcohols 349 342 Meta-Chloroperoxybenzoic acid used as an oxidant in organic synthesis Methyl tert-butyl ether a gasoline additive; also used in organic chemistry as a relatively inexpensive solvent Millon's reagent an analytical reagent used to detect the presence of soluble proteins Nitric acid highly corrosive and toxic strong acid; used for the production of fertilizers, production of explosives, and as a component of aqua regia Osmium tetroxide in organic synthesis, is widely used to oxidise alkenes to the vicinal diols Oxalyl chloride used in organic synthesis for the preparation of acid chlorides from the corresponding carboxylic acids Palladium(II) acetate a catalyst for many organic reactions by combining with many common classes of organic compounds to form reactive adduct Perchloric acid a powerful oxidizing agent; readily forms explosive mixtures; mainly used in the production of rocket fuel Phosphoric acid a mineral acid with many industrial uses; commonly used in the laboratory preparation of hydrogen halides Phosphorus pentachloride one of the most important phosphorus chlorides; a chlorinating reagent. Also used as a dehydrating agent 350 343 for oximes which turn them into nitriles. Phosphorus tribromide used for the conversion of alcohols to alkyl bromides Phosphorus trichloride most important of the three phosphorus chlorides; used to manufacture organophosphorus compounds; used to convert primary and secondary alcohols into alkyl chlorides, or carboxylic acids into acyl chlorides Phosphoryl chloride used to make phosphate esters such as tricresyl phosphate Potassium dichromate a common inorganic chemical reagent, most commonly used as an oxidizing agent in various laboratory and industrial applications Potassium hydroxide a strong base; precursor to most soft and liquid soaps as well as numerous potassium-containing chemicals Potassium permanganate a strong oxidizing agent; can be used to quantitatively determine the total oxidisable organic material in an aqueous sample; a reagent for the synthesis of organic compounds Pyridinium chlorochromate used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones Pyridinium dichromate (Cornforth reagent) converts primary and secondary alcohols to ketones Raney nickel an alternative catalyst for the hydrogenation of vegetable 351 344 oils; in organic synthesis, used for desulfurization Sakaguchi's Reagent Detects the presence of arginine Samarium(II) iodide (Kagan Reagent) a powerful reducing agent Silver oxide used to prepare other silver compounds; in organic chemistry, used as a mild oxidizing agent Silver nitrate precursor to many other silver compounds; commonly used in inorganic chemistry to abstract halides Sodium amide used in the industrial production of indigo, hydrazine, and sodium cyanide; used for the drying of ammonia; used as a strong base in organic chemistry Sodium azide gas-forming component in airbag systems; used in organic synthesis to introduce the azide functional group by displacement of halides Sodium bis(trimethylsilyl)amide a strong base; deprotonates ketones and esters to generate enolate derivative Sodium borohydride a versatile reducing agent; converts ketones and aldehydes to alcohols Sodium chlorite in organic synthesis, used for the oxidation of aldehydes to carboxylic acids Sodium hydride a strong base used in organic synthesis 352 345 Sodium hydroxide strong base with many industrial uses; in the laboratory, used with acids to produce the corresponding salt, also used as an electrolyte Sodium hypochlorite frequently used as a disinfectant or a bleaching agent Sodium nitrite used to convert amines into diazo compounds Sulfuric acid strong mineral acid; major industrial use is the production of phosphoric acid tert-Butyl hydroperoxide used in a variety of oxidation processes; industrially, is used as a starter of radical polymerization Tetrahydrofuran one of the most polar ethers; a useful solvent; its main use is as a precursor to polymers Tetrakis(triphenylphosphine)palladium(0) a catalyst for palladium-catalyzed coupling reactions Tetramethylammonium hydroxide a quaternary ammonium salt; used as an anisotropic etchant of silicon; used as a basic solvent in the development of acidic photoresist in the photolithography process Tetramethylsilane the simplest tetraorganosilane; a building block in organometallic chemistry Thionyl chloride an inorganic compound; used in chlorination reactions; converts carboxylic acids to acyl chlorides 353 346 Thiophenol an organosulfur compound; the simplest aromatic thiol Titanium tetrachloride an intermediate in the production of titanium metal and titanium dioxide Tollens' reagent a chemical test most commonly used to determine whether a known carbonyl-containing compound is an aldehyde or a ketone Triphenylphosphine used in the synthesis of organic and organometallic compounds The Four Fundamental Interactions of Nature Interaction Current theory Mediators Relative strength Range (m) Weak Electroweak theory (EWT) W and Z bosons 1025 10−18 Strong Quantum chromodynamics gluons 1038 10−15 photons 1036 ∞ gravitons 1 ∞ (QCD) Electromagnetic Quantum electrodynamics (QED) Gravitation General relativity (GR) (hypothetical) 354 347 Table of liquid–vapor critical temperature and pressure for selected substances Substance Critical temperature Critical pressure (absolute) Argon −122.4 °C (150.8 K) 48.1 atm (4,870 kPa) Ammonia (NH3) 132.4 °C (405.5 K) 111.3 atm (11,280 kPa) R-134a 101.06 °C (374.21 K) 40.06 atm (4,059 kPa) R-410A 72.8 °C (345.9 K) 47.08 atm (4,770 kPa) Bromine 310.8 °C (584.0 K) 102 atm (10,300 kPa) Caesium 1,664.85 °C (1,938.00 K) 94 atm (9,500 kPa) Chlorine 143.8 °C (416.9 K) 76.0 atm (7,700 kPa) Ethanol (C2H5OH) 241 °C (514 K) 62.18 atm (6,300 kPa) Fluorine −128.85 °C (144.30 K) 51.5 atm (5,220 kPa) Helium −267.96 °C (5.19 K) 2.24 atm (227 kPa) Hydrogen −239.95 °C (33.20 K) 12.8 atm (1,300 kPa) Krypton −63.8 °C (209.3 K) 54.3 atm (5,500 kPa) Methane (CH4) −82.3 °C (190.8 K) 45.79 atm (4,640 kPa) 355 348 Neon −228.75 °C (44.40 K) 27.2 atm (2,760 kPa) Nitrogen −146.9 °C (126.2 K) 33.5 atm (3,390 kPa) Oxygen (O2) −118.6 °C (154.6 K) 49.8 atm (5,050 kPa) Carbon dioxide (CO2) 31.04 °C (304.19 K) 72.8 atm (7,380 kPa) Nitrous oxide (N2O) 36.4 °C (309.5 K) 71.5 atm (7,240 kPa) Sulfuric acid (H2SO4) 654 °C (927 K) 45.4 atm (4,600 kPa) Xenon 16.6 °C (289.8 K) 57.6 atm (5,840 kPa) Lithium 2,950 °C (3,220 K) 652 atm (66,100 kPa) Mercury 1,476.9 °C (1,750.1 K) 1,720 atm (174,000 kPa) Sulfur 1,040.85 °C (1,314.00 K) 207 atm (21,000 kPa) Iron 8,227 °C (8,500 K) Gold 6,977 °C (7,250 K) Aluminum 7,577 °C (7,850 K) Water (H2O) 373.946 °C (647.096 K) 356 349 5,000 atm (510,000 kPa) 217.7 atm (22,060 kPa) List of Natural Satellites Name of Natural Satellite Planet of Origin Moon Earth Mimas Saturn Enceladus Saturn Tethys Saturn Rhea Saturn Dione Saturn Titan Saturn Hyperion Saturn Iapetus Saturn Phobos Mars Deimos Mars Metis Jupiter Adrastea Jupiter Amalthea Jupiter Thebe Jupiter Io Jupiter Europa Jupiter Ganymede Jupiter Callisto Jupiter Themisto Jupiter Leda Jupiter Himalia Jupiter Lysithea Jupiter Elara Jupiter Dia Jupiter Carpo Jupiter 357 350 S/2003 J 12 Jupiter Euporie Jupiter S/2003 J 3 Jupiter S/2011 J 1 Jupiter S/2003 J 18 Jupiter S/2010 J 2 Jupiter Thelxinoe Jupiter Euanthe Jupiter Helike Jupiter Orthosie Jupiter S/2016 J 1 Jupiter Iocaste Jupiter S/2003 J 16 Jupiter Praxidike Jupiter Harpalyke Jupiter Mneme Jupiter Hermippe Jupiter Thyone Jupiter Ananke Jupiter Herse Jupiter Aitne Saturn Kale Jupiter Taygete Jupiter S/2003 J 19 Jupiter Chaldene Jupiter S/2003 J 15 Jupiter S/2003 J 10 Jupiter S/2003 J 23 Jupiter Erinome Jupiter Aoede Jupiter 358 351 Kallichore Jupiter Kalyke Jupiter Carme Jupiter Callirrhoe Jupiter Eurydome Jupiter Pasithee Jupiter S/2010 J 1 Jupiter Kore Jupiter Cyllene Jupiter S/2011 J 2 Jupiter Eukelade Jupiter S/2017 J 1 Jupiter S/2003 J 4 Jupiter Pasiphae Jupiter Hegemone Jupiter Arche Jupiter Isonoe Jupiter S/2003 J 9 Jupiter S/2003 J 5 Jupiter Sinope Jupiter Sponde Jupiter Autonoe Jupiter Megaclite Jupiter S/2003 J 2 Jupiter S/2009 S 1 Saturn Pan Saturn Daphnis Saturn Atlas Saturn Peggy Saturn Prometheus Saturn 359 352 Pandora Saturn Epimetheus Saturn Janus Saturn Aegaeon Saturn Mimas Saturn Methone Saturn Anthe Saturn Pallene Saturn Enceladus Saturn Tethys Saturn Telesto Saturn Calypso Saturn Dione Saturn Helene Saturn Polydeuces Saturn Rhea Saturn Titan Saturn Hyperion Saturn Iapetus Saturn Kiviuq Saturn Ijiraq Saturn Phoebe Saturn Paaliaq Saturn Skathi Saturn Albiorix Saturn S/2007 S 2 Saturn Bebhionn Saturn Erriapus Saturn Skoll Saturn Siarnaq Saturn 360 353 Tarqeq Saturn S/2004 S 13 Saturn Greip Saturn Hyrrokkin Saturn Jarnsaxa Saturn Tarvos Saturn Mundilfari Saturn S/2006 S 1 Saturn S/2004 S 17 Saturn Bergelmir Saturn Narvi Saturn Suttungr Saturn Hati Saturn S/2004 S 12 Saturn Farbauti Saturn Thrymr Saturn Aegir Saturn S/2007 S 3 Saturn Bestla Saturn S/2004 S 7 Saturn S/2006 S 3 Saturn Fenrir Saturn Surtur Saturn Kari Saturn Ymir Saturn Loge Saturn Fornjot Saturn Themis (Destroyed) Saturn Chiron (Destroyed) Saturn Cordelia Uranus 361 354 Ophelia Uranus Bianca Uranus Cressida Uranus Desdemona Uranus Juliet Uranus Portia Uranus Rosalind Uranus Cupid Uranus Belinda Uranus Perdita Uranus Puck Uranus Mab Uranus Miranda Uranus Ariel Uranus Umbriel Uranus Titania Uranus Oberon Uranus Francisco Uranus Caliban Uranus Stephano Uranus Trinculo Uranus Sycorax Uranus Margaret Uranus Prospero Uranus Setebos Uranus Ferdinand Uranus Naiad Neptune Thalassa Neptune Despina Neptune Galatea Neptune 362 355 Larissa Neptune Hippocamp Neptune Proteus Neptune Triton Neptune Nereid Neptune Halimede Neptune Sao Neptune Laomedeia Neptune Psamathe Neptune Neso Neptune Charon Pluto Styx Pluto Nix Pluto Kerberos Pluto Hydra Pluto MK 2 Makemake Namaka Haumea Hi'laka Dysnomia Eris Dactyl 243 Ida Skamandrios 624 Hektor Remus 87 Sylvia Romulus 87 Sylvia S/2001 (107) 1 107 Camilla S/2016 (107) 1 107 Camilla Petit-Prince 45 Eugenia S/2004 (45) 1 45 Eugenia S/2007 (225088) 1 Snow-White S/2013 (285263) 1 (285263) 1998 QE2 Alexhelios 216 Kleopatra 363 356 Cleoselene 216 Kleopatra Weywot 50000 Quaoar Didymoon 65803 Didymos Groups Neurotransmitter Function Acetylcholine Acetylcholine Excitatory Amines Epinephrine Excitatory Norephinephrine Excitatory Dopamine Excitatory and Inhibitory Serotonin Excitatory Glutamate Excitatory Glycine Mainly inhibitory g-Aminobutiric acid (GABA) Inhibitory Amino Acids Binary star Orbital period AM Canum Venaticorum 17.146 minutes Beta Lyrae AB 12.9075 days Alpha Centauri AB 79.91 years Proxima Centauri – Alpha Centauri AB 500,000 years or more 364 357 Properties of Ionic Diatomic Molecules Molecule Dissociation Energy(eV) Equilibrium Separation (nm) (Bond length) NaCl 4.26 0.236 NaF 4.99 0.193 NaBr 3.8 0.250 NaI 3.1 0.271 NaH 2.08 0.189 LiCl 4.86 0.202 LiH 2.47 0.239 LiI 3.67 0.238 KCl 4.43 0.267 KBr 3.97 0.282 RbF 5.12 0.227 RbCl 4.64 0.279 CsI 3.57 0.337 Properties of Heteronuclear Diatomic Molecules Molecule Dissociation Energy(eV) Equilibrium Separation (nm) (Bond length) BN 4.0 0.128 CO 11.2 0.113 HBr ... 0.141 HCl 4.4 0.127 HF 5.8 0.092 NO 7.0 0.115 PbO 4.1 0.192 PbS 3.3 0.239 365 358 Thermal Conductivity and Debye Temperature Li Be Debye temperature and thermal conductivity B C N O F Ne 344 1440 Low temperature limit of Debye temperature in Kelvin ... 2230 ... ... ... 75 0.85 2.00 Thermal conductivity at 300K, in W/cmK 0.27 1.29 ... ... ... ... Na Mg ... Al Si P S Cl Ar 158 400 428 645 ... ... ... 92 1.41 1.56 2.37 1.48 ... ... ... ... K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 91 230 360 420 380 630 410 470 445 450 343 327 320 374 282 90 ... 72 1.02 ... 0.16 0.22 0.31 0.94 0.08 0.80 1.00 0.91 4.01 1.16 0.41 0.6 0.50 0.02 ... ... Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe 56 147 280 291 275 450 ... 600 480 274 225 209 108 200 211 153 ... 64 0.58 ... 0.17 0.23 0.54 1.38 0.51 1.17 1.50 0.72 4.29 0.97 0.82 0.67 0.24 0.02 ... ... Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn 38 110 142 252 240 400 430 500 420 240 165 71.9 78.5 105 119 ... ... 64 0.36 ... 0.14 0.23 0.58 1.74 0.48 0.88 1.47 0.72 3.17 ... 0.46 0.35 0.08 ... ... ... Fr Ra Ac ... ... ... ... ... ... ... ... ... ... Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu ... ... ... ... ... ... 200 ... 210 ... ... ... 120 210 0.11 0.13 0.16 ... 0.13 ... 0.11 0.11 0.11 0.16 0.14 0.17 0.35 0.16 Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr 163 ... 207 ... ... ... ... ... ... ... ... ... ... ... 0.54 ... 0.28 0.06 0.07 ... ... ... ... ... ... ... ... ... 366 359 ... Vibrational frequencies of diatomic molecules Molecule Frequency (1013 Hz) HH 13 NN 7.0 CO 6.4 NO 5.7 OO 4.7 Superconductor coherence lengths and penetration depths Material Coherence length London penetration depth Ratio 𝛌𝐋 𝛏𝟎 ξ0(nm) λL(nm) Sn 230 34 0.16 Al 1600 16 0.010 Pb 83 37 0.45 Cd 760 110 0.14 Nb 38 39 1.02 Semiconductor Band Gaps 367 360 Material Energy gap (eV) 0K 300K Si 1.17 1.11 Ge 0.74 0.66 InSb 0.23 0.17 InAs 0.43 0.36 InP 1.42 1.27 GaP 2.32 2.25 GaAs 1.52 1.43 GaSb 0.81 0.68 CdSe 1.84 1.74 CdTe 1.61 1.44 ZnO 3.44 3.2 ZnS 3.91 3.6 Quarks Generation 1 Name up down Symbol Antiparticle Spin Charge (e) u d Mass (MeV/c2) u̅ 1 + 2 2.2+0.6 −0.4 d̅ 1 − 1 4.6+0.5 −0.4 368 361 2 2 3 3 2 charm strange 3 top bottom c s t b c̅ 1 + 2 1,280±30 s̅ 1 − 1 96+8 −4 t̅ 1 + 2 173,100±600 ̅ b 1 − 1 4,180+40 −30 2 2 2 2 3 3 3 3 Leptons Generation Name Symbol Antiparticle Spin Charge (e) 1 Electron e− e+ 2 νe ν̅e Muon Muon neutrino μ− μ+ νμ νμ ̅̅̅ 369 362 (MeV/c2) 1 −1 0.511 1 0 < 0.0000022 1 −1 105.7 1 0 < 0.170 2 Electron neutrino Mass 2 2 2 3 Tau Tau neutrino τ− τ+ 1 −1 1,776.86±0.12 ντ ν̅τ 1 0 < 15.5 2 2 Bosons Name Symbol Antiparticle Spin Charge Mass (e) Interaction Observed mediated (GeV/c2) Photon γ Self W− W+ 1 0 0 Electromagnetism Yes 1 −1 80.385±0.015 Weak interaction Yes Self 1 0 91.1875±0.0021 Weak interaction Yes Self 1 0 0 Strong interaction Yes Self 0 0 125.09±0.24 Mass Yes Self 2 2 0 Gravitation No W boson Z boson Z Gluon g Higgs boson H Graviton G 0 370 363 Low-frequency dielectric constants of some common solvents Solvent Dielectric constant Temperature (K) benzene 2.3 298 diethyl ether 4.3 293 tetrahydrofuran (THF) 7.6 298 dichloromethane 9.1 293 liquid ammonia 17 273 ethanol 24.3 298 methanol 32.7 298 nitromethane 35.9 303 dimethyl formamide (DMF) 36.7 298 acetonitrile 37.5 293 water 78.4 298 formamide 109 293 371 364 Poisson's ratio values for different materials Material Poisson's ratio rubber 0.4999 gold 0.42–0.44 saturated clay 0.40–0.49 magnesium 0.252–0.289 titanium 0.265–0.34 copper 0.33 aluminium-alloy 0.32 clay 0.30–0.45 stainless steel 0.30–0.31 steel 0.27–0.30 cast iron 0.21–0.26 sand 0.20–0.455 concrete 0.1–0.2 glass 0.18–0.3 372 365 Material metallic glasses 0.276–0.409 foam 0.10–0.50 cork 0.0 Typical values for shear modulus (GPa) (at room temperature) Diamond 478.0 Steel 79.3 Iron 52.5 Copper 44.7 Titanium 41.4 Glass 26.2 Aluminium 25.5 Polyethylene 0.117 Rubber 0.0006 Granite 24 Shale 1.6 Limestone 24 Chalk 3.2 Sandstone 0.4 Wood 4 373 366 Thermal diffusivity of selected materials and substances Material Thermal diffusivity (mm²/s) Wood (Yellow Pine) 0.082 Water vapour (1 atm, 400 K) 23.38 Water at 25 °C 0.143 Tin 40 Steel, stainless 310 at 25 °C 3.352 Steel, stainless 304A at 27 °C 4.2 Steel, AISI 1010 (0.1% carbon) 18.8 Steel, 1% carbon 11.72 Silver, pure (99.9%) 165.63 Silicon Dioxide (Polycrystalline) 0.83 Silicon 88 Si3 N4 with CNTs 26 °C 9.142 Si3 N4 without CNTs 26 °C 8.605 Sandstone 1.15 374 367 Rubber 0.089 - 0.13 Quartz 1.4 Pyrolytic graphite, parallel to layers 1220 Pyrolytic graphite, normal to layers 3.6 PVC (Polyvinyl Chloride) 0.08 PTFE (Polytetrafluorethylene) at 25 °C 0.124 PP (Polypropylene) at 25 °C 0.096 PC (Polycarbonate) at 25 °C 0.144 Paraffin at 25 °C 0.081 Oil, engine (saturated liquid, 100 °C) 0.0738 Nylon 0.09 Nitrogen (300 K, 1 atm) 22 Molybdenum (99.95%) at 25 °C 54.3 Iron 23 Inconel 600 at 25 °C 3.428 Ice at 0 °C 1.02 375 368 Hydrogen (300 K, 1 atm) 160 Helium (300 K, 1 atm) 190 Gold 127 Glass, window 0.34 Copper at 25 °C 111 Carbon/carbon composite at 25 °C 216.5 Brick, common 0.52 Brick, adobe 0.27 Argon (300 K, 1 atm) 22 Aluminium oxide (polycrystalline) 12.0 Aluminium 6061-T6 Alloy 64 Aluminium 97 Alcohol 0.07 Al-10Si-Mn-Mg (Silafont 36) at 20 °C 74.2 Al-5Mg-2Si-Mn (Magsimal-59) at 20 °C 44.0 Air (300 K) 19 376 369 Substance Vapor pressure Temperature (°C) (Pa) (bar) (mmHg) Tungsten 100 Pa 0.001 0.75 3203 Ethylene glycol 500 Pa 0.005 3.75 20 Xenon difluoride 600 Pa 0.006 4.50 25 Water (H2O) 2.3 kPa 0.023 17.5 20 Propanol 2.4 kPa 0.024 18.0 20 Methyl isobutyl ketone 2.66 kPa 0.0266 19.95 25 Ethanol 5.83 kPa 0.0583 43.7 20 Freon 113 37.9 kPa 0.379 284 20 Acetaldehyde 98.7 kPa 0.987 740 20 Butane 220 kPa 2.2 1650 20 Formaldehyde 435.7 kPa 4.357 3268 20 Propane 997.8 kPa 9.978 7584 26.85 Carbonyl sulfide 1.255 MPa 12.55 9412 25 Nitrous oxide 5.660 MPa 56.60 42453 25 Carbon dioxide 5.7 MPa 57 42753 20 377 370 Antibody isotypes of mammals Class Subclasses IgA 2 Description Found in mucosal areas, such as the gut, respiratory tract and urogenital tract, and prevents colonization by pathogens. Also found in saliva, tears, and breast milk. IgD 1 Functions mainly as an antigen receptor on B cells that have not been exposed to antigens. It has been shown to activate basophils and mast cells to produce antimicrobial factors. IgE 1 Binds to allergens and triggers histamine release from mast cells and basophils, and is involved in allergy. Also protects against parasitic worms. IgG 4 In its four forms, provides the majority of antibody-based immunity against invading pathogens. The only antibody capable of crossing the placenta to give passive immunity to the fetus. IgM 1 Expressed on the surface of B cells (monomer) and in a secreted form (pentamer) with very high avidity. Eliminates pathogens in the early stages of B cell-mediated (humoral) immunity before there is sufficient IgG. 378 371 Antibody isotypes not found in mammals Class Types Description IgY Found in birds and reptiles; related to mammalian IgG. IgW Found in sharks and skates; related to mammalian IgD. The luminosity L of a star is related to its apparent brightness b and its distance d to us by: b= L 4πd2 The luminosity L of a star is related to its radius R and its temperature T by: L = 4πR2σT4 where σ is Stefan–Boltzmann constant. Helmholtz free energy: F = U − TS Gibbs free energy: G = H − TS Enthalpy: H = U + PV 379 372 where: H → enthalpy, P → pressure, V → volume, T → temperature, S → entropy and U → internal energy. Limiting Magnitudes for Visual Observation at High Magnification Telescope aperture Limiting (mm) Magnitude 35 11.3 60 12.3 102 13.3 152 14.1 203 14.7 305 15.4 406 15.7 508 16.4 380 373 Neutron energy range names Neutron energy Energy range 0.0–0.025 eV Cold neutrons 0.025 eV Thermal neutrons 0.025–0.4 eV Epithermal neutrons 0.4–0.5 eV Cadmium neutrons 0.5–1 eV EpiCadmium neutrons 1–10 eV Slow neutrons 10–300 eV Resonance neutrons 300 eV–1 MeV Intermediate neutrons 1–20 MeV Fast neutrons > 20 MeV Ultrafast neutrons 381 374 Black hole Equations:  Rs = 2GM  T= ħc3  P=  tev =  S= c2 8πGMkB ħc6 15360πG2M2 5120πG2 M3 ħc4 kB A  dE =  dA ρ= ħG 16πG2 M2 A=  480c2 V 4L2Planck  dt = κ c4 8π dA + ΩdJ + ϕdQ ≥0 3c6 32πG3 M2 where: M is the Mass, G is the gravitational constant, S is the Entropy, A is the Horizon area, t ev is the evaporation time, T is the temperature, kB is the Boltzmann constant, ρ is the density, c is Għ the speed of light, LPlanck = √ 3 is the Planck length, V is the volume, Rs is the Schwarzschild c radius, E = Mc2 is the energy, κ is the surface gravity, Ω is the angular velocity, J is the angular momentum, ϕ is the electrostatic potential and Q is the electric charge. 382 375 Thermodynamics of the universe: 0 = dQ = dU + PdV dU = − PdV where Q is the total heat which is assumed to be constant, U is the internal energy of the matter and radiation in the universe, P is the pressure and V the volume. Energy density u = For radiation, p = U u 3 V du = − (P + u) dV V = − 3(P + u) d𝑎 𝑎 whereas for matter p << u and the pressure can be neglected. Thus we get: For radiation du = − 4u d𝑎 thus u is proportional to a−4 du = − 3u d𝑎 thus u is proportional to a−3 For matter 𝑎 𝑎 a being the scale factor of the universe. Redshift λnow λthen 383 376 = 𝑎now 𝑎then 1+z= 𝑎now 𝑎then If the source moves away from the observer with velocity v, which is much less than the speed of light (v ≪ c), the redshift is given by: z= v c Gravitational redshift: 1 1+ z = 2GM rc2 √1− where  G is the gravitational constant,  M is the mass of the object creating the gravitational field,  r is the radial coordinate of the source (which is analogous to the classical distance from the center of the object, but is actually a Schwarzschild coordinate), and  c is the speed of light. Hubble's law: v = HD where  v is the recessional velocity, typically expressed in km/s.  H is the Hubble parameter  D is the proper distance from the galaxy to the observer, measured in mega parsecs (Mpc) 384 377 Hubble Distance = Hubble Time = dH c H 1 H = −H2 (1+ q) dt q being the deceleration parameter. Critical density of the universe: ρc = 3H2 8πG Density parameter: Ω= ρ ρc = 8πGρ 3H2  Ω = 0: empty universe  Ω < 1: expansion overcomes gravity; universe expands forever  Ω = 1: critical density; mass is just enough to stop it expanding but not enough to make it recollapse  Ω > 1 : gravity overcomes expansion; universe recollapse General relativity: Ω determines the curvature (k), or "shape", of the universe:  Ω = 1: flat universe, k = 0 385 378  Ω > 1: closed (or bound) universe, k = +1  Ω < 1: open (or unbound) universe, k = −1 The virial theorem relates the total kinetic energy of a self-gravitating body due to the motions of its constituent parts, T to the gravitational potential energy, U of the body. 2T + U = 0 Chandrasekhar limit: Mlimit =  ѡ03 √3π 2 × 1 μe × (Planck mass)3 (proton mass)2 μe is the average molecular weight per electron, which depends upon the chemical composition of the star.  ω03 ≈ 2.018236 is a constant connected with the solution to the Lane–Emden equation. Schönberg–Chandrasekhar limit: Mcore M μ2env ≈ 0.37 2 μ core  Mcore − mass of the core.  M − mass of the whole star.  μcore − mean molecular mass of the core.  μenv − mean molecular mass of the envelope. Eddington luminosity: LEdd = 4πGMmp c σT 379 386 Eddington Parameter A= Luminosity of the star Eddington Luminosity where M is the mass of the star, G is the gravitational constant, mp is the proton mass, c is the speed of light and σT is the Thomson cross section. σT = 8πr2e 3 Classical electron radius re = e2 4πε0 me c2 where e is the elementary charge, me is the electron rest mass, c is the speed of light, and ε0 is the permittivity of free space. Fine-structure constant α= where ħ = h 2π is the reduced Planck constant. e2 4πε0 ħc Gravitational coupling constant αG = (electron rest mass)2 (Planck mass)2 387 380 αG = (proton rest mass)2 (Planck mass)2 Compton scattering λ'–λ= h me c (1− cosθ) where λ is the initial wavelength, λ' is the wavelength after scattering, h is the Planck constant, me is the electron rest mass, c is the speed of light, and θ is the scattering angle. Photoelectric effect Energy of the photon = Work function of the surface + Kinetic energy of the emitted electron E = W + KE hυ = hυ0 + υ < υ0 → no photoelectric emission 388 381 m0 v2 2 hυ = hυ0 + eVstop where e is the electron charge and Vstop is the stopping voltage (or stopping potential). Photoemission from atoms: hυ = electron's binding energy + KE Photoemission from solids: hυ = W + electron's binding energy + KE Photon gas 4σT4  U=  μ=0 c U  P=  S=  H=  A=−  G=0 3V = 4U ×V 4σT4 3c 3T 4U 3 U 3 where U is the internal energy, Gibbs free energy, H is the Enthalpy, A is the Helmholtz free energy, S is the entropy, T is the temperature, V is the volume, μ is the chemical potential, c is the speed of light and σ = π2 k2B 60ħ3 c2 is the Stefan's constant. 389 382 Poynting–Robertson effect The Poynting–Robertson force is equal to: FPR = v c2 W= r2 Lsun 4c2 GMsun √ R5 where v is the grain's velocity, c is the speed of light, W is the power of the incoming radiation, r the grain's radius, G is the universal gravitational constant, Msun the Sun's mass, Lsun is the solar luminosity and R the grain's orbital radius. The ratio of the force due to radiation pressure to the force of gravity on the particle: β= FR FG = 3Lsun QPR 16πGMsun cρr where QPR is the Mie scattering coefficient and ρ is the density and r is the radius of the dust grain. The scale height is related to the temperature (T) and mean molecular mass (m) of the atmosphere kB T by the formula H = where kB is Boltzmann's constant and g is the gravitational acceleration of mg the body. 390 383 If electrons are accelerated to a velocity v by a potential difference V and then allowed to collide with a metal target, the maximum frequency of the X-rays emitted is given by the equation: Therefore: m0 v2 2 = eV = hυmax υmax = eV h This shows that the maximum frequency is directly proportional to the accelerating voltage. Fermi energy 1 The Fermi energy for a non-interacting ensemble of identical spin- fermions in a three2 dimensional (non-relativistic) system is given by: EF = ħ2 2m0 ( 3π2 N 2/3 ) V where N is the number of particles, m0 the rest mass of each fermion, V the volume of the system, and ħ the reduced Planck constant. EF = k B TF vF = pF m0 pF = ħkF where TF is the Fermi temperature, vF is the Fermi velocity, pF is the Fermi momentum and kF is Fermi wave-vector. 391 384 Heat capacity ratio for various gases Temp. Gas γ Temp. Gas γ −181 °C H2 1.597 200 °C Dry air 1.398 20 °C NO 1.400 −76 °C 1.453 400 °C 1.393 20 °C N2O 1.310 20 °C 1.410 1000 °C 1.365 −181 °C N2 1.470 100 °C 1.404 15 °C 1.404 400 °C 1.387 0 °C 1.310 20 °C Cl2 1.340 1000 °C 1.358 20 °C 1.300 −115 °C CH4 1.410 2000 °C 1.318 100 °C 1.281 −74 °C 1.350 1.660 400 °C 1.235 20 °C 1.320 1000 °C 1.195 15 °C NH3 1.310 20 °C 20 °C He Water vapour 1.330 Gas CO2 γ Temp. 100 °C 1.324 20 °C CO 1.400 19 °C Ne 1.640 200 °C 1.310 −181 °C O2 1.450 19 °C Xe 1.660 1.760 −76 °C 1.415 19 °C Kr 1.680 1.670 20 °C 1.400 15 °C SO2 1.290 1.403 100 °C 1.399 360 °C Hg 1.670 20 °C 1.400 200 °C 1.397 15 °C C2H6 1.220 100 °C 1.401 400 °C 1.394 16 °C C3H8 1.130 −180 °C Ar 20 °C 0 °C Dry air 392 385 The acid in our stomach is strong enough to dissolve razor blades An average cumulus cloud weighs over a million pounds. There are more trees on Earth than stars in our galaxy Cold water heats up faster than hot water Water can exist in all three states: solid (ice), liquid and gas (vapor) at the same time at a temperature called triple point. Men are more likely to be colorblind than women Sound waves almost always generate a little bit of heat when they travel and are absorbed by materials. According to Albert Einstein's theory of Relativity, the farther you are from the earth's surface, the faster time passes. 386 Gravitational waves P=− − dE dt dr dt = = tlife = 32G4(m1 m2 )2 5c5 64G3(m1 m2 ) 5c5 × 5c5 r4 × (m1 +m2 ) r5 (m1 +m2 ) r3 256G3 (m1 m2 )(m1 +m2 ) where:  P is the rate of loss of energy from the binary system through gravitational radiation.  m1, m2 = masses of the orbiting bodies.  tlife is the lifetime of distance "r" between the masses orbiting each other in highly circular orbit about their center of mass. Relative size of a scattering particle is defined by size parameter which is the ratio of its characteristic dimension and wavelength of incident radiation α=   2πr λ α ≪ 1: Rayleigh scattering (small particle compared to wavelength of light) α ≈ 1: Mie scattering (particle about the same size as wavelength of light, valid only for spheres)  α ≫ 1: geometric scattering (particle much larger than wavelength of light). 393 387 Laws of reflection:  The incident ray, the reflected ray and the normal ray at the point of incidence, lie in the same plane.  The angle of incidence is equal to the angle of reflection Laws of refraction:  The incident ray refracted ray, and the normal to the interface of two media at the point of incidence all lie on the same plane.  The ratio of the sine of the angle of incidence to the sine of the angle of refraction is a constant. sin i sin r = constant Zeroth Law of Thermodynamics: C A B If two bodies A and B are in thermal equilibrium with third body C, then body A and B are also in thermal equilibrium with each other. Tyndall effect The scattering of light by very small particles suspended in a gas or liquid 388 Wiedemann-Franz Law: Thermal conductivity of the material Electrical conductivity of the material Thermal conductivity of the material Electrical conductivity of the material Plant Cell ∝ Temperature = Lorenz number × Temperature Animal Cell Cell Shape Square or rectangular in shape Irregular or round in shape Cell Wall Present Absent Cell Membrane Present Present Endoplasmic Reticulum Present Present Nucleus Present and lies on one side of the cell Present and lies in the centre of the cell Lysosomes Present but are very rare Present Centrosomes Absent Present Golgi Apparatus Present Present Cytoplasm Present Present Ribosomes 389 Present Present Plastids Present Absent Vacuoles Few large or a single, centrally positioned vacuole Usually small and numerous Cilia Absent Present in most of the animal cells Mitochondria Present but fewer in number Present and are numerous Mode of Nutrition Primarily autotrophic Heterotrophic Mitosis Meiosis It takes place in both Haploid cells and diploid cells It takes place only in diploid cells. It takes place in all body cells or vegetative cells or It takes place in reproductive cells or germinal cells. somatic. Nucleus divides once Nucleus divides twice to produce 4 nuclei. Daughter cells are identical to mother cells Daughter cells are not identical. Chromosomes do not pair Homologous chromosomes (similar) pair to form bivalent ones. Chiasmata is absent, Also there is no crossing over Chiasmata present. Crossing over between non-sister chromatids occurs. The chromosome number in the daughter cell is Chromosome number is reduced to half of the parent cell. unchanged. The entire cell division is short comparatively. The duration of cell division is very large as it involves many steps. It helps for the growth of the body and in lower forms It helps in gamete formation for sexual reproduction. like bacteria, to multiply organism numbers. 390 Soap Detergent Sodium salt of Carboxylic acids Sodium salts of benzene sulphonic acids. Soaps are bio-degradable Some detergents are non- biodegradable Soaps do not lather in hard water Detergent lather well in hard water Weak cleansing action Have strong cleansing action Photosynthesis Respiration It is the process by which plants use sunlight, water, It refers to a metabolic pathway that breaks down and carbon dioxide to create oxygen and energy in the glucose and produces ATP. form of sugar. Occurs in plants containing chlorophyll and some Occurs in all living organisms bacteria It takes place in chloroplasts It takes place in mitochondria Anabolic process Catabolic process Endothermic reaction because it needs energy Exergonic reaction because it releases energy Produces food and captures the energy Takes in oxygen and liberates out carbon dioxide Requires sunlight because it is mandatory Does not require sunlight as it takes place all the time Absorbs carbon dioxide and water Releases carbon dioxide and water 6CO2 + 6H2O → C6H12O6 + 6O2 C6H12O6 + 6O2 → 6CO2 + 6H2O 391 Bragg's Law n λ = 2 d sin θ where λ is the wavelength of the radiation used, d is the inter-planar spacing involved and θ is the angle between the incident (or diffracted) ray and the relevant crystal planes; n is an integer, referred to as the order of diffraction. The Nuclear radius is given by the following relation: R = R0 A1/3 where R0 is constant for all nuclei and its value is 1.2 × 10−15 m and A = Mass number of nucleus (the number of protons Z, plus the number of neutrons N). Moore's law → the number of transistors in a dense integrated circuit (IC) doubles about every two years. In a medium of constant refractive index, n, the Optical path length for a path of geometrical length L is just OPL = nL Optical depth = ln10 × Absorbance 394 392 Refractive index n= c v where c is the speed of light in vacuum and v is the phase velocity of light in the medium. For example, the refractive index of water is 1.333, meaning that light travels 1.333 times as fast in c vacuum as in water. The speed of light in a medium is v = , and similarly the wavelength in that n medium is λ = λ0 n , where λ0 is the wavelength of that light in vacuum. Refractivity = (n – 1) Specific refractivity = Refractivity of the medium Density of the medium Eyring equation ∆G0∗ k=κ exp (− ) h RT kB T where ∆G∗0 is the standard Gibbs free energy of activation, κ is the transmission coefficient, kB is Boltzmann's constant, T is the absolute temperature, k is the reaction rate constant, R is the gas constant and h is Planck's constant. Michaelis–Menten equation 395 393 The Michaelis–Menten kinetics takes the form of an equation describing the rate of enzymatic reactions, by relating reaction rate v (rate of formation of product, [P]) to [S], the concentration of a substrate S. Its formula is given by: v= d[P] dt = vmax [S] Km + [S] This equation is called the Michaelis–Menten equation. Here, vmax represents the maximum rate achieved by the system, happening at saturating substrate concentration. The value of the Michaelis constant Km is numerically equal to the substrate concentration at which the reaction rate is half of vmax. k1 E + S → ES k2 ES → E + S k3 ES → P + E Km = (k2 + k3 ) k3 k1 (catalytic efficiency) is a measure of how efficiently an enzyme converts a Km substrate into product. The ratio 396 394 Monod equation μ = μmax S Ks + S where:  μ is the specific growth rate of the microorganisms  μmax is the maximum specific growth rate of the microorganisms  S is the concentration of the limiting substrate for growth  Ks is the "half-velocity constant" or the value of S when Nernst Equation 0 Ecell = Ecell − RT nF lnQ where:  Ecell = cell potential of the cell  0 Ecell = cell potential under standard conditions  R = universal gas constant  T = temperature  n = number of electrons transferred in the redox reaction  F = Faraday constant  Q = reaction quotient 397 395 μ μmax = 0.5 Faraday's law of electrolysis The mass m of elements deposited at an electrode in g is directly proportional to the Charge Q in Coulombs. m=Z×Q Here, the constant of proportionality Z is called the Electro-Chemical Equivalent of the substance. Chemical equivalent of a substance = atomic weight valency Activity of sample at instant t is given by A = A0 eλt where λ is the Decay constant Activity per unit mass → Specific activity Half life: T1 = 2 0.693 Average life: Tav = 398 396 λ T1 2 0.693 Quantum numbers  Principal Quantum Number (n) = 1, 2, 3, …, ∞  Orbital angular momentum of electron in any orbit =  Angular Momentum (Secondary, Azimuthal) Quantum Number ( l ) = 0,1, ..., (n −1).  Number of orbitals in a subshell = 2l + 1  Maximum number of electrons in particular subshell = 2 × (2l +1)  Orbital angular momentum (L) = Name Symbol h 2π 𝑛ℎ 2π √𝑙 (𝑙 + 1) Orbital meaning Range of Value examples values Principal quantum number n shell 1≤n n = 1, 2, 3, … Azimuthal quantum l subshell (s orbital is listed as 0, p 0≤l≤n−1 for n = 3: number (angular momentum) Magnetic quantum number orbital as 1 etc.) ml energy shift (orientation of the l = 0, 1, 2 (s, p, d) −l ≤ ml ≤ l ml = −2, −1, 0, 1, 2 subshell's shape) (projection of angular momentum) spin of the electron Spin quantum number ms 1 (− = "spin down", 2 1 2 = "spin up") 399 397 for l = 2: −s ≤ ms ≤ s for an electron 1 s= , 2 1 1 so ms = −2, +2 Nuclide Ratio of atomic mass to mass number 1 H 1.00782505 2 H 1.0070508885 3 H 1.0053497592 3 He 1.0053431064 4 He 1.0006508135 6 Li 12 1.0025204658 C 1 14 N 1.0002195718 16 O 0.9996821637 Fe 0.9988381696 56 210 232 Po 0.9999184462 Th 1.0001640315 238 U 1.0002133958 400 398 Equivalent weight of acid = Molar mass Basicity Basicity → The number of hydrogen atoms replaceable by a base in a particular acid Equivalent weight of base = Molar mass Acidity Acidity → The number of ionizable hydrogen ions (OH−) present in one molecule of a base Oxidation number = number of electrons in the valence shell – number of electrons left after bonding Hardness in ppm = mass of CaCO3 Total mass of water × 106 Thermodynamic processes  Isothermal process: Temperature = constant  Isochoric process: Volume = constant  Isobaric process: Pressure = constant  Adiabatic process: Heat exchange with the surroundings = 0 401 399 Work done on the system = positive Work done by the system = negative Law of Equipartition Energy Internal energy = N 2 × number of moles × universal gas constant × absolute temperature where: N = number of active degrees of freedom (Translational + Rotational)  N = 3 for monoatomic gas  N=5 for diatomic or linear polyatomic gas  N=6 for non-linear polyatomic gas Second law of Thermodynamics ∆Suniverse = ∆Ssystem + ∆Ssurrounding > 0 for a spontaneous process Third law of thermodynamics The entropy change associated with any condensed system undergoing a reversible isothermal process approaches zero as the temperature at which it is performed approaches 0 K. Criteria of spontaneity: ∆G = ∆H − T∆S 402 400  If ∆G is negative (< 0), the process is spontaneous.  If ∆G is positive (> 0), the process is non spontaneous. Endothermic → absorbs heat Exothermic → releases heat Degree of dissociation α= number of moles dissociated initial number of moles % Dissociation = α × 100 Relative humidity = partial pressure of water vapor equilibrium vapor pressure of water at a given temperature The quantum yield for the decomposition of a reactant molecule in a decomposition reaction is defined as: Φ= number of molecules decomposed number of photons absorbed Quantum yield can also be defined for other events, such as fluorescence: Φ= number of photons emitted number of photons absorbed 403 401 Simple buffering agents Buffering agent pKa pH range Citric acid 3.13, 4.76, 6.40 2.1–7.4 Acetic acid 4.8 3.8–5.8 KH2PO4 7.2 6.2–8.2 CHES 9.3 8.3–10.3 Borate 9.24 8.25–10.25 Acid Buffer: CH3COOH and CH3COONa (weak acid and salt of its conjugate base). pH = pKa + log [Salt] [Acid] (Henderson–Hasselbalch equation) Basic Buffer: NH4OH and NH4Cl (weak base and salt of its conjugate acid). pH = pKb + log [Salt] [Base] Buffer capacity: β= dCb d(pH) where dCb is an infinitesimal amount of added base 404 402 β=− dCa d(pH) where dCa is an infinitesimal amount of added acid. pH is defined as −log10[H+], and d(pH) is an infinitesimal change in pH. van 't Hoff factor i = Observed value of colligative property Theoretical value of colligative property Steric Number = (number of lone electron pairs on the central atom) + (number of atoms bonded to the central atom) Steric Number Predicted Shape Bond angle (Degrees) 2 Linear 180 3 Trigonal Planar 120 4 Tetrahedral 109.5 5 Trigonal Bipyramidal 90,120 6 Octahedral 90 Table of Common Ligands Type monodentate Charge neutral Name in Ligand Formula ammonia NH3 ammine water H2O aqua carbon monoxide CO carbonyl 405 403 Complexes pyridine pyr pyridine azide N3 azido bromide Br bromido chloride Cl chlorido cyanide CN cyanido fluoride F fluorido hydroxide OH hydroxido nitrite NO2 nitrito thiocyanate SCN or NCS thiocyanato bipyridine bipy bipyridine ethylenediamine en ethylenediamine carbonate CO32 carbonato oxide O2 oxo oxalate C2O42 oxolato sulfate SO42 sulfato minus one neutral bidentate minus two Hybridisation Geometry Coordination number sp linear 2 sp2 Trigonal planar 3 sp3 Tetrahedral 4 dsp2 Square planar 4 dsp3 Trigonal bipyramidal 5 406 404 dsp3 Square-based pyramid 5 d2sp3 Octahedral 6 Bead test Metal Color in Oxidizing flame Color in Reducing flame Aluminum colorless (hot and cold), opaque colorless, opaque Antimony colorless, yellow or brown (hot) gray and opaque Barium colorless Bismuth colorless, yellow or brownish (hot) gray and opaque Cadmium colorless gray and opaque Calcium colorless Cerium red (hot) colorless (hot and cold) Copper sky blue (hot and cold), opaque red, opaque Iron yellow (hot and cold), opaque bottle-green, opaque Manganese pink (hot and cold), opaque colorless, opaque 407 405 Cobalt deep blue (hot and cold), opaque deep blue, opaque Nickel yellow-brown (hot and cold), opaque grey, opaque Silver colourless (hot and cold), opaque grey, opaque Vanadium colourless (hot and cold), opaque green, opaque Uranium yellow-brown (hot and cold), opaque green, opaque Chromium green (hot and cold), opaque green, opaque Platinum colourless (hot and cold), opaque grey, opaque Gold yellow-brown (hot and cold), opaque grey, opaque Tin colourless (hot and cold), opaque colourless, opaque Titanium colourless (hot and cold), opaque yellow, opaque (hot) violet (cold) Tungsten colourless (hot and cold), opaque brown, opaque Magnesium colourless (hot and cold), opaque colourless, opaque Molybdenum colourless (hot and cold), opaque yellow or brown, opaque Strontium colourless (hot and cold), opaque colourless, opaque Thorium colourless (hot and cold), opaque colourless, opaque 408 406 Yttrium colourless (hot and cold), opaque colourless, opaque Neodymium colourless (hot and cold), opaque colourless, opaque Praseodymium colourless (hot and cold), opaque colourless, opaque Silicon colourless (hot and cold), opaque colourless, opaque Germanium colourless (hot and cold), opaque colourless, opaque List of oncogenic bacteria Species or genera Possibly associated cancers Bacteroides fragilis Colon cancer. Borrelia burgdorferi MALT lymphoma. Campylobacter jejuni Immunoproliferative small intestinal disease (IPSID), which is rare a type of MALT lymphoma. Chlamydia pneumonia Lung MALT lymphoma. Chlamydia trachomatis (chlamydia) Cervical cancer. Chlamydophila psittaci Ocular/adnexal lymphoma (forms of eye cancer). Clostridium ssp Colon cancer. Helicobacter bilis Biliary cancers (such as gallbladder and biliary tract cancers). Helicobacter bizzozeronii Gastric MALT lymphoma. Helicobacter felis Gastric MALT lymphoma. Helicobacter heilmannii Marginal zone B-cell lymphoma of the stomach. Helicobacter hepaticus Biliary cancer. Helicobacter pylori Stomach cancer, Marginal zone B-cell lymphoma 409 407 of the stomach, and bile duct cancer Helicobacter salomonis Gastric MALT lymphoma. Helicobacter suis Gastric MALT lymphoma. Mycoplasma spp Stomach, colon, ovarian, and lung cancers (particularly M. fermentans, M. penetrans, M. hyorhinis). Neisseria gonorrhoeae (gonorrhea) Bladder cancer and possibly prostate cancer. Cutibacterium acnes Bladder and prostate cancer. Salmonella enterica serovar Paratyphi Biliary cancer. Salmonella enterica serovar Typhimurium Biliary cancer. Treponema pallidum (syphilis) Bladder cancer and possibly prostate cancer. List of infectious diseases Infectious agent Common name Acinetobacter baumannii Acinetobacter infections Actinomyces israelii, Actinomyces Actinomycosis gerencseriae and Propionibacterium propionicus Trypanosoma brucei African sleeping sickness (African trypanosomiasis) HIV (Human immunodeficiency virus) AIDS (acquired immunodeficiency syndrome) Entamoeba histolytica Amoebiasis Anaplasma species Anaplasmosis Angiostrongylus Angiostrongyliasis Anisakis Anisakiasis Bacillus anthracis Anthrax Arcanobacterium haemolyticum Arcanobacterium haemolyticum infection 410 408 Junin virus Argentine hemorrhagic fever Ascaris lumbricoides Ascariasis Aspergillus species Aspergillosis Astroviridae species Astrovirus infection Babesia species Babesiosis Bacillus cereus Bacillus cereus infection multiple bacteria Bacterial meningitis multiple bacteria Bacterial pneumonia List of bacterial vaginosis microbiota Bacterial vaginosis Bacteroides species Bacteroides infection Balantidium coli Balantidiasis Bartonella Bartonellosis Baylisascaris species Baylisascaris infection BK virus BK virus infection Piedraia hortae Black piedra Blastocystis species Blastocystosis Blastomyces dermatitidis Blastomycosis Machupo virus Bolivian hemorrhagic fever Clostridium botulinum; Note: Botulism is not an Botulism (and Infant botulism) infection by Clostridium botulinum but caused by the intake of botulinum toxin. Sabiá virus Brazilian hemorrhagic fever Brucella species Brucellosis Yersinia pestis Bubonic plague usually Burkholderia cepacia and Burkholderia infection other Burkholderia species Mycobacterium ulcerans Buruli ulcer Caliciviridae species Calicivirus infection (Norovirus and Sapovirus) Campylobacter species Campylobacteriosis 411 409 usually Candida albicans and other Candida species Candidiasis (Moniliasis; Thrush) Intestinal disease by Capillaria philippinensis, hepatic Capillariasis disease by Capillaria hepatica and pulmonary disease by Capillaria aerophila Bartonella bacilliformis Carrion's disease Bartonella henselae Cat-scratch disease usually Group A Streptococcus and Staphylococcus Cellulitis Trypanosoma cruzi Chagas disease (American trypanosomiasis) Haemophilus ducreyi Chancroid Varicella zoster virus (VZV) Chickenpox Alphavirus Chikungunya Chlamydia trachomatis Chlamydia Chlamydophila pneumoniae Chlamydophila pneumoniae infection (Taiwan acute respiratory agent or TWAR) Vibrio cholerae Cholera usually Fonsecaea pedrosoi Chromoblastomycosis Batrachochytrium dendrabatidis Chytridiomycosis Clonorchis sinensis Clonorchiasis Clostridium difficile Clostridium difficile colitis Coccidioides immitis and Coccidioides posadasii Coccidioidomycosis Colorado tick fever virus (CTFV) Colorado tick fever (CTF) usually rhinoviruses and coronaviruses Common cold (Acute viral rhinopharyngitis; Acute coryza) Severe acute respiratory syndrome coronavirus Coronavirus disease 2019 (COVID- 2 (SARS-CoV-2) 19) PRNP Creutzfeldt–Jakob disease (CJD) Crimean-Congo hemorrhagic fever virus Crimean-Congo hemorrhagic fever (CCHF) 412 410 Cryptococcus neoformans Cryptococcosis Cryptosporidium species Cryptosporidiosis usually Ancylostoma braziliense; multiple other Cutaneous larva migrans (CLM) parasites Cyclospora cayetanensis Cyclosporiasis Taenia solium Cysticercosis Cytomegalovirus Cytomegalovirus infection Dengue viruses (DEN-1, DEN-2, DEN-3 and DEN-4) – Dengue fever Flaviviruses Green algae Desmodesmus armatus Desmodesmus infection Dientamoeba fragilis Dientamoebiasis Corynebacterium diphtheriae Diphtheria Diphyllobothrium Diphyllobothriasis Dracunculus medinensis Dracunculiasis Ebolavirus (EBOV) Ebola hemorrhagic fever Echinococcus species Echinococcosis Ehrlichia species Ehrlichiosis Enterobius vermicularis Enterobiasis (Pinworm infection) Enterococcus species Enterococcus infection Enterovirus species Enterovirus infection Rickettsia prowazekii Epidemic typhus Parvovirus B19 Erythema infectiosum (Fifth disease) Human herpesvirus 6 (HHV-6) and human herpesvirus Exanthem subitum (Sixth disease) 7 (HHV-7) Fasciola hepatica and Fasciola gigantica Fasciolasis Fasciolopsis buski Fasciolopsiasis PRNP Fatal familial insomnia (FFI) Filarioidea superfamily Filariasis Clostridium perfringens Food poisoning by Clostridium perfringens 413 411 multiple Free-living amebic infection Fusobacterium species Fusobacterium infection usually Clostridium perfringens; Gas gangrene (Clostridial other Clostridium species myonecrosis) Geotrichum candidum Geotrichosis PRNP Gerstmann-Sträussler-Scheinker syndrome (GSS) Giardia lamblia Giardiasis Burkholderia mallei Glanders Gnathostoma spinigerum and Gnathostoma hispidum Gnathostomiasis Neisseria gonorrhoeae Gonorrhea Klebsiella granulomatis Granuloma inguinale (Donovanosis) Streptococcus pyogenes Group A streptococcal infection Streptococcus agalactiae Group B streptococcal infection Haemophilus influenzae Haemophilus influenzae infection Enteroviruses, mainly Coxsackie Hand, foot and mouth A virus and enterovirus 71 (EV71) disease (HFMD) Sin Nombre virus Hantavirus Pulmonary Syndrome (HPS) Heartland virus Heartland virus disease Helicobacter pylori Helicobacter pylori infection Escherichia coli O157:H7, O111 and O104:H4 Hemolytic-uremic syndrome (HUS) Bunyaviridae species Hemorrhagic fever with renal syndrome (HFRS) Hendra virus Hendra virus infection Hepatitis A virus Hepatitis A Hepatitis B virus Hepatitis B Hepatitis C virus Hepatitis C Hepatitis D Virus Hepatitis D Hepatitis E virus Hepatitis E 414 412 Herpes simplex virus 1 and 2 (HSV-1 and HSV-2) Herpes simplex Histoplasma capsulatum Histoplasmosis Ancylostoma duodenale and Necator americanus Hookworm infection Human bocavirus (HBoV) Human bocavirus infection Ehrlichia ewingii Human ewingii ehrlichiosis Anaplasma phagocytophilum Human granulocytic anaplasmosis (HGA) Human metapneumovirus (hMPV) Human metapneumovirus infection Ehrlichia chaffeensis Human monocytic ehrlichiosis One of the human papillomaviruses Human papillomavirus (HPV) infection Human parainfluenza viruses (HPIV) Human parainfluenza virus infection Hymenolepis nana and Hymenolepis diminuta Hymenolepiasis Epstein–Barr virus (EBV) Epstein–Barr virus infectious mononucleosis (Mono) Orthomyxoviridae species Influenza (flu) Isospora belli Isosporiasis unknown; evidence supports that it is infectious Kawasaki disease multiple Keratitis Kingella kingae Kingella kingae infection PRNP Kuru Lassa virus Lassa fever Legionella pneumophila Legionellosis (Legionnaires' disease) Legionella pneumophila Pontiac fever Leishmania species Leishmaniasis Mycobacterium leprae and Mycobacterium Leprosy lepromatosis Leptospira species Leptospirosis Listeria monocytogenes Listeriosis Borrelia burgdorferi, Borrelia garinii, and Borrelia Lyme disease (Lyme borreliosis) 415 413 afzelii Wuchereria bancrofti and Brugia malayi Lymphatic filariasis (Elephantiasis) Lymphocytic choriomeningitis virus (LCMV) Lymphocytic choriomeningitis Plasmodium species Malaria Marburg virus Marburg hemorrhagic fever (MHF) Measles virus Measles Middle East respiratory syndrome coronavirus Middle East respiratory syndrome (MERS) Burkholderia pseudomallei Melioidosis (Whitmore's disease) multiple Meningitis Neisseria meningitidis Meningococcal disease usually Metagonimus yokagawai Metagonimiasis Microsporidia phylum Microsporidiosis Molluscum contagiosum virus (MCV) Molluscum contagiosum (MC) Monkeypox virus Monkeypox Mumps virus Mumps Rickettsia typhi Murine typhus (Endemic typhus) Mycoplasma pneumoniae Mycoplasma pneumonia Mycoplasma genitalium Mycoplasma genitalium infection numerous species of bacteria (Actinomycetoma) Mycetoma and fungi (Eumycetoma) parasitic dipterous fly larvae Myiasis most commonly Chlamydia trachomatis and Neisseria Neonatal conjunctivitis (Ophthalmia gonorrhoeae neonatorum) Nipah virus Nipah virus infection Norovirus Norovirus (children and babies) PRNP (New) Variant Creutzfeldt–Jakob disease (vCJD, nvCJD) usually Nocardia asteroides and other Nocardia species Nocardiosis Onchocerca volvulus Onchocerciasis (River blindness) 416 414 Opisthorchis viverrini and Opisthorchis felineus Opisthorchiasis Paracoccidioides brasiliensis Paracoccidioidomycosis (South American blastomycosis) usually Paragonimus westermani and Paragonimiasis other Paragonimus species Pasteurella species Pasteurellosis Pediculus humanus capitis Pediculosis capitis (Head lice) Pediculus humanus corporis Pediculosis corporis (Body lice) Pthirus pubis Pediculosis pubis (pubic lice, crab lice) multiple Pelvic inflammatory disease (PID) Bordetella pertussis Pertussis (whooping cough) Yersinia pestis Plague Streptococcus pneumoniae Pneumococcal infection Pneumocystis jirovecii Pneumocystis pneumonia (PCP) multiple Pneumonia Poliovirus Poliomyelitis Prevotella species Prevotella infection usually Naegleria fowleri Primary amoebic meningoencephalitis (PAM) JC virus Progressive multifocal leukoencephalopathy Chlamydophila psittaci Psittacosis Coxiella burnetii Q fever Rabies virus Rabies Borrelia hermsii, Borrelia recurrentis, and Relapsing fever other Borrelia species Respiratory syncytial virus (RSV) Respiratory syncytial virus infection Rhinosporidium seeberi Rhinosporidiosis Rhinovirus Rhinovirus infection 417 415 Rickettsia species Rickettsial infection Rickettsia akari Rickettsialpox Rift Valley fever virus Rift Valley fever (RVF) Rickettsia rickettsii Rocky Mountain spotted fever (RMSF) Rotavirus Rotavirus infection Rubella virus Rubella Salmonella species Salmonellosis SARS coronavirus SARS (severe acute respiratory syndrome) Sarcoptes scabiei Scabies Group A Streptococcus species Scarlet fever Schistosoma species Schistosomiasis multiple Sepsis Shigella species Shigellosis (bacillary dysentery) Varicella zoster virus (VZV) Shingles (Herpes zoster) Variola major or Variola minor Smallpox (variola) Sporothrix schenckii Sporotrichosis Staphylococcus species Staphylococcal food poisoning Staphylococcus species Staphylococcal infection Strongyloides stercoralis Strongyloidiasis Measles virus Subacute sclerosing panencephalitis Treponema pallidum Bejel, Syphilis, and Yaws Taenia species Taeniasis Clostridium tetani Tetanus (lockjaw) usually Trichophyton species Tinea barbae (barber's itch) usually Trichophyton tonsurans Tinea capitis (ringworm of the scalp) usually Trichophyton species Tinea corporis (ringworm of the body) usually Epidermophyton floccosum, Trichophyton Tinea cruris (Jock itch) rubrum, and Trichophyton mentagrophytes 418 416 Trichophyton rubrum Tinea manum (ringworm of the hand) usually Hortaea werneckii Tinea nigra usually Trichophyton species Tinea pedis (athlete’s foot) usually Trichophyton species Tinea unguium (onychomycosis) Malassezia species Tinea versicolor (Pityriasis versicolor) Toxocara canis or Toxocara cati Toxocariasis (ocular larva migrans (OLM)) Toxocara canis or Toxocara cati Toxocariasis (visceral larva migrans (VLM)) Toxoplasma gondii Toxoplasmosis Chlamydia trachomatis Trachoma Trichinella spiralis Trichinosis Trichomonas vaginalis Trichomoniasis Trichuris trichiura Trichuriasis (whipworm infection) usually Mycobacterium tuberculosis Tuberculosis Francisella tularensis Tularemia Salmonella enterica subsp. enterica, serovar typhi Typhoid fever Rickettsia Typhus fever Ureaplasma urealyticum Ureaplasma urealyticum infection Coccidioides immitis or Coccidioides posadasii. Valley fever Venezuelan equine encephalitis virus Venezuelan equine encephalitis Guanarito virus Venezuelan hemorrhagic fever Vibrio vulnificus Vibrio vulnificus infection Vibrio parahaemolyticus Vibrio parahaemolyticus enteritis multiple viruses Viral pneumonia West Nile virus West Nile fever Trichosporon beigelii White piedra (tinea blanca) Yersinia pseudotuberculosis Yersinia pseudotuberculosis infection Yersinia enterocolitica Yersiniosis Yellow fever virus Yellow fever 419 417 Zeaspora fungus Zeaspora Zika virus Zika fever Mucorales order (Mucormycosis) Zygomycosis and Entomophthorales order (Entomophthoramycosis) Pharmacokinetics  Volume of Distribution =  Volume of Distribution =  Total Dose Drug Concentration clearance elimination rate constant 0.693 Half Life = elimination rate constant 𝐁𝐢𝐨𝐚𝐯𝐚𝐢𝐥𝐚𝐛𝐢𝐥𝐢𝐭𝐲 ×Dose  Clearance =  Dose Rate = Desired concentration of drug in plasma at steady state × Clearance  Adjusted Dose Rate = Initial Dose Rate × area under curve Desired concentration of drug in plasma at steady state Measured concentration of drug in plasma at steady state 420 418 Molecularity of Reaction The molecularity of an elementary reaction is defined as the number of reactant molecules taking part in the chemical reaction. Chemical Reaction Molecularity PCl5 → PCl3 + Cl2 Unimolecular 2HI → H2 + I2 Bimolecular 2SO2 + O2 → 2SO3 Trimolecular NO + O3 → NO2 + O2 Bimolecular 2CO + O2 → 2CO2 Trimolecular 2FeCl3 + SnCl2 → SnCl2 + 2FeCl2 Trimolecular Common Multiferroic Materials Material Ferroelectric TC [K] magnetic TN or TC [K] Type of Ferroelectricity BiFeO3 1100 HoMn2O5 39 TbMnO3 27 Ni3V2O8 6.5 653 lone pair magnetically driven 42 421 419 magnetically driven MnWO4 13.5 magnetically driven CuO 230 230 ZnCr2Se4 110 20 magnetically driven Ranges of the Trig Functions −1 ≤ sinθ ≤ 1 −1 ≤ cosθ ≤ 1 −∞ ≤ tanθ ≤ ∞ cscθ ≥ 1 and cscθ ≤ −1 secθ ≥ 1 and secθ ≤ −1 −∞ ≤ cotθ ≤ ∞ Periods of the Trig Functions The period of a function is the number, T, such that f (θ + T) = f (θ). So, if ω is a fixed number and θ is any angle we have the following periods. sin(ωθ) → T = cos(ωθ) → T = tan(ωθ) → T = 422 420 2π ω 2π ω π ω csc(ωθ) → T = sec(ωθ) → T = cot(ωθ) → T = 2π ω 2π ω π ω If n is an integer sin(θ+ 2πn) = sinθ cos(θ + 2πn) = cosθ tan(θ + πn) = tanθ csc(θ + 2πn) = cscθ sec(θ + 2πn) = secθ cot(θ + πn) = cotθ Degrees to Radians Formulas If x is an angle in degrees and t is an angle in radians then: x= 180o t π Conic Sections  Circle Standard Form: (x − h) 2 + (y − k) 2 = r2 423 421 where (h, k) = center and r = radius  Ellipse Standard Form for Horizontal Major Axis: Standard Form for Vertical Major Axis: (x − h)2 a2 (x − h)2 b2 + + (y − k)2 b2 (y − k)2 a2 =1 =1 where (h, k) = center 2a=length of major axis 2b=length of minor axis (0 < b < a) Foci can be found by using c2 = a2 − b2 where c = foci length  Hyperbola Standard Form for Horizontal Transverse Axis: Standard Form for Vertical Transverse Axis: (x − h)2 a2 (y − k)2 a2 − − (y − k)2 b2 (x − h)2 b2 where (h, k) = center a=distance between center and either vertex Foci can be found by using b2 = c2 − a2 where c is the distance between center and either focus. (b > 0) 424 422 =1 =1  Parabola Vertical axis: y = a(x − h) 2 + k Horizontal axis: x = a(y − k) 2 + h where (h, k) = vertex a=scaling factor Range of Trigonometric Expression: − √a2 + b 2 ≤ asinθ +bcosθ ≤ √a2 + b 2 Coefficient of Determination Formula r= n(Σxy)−(Σx) (Σy) √[nΣx2 −(Σx2 )][nΣy2 −(Σy2 )] where,  r = Correlation coefficient  x = Values in first set of data  y = Values in second set of data  n = Total number of values. Formula for Conditional Probability Conditional Probability of A given B Conditional Probability of B given A 425 423 P (A|B) = P(A ∩ B) P (B|A) = P(B ∩ A) P(B) P(A) Covariance Formula Population Covariance Formula Sample Covariance Formula      Cov(x, y) = ∑(xi −x̅ )(yi −y ̅) Cov(x, y) = ∑(xi −x̅ )(yi −y ̅) N N−1 xi = data value of x yi = data value of y x̄ = mean of x ȳ = mean of y N = number of data values. Correlation = Cov(x,y) σx σy where: Cov(x, y) is the covariance between x and y while σx and σy are the standard deviations of x and y. Anova Formula Mean Square Factor = Mean Square Error = sum of squares factor degrees of freedom factor sum of squares error degrees of freedom error Degrees of freedom factor = number of factor levels – 1 426 424 Degrees of freedom error = total number of observations − number of factor levels F-value = R2 = R2 (adjusted) = 1 – Mean square factor Mean square error sum of squares error sum of squares total Mean Square error Sum of Squares total / degrees of freedom total R2 (predicted) = 1 − Predicted Residual Sum of squares Sum of Squares total Process capability Formula Process capability = upper specification limit − lower specification limit 6 × standard deviation Effect Size Formula Cohen's index = Mean of first observation−Mean of second observation √(Standard deviation of first observation) 2 + (Standard deviation of second observation)2 Effect-size coefficient = where: d denote the Cohen's index 427 425 2 d √d2 + 4 Euler's Formula Equation eix = cos x + i sin x Exponential Equation Formula y = abx  x and y are the variables  a and b are constants Fibonacci Formula Fn = Fn – 1 + Fn – 2 where,  Fn = nth term of the series  Fn – 1 and Fn – 2 are the (n −1) th and (n – 2) th terms respectively Gaussian Distribution Formula The probability density function formula for Gaussian distribution is given by: f (x, μ, σ) = where,    1 σ√2π x is the variable μ is the mean σ is the standard deviation 428 426 exp ( −(x−μ)2 2σ2 ) Infinite Series Formula n ∑∞ 0 r = 1 1− r Linear Interpolation Formula y = y1 + (x−x1 ) (x2 −x1 ) × (y2 − y1) Percent Decrease Formula Percent Decrease = Decreased Value × 100 Original Value Percentage Increase Formula Percent Increase = Increased Value Original Value × 100 Percentile Formula Percentile = Number of Values Below "x" Total Number of Values Perfect Square Trinomial Formula 429 427 × 100 (ax)2 + 2abx + b2 = (ax + b)2 (ax)2 − 2abx + b2 = (ax − b)2 Poisson Distribution Formula Suppose we conduct a Poisson experiment, in which the average number of successes within a given region is μ. Then, the Poisson probability is: P(x, μ) = e−μ μx x! where x is the actual number of successes that result from the experiment, and e is approximately equal to 2.71828. Quartile Formula When the set of observation is arranged in an ascending order, then the lower percentile is given by: Q1 = ( N+1 ) th Term Q2 = ( N+1 ) th Term The middle quartile is given by: The upper quartile is given by: Q3 = ( 4 2 3(N+1) 4 430 428 ) th Term inter quartile range = Q3 – Q1  N → number of observations Ratio Analysis Formula  Liquidity Ratios Current Ratio = Quick Ratio =  Current Liabilities (Total Current Ratio − Inventory) Total Current Liabilities Profitability Ratios Net Profit Ratio = Net profit after tax NetSales Gross Profit Ratio = Operating Ratio = Earnings per share =  Current Asset GrossProfit NetSales × 100 Operating Cost NetSales × 100 × 100 Net Income – Preferred Dividends average outstanding common shares Activity Ratios 431 429 Inventory Turnover Ratio = Receivables Turnover Ratio =  Cost of goods sold Average Inventory Net Credit Sales Average Trade Receivable Solvency Ratios Debt Equity Ratio = Proprietary Ratio = Total Liabilities Stakeholder Equity Stakeholder Equity Total Assets ×100 Relative frequency formula relative frequency = number of times the data occurred in an observation total frequencies Sampling Error Formula Sampling Error = Z × σ √n where,  Z is the Z score value based on the confidence interval (approx = 1.96)  σ is the population standard deviation  n is the size of the sample 432 430 Stirling Formula n! ≈ ( n n ) e √2πn Annulus Formula A = π (R2 − r2) where,  A = Area of Annulus  R = Outer radius  r = Inner radius  (Pi) π = is approximately 3.142 Bayes' theorem P(A | B) = P(B | A) P(A) P(B) where A and B are events and P(B) ≠ 0.  P(A | B) is a conditional probability: the likelihood of event A occurring given that B is true.  P(B | A) is also a conditional probability: the likelihood of event B occurring given that A is true.  P(A) and P(B) are the probabilities of observing A and B respectively; they are known as the marginal probability. 433 431 32 × 31 = ? 35 × 11 9 × 1 = 09 3 + 5 3 8 5 9 × 2 = 18 9 × 3 = 27 9 × 4 = 36 9 × 5 = 45 35 × 11 = 385 9 9 × 6 = 54 6 +3 = 9 2 9 × 7 = 63 992 9 × 8 = 72 32 × 11 9 × 9 = 81 32 × 31 = 992 9 × 10 = 90 19 = 1❾ = 1 16 = 1❻ = 1 95 64 26 65 = ❾5 ❻4 2❻ ❻5 = 3 + 2 3 5 2 32 × 11 = 352 374 × 43 = ?  374 = 300 + 70 + 4 43 = 40 + 3  5 4 1 5 300 70 4 40 12000 2800 160 3 900 210 12 12000 + 2800 + 160 + 900 + 210 + 12 =16082 374 × 43 = 16082 432 Central Limit Theorem Formula Central limit theorem is applicable for a sufficiently large sample sizes (n ≥ 30). The formula for central limit theorem can be stated as follows: Sample mean = Population mean and Sample standard deviation = Population standard deviation √Sample size Coefficient of Variation Formula Coefficient of variation = Standard Deviation Mean ×100% Process capability index (Cpk) Formula Cpk = min( upper specification limit − mean 3 × standard deviation , mean− lower specification limit 3 × standard deviation Signal to Noise Ratio Formula signal to noise ratio = standard deviation mean of the given data Uniform Distribution Formula Theoretical Mean = 434 433 x+y 2 ) (y−x)2 Standard Deviation = √ 12 Z Score Formula Z Score = Standardized random variable − mean Standard deviation Inductance Formula The total series inductance is L=L1 + L2 + L3 +…. + Ln The parallel inductance is 1 L = 1 L1 + 1 L2 + 1 L3 +….+ 1 Ln where, L1, L2, L3….. Ln denotes the inductance values. Soil Erosion Formula The universal soil loss equation predicts the annual soil loss per unit area. The universal soil loss equation is given by: A = R × K × L× S × CP where, 435 434  A is the estimated annual soil loss  R is the rainfall and runoff factor representing the summed erosive potential of all rainfall events in a year.  L is the slope length  S is the slope steepness  K is the soil erodibility factor representing units of soil loss per unit of soil erosivity  CP characterizes conservation management and land cover practices. Critical Velocity Formula Critical velocity of a liquid flowing through a tube = where:  K is the Reynold's number  η is the coefficient of the viscosity of the liquid  r is the radius of the tube through which the liquid flows  ρ is the density of the liquid Horsepower Formula One Horsepower equals to 33,000 lb. ft/min Horsepower (HP) = Torque × Speed 5252 Horsepower (HP) = Weight × ( 436 435 velocity 234 )2 K× η ρ×r Beat Frequency Formula The formula for beat frequency is the difference in frequency of the two superimposed waves. fb = f2−f1  f1 and f2 are the frequency of two waves Voltage Drop Formula voltage drop across the circuit = Current in amperes × impedance in Ω Brewster's law Formula µ = tanθp where,   µ is the refractive index of the medium θp is the polarizing angle Hagen–Poiseuille equation Δp = 8πμLQ A2 where:  Δp is the pressure difference between the two ends,  L is the length of pipe,  μ is the dynamic viscosity,  Q is the volumetric flow rate, 437 436  R is the pipe radius,  A is the cross section of pipe. Pressure Drop Formula J = fLv2 / 2gD where:  J = pressure drop  f = friction factor  L = length of the tube  v = velocity of the fluid  g = acceleration due to gravity  D = inner diameter of the tube Strain Energy Formula strain energy = F×δ strain energy = 1 where,  δ = compression,  F = force applied. where,  σ = stress  ε= strain  V = volume of body 438 437 2 2 Vσε strain energy = where,  σ = stress,  E = Young's modulus,  V = volume of body. 2E × V Rate Law  Zero order − dC =k dt t1 = 2  2k dC dt = kC t1 = 2  C0 First order − ln2 2k Second − dC = kC2 dt 439 438 σ2 t1 = 2  kC0 nth order −  n → order of the reaction  C → reactant concentration  C0 → initial reactant concentration  t 1 → Half life period  1 dC n dt = kC 2 k → rate constant List of ester odorants Ester name Odor or occurrence Allyl hexanoate pineapple Benzyl acetate pear, strawberry, jasmine Bornyl acetate pine Butyl acetate apple, honey Butyl butyrate pineapple 440 439 Butyl propanoate pear drops Ethyl acetate nail polish remover, model paint, model airplane glue Ethyl benzoate sweet, wintergreen, fruity, medicinal, cherry, grape Ethyl butyrate banana, pineapple, strawberry Ethyl hexanoate pineapple, waxy-green banana Ethyl cinnamate cinnamon Ethyl formate lemon, rum, strawberry Ethyl heptanoate apricot, cherry, grape, raspberry Ethyl isovalerate apple Ethyl lactate butter, cream Ethyl nonanoate grape Ethyl pentanoate apple Geranyl acetate geranium Geranyl butyrate cherry Geranyl pentanoate apple Isobutyl acetate cherry, raspberry, strawberry Isobutyl formate raspberry 441 440 Isoamyl acetate pear, banana (flavoring in Pear drops) Isopropyl acetate fruity Linalyl acetate lavender, sage Linalyl butyrate peach Linalyl formate apple, peach Methyl acetate glue Methyl anthranilate grape, jasmine Methyl benzoate fruity, ylang ylang, feijoa Methyl butyrate pineapple, apple, strawberry (methyl butanoate) Methyl cinnamate strawberry Methyl pentanoate flowery (methyl valerate) Methyl phenylacetate honey Methyl salicylate Modern root beer, wintergreen, (oil of wintergreen) Germolene and Ralgex ointments (UK) Nonyl caprylate orange Octyl acetate fruity-orange 442 441 Octyl butyrate parsnip Amyl acetate apple, banana (pentyl acetate) Pentyl butyrate apricot, pear, pineapple (amyl butyrate) Pentyl hexanoate apple, pineapple (amyl caproate) Pentyl pentanoate apple (amyl valerate) Propyl acetate pear Propyl hexanoate blackberry, pineapple, cheese, wine Propyl isobutyrate rum Terpenyl butyrate cherry List of dyes with Colour Index International generic names and numbers Common name Synonyms C.I. generic name C.I. number Alcian Blue 8GX Alcian Blue Ingrain Blue 74240 Alcian yellow GXS Sudan orange Ingrain yellow 1 12840 443 442 Alizarin Mordant red 11 58000 Alizarin Red S Mordant red 3 58005 Alizarin yellow GG Mordant yellow 1 14025 Alizarin yellow R Mordant orange 1 14030 Azophloxin Azogeranin B Acid red 1 18050 Bismarck brown R Vesuvine brown Basic brown 4 21010 Bismarck brown Y Vesuvine Phenylene brown Basic brown 1 21000 Brilliant cresyl blue Cresyl blue BBS Basic dye 51010 Chrysoidine R Basic orange 1 11320 Chrysoidine Y Basic orange 2 11270 Congo red Direct red 28 22120 Crystal violet Basic violet 3 42555 Ethyl Green 42590 Fuchsin acid Acid violet 19 42685 Gentian violet Basic violet 1 42535 Janus green Basic dye 11050 Acid yellow 17 18965 Lissamine fast yellow Yellow 2G 444 443 Malachite green Martius yellow Acid yellow 24 10315 Basic blue 6 51175 Metanil yellow Acid yellow 36 13065 Methyl orange Acid orange 52 13025 Methyl red Acid red 2 13020 Acid black 1 20470 Naphthol green B Acid green 1 10020 Naphthol yellow S Acid yellow 1 10316 Orange G Acid orange 10 16230 Purpurin Verantin Rose bengal Acid red 94 45440 Sudan II Solvent orange 7 12140 Titan yellow Direct yellow 9 19540 Acid orange 6 14270 Acid orange 5 13080 Acid orange 7 15510 Meldola blue Naphthalene black 12B Tropaeolin O Phenylene blue Amido black 10B Sulpho orange Tropaeolin OO Tropaeolin OOO Orange II 445 444 Victoria blue 4R Basic blue 8 42563 Victoria blue B Basic blue 26 44045 Victoria blue R Basic blue 11 44040 Xylene cyanol FF Acid blue 147 42135 List of copper salts Name Chemical Formula Anion Copper silicide Cu5Si Silicide (silane) Copper(I) oxide Cu2O Oxide (oxygen) Copper(I) chloride CuCl Chloride (hydrochloric acid) Copper(I) iodide CuI Iodide (hydroiodic acid) Copper(I) cyanide CuCN Cyanide (hydrocyanic acid) Copper(I) thiocyanate CuSCN Thiocyanate (thiocyanic acid) Copper(I) sulfate Cu2SO4 Sulfate (sulfuric acid) Copper(I) sulfide Cu2S Sulfide (hydrogen sulfide) Copper(I) acetylide Cu2C2 Acetylide (acetylene) Copper(I) bromide CuBr Bromide (hydrobromic acid) Copper(I) fluoride CuF Fluoride (hydrofluoric acid) Copper(I) hydroxide CuOH Hydroxide (water) Copper(I) hydride CuH Hydride (hydrogen gas) Copper(I) nitrate CuNO3 Nitrate (nitric acid) Copper(I) phosphide Cu3P Phosphide (phosphine) Copper(I) thiophene-2- C5H3CuO2S thiophene-2-carboxylate (thiophene-2- carboxylate carboxylic acid) Copper(I) t-butoxide C16H36Cu4O4 t-butoxide (t-butyl alcohol) Copper(II) sulfate CuSO4 Sulfate (sulfuric acid) 446 445 Copper(II) chloride CuCl2 Chloride (hydrochloric acid) Copper(II) hydroxide Cu(OH)2 Hydroxide (water) Copper(II) nitrate Cu(NO3)2 Nitrate (nitric acid) Copper(II) oxide CuO Oxide (oxygen) Copper(II) acetate Cu(OAc)2 Acetate (acetic acid) Copper(II) fluoride CuF2 Fluoride (hydrofluoric acid) Copper(II) bromide CuBr2 Bromide (bromine) Copper(II) carbonate CuCO3 Carbonate (carbonic acid) Copper(II) carbonate Cu2CO3(OH)2 Hydroxide (water) hydroxide Carbonate (carbonic acid) Copper(II) chlorate Cu(ClO3)2 Chlorate (chloric acid) Copper(II) arsenate Cu3(AsO4)2 Arsenate (arsenic acid) Copper(II) azide Cu(N3)2 Azide (hydrazoic acid) Copper(II) Cu(O2C5H7)2 Acetylacetonate (acetylacetone) Copper(II) aspirinate C36H28Cu2O16 Acetylsalicylate (acetylsalicylic acid) Copper(II) cyanurate CuC3HN3O3 Cyanurate (cyanuric acid) Copper(II) glycinate Cu(H2NCH2CO2)2 Glycinate (glycine) Copper(II) phosphate Cu3(PO4)2 Phosphate (phosphoric acid) Copper(II) perchlorate Cu(ClO4)2 Perchlorate (perchloric acid) Copper(II) selenite CuSeO3 Selenite (selenous acid) Copper(II) sulfide CuS Sulfide (hydrogen sulfide) Copper(II) thiocyanate Cu(SCN)2 Thiocyanate (thiocyanic acid) Copper(II) triflate Cu(OSO2CF3)2 Triflate (triflic acid) Copper(II) Cu(BF4)2 Tetrafluoroborate (tetrafluoroboric acid) acetylacetonate tetrafluoroborate 447 446 Copper(II) acetate Cu(C2H3O2)2·3Cu(AsO2)2 Acetate (acetic acid) triarsenite Triarsenite (Paris Green) (1,3,5,2,4,6-Trioxatriarsinane-2,4,6-triol) Copper(II) benzoate Cu(C6H5CO2)2 Benzoate (benzoic acid) Copper(II) arsenite AsCuHO3 Arsenite (Arsenous acid) Copper(II) chromite Cu2Cr2O5 Chromite (chromic acid) Copper(II) gluconate C12H22CuO14 Gluconate (gluconic acid) Copper(II) peroxide CuO2 Peroxide (hydrogen peroxide) Copper(II) usnate C18H14CuO7 Usnate (usnic acid) Copper(III) oxide Cu2O3 Oxide (oxygen) (Scheele's Green) List of purification methods in chemistry  Affinity purification purifies proteins by retaining them on a column through their affinity to antibodies, enzymes, or receptors that have been immobilised on the column.  Filtration is a mechanical method to separate solids from liquids or gases by passing the feed stream through a porous sheet such as a cloth or membrane, which retains the solids and allows the liquid to pass through.  Centrifugation is a process that uses an electric motor to spin a vessel of fluid at high speed to make heavier components settle to the bottom of the vessel.  Evaporation removes volatile liquids from non-volatile solutes, which cannot be done through filtration due to the small size of the substances.  Liquid–liquid extraction removes an impurity or recovers a desired product by dissolving the crude material in a solvent in which other components of the feed material are soluble.  Crystallization separates a product from a liquid feed stream, often in extremely pure form, by cooling the feed stream or adding precipitants that lower the solubility of the desired product so that it forms crystals. The pure solid crystals are then separated from the remaining liquor by filtration or centrifugation.  Recrystallization: In analytical and synthetic chemistry work, purchased reagents of doubtful purity may be recrystallized, e.g. dissolved in a very pure solvent, and then crystallized, and the crystals recovered, in order to improve and/or verify their purity. 448 447  Trituration removes highly soluble impurities from usually solid insoluble material by rinsing it with an appropriate solvent.  Adsorption removes a soluble impurity from a feed stream by trapping it on the surface of a solid material, such as activated carbon, that forms strong non-covalent chemical bonds with the impurity.  Chromatography employs continuous adsorption and desorption on a packed bed of a solid to purify multiple components of a single feed stream. In a laboratory setting, mixture of dissolved materials are typically fed using a solvent into a column packed with an appropriate adsorbent, and due to different affinities for solvent (moving phase) versus adsorbent (stationary phase) the components in the original mixture exit the column in the moving phase at different rates, which thus allows to selectively collect desired materials out of the initial mixture.  Smelting produces metals from raw ore, and involves adding chemicals to the ore and heating it up to the melting point of the metal.  Refining is used primarily in the petroleum industry, whereby crude oil is heated and separated into stages according to the condensation points of the various elements.  Distillation is widely used in petroleum refining and in purification of ethanol separates volatile liquids on the basis of their relative volatilities. There is several type of distillation: simple distillation, steam distillation etc.  Water purification combines a number of methods to produce potable or drinking water.  Downstream processing refers to purification of chemicals, pharmaceuticals and food ingredients produced by fermentation or synthesized by plant and animal tissues, for example antibiotics, citric acid, vitamin E, and insulin.  Fractionation refers to a purification strategy in which some relatively inefficient purification method is repeatedly applied to isolate the desired substance in progressively greater purity.  Electrolysis refers to the breakdown of substances using an electric current. This removes impurities in a substance that an electric current is run through  Sublimation is the process of changing of any substance (usually on heating) from a solid to a gas (or from gas to a solid) without passing through liquid phase. In terms of purification - material is heated, often under vacuum, and the vapors of the material are then condensed back to a solid on a cooler surface. The process thus in its essence is similar to distillation, however the material which is condensed on the cooler surface then has to be removed mechanically, thus requiring different laboratory equipment.  Bioleaching is the extraction of metals from their ores through the use of living organisms. 449 448 Physics Glossary  Absolute zero: The lowest possible temperature T, at which substances contain no heat energy Q.  Acceleration: The rate at which the speed of an object is changing and it is given by the equation a =  𝐝𝐯 𝐝𝐭 . Anthropic principle: We see the universe the way it is because if it were different we would not be here to observe it through a gigantic telescopes pointing deep into the immense sky – merely stating that the constants of nature must be tuned to allow for intelligence (otherwise we would not be here). Some believe that this is the sign of a cosmic creator. Others believe that this is a sign of the multiverse.  Antiparticle: Each type of matter particle has a corresponding antiparticle – first predicted to exist by P. A. M. Dirac. When a particle collides with its antiparticle, they annihilate, leaving only pure energy in the form of discrete bundle (or quantum) of electromagnetic (or light) energy called photons.  Atom: The basic unit of ordinary matter, made up of a tiny nucleus (consisting of positively charged protons and electrically neutral neutrons – which obey the strong interactions) surrounded by orbiting negatively charged weakly interacting particles called the electrons.  Big Bang: The singularity at the beginning of the universe. The titanic explosion that created the universe, sending the galaxies hurtling in all directions. When the universe was created, the temperature was extremely hot, and the density of material was enormous i.e., infinite. The big bang took place 13.7 billion years ago, according to the WMAP satellite. The afterglow of the big bang is seen today as the cosmic background microwave radiation (of temperature 2.7 degrees above absolute zero). There are three experimental "proofs" of the big bang: the redshift of the galaxies, the cosmic background microwave radiation, and nucleosynethsis of the elements.  Big crunch: The singularity at the end of the universe i.e., The final collapse of the universe. If the density of matter is large enough (Omega – The parameter that measures the average density of matter in the universe – being larger than 1), then there is enough matter in the universe to reverse the original expansion and cause the universe to recollapse. Temperatures rise to infinity at the instant of the big crunch.  Big freeze: The end of the universe when it reaches near absolute zero. The big freeze is probably the final state of our universe, because the sum of Omega and Lambda is believed to be 1.0, and 450 449 hence the universe is in a state of inflation. There is not enough matter and energy to reverse the original expansion of the universe, so it will probably expand forever.  Big Bang nucleosynthesis: The production of deuterium, Helium-3 and Helium-4 (the latter to about 25% mass fraction) in the first 500 to 1000 sec of the early universe. These light isotopes, plus measurable amounts of lithium-7 and trace amounts of elements B, Be, are the result of nonequilibrium nuclear reactions as the universe cooled to about 10 to the power of 8 K. Heavier isotopes were produced in stellar nucleosynthesis.  Black hole: A region of space-time from which nothing, not even light, can escape, because gravity is so strong and escape velocity equals the speed of light. Because the speed of light is the ultimate velocity in the universe, this means that nothing can escape a black hole, once an object has crossed the event horizon. Black holes can be of various sizes. Galactic black holes, lurking in the center of galaxies and quasars, can weight millions to billions of solar masses. Stellar black holes are the remnant of a dying star, perhaps originally up to forty times the mass of our Sun. Both of these black holes have been identified with our instruments. Mini–black holes may also exist, as predicted by theory, but they have not yet been seen in the laboratory conditions.  Black Hole Escape Velocity: It is widely held by astrophysicists and astronomers that a black hole has an escape velocity c (or c, the speed of light in Vacuum). Chandrasekhar [Nobel laureate] remarked, "Let me be more precise as to what one means by a black hole. One says that a black hole is formed when the gravitational forces on the surface become so strong that light cannot escape from it. ... A trapped surface is one from which light cannot escape to infinity." According to Hawking, "Eventually when a star has shrunk to a certain critical radius, the gravitational field at the surface becomes so strong that the light cones are bent inward so much that the light can no longer escape. According to the theory of relativity, nothing can travel faster than light. Thus, if light cannot escape, neither can anything else. Everything is dragged back by the gravitational field. So one has a set of events, a region of space-time from which it is not possible to escape to reach a distant observer. Its boundary is called the event horizon. It coincides with the paths of the light rays that just fail to escape from the black hole." A neutron star has a radius of about ten miles, only a few times the critical radius at which a star becomes a black hole. 451 450 "I had already discussed with Roger Penrose the idea of defining a black hole as a set of events from which it is not possible to escape to a large distance. It means that the boundary of the black hole, the event horizon, is formed by rays of light that just fail to get away from the black hole. Instead, they stay forever hovering on the edge of the black hole." However, according to the alleged properties of a black hole, nothing at all can even leave the black hole. In the very same paper Chandrasekhar made the following quite typical contradictory assertion: "The problem we now consider is that of the gravitational collapse of a body to a volume so small that a trapped surface forms around it; as we have stated, from such a surface no light can emerge." Hughes reiterates, "Things can go into the horizon (from r > 2M to r < 2M), but they cannot get out; once inside, all causal trajectories (time-like or null) take us inexorably into the classical singularity at r = 0." The defining property of black holes is their event horizon. Rather than a true surface, black holes have a 'one-way membrane' through which stuff can go in but cannot come out. Taylor and Wheeler assert, "... Einstein predicts that nothing, not even light, can be successfully launched outward from the horizon ... and that light launched outward EXACTLY at the horizon will never increase its radial position by so much as a millimeter."  Zero point Energy: an intrinsic and unavoidable part of quantum physics. The ZPE has been studied, both theoretically and experimentally, since the discovery of quantum mechanics in the 1920s and there can be no doubt that the ZPE is a real physical effect.  Casimir effect: The attractive pressure between two flat, parallel metal plates placed very near to each other in a vacuum. The pressure is due to a reduction in the usual number of virtual particles in the space between the plates. This tiny effect has been measured in the laboratory. The Casimir effect may be used as the energy to drive a time machine or wormhole, if its energy is large enough.  Chandrasekhar limit: The maximum possible mass of a stable cold star (i.e., 1.4 solar masses), above which it must collapse into a black hole. 452 451  Conservation of energy: The law of science that states that energy (or its equivalent in mass) can neither be created nor destroyed i.e., they never change with time. For example, the conservation of matter and energy posits that the total amount of matter and energy in the universe is a constant.  Coordinates: Numbers that specify the position of a point in 4 dimensional space-time.  Cosmological constant: A mathematical parameter (which measures the amount of dark energy in the universe) introduced by Albert Einstein to give space-time an inbuilt tendency to expand. At present, the data supports density parameter + cosmological constant = 1, which fits the prediction of inflation for a flat universe. Cosmological constant, which was once thought to be zero, is now known to determine the ultimate destiny of the universe.  Cosmology: The study of the universe as a whole.  COBE: The Cosmic Observer Background Explorer satellite.  Dark matter: Invisible Matter usually found in a huge halo around galaxies, clusters, and possibly between clusters, that cannot be observed directly but can be detected by its gravitational effect and they does not interact with light. As much as 90 percent of the mass of the universe may be in the form of dark matter and they makes up 23 percent of the total matter/energy content of the universe. According to string theory, dark matter may be made of subatomic particles, such as the neutralino, which represent higher vibrations of the superstring.  Duality: A correspondence between apparently different theories that lead to the same physical results.  Einstein-Rosen bridge: A thin tube of space-time linking two black holes.  Electric charge: A property of a particle by which it may repel (or attract) other particles that have a charge of similar (or opposite) sign.  Electromagnetic force: The force of electricity and magnetism that arises between particles with electric charge; the second strongest of the four fundamental forces – which obeys Maxwell's equations.  Electron: A negatively charged subatomic particle with negative electric charge that orbits the nucleus of an atom and determines the chemical properties of the atom.  Electroweak unification energy: The energy (around 100 GeV) above which the distinction between the electromagnetic force and the weak force disappears.  Elementary particle: A particle that, it is believed fundamental building block of Nature, cannot be subdivided and are not composed of other simpler particles. 453 452  Event: A point in space-time, specified by its time and place.  Event horizon: The boundary of a black hole. The point of no return, often called the horizon.  Exclusion principle: The idea that two identical spin-1/2 particles cannot have (within the limits set by the uncertainty principle) both the same position and the same velocity. This means that two electrons cannot occupy precisely the same point with the same properties, so that there is a net force pushing the electrons apart (in addition to electrostatic repulsion).  Field: Something that exists throughout 4 dimensional fabric of space -time, as opposed to a particle that exists at only one point at a time.  Frequency: For a wave, the number of complete cycles per second.  Gamma rays: Electromagnetic rays of very short wavelength, produced in radio-active decay or by collisions of elementary particles.  General relativity: Einstein's theory of gravity based on the idea that the laws of science should be the same for all observers, no matter how they are moving. It explains the force of gravity in terms of the curvature of a four dimensional space-time; so that the curvature of spacetime gives the illusion that there is a force of attraction called gravity. It has been verified experimentally to better than 99.7 percent accuracy and predicts the existence of black holes and the expanding universe. The theory, however, break down at the center of a black hole or the instant of creation, where the theory predicts nonsense. To explain these phenomena, one must resort to a theory of subatomic physics.  Geodesic: The shortest (or longest) path between two points.  Grand unification energy: The energy above which, it is believed, the electromagnetic force, weak force, and strong force become indistinguishable from each other.  Grand unified theory (GUT): A theory which unifies the electromagnetic, strong, and weak forces (but not gravity). The proton is not stable in these theories and can decay into positrons. GUT theories are inherently unstable (unless one adds super symmetry). GUT theories also lack gravity. (Adding gravity to GUT theories makes them diverge with infinities.)  Imaginary time: Time measured using imaginary numbers.  Inflation: The theory which states that the universe underwent an incredible amount of superliminal expansion at the instant of its birth i.e., A distance of one nanometer was enlarged to a quarter of a billion light-years.  Hyperspace: Dimensions higher than four. 454 453  Light cone: A surface in space-time that marks out the possible directions for light rays passing through a given event.  Light year: The distance light travels in one year, or approximately 5.88 trillion miles (9.46 trillion kilometers).  LIGO: The Laser Interferometry Gravitational-Wave Observatory, based in Washington state and Louisiana,which is the world’s largest gravity wave detector.  LISA: The Laser Interferometry Space Antenna- which is a series of three space satellites using laser beams to measure gravity waves. It is sensitive enough to confirm or disprove the inflationary theory and possibly even string theory.  Magnetic field: The field responsible for magnetic forces, now incorporated along with the electric field, into the electromagnetic field.  Muon: A subatomic particle identical to the electron but with a much larger mass. It belongs to the second redundant generation of particles found in the Standard Model.  Mass: The quantity of matter in a body; its inertia, or resistance to acceleration.  Microwave background radiation: The remnant radiation (with a temperature of about 2.7 degrees K) from the glowing of the hot early universe (big bang), now so greatly red-shifted that it appears not as light but as microwaves (radio waves with a wavelength of a few centimeters). Tiny deviations in this background radiation give scientists valuable data that can verify or rule out many cosmological theories.  Naked singularity: A space-time singularity not surrounded by a black hole.  Neutrino: An extremely light (possibly massless) subatomic particle that react very weakly with other particles and may penetrate several light-years of lead without ever interacting with anything and is affected only by the weak force and gravity.  Neutron: A neutral subatomic particle, very similar to the proton, which accounts for roughly half the particles in an atomic nucleus.  Neutron star: A cold collapsed star consisting of a solid mass of neutrons — which is usually about 10 to 15 miles across — supported by the exclusion principle repulsion between neutrons. If the mass of the neutron stars exceeds (3- 4 solar masses) i.e., if the number of neutrons becomes ≥ 5.9 × 10 57, then the degenerate neutron pressure will not be large enough to overcome the gravitational contraction and the star collapses into the next stage called black holes.  No boundary condition: The idea that the universe is finite but has no boundary (rooted in the Euclidean formalism) to account for the initial conditions in the big bang. 455 454  Nuclear fusion: The process by which two nuclei collide and coalesce to form a single, heavier nucleus.  Nucleus: The tiny core of an atom, which is roughly 10 −13 cm across, consisting only of protons and neutrons, held together by the strong force.  Particle accelerator: A machine — based in Geneva, Switzerland — that, using electromagnets, can accelerate moving charged particles, giving them more energy.  Phase: For a wave, the position in its cycle at a specified time: a measure of whether it is at a crest, a trough, or somewhere in between.  Photon: A quantum of light (which was first proposed by Einstein to explain the photoelectric effect—that is, the fact that shining light on a metal results in the ejection of electrons).  Planck's quantum principle: The idea that light (or any other classical waves) can be emitted or absorbed only in discrete quanta, whose energy E is proportional to their wavelength λ (i.e., E = hc ). λ  Positron: The (positively charged) antiparticle of the electron.  Primordial black hole: A black hole created in the very early universe.  Negative energy: Energy that is less than zero.  Proton: A positively charged subatomic particle, very similar to the neutron, that accounts for roughly half the particles in the nucleus of most atoms. They are stable, but Grand Unification theory predicts that they may decay over a long period of time.  Pulsar: A rotating neutron star that emits regular pulses of radio waves.  Quantum: The indivisible unit in which waves may be emitted or absorbed.  Quark: A subatomic particle that makes up the proton and neutron and feels the strong force. Three quarks make up a proton or neutron, and a quark and antiquark pair makes up a meson.  Quantum chromodynamics (QCD): The theory that describes the interactions of quarks and gluons.  Quantum mechanics: The theory developed from wave equations, Planck's quantum principle and Heisenberg's uncertainty principle. No deviation from quantum mechanics has ever been found in the laboratory. Its most advanced version today is called quantum field theory, which combines special relativity and quantum mechanics. A fully quantum mechanical theory of gravity, however, is exceedingly difficult. 456 455  Quasar: Quasi-stellar object. They are huge galaxies that were formed shortly after the gigantic explosion called the big bang.  Quantum foam: Tiny, foam like distortions of 4 dimensional fabric of space-time at the level of the Planck length.  Radioactivity: The spontaneous breakdown of one type of atomic nucleus into another.  Red shift: The reddening or decrease in frequency of light from a star that is moving away from us, due to the Doppler effect.  Singularity: A point in space-time at which the space-time curvature becomes infinite – which represent a breakdown of general relativity, forcing the introduction of a quantum theory of gravity.  Singularity theorem: A theorem that states that the universe must have started with a singularity.  Space-time: The four-dimensional space whose points are events.  Spatial dimension: Any of the three dimensions that are space like – that is, any except the time dimension.  Special relativity: Einstein's 1905 theory based on the idea that the laws of science should be the same for all observers, no matter how they are moving, in the absence of gravitational phenomena. Consequences include: time slows down, mass increases, and distances shrink the faster you move. Also, matter and energy are related via E = mc2. One consequence of special relativity is the atomic bomb.  Spectrum: The different colors or component frequencies that make up a wave. By analyzing the spectrum of starlight, one can determine that stars are mainly made of hydrogen and helium.  Spin: An internal property of elementary particles.  Stationary state: One that is not changing with time.  Supernova: An exploding star. They are so energetic that they can sometimes outshine a galaxy.  String theory: A theory of physics based on tiny vibrating strings, such that each particle is described as a wave on a string. It is the only theory that can combine gravity with the quantum theory, making it the leading candidate for a theory of everything.  Strong force: The strongest of the four fundamental forces, with the shortest range of all. It holds the quarks together within protons and neutrons, and holds the protons and neutrons together to form atoms.  Steady state theory: The theory which states that the universe had no beginning but constantly generates new matter as it expands, keeping the same density. 457 456  Uncertainty principle: The principle, formulated by Heisenberg, that one can never be exactly sure of both the position and the velocity of a particle; the more accurately one knows the one, the less accurately one can know the other. Δx Δp ≥ ΔE Δt ≥  ħ 2 ħ 2 Avogadro's Number: 6.022 × 1023. The number of nucleons (protons and neutrons) in 1 gram of matter.  Virtual particle: In quantum mechanics, a particle that briefly dart in and out of the vacuum but can never be directly detected, but whose existence does have measurable effects. They violate known conservation laws but only for a short period of time, via the uncertainty principle.  Baryon: A particle that is composed of three quarks, such as the proton or neutron.  Baryon Asymmetry Problem: The fact that the universe contains a billion times as many baryons (ordinary matter) as antibaryons (antimatter), when they would be expected to have been produced in equal quantities in the early universe.  Brownian Motion: The random motion of macroscopic particles that results from their being bombarded by molecules.  Copernican Principle: The earth is not the center of the universe.  Curie Point: The temperature below which iron becomes magnetic.  Generalized Copernican Principle: There is no center of the universe, no special point in space or time.  Hilbert Space: An abstract mathematical space used to describe quantum mechanical states.  Occam's Razor: The principle that one should introduce no more hypotheses than are necessary to explain the data.  Wave / particle duality: The concept in quantum mechanics that there is no distinction between waves and particles; particles may sometimes behave like waves, and waves like particles. 458 457  Wavelength: For a wave, the distance between two adjacent troughs or two adjacent crests.  Weak force: The second weakest of the four fundamental forces – which is carried by the W- and Z-bosons- that makes possible nuclear decay. It affects all matter particles, but not force carrying particles.  Selectron: The supersymmetric partner of the electron. Not yet observed.  Weight: The force exerted on a body by a gravitational field. It is proportional to, but not the same as, its mass.  Principle of Galilean Relativity: Velocity is relative. There is no difference between being in motion at constant velocity and being at rest.  Parity Violation: The observation that the mirror image of a natural process is not always fundamentally equivalent to the original process.  Quantum Electrodynamics (QED): The quantum theory of electromagnetism.  White dwarf: A stable cold star consisting of lower elements such as oxygen, lithium, carbon, and so forth, supported by the exclusion principle repulsion between electrons.  Wormhole: A passageway between two universes or a thin tube of space-time connecting distant regions of the universe. Wormholes might also link to parallel or baby universes and could provide the possibility of time travel.  Neutrino-Dominated Universe: The model in which neutrinos with mass constitute the dark matter of the universe. Gravitational binding energy of the star: U=− 3GM2 5R where:  M and R denote the mass and radius of the star  G is the Gravitational constant 459 458 Core pressure of the star: Pcore = 5GM2 4πR2 Core density of the star: ρcore = 3M πR3 Core Temperature of the star: Tcore = 5μmH GM 3kB R where:  μ denotes mean molecular weight of the matter insider the star  mH is the mass of hydrogen nucleus  kB is the Boltzmann constant The ideal gas equation PV = NkBT does not hold good for the matter present inside a star. Because, most stars are made up of more than one kind of particle and the gas inside the star is ionized. There is no indication of these facts in the above equation. We need to change the ideal gas equation, so that it holds good for the material present inside the star. It can be shown that the required equation can be written as PV = 1 MkB T μ mH where μ denotes mean molecular weight of the matter inside the star, M is the mass of the star and mH is the mass of hydrogen nucleus. 460 459 Stellar timescales  Nuclear timescale: tnuc = total mass of fuel available rate of fuel consumption × fraction of star over which fuel is burned tnuc = MX L Q ×F where M is the mass of the star, X is the fraction of the star (by mass) that is composed of the fuel, L is the star's luminosity, Q is the energy released per mass of the fuel from nuclear fusion, and F is the fraction of the star where the fuel is burned.    Einstein timescale: tE = Mc2 tth ≈ GM2 L Thermal time scale 2RL Dynamical timescale R3 tdyn = √ GM where c is the speed of light 461 460 Richardson-Dushman Equation: The Richardson-Dushman equation relates the current density of a thermionic emission (js) to the work function (W) and temperature (T) of the emitting material: js = A T 2 𝑒 −W kB T where A denotes the Richardson's constant and kB is the Boltzmann constant. In a nuclear reaction: MA+ MB → MC+ MD Q = (MA+ MB −MC −MD) c2 The amount of energy released or absorbed in a nuclear reaction is called the Q value, or reaction energy. If MA+ MB > MC+ MD→ Q > 0 ≡ exoergic reaction If MA+ MB < MC+ MD → Q < 0 ≡ endoergic reaction An endoergic reaction will not proceed unless the incoming particle provides the reaction energy "Q". Drake equation: N = R∗ × fp × nE × fl × fi × fc × L 462 461 where:  N = the number of civilizations in our galaxy with which communication might be possible.   R∗ = the average rate of star formation in our galaxy.  nE = the average number of planets that can potentially support life per star that has fp = the fraction of those stars that have planets. planets.  fl = the fraction of planets that could support life that actually develop life at some point.  fi = the fraction of planets with life that actually go on to develop intelligent life (civilizations).  fc = the fraction of civilizations that develop a technology that releases detectable signs of their existence into space.  L = the length of time for which such civilizations release detectable signals into space. Borda–Carnot equation ∆E = ξ 1 2 ρ (v1 − v2) 2 where:  ΔE is the fluid mechanical energy loss,  ξ is an empirical loss coefficient, which is dimensionless and has a value between zero and one, 0 ≤ ξ ≤ 1  ρ is the fluid density  v1 and v2 are the mean flow velocities before and after the expansion. 463 462 Kepler's equation M = E – e sin E where M is the mean anomaly, E is the eccentric anomaly, and e is the eccentricity. Maxwell's Equations Gauss's law for electricity ∇⦁E= Gauss's law for magnetism ∇×E=− (Faraday's law of induction) Ampere's circuital law ∇ = Laplace operator E = Electric field  ρ = charge density  B = Magnetic field  ε0 = absolute permittivity  J = current density  μ0 = absolute permeability ∂B ∂t ∇ × B = μ0 ( J + ε0 where:  ε0 ∇⦁B= 0 Maxwell–Faraday equation  ρ 464 463 ∂E ) ∂t Prony equation The Prony equation is a historically important equation in hydraulics, used to calculate the head loss due to friction within a given run of pipe. It is an empirical equation developed by Frenchman Gaspard de Prony in the 19th century: hf = L D (aV + bV2) where "hf" is the head loss due to friction, calculated from: the ratio of the length to diameter of the pipe " friction. L D ", the velocity of the flow "V", and two empirical factors "a" and "b" to account for Rankine-Hugoniot conditions In a coordinate system that is moving with the shock, the Rankine–Hugoniot conditions can be expressed as: ρ1 us = ρ2 (us − u2) → Conservation of mass p2 − p1 = ρ2 u2 (us − u2) = ρ1 u2 us → Conservation of momentum p2 u2 = ρ1 us ( 1 2 u22 + e2 − e1) → Conservation of energy where us is the shock wave speed, ρ1 and ρ2 are the mass density of the fluid behind and inside the shock, u2 is the particle velocity of the fluid inside the shock, p1 and p2 are the pressures in the two regions, and e1 and e2 are the specific (with the sense of per unit mass) internal energies in the two regions. Sackur–Tetrode equation 465 464 The Sackur–Tetrode equation expresses the entropy S of a monatomic ideal gas in terms of its thermodynamic state − specifically, its volume V, internal energy U, and the number of particles N: S kB N where:  kB = Boltzmann's constant  m =Mass of a gas particle  h = Planck's constant = ln [ V N ( 4πmU 3/2 5 ) ]+ 2 3h N 2 Butler–Volmer equation j = j0 {exp [ α𝑎 zFη RT ] − exp [ − αc zFη RT ]} where:  j: electrode current density, A/m2 (defined as j = I/S)  j0: exchange current density, A/m2  E: electrode potential, V  Eeq: equilibrium potential, V  T: absolute temperature, K  z: number of electrons involved in the electrode reaction  F: Faraday constant  R: universal gas constant  αc: so-called cathodic charge transfer coefficient, dimensionless  αa: so-called anodic charge transfer coefficient, dimensionless  η: activation overpotential (defined as η = E − E eq). 466 465 Lotka–Volterra equations dx = αx − βxy dy = δxy − γy dt dt where:  x is the number of prey (for example, rabbits)  y is the number of some predator (for example, foxes)  dy   dt and dx represent the instantaneous growth rates of the two populations dt t represents time α, β, γ, δ are positive real parameters describing the interaction of the two species Black–Scholes equation In mathematical finance, the Black–Scholes equation is a partial differential equation (PDE) governing the price evolution of a European call or European put under the Black–Scholes model. Broadly speaking, the term may refer to a similar PDE that can be derived for a variety of options, or more generally, derivatives. For a European call or put on an underlying stock paying no dividends, the equation is: ∂V ∂t + 1 2 σS 2 2 ∂2 V ∂S2 + rS ∂V ∂S – rV = 0 where V is the price of the option as a function of stock price S and time t, r is the risk-free interest rate, and σ is the volatility of the stock. 467 466 Password length parameter In telecommunication, a password length parameter is a basic parameter the value of which affects password strength against brute force attack and so is a contributor to computer security. One use of the password length parameters is in the expression P = L × R , where P is the S probability that a password can be guessed in its lifetime, L is the maximum lifetime a password can be used to log into a system, R is the number of guesses per unit of time, and S is the number of unique algorithm-generated passwords. Stellar structure  The Equation of mass conservation dm dr = 4πr2ρ where: ρ is the matter density and m is the cumulative mass inside the shell at r and G is the gravitational constant.  The Equation of hydrostatic equilibrium dP dr =− Gm r2 ρ where: P is the total pressure (matter plus radiation).  The Equation of energy generation 468 467 dL dr = 4πr2ρq where: L is the luminosity and q is the rate of energy generation per unit mass  The Equation of energy transport dT dr =− 3κρL 64πr2 σT3 where: T is the temperature, κ is the opacity of the matter and σ is the Stefan–Boltzmann constant For stars: tdyn <tth < tnuc  tdyn = timescale of collapsing star, e.g. supernova  tth = timescale of star before nuclear fusion starts, e.g. pre-main sequence lifetime  tnuc = timescale of star during nuclear fusion, i.e. main-sequence lifetime Taft equation log ( ks kCH3 ) = ρ* σ* + δEs 469 468 where log ( ks kCH3 ) is the ratio of the rate of the substituted reaction compared to the reference reaction, σ* is the polar substituent constant that describes the field and inductive effects of the substituent, Es is the steric substituent constant, ρ* is the sensitivity factor for the reaction to polar effects, and δ is the sensitivity factor for the reaction to steric effects. Hammett equation log ( where:    k k0 ) = σρ σ = substituent constant ρ = reaction constant k0 is the reference reaction rate of the unsubstituted reactant, and k that of a substituted reactant. ∆s2 = −c2∆t2 + ∆x2 + ∆y2 + ∆z2  ∆s2 < 0 is a timelike interval. Events separated by this interval can be causally related.  ∆s2 = 0 is a lightlike interval. Events separated by this interval can be causally related, but only by a light speed signal.  ∆s2 > 0 is a spacelike interval. Events separated by this interval cannot be causally related. 470 469 Basic terms in chemistry  Chemistry - a science that deals with the structure and properties of substances and their reactions, it studies matter and energy  Organic chemistry – the branch of chemistry that deals with the chemistry of carbon and living organisms  Analytical chemistry – the branch of chemistry that studies the properties of materials and analyzes materials  Matter - the thing that forms physical objects and occupies space, it exists in four main states as solids, liquids, gases and plasma  Solid – a substance that has a definite shape and a definite volume, it is not compressible  Liquid – a substance (state of matter) which has an indefinite shape and a definite volume, not easily compressible  Gas – a substance with an indefinite shape and volume, easily compressible  Melting point – the temperature at which solids turn into liquid  Condensation – the phase change when gas forms a liquid  Sublimation – the phase change when a solid state changes into a gaseous state  Evaporation – the phase change when a substance changes from a liquid state into a gaseous state  Atom – the smallest unit of matter which has all the chemical properties of a particular element  Molecule − the smallest possible amount of a particular substance that has all the characteristics of that substance  Neutron − a particle found in the nucleus of an atom which has the same mass as a proton but no charge  Element – a substance that consists only of one type of atom  Compound – a chemical substance that consists of two or more elements that together form a molecule  Mixture − a material system made up of two or more different substances which are mixed but are not combined chemically 471 470  Solvent − A liquid in which a substance (solute) dissolves.  Acid − a chemical with a sour taste that forms a salt when mixed with a base  Base − a chemical that reacts with an acid to form a salt, it has a pH higher than 7  Atomic number – the number of protons in an atom  Mass number – the sum of the number of protons and neutrons in one atom  Bond − a force that holds together the atoms in a molecule, an attraction between atoms or molecules  Ion − an atom or group of atoms that has a positive or negative electric charge from losing or gaining one or more electrons  Covalent bond – a type of bond between non-metal atoms, consists of a shared pair of electrons  Shell / orbital – region a of space around the nucleus of an atom where an electron is likely to be found  Steric hindrance − the phenomenon of physical blockage of a particular site within a molecule by the presence of local atoms or groups of atoms.  Structural isomerism − isomers which differ in the order of bonding of the constituent atoms.  Reactant – an original substance that changes when it is combined with another substance in a chemical reaction  Product – resulting substance of a chemical reaction  Mole − A formula mass expressed in grams  Nucleophile − a substance which donates a pair of electrons in the reaction considered.  Chemical equation – a shorthand representation of a chemical reaction with formulas of reactants to the left of an arrow and the formulas of the products to the right of an arrow  Catalyst – a substance that speeds up the rate of a chemical reaction  Enzyme − A biological catalyst.  Combination (synthesis) reaction – chemical change in which two or more substances react to form a single (one) new substance  Period − A horizontal row in the periodic table. 472 471  Beaker − a wide glass with a lip for pouring that is used for holding and measuring liquids  Test tube − a glass container that is shaped like a tube which is closed at one end and that is used especially in science experiments  Funnel − a device shaped like a hollow cone with a tube extending from the point which is used for pouring something (such as a liquid) into a narrow opening  Flask − a glass bottle used in scientific laboratories that is used to carry liquids  Thermometer − an instrument used for measuring temperature  Condenser − a device used for changing a gas into a liquid  Forceps / tweezers − a tool that is used for grasping or holding little things  Spatula − a tool that has a long handle which is bent upward and a wide, thin blade used for lifting and turning chemicals  Bunsen burner − a piece of equipment that produces a hot flame and that is used in scientific experiments  Dropper − a glass or plastic tube that is used to measure out liquids by drops  Tongs − a tool used for lifting or holding objects that is made of two long pieces connected in the middle  Tautomerism − a form of structural isomerism where the two structures are interconvertible by means of the migration of a proton.  Crucible − a pot in which metals or other substances are heated to a very high temperature or melted  Clamp − a device that holds or presses parts tightly together  Petri dish − a small, shallow dish that has a loose cover and that is is used in scientific experiments especially for growing bacteria  Analytical balance − a device that measures weight and shows how heavy things are.  Fume hood − a piece of laboratory equipment designed to limit exposure to dangerous fumes  Markownikow's rule − in the ionic addition of hydrogen halides to a carbon-carbon double bond the halogen attaches itself to the carbon atom bearing the least number of hydrogen atoms. 473 472 Greek Alphabet and SI Prefixes A α alpha N ν nu B β beta Ξ ξ xi Γ γ gamma O o omicron ∆ δ delta Π π pi E ϵ, ε epsilon P ρ rho Z ζ zeta Σ σ, ς sigma H η eta T τ tau Θ θ, ϑ theta Y υ upsilon I ι iota Φ φ, ϕ phi K κ kappa X χ chi Λ λ lambda Ψ ψ psi M µ mu Ω ω omega Double Factorial n!! = n × (n − 2) × … × 5 × 3 × 1 for n > 0 odd n × (n − 2) × … × 6 × 4 × 2 for n > 0 even 1 for n = −1, 0 Convergence Tests D'Alembert's ratio test In a series, ∑∞ 𝑛=1 𝑎𝑛 , let the ratio R =  lim ( 𝑛→∞ If R < 1 the series is convergent 𝑎𝑛+1 𝑎𝑛 474 473 )  If R > 1 the series is divergent  If R = 1 the test fails. The Integral Test ∞ A sum to infinity of an converges if ∫1 𝑎𝑛 𝑑𝑛 is finite. This can only be applied to series where an is positive and decreasing as n gets larger. Maxwell's thermodynamic relations ∂T ( ) ∂V S =−( ∂T ( ) ∂P S ∂V ( ) ∂T P ∂S ( ) ∂V T 475 474 = ∂P ∂V ( ) ∂S P =−( = ) ∂S V ∂S ) ∂P T ∂P ( ) ∂T V Cramer's Rule Two simultaneous equations in unknowns x and y, a1x + b1y = c1 and a2 x + b2 y = c2, have the solutions and c b1 | 1 | c2 b2 x= a b 1 | 1 | a 2 b2 a1 c1 | a c | y = a 2 b2 1 | 1 | a 2 b2 = c1 b2 −c2 b1 = a1 c2 −a2c1 a1 b2 −a2 b1 a1 b2 −a2 b1 When a surface intercepts electromagnetic radiation, a force and a pressure are exerted on the surface. If the radiation is totally absorbed by the surface, the force is F= IA c (total absorption), in which I is the intensity of the radiation, c is the speed of light, and A is the area of the surface perpendicular to the path of the radiation. If the radiation is totally reflected back along its original path, the force is F= 2IA c (total reflection back along path). The radiation pressure pr is the force per unit area: and I pr = (total absorption) c pr = 2I c (total reflection back along path). 475 476 I= E2 cμ0 Because E = c × B and c is such a very large number: the energy associated with the electric field is much greater than that associated with the magnetic field. The rate per unit area at which energy is transported via an electromagnetic wave is given by the Poynting vector: ⃗⃗⃗⃗ × B ⃗⃗⃗⃗ E S⃗⃗⃗ = μ0 Masses are usually measured in atomic mass units, where 1 u = 1.660 538 86 ×10−27 kg and energies are usually measured in electron-volts or multiples of it, where 1 eV = 1.602 176 462 × 10−19 J. Angular wave number = 2π Wavelength The probability that a given particle of mass m and energy E will tunnel through a barrier of height Ub and thickness L is given by the transmission coefficient T: T ≈ e−2bL 8π2 m(Ub −E) where b = √ h2 (h: Planck's constant) 476 477 Because it is a matter wave, an electron confined to an infinite potential well can exist in only certain discrete states. If the well is one-dimensional with length L, the energies associated with these quantum states are En = h 2 n2 8mL2 for n = 1, 2, 3. . . where m is the electron mass and n is a quantum number. Moseley's law υ = A × (Z − b) 2 where:  υ is the frequency of the observed X-ray emission line  Z is the atomic number  A and b are constants that depend on the type of line (that is, K, L, etc. in X-ray notation) Number of conduction electrons in sample = number of atoms in sample × number of valence electrons per atom. 1 becquerel = 1 Bq = 1 decay per second. 1 curie = 1 Ci = 3.7 × 1010 Bq 477 478 Physical Data Often Used Average Earth–Moon distance 8 3.84 × 10 m Average Earth–Sun distance 1.496 × 10 11 m Average Radius of the Earth 6.37 × 10 m Density of air (20°C and 1 atm) 1.20 kg/m Density of water (20°C and 1 atm) 1.00 × 10 kg/m Free-fall acceleration 9.80 m/s 6 3 3 3 2 Mass of the Earth 5.98 × 10 24 kg Mass of the Moon 7.36 × 10 22 kg Mass of the Sun 1.99 × 10 30 kg 5 Standard atmospheric pressure 1.013 × 10 Pa  Distance from the Earth to the most remote known quasar: 1.4 × 1026 m  Distance from the Earth to the most remote normal galaxies: 9 × 10 25 m  Distance from the Earth to the nearest large galaxy (Andromeda): 2 × 1022 m  Distance from the Sun to the nearest star (Proxima Centauri): 4 × 1016 m  One light-year: 9.46 × 1015 m  Mean orbit radius of the Earth about the Sun: 1.50 × 1011 m  Mean distance from the Earth to the Moon: 3.84 × 108 m  Distance from the equator to the North Pole: 1.00 × 107 m  Typical altitude (above the surface) of a satellite orbiting the Earth: 2 × 105 m  Length of a housefly: 5 × 10−3 m  Size of smallest dust particles: ~10−4 m 478 479  Size of cells of most living organisms: ~10−5 m  Diameter of a hydrogen atom: ~10−10 m  Diameter of an atomic nucleus: ~10−14 m  Diameter of a proton: ~10−15 m  Age of the Universe: 5 × 1017 s  Age of the Earth: 1.3 × 1017 s  One year: 3.2 × 107s  One day: 8.6 × 104 s  Time interval between normal heartbeats: 8 × 10−1 s  Period of audible sound waves: ~10−3 s  Period of typical radio waves: ~10−6 s  Period of vibration of an atom in a solid: ~10−13 s  Period of visible light waves: ~10−15 s  Duration of a nuclear collision: ~10−22 s  Time interval for light to cross a proton: ~10−24 s  1000 kg = 1 t (metric ton)  1 slug = 14.59 kg Compressibility Factor (Z) = PV nRT where P is the pressure, n is the number of moles of gas, T is the absolute temperature, and R is the gas constant. 479 480 Garland or mala product: A product of numbers remains the same when read from left to right or vice. 139 × 139 = 15151 152207 × 73 = 11111111 14287143 × 7 = 100010001 12345679 × 9 = 111111111 142857143 × 7 = 1000000001 11011011 × 91 = 1002002001 27994681 × 441 = 12345654321 333333666667 × 33 = 11000011000011 Kaprekar Numbers: 8426 Ascending order: 2468 Descending order: 8642 Difference: 6174 4671 Ascending order: 1467 Descending order: 7641 Difference: 6174 480 481 1, 9, 45, 55, 703, 2223 … are known as Kaprekar numbers. Stoke's Law of Viscosity: F = 6πηrv  F= Drag Force  η = Viscosity Coefficient  r = Radius of the Particle  v = Relative velocity of the Particle Reynolds Number: Re = r×ρ×v μ  Re = Reynolds Number  r = The diameter or length (basically length of the shape of the object)  ρ = The density of the fluid  v = The velocity of the object  μ = Viscosity of the fluid; Eotvos Ramsay-Shield relation: [ M ρ ] 2 3 γ = k (Tc − T − 6) 481 482  M=Molecular Weight  ρ = density  γ = Surface Tension  k = Eotvos-Ramsay Coefficient  Tc = Critical Temperature  T = System Temperature Young-Laplace Equation: Pin = Pout + 2γ  Pin = Pressure Inside the Curved Surface  Pout = Pressure Outside the Curved Surface  γ = Surface Tension  r = Radius of Curvature of the Curved Surface r Dieterici Equation of State:  P = Pressure  V = Volume  a , b = Dieterici Constants  n = Number of Moles  R = Universal Gas Constant  T = Temperature Pe an RTV (V − nb) = nRT 482 483 Energy of Polyatomic Gas (Non-Linear): E = 3 (n −1) RT  E = Average energy per mole  n = Number of atoms in a non-linear Molecule  R= Gas Constant  T= Temperature Energy of Polyatomic Gas (Linear): E= 5 2 RT + (3n − 5) RT  E = Average energy per mole  n = Number of atoms in a linear Molecule  R= Gas Constant  T= Temperature Collision Frequency of a single gas: ZAA = π n σ cave √2  ZAA=Collision frequency  n = Molecules per unit Volume  σ = Diameter of the gas molecules  cave = Average Velocity of the gas molecules 483 484 Root Mean Square, Average, Median Velocity of Gas: 3RT crms = √ M 8RT cave = √ πM 2RT cm = √ M  crms, cave , cm = Root Mean Square, Average Velocity and Most Probable Velocity of gas molecules  M= Molecular Weight  T =Temperature  R= Universal Gas Constant Clausius Clapeyron Equation: ln ( P2 P1 )= ΔHm R  P1 and P2 = Initial and Final Pressure  ΔHm = Molar Enthalpy of vaporization  T1 and T2 = Initial and Final Temperature  R= Gas Constant [ 484 485 1 T1 − 1 T2 ] Relative Population of rotational energy states: Nj N0 = exp (− B h c J (J+1) kB T  NJ = Number of molecule in J state  N0 = Number of molecule in the ground state (J= 0)  kB =Boltzmann Constant  T = Temperature  B = Rotational Constant  h = Plank Constant  c = Velocity of light  J = Rotational Quantum Number Double Bond Equivalent (DBE) = C + 1 −  C= Number of Carbon atoms present  H = Number of Hydrogen atoms present  X= Number of Halogen atoms present (Cl, Br, I or F)  N= Number of Nitrogen atoms present Langmuir Isotherm: θ= KP 1+KP 485 486 ) H 2 − X 2 + N 2  K = Equilibrium Constant of Adsorption  P = Partial Pressure or Concentration of the absorbate  θ = The fraction of adsorbent surface covered by adsorbate Slater's Rule: Zeff = Z − σ  Zeff = Effective nuclear charge  Z = Atomic Number  σ = number of shielding electrons Interplanar Spacing of Cubic Lattice: dhkl =  dhkl = Lattice Spacing  a = Lattice Constant  h , k , l = Miller Indices a √h2 + k2 + 𝑙 2 Interplanar Spacing of Tetragonal Lattice: 1 d2  d= Interplanar Spacing  h , k, l = Miller Indices  a, c = Lattice Constants = h2 + k2 a2 486 487 + 𝑙2 c2 The Dead Sea is much denser and heavier than freshwater because of its salt content, which would make it impossible for us to sink. Pi is an irrational number, which means that it is a real number that cannot be expressed by a simple fraction. If we travel faster than the speed of light, we will age less. Gravitational potential energy increases as height increases. Adding a resistor in series increases the total resistance of a circuit. Adding a resistor in parallel decreases the total resistance of a circuit. The insulator does not permit the free flow of electrons Light slows down, bends toward the normal and has a shorter wavelength when it enters a medium with a higher index of refraction A prism produces a rainbow from white light by the phenomenon of dispersion 487 Spectrum of Electromagnetic Radiation Region Wavelength Wavelength Frequency Energy (Angstroms) (centimeters) (Hz) (eV) Radio > 109 > 10 < 3 × 109 < 10−5 Microwave 109 −106 10 − 0.01 3 × 109 − 3 × 1012 10−5 − 0.01 Infrared 106 − 7000 0.01 − 7 × 10−5 3 × 1012 − 4.3 × 1014 Visible 7000 − 4000 7 × 10−5 − 4 × 10−5 4.3 × 1014 − 7.5 × 1014 2−3 Ultraviolet 4000 − 10 4 × 10−5 − 10−7 7.5 × 1014 − 3 × 1017 3 − 103 X−Rays 10 − 0.1 10−7 − 10−9 3 × 1017 − 3 × 1019 103 − 105 Gamma Rays < 0.1 < 10−9 > 3 × 1019 > 105 0.01 − 2 Doppler Effect When a wave source moves toward us, we will perceive waves with a shorter wavelength and higher frequency than the waves emitted by the source. When a wave source moves away from us, we will perceive waves with a longer wavelength and lower frequency. At the critical angle a wave will be refracted to 90 degrees. At angles larger than the critical angle, light is reflected not refracted. 488 Natural abundance of some elements Isotope % Natural Abundance Atomic Mass 1H 99.985 1.007825 2H 0.015 2.0140 12C 98.89 12 (formerly by definition) 13C 1.11 13.00335 14N 99.64 14.00307 15N 0.36 15.00011 16O 99.76 15.99491 17O 0.04 16.99913 18O 0.2 17.99916 28Si 92.23 27.97693 29Si 4.67 28.97649 30Si 3.10 29.97376 32S 95.0 31.97207 33S 0.76 32.97146 34S 4.22 33.96786 489 35Cl 75.77 34.96885 37Cl 24.23 36.96590 79Br 50.69 78.9183 81Br 49.31 80.9163 There are 2 basic types of elementary particles: Hadrons and Leptons There are 2 types of Hadrons: Baryons and Mesons Made up of 3 quarks Made up of a quark and antiquark As the frequency of an electromagnetic radiation increases, its energy increases and its wavelength decreases and its velocity remains constant as long as it doesn't enter a medium with a different refractive index Ionized gases conduct electric current using positive ions, negative ions and electrons. 490 Thermal DeBroglie wavelength of an electron: λD = √ h2 2πme kB T where: h is the Planck's constant, me is the mass of the electron, kB is the Boltzmann's constant, and T is the temperature. Debye screening wave vector = 1 Debye length The Debye length of semiconductors: εkB T LD = √ 2 q Ndop where:  ε is the dielectric constant,  kB is the Boltzmann's constant,  T is the absolute temperature in Kelvins,  q is the elementary charge, and  Ndop is the net density of dopants (either donors or acceptors). 491 488 The Bjerrum length is given by: λB = e2 4πε0 εr kB T where: e is the elementary charge, εr is the relative dielectric constant of the medium and ε0 is the vacuum permittivity. Drift velocity = electrical mobility of the particle × magnitude of the applied electric field Fusion energy gain factor = Pfusion Pheating  Pfusion = power produced in a nuclear fusion reactor  Pheating = power of external heating required to keep fusion going The Hall parameter, β, in a plasma is the ratio between the electron gyrofrequency, Ωe, and the electron-heavy particle collision frequency, ν: β= Ωe ν = eB νme where:  e is the elementary charge (approximately 1.6×10−19 C)  B is the magnetic field (in teslas) 492 489  me is the electron mass (approximately 9.1×10−31 kg) Magnetic Reynolds number: Rm = UL η where:  U is a typical velocity scale of the flow  L is a typical length scale of the flow  η is the magnetic diffusivity Péclet number = advective transport rate diffusive transport rate Nusselt number = hL k where h is the convective heat transfer coefficient of the flow, L is the characteristic length, k is the thermal conductivity of the fluid. Magnetic Prandtl number = 493 490 momentum diffusivity magnetic diffusivity The magnetic pressure PB is given in SI units (P in Pa, B in T, μ0 in H/m) by: PB = B2 2μ0 where: B is the strength of magnetic field and μ0 is the permeability of free space. Static resistance = small change in current Static conductance = Differential conductance = 1 Static resistance small change in current small change in voltage The acceleration gradient for a linear plasma wave is: me ne 494 491 current small change in voltage Differential resistance = E=c√ voltage ε0 In this equation, E is the electric field, c is the speed of light in vacuum, me is the mass of the electron, ne is the plasma electron density (in particles per metre cubed), and ε0 is the permittivity of free space. Bond distance d in Rydberg matter is given by: d = 2.9 n2a0 where n is the principal quantum number and a0 is the Bohr radius. The ram pressure is a function of wind speed and density. The formula is P = mp n v2 where mp is the proton mass, pressure P is in nPa (nanopascals), n is the density in particles/cm 3 and v is the speed in km/s of the solar wind. For a gas composed of a single atomic species, the Saha equation is written: ni+1 ne ni = 2 gi+1 exp λ3 gi [− εi+1 − εi kB T ] where: ni + 1 and ni are the number of atoms in the (i + 1) th and ith ionization states, respectively; g i + 1 and gi describe how energy is partitioned among the (i + 1) 495 492 th and ith ionization states; εi + 1 and εi are the energies of the ionization states; ne is the number of electrons; and T is the temperature. λ = √ h2 2πme kB T is the thermal de Broglie wavelength of an electron. The other quantities in the equation are physical constants: me is the mass of the electron, kB is the Boltzmann's constant, and h is Planck's constant. Bowen ratio = sensible heating latent heating Bejan number = entropy generation contributed by heat transfer entropy generation contributed by heat transfer+ entropy generation contributed by fluid friction Antoine equation log10 p = A − B C+T where: p is the vapor pressure, T is temperature and A, B and C are component-specific constants. Kopp–Neumann law: 496 493 The Kopp–Neumann law, named for Kopp and Franz Ernst Neumann, is a common approach for determining the specific heat C (in J·kg−1·K−1) of compounds using the following equation: C = ∑𝑁 𝑖 =1(𝐶𝑖 ∙ 𝑓𝑖 ) where: N is the total number of compound constituents, and Ci and fi denote the specific heat and mass fraction of the ith constituent. This law works surprisingly well at roomtemperature conditions, but poorly at elevated temperatures. Stefan number = sensible heat latent heat Duhem–Margules equation: ( dlnPA dlnPB ) =( ) dlnxA T, P dlnxB T, P where PA and PB are the partial vapor pressures of the two constituents and x A and xB are the mole fractions of the liquid. Airway Conductance = Airway Resistance = 1 Airway Resistance Atmospheric Pressure−Alveolar Pressure Volumetric Airflow 497 494 Cardiac index = Cardiac output Body surface area = Stroke volume × Heart rate Body surface area Stroke volume = End-systolic volume − End-diastolic volume Mean arterial pressure = (cardiac output × systemic vascular resistance) + central venous pressure In practice, the contribution of central venous pressure (which is small) is generally ignored and so: Mean arterial pressure = cardiac output × systemic vascular resistance Pulse pressure = systolic pressure − diastolic pressure Ejection fraction (%) = stroke volume end diastolic volume 498 495 × 100 Body mass index = body mass (body height)2 Low-density lipoprotein: LDL = C – HDL − kT where: HDL is High Density Lipoprotein, C is total cholesterol, T denote the triglycerides, and k is 0.20 if the quantities are measured in mg/dl and 0.45 if in mmol/l. Widmark formula: Blood Alcohol Content = Alcohol consumed in grams Body weight in grams × r × 100 In this formula, "r" is the gender constant: r = 0.55 for females and 0.68 for males. Creatinine Clearance: CrCl (male) = (140 − age) (weight in kg) 72 × serum creatinine For women, this result is multiplied by the factor 0.85. 499 496 The Doppler frequency shift for active radar is as follows, where FD is Doppler frequency, FT is transmit frequency, vR is radial velocity, and c is the speed of light: FD = 2 × FT × vR c For Passive radar: FD = FT × vR c Output voltage of the transducer: Vout = P × K × Vsa Vsi where:  P is the actual measured pressure.  K is the nominal transducer scale factor.  Vsa is the actual transducer supply voltage.  Vsi is the ideal transducer supply voltage. Critical damping coefficient = 500 497 actual damping critical damping True Positive True Positive Rate = True Positive +False Negative False Positive Rate = False Positive True Negative +False Positive The specific intensity Iν of radiation is defined by: Iν = dP (cosθ dσ) dν dΩ where dP is the power received by a detector with projected area (cosθ dσ) in the solid angle dΩ and in the frequency range ν to ν + dν. Iλ is the brightness per unit wavelength: Iλ = dP (cosθ dσ) dλ dΩ These two quantities are related by: Iλ Iν = dν dλ = c λ2 The spectral energy density of radiation is: uν = 1 c ∫ Iν dΩ The mean photon energy of blackbody radiation is: E = 2.7 kBT 501 498 The flux density of isotropic radiation is: Sν = π Iν The Nyquist approximation for the spectral power generated by a warm resistor in the limit hν ≪ kBT is Pν = kBT At any frequency, the exact Nyquist formula is Pν = exp( hν hν )−1 kB T The CMB temperature at redshift z is T = T0 (1 + z) T0 is the temperature of the CMB as observed in the present day (2.725 K) The total power emitted by an accelerated charge is given by Larmor's formula: P= q2 a 2 6πε0 c3 which is valid only if v << c where a is the proper acceleration, q is the charge, and c is the speed of light. If an antenna delivers Po watts to the load connected to its output terminals (e.g. the receiver) when irradiated by a uniform field of power density S watts per square meter, the antenna's aperture Ae in square meters is given by: Ae = Po S 502 499 PN B where: = kBT  PN is the noise power  B is the total bandwidth over which that noise power is measured  kB is the Boltzmann constant (1.381×10−23 J/K)  T is the noise temperature The minimum mean density of a pulsar with period P is: ρ>  3π GP2 G is the Newtonian constant of gravitation The spin-down luminosity of a pulsar is: − dErot dt  I is the moment of inertia  Erot is the rotational kinetic energy = −4π2 I The characteristic age of a pulsar is defined by: τ= P 2× 503 500 dP dt P3 × dP dt Bremermann's limit: c2 h ≈ 1.36 × 1050 bits per second per kilogram is a limit on the maximum rate of computation that can be achieved in a self-contained system in the material universe. Bekenstein bound: S≤ 2πkB RE ℏc where S is the entropy, kB is Boltzmann's constant, R is the radius of a sphere that can enclose the given system, E is the total mass–energy including any rest masses, ℏ is the reduced Planck constant, and c is the speed of light. In informational terms, with S = kB × I × ln 2, the bound is given by I≤ 2πRE ℏc ln2 where I is the information expressed in number of bits contained in the quantum states in the sphere. The ln 2 factor comes from defining the information as the logarithm to the base 2 of the number of quantum states. Using mass–energy equivalence (E=Mc2), the informational limit may be reformulated as I≤ 2πcRM ℏ ln2 504 501 Band ratio (TM) Mineral 5/7 clay, carbonate, silica, mica group 3/1 heamtite goethite and jarosite 5/4 bare rock and soil Geology: Drainage density = Asymmetry factor = Bifurcation ratio = total length of channel in a drainage basin total area area of the basin to the right of the trunk stream total area of the drainage basin × 100 The number of streams of one order The number of streams of the next higher order in a drainage network Discharge = width of the channel × depth of the channel × velocity of flow the length of the stream channel Channel sinuosity = the straight line distance between the end points of the selected channel reach Ripple index = ripple wavelength ripple height Symmetry index = 505 502 stoss length lee length  Tonnage = Volume of ore-block × Specific gravity  Metal content = tonnage × grade (or assay value)  Mineral matter = 1.1 × Ash content  Weight loss due to Volatile Matter = Total Weight loss – moisture  % Volatile Matter =  Fixed carbon = 100 – (% moisture + % Ash content + % volatile matter)  % moisture =  % Ash content =  Dry mineral matter free volatile matter = 100 − Dry mineral matter free Fixed carbon  % Fixed carbon on dry ash free basis = 100 – (% moisture + % Ash content)  Analysis on dry ash free basis =  Darcy's law: Weight loss due to volatile matter Weight of sample × 100 Weight loss due to moisture × 100 Weight of sample Weight of residue × 100 Weight of sample % Volatile Matter 100−(% moisture + % Ash content) permeability × 100 Instantaneous flow rate = − dynamic viscosity of the fluid × pressure drop  Plasticity index = Liquid limit – Plastic limit  Consistency index =  Bulk density of soil = Liquid limit – water content Liquid limit – Plastic limit dry weight of soil volume of soil 506 503 dry weight of soil  Particle density of soil =  Mass wetness =  Void ratio =  Porosity =  Degree of saturation =  Uniformity coefficient =  Coefficient of curvature: Cc = volume of solid mass of water mass of soil volume of voids volume of solids void volume total volume volume of water in a soil volume of voids × 100 The size opening that will just pass 60% of the sand (d60 value) The size opening that will just pass 10% of the sand sample (d10 value) (Size of particle corresponding to 30% finer)2 Size of the particle corresponding to 60% finer × Size of the particle corresponding to 10% finer the density of a substance  Relative density =  Total core recovery = Sum of length of core pieces  Solid core recovery = Sum of length of solid , cylindrical, core pieces > core diameter  Rock quality designation = the density of a given reference material Total length of core run × 100 Total length of core run Sum of length of core pieces >100mm Total length of core run Rock quality designation Rock mass quality < 25% Very poor 25-50% Poor 51-75% Fair 76-90% Good 91-100% Excellent 507 504 × 100 × 100  Rock quality designation (RQD) = 115 − 3.5 Jn  Rock tunneling index = where: RQD Jn × Jr Ja × Jw SRF  Jn = Joint set number (1−20)  Jr = Joint roughness (1−20)  Ja = Joint alteration number  Jw = Joint water flow (1−20)  SRF = stress reduction factor  Geological strength index = 9log[  Slake durability index = where: C−D A−D RQD Jn × 100 × Jr Ja ] + 44  D = dry drum mass  A = drum mass with rock before run  C = drum mass with rock after run elastic modulus of a particular material in a cross−section  Modular ratio =  Point load index (Is) → The force needed to fracture a sample of rock between conical points: Is = P D2 elastic modulus of the base or the reference material , where P is force and D is the distance between the points, both at failure. Is is related to uniaxial compressive strength (approximately equal to Is × 24)  Wyllie time-average equation: 1 wave velocity in rock = porosity in rock velocity of the fluid in the pores 508 505 + (1− porosity in rock) velocity of the rock matrix sinC = 1 n where:  C is the critical angle.  n is the refractive index of the medium. Substance medium Refractive index Critical angle Water 1.33 48.75° Crown glass 1.52 41.14° Dense flint glass 1.62 37.31° Diamond 2.42 24.41° Science Technology Explores new knowledge methodically through The application of scientific knowledge for various observation and experimentation. purposes. The wave nature of light was demonstrated convincingly for the first time in 1801 by Thomas Young by a wonderfully simple experiment. He let a ray of sunlight into a dark room, placed a dark screen in front of it, pierced with two small pinholes, and beyond this, at some distance, a white screen. He then saw two darkish lines at both sides of a bright line, which gave him sufficient encouragement to repeat the experiment, this time with spirit flame as light source, with a little salt in it to produce the bright yellow sodium light. This time he saw a number of dark lines, regularly spaced; the first clear proof that light added to light can produce darkness. This phenomenon is called interference. Thomas Young had expected it because he believed in the wave theory of light. − Dennis Gabor 509 506 Physical quantities with same dimensional formula: Physical Quantity Dimensional Formula Momentum and impulse [M1L1T-1] Angular momentum and Planck's constant [M1L2T-1] Work, Energy, Moment of a force, Torque and couple [M1L2T-2] Frequency, Angular Frequency, Angular velocity and Velocity gradient [M0L0T-1] Pressure, Stress, Elastic constant and Energy density [M1L-1T-2] Force constant (spring), Surface Tension and surface energy [M1L0T-2] Radius of gyration, light year and wavelength [M0L1T0] The Spectral Lines for Atomic Hydrogen: Series n1 n2 Spectral Region Lyman 1 2, 3 … Ultraviolet Balmer 2 3, 4 … Visible Paschen 3 4, 5 … Infrared Brackett 4 5, 6 … Infrared Pfund 5 6, 7 … Infrared Formal charge (F.C.) on an atom in a Lewis structure = Total number of valence electrons in the free atom Total number of − non bonding (lone pair) electrons 510 507 Total number of − 1 2 bonding (shared) electrons Bonding molecular orbital Anti Bonding molecular orbital Molecular orbitals formed by the additive Molecular orbitals formed by the subtractive effect of the atomic orbitals effect of atomic orbitals Probability of finding the electrons is more Probability of finding the electrons is less ΔG0 = ΔH0−TΔS0 ΔH0 ΔS0 ΔG0 – + – Reaction spontaneous at all temperatures – – – (at low Temperature) Reaction spontaneous at low temperature – – + (at high Temperature) Reaction non-spontaneous at high temperature + + + (at low Temperature) Reaction Non-spontaneous at low temperature + + – (at high Temperature) Reaction spontaneous at high temperature + – + (at all Temperature) Reaction non-spontaneous at all temperatures Description Temperature Corrected Density = (Density of Fuel Oil @ 15⁰C) × [1− {(T−15) × 0.00064}] where: T = temperature of oil in bunker tanks in degree Celsius Metric Tonnes = (Actual Sounder Volume) × (Temperature Corrected Density) Specific Fuel Oil Consumption (SFOC): SFOC (g/KWh) = Mass of fuel consumed per hour Power developed in KW Engine distance in nautical mile = (Pitch × revolutions per day) 511 508 List of physical quantities: Base quantity Description SI base unit Length The one-dimensional extent of an object metre Mass A measure of resistance to acceleration kilogram Time The duration of an event second Electric Current Rate of flow of electrical charge per unit time ampere Temperature Average kinetic energy per degree of freedom of Kelvin a system Amount of substance The quantity proportional to the number of mole particles in a sample, with the Avogadro constant as the proportionality constant Luminous intensity Wavelength-weighted power of emitted light candela per unit solid angle Derived quantity Description SI derived unit Young's modulus Ratio of stress to strain pascal (Pa = N/m2) Work Transferred energy joule (J) Weight Gravitational force on an object newton (N = kg⋅m/s2) 512 Derived quantity Wavevector Wavenumber Wavelength Volumetric flow rate Volume Velocity Description Repetency or spatial frequency vector: the number of cycles per unit distance Repetency or spatial frequency: the number of cycles per unit distance Perpendicular distance between repeating units of a wave Rate of change of volume with respect to SI derived unit m−1 m−1 m time m3⋅s−1 Three dimensional extent of an object m3 Moved distance per unit time: the first time derivative of position m/s Product of a force and the perpendicular Torque distance of the force from the point about newton-metre (N⋅m) which it is exerted Thermal resistivity Thermal resistance Thermal conductivity Thermal conductance Measure for the ease with which a material resists conduction of heat Measure for the ease with which an object resists conduction of heat Measure for the ease with which a material conducts heat Measure for the ease with which an object conducts heat 513 K⋅m/W K/W W/(m⋅K) W/K Derived quantity Temperature gradient Surface tension Description steepest rate of temperature change at a particular location Energy change per unit change in surface area SI derived unit K/m N/m or J/m2 Stress Force per unit oriented surface area Pa Strain Extension per unit length unitless Spin Quantum-mechanically defined angular momentum of a particle kg⋅m2⋅s−1 Specific volume Volume per unit mass (reciprocal of density) m3⋅kg−1 Specific heat capacity Heat capacity per unit mass J/(K⋅kg) Specific energy Energy density per unit mass J⋅kg−1 Solid angle Reluctance Refractive index Reaction rate Radiant intensity Radiance Ratio of area on a sphere to its radius squared resistance to the flow of magnetic flux Factor by which the phase velocity of light is reduced in a medium Rate of a chemical reaction for unit time Power of emitted electromagnetic radiation per unit solid angle Power of emitted electromagnetic radiation 514 steradian (sr) H−1 unitless mol/(m3⋅s) W/sr W/(m2⋅sr) Derived quantity Description SI derived unit per unit solid angle per emitting source area Pressure Force per unit area pascal (Pa = N/m2) Power Rate of transfer of energy per unit time watt (W) Pop Plane angle Rate of change of crackle per unit time: the sixth time derivative of position Ratio of circular arc length to radius m/s6 radian (rad) Measure for how the polarization of a Permittivity material is affected by the application of an F/m external electric field Measure for how the magnetization of Permeability material is affected by the application of an H/m external magnetic field Optical power Momentum Moment of inertia Molar heat capacity Measure of the effective curvature of a lens or curved mirror; inverse of focal length Product of an object's mass and velocity Inertia of an object with respect to angular acceleration Heat capacity of a material per unit amount of substance dioptre (dpt = m−1) kg⋅m/s kg⋅m2 J/(K⋅mol) Molar entropy Entropy per unit amount of substance J/(K⋅mol) Molar energy Amount of energy present in a system per J/mol 515 Derived quantity Description SI derived unit unit amount of substance Molar concentration Mean lifetime Mass fraction Magnetization Magnetic flux density Magnetic flux Magnetic field strength Mach number (or mach) Luminous flux (or luminous power) Linear density Jounce (or snap) Jerk Amount of substance per unit volume Average time for a particle of a substance to decay Mass of a substance as a fraction of the total mass Amount of magnetic moment per unit volume Measure for the strength of the magnetic field Measure of magnetism, taking account of the strength and the extent of a magnetic field Strength of a magnetic field Ratio of flow velocity to the local speed of sound mol⋅m−3 s kg/kg A/m tesla (T = Wb/m2) weber (Wb) A/m unitless Perceived power of a light source lumen (lm = cd⋅sr) Mass per unit length kg⋅m−1 Change of jerk per unit time: the fourth time derivative of position Change of acceleration per unit time: the 516 m/s4 m/s3 Derived quantity Description SI derived unit third time derivative of position Irradiance Intensity Inductance Impulse Impedance Electromagnetic radiation power per unit surface area Power per unit cross sectional area Magnetic flux generated per unit current through a circuit Transferred momentum Resistance to an alternating current of a given frequency, including effect on phase W/m2 W/m2 henry (H) newton-second (N⋅s = kg⋅m/s) ohm (Ω) Illuminance Luminous flux per unit surface area lux (lx = cd⋅sr/m2) Heat flux density Heat flow per unit time per unit surface area W/m2 Heat capacity Energy per unit temperature change J/K Heat Thermal energy joule (J) Half-life Frequency Force Entropy Time for a quantity to decay to half its initial value Number of (periodic) occurrences per unit time Transfer of momentum per unit time Logarithmic measure of the number of available states of a system 517 s hertz (Hz = s−1) newton (N = kg⋅m⋅s−2) J/K Derived quantity Description SI derived unit Energy density Energy per unit volume J⋅m−3 Energy Energy J Electrical resistivity Electrical resistance Electrical conductivity Electrical conductance Bulk property equivalent of electrical resistance Electric potential per unit electric current Measure of a material's ability to conduct an electric current Measure for how easily current flows through a material ohm-metre (Ω⋅m) ohm (Ω = V/A) S/m siemens (S = Ω−1) Energy required to move a unit charge Electric potential through an electric field from a reference volt (V = J/C) point Electric field strength Strength of the electric field V/m Electric displacement field Strength of the electric displacement C/m2 Electric charge density Electric charge per unit volume C/m3 Electric charge The force per unit electric field strength coulomb (C = A⋅s) Dynamic viscosity Dose equivalent Measure for the resistance of an incompressible fluid to stress Received radiation adjusted for the effect on biological tissue 518 Pa⋅s sievert (Sv = m2/s2) Derived quantity Description SI derived unit Current density Electric current per unit cross-section area A/m2 Crackle Chemical potential Change of jounce per unit time: the fifth time derivative of position Energy per unit change in amount of substance m/s5 J/mol Inertial force that appears to act on all Centrifugal force objects when viewed in a rotating frame of N⋅rad = kg⋅m⋅rad⋅s−2 reference Catalytic activity Change in reaction rate due to presence of concentration a catalyst per unit volume of the system Capacitance Stored charge per unit electric potential farad (F = C/V) Area density Mass per unit area kg⋅m−2 Area Extent of a surface m2 kat⋅m−3 The angle incremented in a plane by a Angular velocity segment connecting an object and a rad/s reference point per unit time Angular momentum Angular acceleration Acceleration Measure of the extent and direction of an object rotates about a reference point Change in angular velocity per unit time Rate of change of velocity per unit time: the second time derivative of position 519 kg⋅m2/s rad/s2 m/s2 Derived quantity Description SI derived unit Absorbed dose rate Absorbed dose received per unit of time Gy/s Measure of sustained displacement: the first Absement Ionizing radiation energy absorbed by (Radioactive) Dose biological tissue per unit mass (Radioactive) Activity (Mass) Density (or volume density) m⋅s integral with respect to time of displacement gray (Gy = m2/s2) Number of particles decaying per unit time becquerel (Bq = Hz) Mass per unit volume kg/m3 The Earth spins at 1,000 mph but it travels through space at an incredible 67,000 mph. Every year over one million earthquakes shake the Earth. The dinosaurs (a diverse group of reptiles of the clade Dinosauria) became extinct before the Rockies or the Alps were formed. The first synthetic human chromosome was constructed by US scientists in 1997. There are 60,000 miles of blood vessels in the human body. 520 If the Sun were the size of a beach ball then Jupiter would be the size of a golf ball and the Earth would be as small as a pea. List of Nobel laureates in Physics 1901 Wilhelm Röntgen "in recognition of the extraordinary services he has rendered by the discovery of the remarkable rays subsequently named after him" 1902 Hendrik Lorentz "in recognition of the extraordinary service they rendered by their researches into the influence Pieter Zeeman 1903 of magnetism upon radiation phenomena" Antoine Henri Becquerel "for his discovery of spontaneous radioactivity" Pierre Curie "for their joint researches on the radiation phenomena discovered by 1904 Marie Skłodowska-Curie Professor Henri Becquerel" Lord Rayleigh "for his investigations of the densities of the most important gases and for his discovery of argon in connection with these studies" 1905 Philipp Eduard Anton von "for his work on cathode rays" Lenard 1906 Joseph John Thomson "for his theoretical and experimental investigations on the conduction of electricity by gases" 1907 Albert Abraham Michelson "for his optical precision instruments and the spectroscopic and metrological investigations 521 carried out with their aid" 1908 Gabriel Lippmann "for his method of reproducing colours photographically based on the phenomenon of interference" 1909 Guglielmo Marconi "for their contributions to the development of wireless telegraphy" Karl Ferdinand Braun 1910 1911 Johannes Diderik van der "for his work on the equation of state for gases and Waals liquids" Wilhelm Wien "for his discoveries regarding the laws governing the radiation of heat" 1912 Nils Gustaf Dalén "for his invention of automatic valves designed to be used in combination with gas accumulators in lighthouses and buoys" 1913 Heike Kamerlingh-Onnes "for his investigations on the properties of matter at low temperatures which led, inter alia, to the production of liquid helium" 1914 Max von Laue "For his discovery of the diffraction of X-rays by crystals", an important step in the development of Xray spectroscopy. 1915 William Henry Bragg "'For their services in the analysis of crystal structure by means of X-rays', an important step in William Lawrence Bragg the development of X-ray crystallography" 522 Not awarded due to World War I 1916 1917 Charles Glover Barkla "'For his discovery of the characteristic Röntgen radiation of the elements', another important step in the development of X-ray spectroscopy" 1918 Max Planck "for the services he rendered to the advancement of physics by his discovery of energy quanta" 1919 Johannes Stark "for his discovery of the Doppler effect in canal rays and the splitting of spectral lines in electric fields" 1920 Charles Édouard "for the service he has rendered to precision Guillaume measurements in physics by his discovery of anomalies in nickel-steel alloys" 1921 Albert Einstein "for his services to theoretical physics, and especially for his discovery of the law of the photoelectric effect" 1922 Niels Bohr "for his services in the investigation of the structure of atoms and of the radiation emanating from them" 1923 1924 Robert Andrews "for his work on the elementary charge of electricity and Millikan on the photoelectric effect" Manne Siegbahn "for his discoveries and research in the field of X-ray spectroscopy" 1925 James Franck "for their discovery of the laws governing the impact of 523 an electron upon an atom" Gustav Hertz 1926 Jean Baptiste Perrin "for his work on the discontinuous structure of matter, and especially for his discovery of sedimentation equilibrium" 1927 1928 1929 Arthur Holly Compton "for his discovery of the effect named after him" Charles Thomson Rees "for his method of making the paths of electrically Wilson charged particles visible by condensation of vapour" Owen Willans "for his work on the thermionic phenomenon and Richardson especially for the discovery of the law named after him" Louis Victor Pierre "for his discovery of the wave nature of electrons" Raymond, 7th Duc de Broglie 1930 Chandrasekhara "for his work on the scattering of light and for the Venkata Raman discovery of the effect named after him" 1931 1932 Not awarded Werner Heisenberg "for the creation of quantum mechanics, the application of which has, inter alia, led to the discovery of the allotropic forms of hydrogen" 1933 Erwin Schrödinger "for the discovery of new productive forms of atomic theory" Paul Dirac 524 Not awarded 1934 1935 James Chadwick "for the discovery of the neutron" 1936 Victor Francis Hess "for his discovery of cosmic radiation" Carl David Anderson "for his discovery of the positron" Clinton Joseph "for their experimental discovery of the diffraction of Davisson electrons by crystals" 1937 George Paget Thomson 1938 Enrico Fermi "for his demonstrations of the existence of new radioactive elements produced by neutron irradiation, and for his related discovery of nuclear reactions brought about by slow neutrons" 1939 Ernest Lawrence "for the invention and development of the cyclotron and for results obtained with it, especially with regard to artificial radioactive elements" 1940 Not awarded due to World War II 1941 1942 1943 Otto Stern "for his contribution to the development of the molecular ray method and his discovery of the magnetic moment of 525 the proton" 1944 Isidor Isaac Rabi "for his resonance method for recording the magnetic properties of atomic nuclei" 1945 Wolfgang Pauli "for the discovery of the Exclusion Principle, also called the Pauli principle" 1946 Percy Williams "for the invention of an apparatus to produce extremely Bridgman high pressures, and for the discoveries he made there within the field of high pressure physics" 1947 Edward Victor "for his investigations of the physics of the upper Appleton atmosphere especially for the discovery of the socalled Appleton layer" 1948 Patrick Maynard Stuart "for his development of the Wilson cloud Blackett chamber method, and his discoveries therewith in the fields of nuclear physics and cosmic radiation" 1949 Hideki Yukawa "for his prediction of the existence of mesons on the basis of theoretical work on nuclear forces" 1950 Cecil Frank Powell "for his development of the photographic method of studying nuclear processes and his discoveries regarding mesons made with this method" 1951 John Douglas "for their pioneer work on the transmutation of atomic Cockcroft nuclei by artificially accelerated atomic particles" Ernest Thomas Sinton 526 Walton 1952 Felix Bloch "for their development of new methods for nuclear magnetic precision measurements and discoveries in connection therewith" Edward Mills Purcell 1953 Frits Zernike "for his demonstration of the phase contrast method, especially for his invention of the phase contrast microscope" 1954 Max Born "for his fundamental research in quantum mechanics, especially for his statistical interpretation of the wavefunction" Walther Bothe "for the coincidence method and his discoveries made therewith" 1955 Willis Eugene Lamb "for his discoveries concerning the fine structure of the hydrogen spectrum" Polykarp Kusch "for his precision determination of the magnetic moment of the electron" 1956 John Bardeen "for their researches on semiconductors and their discovery of the transistor effect" Walter Houser Brattain William Bradford Shockley 527 1957 Tsung-Dao Lee "for their penetrating investigation of the so-called parity laws which has led to important discoveries regarding the elementary particles" Chen-Ning Yang 1958 Pavel Alekseyevich "for the discovery and the interpretation of Cherenkov the Cherenkov effect" Ilya Frank Igor Yevgenyevich Tamm 1959 Emilio Gino Segrè "for their discovery of the antiproton" Owen Chamberlain 1960 Donald Arthur Glaser "for the invention of the bubble chamber" 1961 Robert Hofstadter "for his pioneering studies of electron scattering in atomic nuclei and for his thereby achieved discoveries concerning the structure of the nucleons" Rudolf Ludwig "for his researches concerning the resonance absorption Mössbauer of gamma radiation and his discovery in this connection of the effect which bears his name" 1962 Lev Davidovich Landau "for his pioneering theories for condensed matter, especially liquid helium" 1963 Eugene Paul Wigner "for his contributions to the theory of the atomic 528 nucleus and the elementary particles, particularly through the discovery and application of fundamental symmetry principles" Maria Goeppert-Mayer "for their discoveries concerning nuclear shell structure" J. Hans D. Jensen 1964 Nicolay Gennadiyevich "for fundamental work in the field of quantum Basov electronics, which has led to the construction of oscillators and amplifiers based on the maser– laser principle" Alexander Prokhorov Charles Hard Townes 1965 Richard Phillips "for their fundamental work in quantum Feynman electrodynamics (QED), with deep-ploughing consequences for the physics of elementary particles" Julian Schwinger Shin'ichirō Tomonaga 1966 Alfred Kastler "for the discovery and development of optical methods for studying Hertzian resonances in atoms" 1967 Hans Albrecht Bethe "for his contributions to the theory of nuclear reactions, especially his discoveries concerning the energy production in stars" 1968 Luis Walter Alvarez "for his decisive contributions to elementary particle physics, in particular the discovery of a large number 529 of resonance states, made possible through his development of the technique of using hydrogen bubble chamber and data analysis" 1969 Murray Gell-Mann "for his contributions and discoveries concerning the classification of elementary particles and their interactions" 1970 Hannes Olof Gösta "for fundamental work and discoveries in magneto- Alfvén hydrodynamics with fruitful applications in different parts of plasma physics" Louis Néel "for fundamental work and discoveries concerning antiferromagnetism and ferrimagnetism whic h have led to important applications in solid state physics" 1971 Dennis Gabor "for his invention and development of the holographic method" 1972 John Bardeen "for their jointly developed theory of superconductivity, usually called the BCS-theory" Leon Neil Cooper John Robert Schrieffer 1973 Leo Esaki "for their experimental discoveries regarding tunneling phenomena in semiconductors and superconductors, respectively" Ivar Giaever Brian David Josephson "for his theoretical predictions of the properties of 530 a supercurrent through a tunnel barrier, in particular those phenomena which are generally known as the Josephson effect" 1974 Martin Ryle "for their pioneering research in radio astrophysics: Ryle for his observations and inventions, in particular of Antony Hewish the aperture synthesis technique, and Hewish for his decisive role in the discovery of pulsars" 1975 Aage Bohr "for the discovery of the connection between collective motion and particle motion in atomic nuclei and the Ben Roy Mottelson development of the theory of the structure of the atomic nucleus based on this connection" Leo James Rainwater 1976 Samuel Chao Chung "for their pioneering work in the discovery of a heavy Ting elementary particle of a new kind" Burton Richter 1977 Philip Warren "for their fundamental theoretical investigations of the Anderson electronic structure of magnetic and disordered systems" Nevill Francis Mott John Hasbrouck Van Vleck 1978 Pyotr Leonidovich "for his basic inventions and discoveries in the area Kapitsa of low-temperature physics" 531 Arno Allan Penzias "for their discovery of cosmic microwave background radiation" Robert Woodrow Wilson 1979 Sheldon Lee Glashow "for their contributions to the theory of the unified weak and electromagnetic interaction between elementary Abdus Salam particles, including, inter alia, the prediction of the weak neutral current" Steven Weinberg 1980 James Watson Cronin "for the discovery of violations of fundamental symmetry principles in the decay of neutral K-mesons" Val Logsdon Fitch 1981 Nicolaas Bloembergen "for their contribution to the development of laser spectroscopy" Arthur Leonard Schawlow 1982 Kai Manne Börje "for his contribution to the development of high- Siegbahn resolution electron spectroscopy" Kenneth G. Wilson "for his theory for critical phenomena in connection with phase transitions" 1983 Subrahmanyan "for his theoretical studies of the physical processes of Chandrasekhar importance to the structure and evolution of the stars" 532 William Alfred Fowler "for his theoretical and experimental studies of the nuclear reactions of importance in the formation of the chemical elements in the universe" 1984 Carlo Rubbia "for their decisive contributions to the large project, which led to the discovery of the field particles W and Z, Simon van der Meer communicators of weak interaction" 1985 Klaus von Klitzing "for the discovery of the quantized Hall effect" 1986 Ernst Ruska "for his fundamental work in electron optics, and for the design of the first electron microscope" Gerd Binnig "for their design of the scanning tunneling microscope" Heinrich Rohrer 1987 Johannes Georg "for their important break-through in the discovery Bednorz of superconductivity in ceramic materials" Karl Alexander Müller 1988 Leon Max Lederman "for the neutrino beam method and the demonstration of the doublet structure of the leptons through the Melvin Schwartz discovery of the muon neutrino" Jack Steinberger 1989 Norman Foster Ramsey "for the invention of the separated oscillatory fields method and its use in the hydrogen maser and 533 other atomic clocks" Hans Georg Dehmelt "for the development of the ion trap technique" Wolfgang Paul 1990 Jerome I. Friedman "for their pioneering investigations concerning deep inelastic scattering of electrons on protons and bound Henry Way Kendall neutrons, which have been of essential importance for the development of the quark model in particle physics" Richard E. Taylor 1991 Pierre-Gilles de Gennes "for discovering that methods developed for studying order phenomena in simple systems can be generalized to more complex forms of matter, in particular to liquid crystals and polymers" 1992 Georges Charpak "for his invention and development of particle detectors, in particular the multiwire proportional chamber" 1993 Russell Alan Hulse "for the discovery of a new type of pulsar, a discovery that has opened up new possibilities for the study of gravitation" Joseph Hooton Taylor Jr. 1994 Bertram Brockhouse "for the development of neutron spectroscopy" and "for pioneering contributions to the development of neutron scattering techniques for studies of condensed matter" Clifford Glenwood "for the development of the neutron diffraction technique" and "for pioneering contributions 534 Shull to the development of neutron scattering techniques for studies of condensed matter" 1995 Martin Lewis Perl "for the discovery of the tau lepton" and "for pioneering experimental contributions to lepton physics" Frederick Reines "for the detection of the neutrino" and "for pioneering experimental contributions to lepton physics" 1996 David Morris Lee "for their discovery of superfluidity in helium-3" Douglas D. Osheroff Robert Coleman Richardson 1997 Steven Chu "for development of methods to cool and trap atoms with laser light." Claude CohenTannoudji William Daniel Phillips 1998 Robert B. Laughlin "for their discovery of a new form of quantum fluid with fractionally charged excitations" Horst Ludwig Störmer Daniel Chee Tsui 1999 Gerard 't Hooft "for elucidating the quantum structure of electroweak 535 interactions in physics" Martinus J. G. Veltman 2000 Zhores Ivanovich "for developing semiconductor heterostructures used in Alferov high-speed- and optoelectronics" Herbert Kroemer 2001 Jack St. Clair Kilby "for his part in the invention of the integrated circuit" Eric Allin Cornell "for the achievement of Bose–Einstein condensation in dilute gases of alkali atoms, and for early fundamental Carl Edwin Wieman studies of the properties of the condensates" Wolfgang Ketterle 2002 Raymond Davis Jr. "for pioneering contributions to astrophysics, in particular for the detection of cosmic neutrinos" Masatoshi Koshiba Riccardo Giacconi "for pioneering contributions to astrophysics, which have led to the discovery of cosmic X-ray sources" 2003 Alexei Alexeyevich "for pioneering contributions to the theory Abrikosov of superconductors and superfluids" Vitaly Lazarevich Ginzburg Anthony James 536 Leggett 2004 David J. Gross "for the discovery of asymptotic freedom in the theory of the strong interaction" Hugh David Politzer Frank Wilczek 2005 Roy J. Glauber "for his contribution to the quantum theory of optical coherence" John L. Hall "for their contributions to the development of laserbased precision spectroscopy, including the optical frequency comb technique" Theodor W. Hänsch 2006 John C. Mather "for their discovery of the blackbody form and anisotropy of the cosmic microwave background radiation" George F. Smoot 2007 Albert Fert "for the discovery of giant magnetoresistance" Peter Grünberg 2008 Makoto Kobayashi "for the discovery of the origin of the broken symmetry which predicts the existence of at least three families of quarks in nature" Toshihide Maskawa Yoichiro Nambu "for the discovery of the mechanism of spontaneous broken symmetry in subatomic physics" 537 2009 Charles K. Kao "for groundbreaking achievements concerning the transmission of light in fibers for optical communication" Willard S. Boyle "for the invention of an imaging semiconductor circuit – the CCD sensor" George E. Smith 2010 Andre Geim "for groundbreaking experiments regarding the twodimensional material graphene" Konstantin Novoselov 2011 Saul Perlmutter "for the discovery of the accelerating expansion of the Universe through observations of distant supernovae" Brian P. Schmidt Adam G. Riess 2012 Serge Haroche "for ground-breaking experimental methods that enable measuring and manipulation of individual quantum systems." David J. Wineland 2013 François Englert "for the theoretical discovery of a mechanism that contributes to our understanding of the origin of mass Peter Higgs of subatomic particles, and which recently was confirmed through the discovery of the predicted fundamental particle, by the ATLAS and CMS experiments at CERN's Large Hadron Collider" 538 2014 Isamu Akasaki "for the invention of efficient blue light-emitting diodes which has enabled bright and energy-saving white light sources" Hiroshi Amano Shuji Nakamura 2015 Takaaki Kajita "for the discovery of neutrino oscillations, which shows that neutrinos have mass" Arthur B. McDonald 2016 David J. Thouless "for theoretical discoveries of topological phase transitions and topological phases of matter" F. Duncan M. Haldane John M. Kosterlitz 2017 Rainer Weiss "for decisive contributions to the LIGO detector and the observation of gravitational waves" Kip Thorne Barry Barish 2018 Arthur Ashkin "for groundbreaking inventions in the field of laser physics", in particular "for the optical tweezers and their application to biological systems" Gérard Mourou "for groundbreaking inventions in the field of laser physics", in particular "for their method of generating Donna Strickland high-intensity, ultra-short optical pulses" 539 2019 James Peebles "for theoretical discoveries in physical cosmology" Michel Mayor "for the discovery of an exoplanet orbiting a solar-type star" Didier Queloz 2020 Roger Penrose "for the discovery that black hole formation is a robust prediction of the general theory of relativity" Reinhard Genzel "for the discovery of a supermassive compact object at the centre of our galaxy" Andrea Ghez Each rubber molecule is made of 65,000 individual atoms. Around a million, billion neutrinos from the Sun will pass through our body every day. Quasars are the most distant objects in the Universe which emit more energy than 100 giant galaxies. 540 List of Nobel laureates in Chemistry Jacobus Henricus van 't "[for his] discovery of the laws of chemical Hoff dynamics and osmotic pressure in solutions" 1902 Hermann Emil Fischer "[for] his work on sugar and purine syntheses" 1903 Svante August Arrhenius "[for] his electrolytic theory of dissociation" 1904 Sir William Ramsay "[for his] discovery of the inert gaseous elements in 1901 air, and his determination of their place in the periodic system" 1905 Adolf von Baeyer "[for] the advancement of organic chemistry and the chemical industry, through his work on organic dyes and hydroaromatic compounds" 1906 Henri Moissan "[for his] investigation and isolation of the element fluorine, and for [the] electric furnace called after him" 1907 Eduard Buchner "for his biochemical researches and his discovery of cell-free fermentation" 1908 Ernest Rutherford "for his investigations into the disintegration of the elements, and the chemistry of radioactive substances" 1909 Wilhelm Ostwald "[for] his work on catalysis and for his investigations into the fundamental principles 541 governing chemical equilibria and rates of reaction" 1910 Otto Wallach "[for] his services to organic chemistry and the chemical industry by his pioneer work in the field of alicyclic compounds" 1911 Maria Skłodowska-Curie "[for] the discovery of the elements radium and polonium, by the isolation of radium and the study of the nature and compounds of this remarkable element" 1912 Victor Grignard "for the discovery of the [...] Grignard reagent" Paul Sabatier "for his method of hydrogenating organic compounds in the presence of finely disintegrated metals" 1913 Alfred Werner "[for] his work on the linkage of atoms in molecules [...] especially in inorganic chemistry" 1914 1915 Theodore William "[for] his accurate determinations of the atomic Richards weight of a large number of chemical elements" Richard Martin "for his researches on plant pigments, Willstätter especially chlorophyll" 1916 Not awarded 1917 542 1918 Fritz Haber "for the synthesis of ammonia from its elements" Not awarded 1919 1920 Walther Hermann Nernst "[for] his work in thermochemistry" 1921 Frederick Soddy "for his contributions to our knowledge of the chemistry of radioactive substances, and his investigations into the origin and nature of isotopes" 1922 Francis William Aston "for his discovery, by means of his mass spectrograph, of isotopes, in a large number of non-radioactive elements, and for his enunciation of the whole-number rule" 1923 Fritz Pregl "for his invention of the method of microanalysis of organic substances" Not awarded 1924 1925 Richard Adolf Zsigmondy "for his demonstration of the heterogeneous nature of colloid solutions and for the methods he used" 1926 The (Theodor) Svedberg "for his work on disperse systems" 1927 Heinrich Otto Wieland "for his investigations of the constitution of the bile acids and related substances" 543 1928 1929 Adolf Otto Reinhold "[for] his research into the constitution of Windaus the sterols and their connection with the vitamins" Arthur Harden "for their investigations on the fermentation of sugar and fermentative enzymes" Hans Karl August Simon von Euler-Chelpin 1930 Hans Fischer "for his researches into the constitution of haemin and chlorophyll and especially for his synthesis of haemin" 1931 Carl Bosch "[for] their contributions to the invention and development of chemical high pressure methods" Friedrich Bergius 1932 Irving Langmuir "for his discoveries and investigations in surface chemistry" Not awarded 1933 1934 Harold Clayton Urey "for his discovery of heavy hydrogen" 1935 Frédéric Joliot "[for] their synthesis of new radioactive elements" Irène Joliot-Curie 1936 Peter Debye "[for his work on] molecular structure through his investigations on dipole moments and 544 the diffraction of X-rays and electrons in gases" 1937 Walter Norman Haworth "for his investigations on carbohydrates and vitamin C" Paul Karrer "for his investigations on carotenoids, flavins and vitamins A and B2" 1938 Richard Kuhn "for his work on carotenoids and vitamins" 1939 Adolf Friedrich Johann "for his work on sex hormones" Butenandt Leopold Ruzicka "for his work on polymethylenes and higher terpenes" 1940 Not awarded 1941 1942 1943 George de Hevesy "for his work on the use of isotopes as tracers in the study of chemical processes" 1944 Otto Hahn "for his discovery of the fission of heavy nuclei" 1945 Artturi Ilmari Virtanen "for his research and inventions in agricultural and nutrition chemistry, especially for his fodder 545 preservation method" 1946 James Batcheller "for his discovery that enzymes can be Sumner crystallized" John Howard Northrop "for their preparation of enzymes and virus proteins in a pure form" Wendell Meredith Stanley 1947 Sir Robert Robinson "for his investigations on plant products of biological importance, especially the alkaloids" 1948 Arne Wilhelm Kaurin "for his research on electrophoresis and Tiselius adsorption analysis, especially for his discoveries concerning the complex nature of the serum proteins" 1949 William Francis Giauque "for his contributions in the field of chemical thermodynamics, particularly concerning the behaviour of substances at extremely low temperatures" 1950 Otto Paul Hermann Diels "for their discovery and development of the diene synthesis" Kurt Alder 1951 Edwin Mattison "for their discoveries in the chemistry McMillan of transuranium elements" 546 Glenn Theodore Seaborg 1952 Archer John Porter "for their invention of partition chromatography" Martin Richard Laurence Millington Synge 1953 Hermann Staudinger "for his discoveries in the field of macromolecular chemistry" 1954 Linus Pauling "for his research into the nature of the chemical bond and its application to the elucidation of the structure of complex substances" 1955 Vincent du Vigneaud "for his work on biochemically important sulphur compounds, especially for the first synthesis of a polypeptide hormone" 1956 Sir Cyril Norman "for their researches into the mechanism of Hinshelwood chemical reactions" Nikolay Nikolaevich Semenov 1957 Lord (Alexander R.) Todd "for his work on nucleotides and nucleotide coenzymes" 1958 Frederick Sanger "for his work on the structure of proteins, 547 especially that of insulin" 1959 Jaroslav Heyrovský "for his discovery and development of the polarographic methods of analysis" 1960 Willard Frank Libby "for his method to use carbon-14 for age determination in archaeology, geology, geophysics, and other branches of science" 1961 Melvin Calvin "for his research on the carbon dioxide assimilation in plants" 1962 Max Ferdinand Perutz "for their studies of the structures of globular proteins" John Cowdery Kendrew 1963 Karl Ziegler "for their discoveries in the field of the chemistry and technology of high polymers" Giulio Natta 1964 1965 Dorothy Crowfoot "for her determinations by X-ray techniques of the Hodgkin structures of important biochemical substances" Robert Burns Woodward "for his outstanding achievements in the art of organic synthesis" 1966 Robert S. Mulliken "for his fundamental work concerning chemical bonds and the electronic structure of molecules by the molecular orbital method" 548 1967 Manfred Eigen "for their studies of extremely fast chemical reactions, effected by disturbing the equilibrium Ronald George Wreyford by means of very short pulses of energy" Norrish George Porter 1968 Lars Onsager "for the discovery of the reciprocal relations bearing his name, which are fundamental for the thermodynamics of irreversible processes" 1969 Derek H. R. Barton "for their contributions to the development of the concept of conformation and its application in 1970 Odd Hassel chemistry" Luis F. Leloir "for his discovery of sugar nucleotides and their role in the biosynthesis of carbohydrates" 1971 Gerhard Herzberg "for his contributions to the knowledge of electronic structure and geometry of molecules, particularly free radicals" 1972 Christian B. Anfinsen "for his work on ribonuclease, especially concerning the connection between the amino acid sequence and the biologically active conformation" Stanford Moore "for their contribution to the understanding of the 549 connection between chemical structure and William H. Stein catalytic activity of the active centre of the ribonuclease molecule" 1973 Ernst Otto Fischer "for their pioneering work, performed independently, on the chemistry of Geoffrey Wilkinson the organometallic, so called sandwich compounds" 1974 Paul J. Flory "for his fundamental work, both theoretical and experimental, in the physical chemistry of macromolecules" 1975 John Warcup Cornforth "for his work on the stereochemistry of enzymecatalyzed reactions" Vladimir Prelog "for his research into the stereochemistry of organic molecules and reactions" 1976 William N. Lipscomb "for his studies on the structure of boranes illuminating problems of chemical bonding" 1977 Ilya Prigogine "for his contributions to non-equilibrium thermodynamics, particularly the theory of dissipative structures" 1978 Peter D. Mitchell "for his contribution to the understanding of biological energy transfer through the formulation of the chemiosmotic theory" 550 1979 Herbert C. Brown "for their development of the use of boron- and phosphorus-containing compounds, respectively, 1980 Georg Wittig into important reagents in organic synthesis" Paul Berg "for his fundamental studies of the biochemistry of nucleic acids, with particular regard to recombinant-DNA" Walter Gilbert "for their contributions concerning the determination of base sequences in nucleic 1981 Frederick Sanger acids" Kenichi Fukui "for their theories, developed independently, concerning the course of chemical reactions" Roald Hoffmann 1982 Aaron Klug "for his development of crystallographic electron microscopy and his structural elucidation of biologically important nucleic acid-protein complexes" 1983 Henry Taube "for his work on the mechanisms of electron transfer reactions, especially in metal complexes" 1984 Robert Bruce Merrifield "for his development of methodology for chemical synthesis on a solid matrix" 1985 Herbert A. Hauptman "for their outstanding achievements in 551 developing direct methods for the determination of Jerome Karle 1986 Dudley R. Herschbach crystal structures" "for their contributions concerning the dynamics of chemical elementary processes" Yuan T. Lee John C. Polanyi 1987 Donald J. Cram "for their development and use of molecules with structure-specific interactions of high selectivity" Jean-Marie Lehn Charles J. Pedersen 1988 Johann Deisenhofer "for their determination of the three-dimensional structure of a photosynthetic reaction centre" Robert Huber Hartmut Michel 1989 Sidney Altman "for their discovery of catalytic properties of RNA" Thomas Cech 1990 Elias James Corey "for his development of the theory and methodology of organic synthesis" 1991 Richard R. Ernst "for his contributions to the development of the 552 methodology of high resolution nuclear magnetic resonance (NMR) spectroscopy" 1992 Rudolph A. Marcus "for his contributions to the theory of electron transfer reactions in chemical systems" 1993 Kary B. Mullis "for contributions to the developments of methods within DNA-based chemistry [...] for his invention of the polymerase chain reaction (PCR) method" Michael Smith "for contributions to the developments of methods within DNA-based chemistry [...] for his fundamental contributions to the establishment of oligonucleotide-based, site-directed mutagenesis and its development for protein studies" 1994 George A. Olah "for his contribution to carbocation chemistry" 1995 Paul J. Crutzen "for their work in atmospheric chemistry, particularly concerning the formation and decomposition of ozone" Mario J. Molina F. Sherwood Rowland 1996 Robert F. Curl Jr. "for their discovery of fullerenes" Sir Harold W. Kroto Richard E. Smalley 553 1997 Paul D. Boyer "for their elucidation of the enzymatic mechanism underlying the synthesis of adenosine John E. Walker triphosphate (ATP)" Jens C. Skou "for the first discovery of an ion-transporting enzyme, Na+, K+ -ATPase" 1998 Walter Kohn "for his development of the density-functional theory" John A. Pople "for his development of computational methods in quantum chemistry" 1999 Ahmed Zewail "for his studies of the transition states of chemical reactions using femtosecond spectroscopy" 2000 Alan J. Heeger "for their discovery and development of conductive polymers" Alan G. MacDiarmid Hideki Shirakawa 2001 William S. Knowles "for their work on chirally catalysed hydrogenation reactions" Ryōji Noyori K. Barry Sharpless "for his work on chirally catalysed oxidation reactions" 554 2002 John B. Fenn "for the development of methods for identification and structure analyses of biological Koichi Tanaka macromolecules [...] for their development of soft desorption ionisation methods for mass spectrometric analyses of biological macromolecules" Kurt Wüthrich "for the development of methods for identification and structure analyses of biological macromolecules [...] for his development of nuclear magnetic resonance spectroscopy for determining the three-dimensional structure of biological macromolecules in solution" 2003 Peter Agre "for discoveries concerning channels in cell membranes [...] for the discovery of water channels" Roderick MacKinnon "for discoveries concerning channels in cell membranes [...] for structural and mechanistic studies of ion channels" 2004 Aaron Ciechanover "for the discovery of ubiquitin-mediated protein degradation" Avram Hershko Irwin Rose 2005 Yves Chauvin "for the development of the metathesis method in 555 organic synthesis" Robert H. Grubbs Richard R. Schrock 2006 Roger D. Kornberg "for his studies of the molecular basis of eukaryotic transcription" 2007 Gerhard Ertl "for his studies of chemical processes on solid surfaces" 2008 Osamu Shimomura "for the discovery and development of the green fluorescent protein, GFP" Martin Chalfie Roger Y. Tsien 2009 Venkatraman "for studies of the structure and function of Ramakrishnan the ribosome" Thomas A. Steitz Ada E. Yonath 2010 Richard F. Heck "for palladium-catalyzed cross couplings in organic synthesis" Ei-ichi Negishi Akira Suzuki 556 2011 Dan Shechtman "for the discovery of quasicrystals" 2012 Robert Lefkowitz "for studies of G-protein-coupled receptors" Brian Kobilka 2013 Martin Karplus "for the development of multiscale models for complex chemical systems" Michael Levitt Arieh Warshel 2014 Eric Betzig "for the development of super-resolved fluorescence microscopy" Stefan W. Hell William E. Moerner 2015 Tomas Lindahl "for mechanistic studies of DNA repair" Paul L. Modrich Aziz Sancar 2016 Jean-Pierre Sauvage "for the design and synthesis of molecular machines" Fraser Stoddart 557 Ben Feringa 2017 Jacques Dubochet "for developing cryo-electron microscopy for the high-resolution structure determination of biomolecules in solution" Joachim Frank Richard Henderson 2018 Frances Arnold "for the directed evolution of enzymes" George Smith "for the phage display of peptides and antibodies" Sir Gregory Winter 2019 John B. Goodenough "for the development of lithium ion batteries" M. Stanley Whittingham Akira Yoshino 2020 Emmanuelle Charpentier "for the development of a method for genome editing" Jennifer Doudna Light would take 0.13 seconds to travel around the Earth. To escape the Earth's gravity a rocket need to travel at 7 miles a second. 558 No one shall expel us from the paradise which Cantor has created for us. {Expressing the importance of Georg Cantor's set theory in the development of mathematics.} ― David Hilbert The largest dinosaur ever discovered was Seismosaurus which was over 100 feet long and weighed up to 80 tones. The risk of being struck by a falling meteorite for a human is one occurrence every 9,300 years. 559 List of Nobel laureates in Physiology or Medicine 1901 Emil Adolf von Behring "for his work on serum therapy, especially its application against diphtheria, by which he has opened a new road in the domain of medical science and thereby placed in the hands of the physician a victorious weapon against illness and deaths" 1902 Sir Ronald Ross "for his work on malaria, by which he has shown how it enters the organism and thereby has laid the foundation for successful research on this disease and methods of combating it" 1903 Niels Ryberg Finsen "[for] his contribution to the treatment of diseases, especially lupus vulgaris, with concentrated light radiation, whereby he has opened a new avenue for medical science" 1904 Ivan Petrovich Pavlov "in recognition of his work on the physiology of digestion, through which knowledge on vital aspects of the subject has been transformed and enlarged" 1905 Robert Koch "for his investigations and discoveries in relation to tuberculosis" 1906 Camillo Golgi "in recognition of their work on the structure of the nervous system" Santiago Ramón y Cajal 1907 Charles Louis Alphonse "in recognition of his work on the role played 560 1908 Laveran by protozoa in causing diseases" Ilya Ilyich Mechnikov "in recognition of their work on immunity" Paul Ehrlich 1909 Emil Theodor Kocher "for his work on the physiology, pathology and surgery of the thyroid gland" 1910 Albrecht Kossel "in recognition of the contributions to our knowledge of cell chemistry made through his work on proteins, including the nucleic substances" 1911 Allvar Gullstrand "for his work on the dioptrics of the eye" 1912 Alexis Carrel "[for] his work on vascular suture and the transplantation of blood vessels and organs" 1913 Charles Richet "[for] his work on anaphylaxis" 1914 Robert Bárány "for his work on the physiology and pathology of the vestibular apparatus" 1915 1916 Not awarded 1917 1918 561 1919 Jules Bordet "for his discoveries relating to immunity" 1920 Schack August "for his discovery of the capillary motor regulating Steenberg Krogh mechanism" Not awarded 1921 1922 Archibald Vivian Hill "for his discovery relating to the production of heat in the muscle" Otto Fritz Meyerhof "for his discovery of the fixed relationship between the consumption of oxygen and the metabolism of lactic acid in the muscle" 1923 Sir Frederick Grant "for the discovery of insulin" Banting John James Rickard Macleod 1924 Willem Einthoven "for the discovery of the mechanism of the electrocardiogram" Not awarded 1925 1926 Johannes Andreas Grib "for his discovery of the Spiroptera carcinoma" Fibiger 1927 Julius Wagner-Jauregg "for his discovery of the therapeutic value of malaria inoculation in the treatment of dementia paralytica" 562 1928 Charles Jules Henri "for his work on typhus" Nicolle 1929 Christiaan Eijkman "for his discovery of the antineuritic vitamin" Sir Frederick Gowland "for his discovery of the growth-stimulating vitamins" Hopkins 1930 Karl Landsteiner "for his discovery of human blood groups" 1931 Otto Heinrich Warburg "for his discovery of the nature and mode of action of the respiratory enzyme" 1932 Sir Charles Scott "for their discoveries regarding the functions Sherrington of neurons" Edgar Douglas Adrian 1933 Thomas Hunt Morgan "for his discoveries concerning the role played by the chromosome in heredity" 1934 George Hoyt Whipple "for their discoveries concerning liver therapy in cases of anaemia" George Richards Minot William Parry Murphy 1935 Hans Spemann "for his discovery of the organizer effect in embryonic development" 563 1936 Sir Henry Hallett Dale "for their discoveries relating to chemical transmission of nerve impulses" Otto Loewi 1937 Albert Szent-Györgyi von "for his discoveries in connection with the biological Nagyrapolt combustion processes, with special reference to vitamin C and the catalysis of fumaric acid" 1938 Corneille Jean François "for the discovery of the role played by Heymans the sinus and aortic mechanisms in the regulation of respiration" 1939 Gerhard Domagk "for the discovery of the antibacterial effects of prontosil" 1940 Not awarded 1941 1942 1943 1944 Carl Peter Henrik Dam "for his discovery of vitamin K" Edward Adelbert Doisy "for his discovery of the chemical nature of vitamin K" Joseph Erlanger "for their discoveries relating to the highly differentiated functions of single nerve fibres" Herbert Spencer Gasser 1945 Sir Alexander Fleming "for the discovery of penicillin and its curative effect in 564 various infectious diseases" Sir Ernst Boris Chain Howard Walter Florey 1946 Hermann Joseph Muller "for the discovery of the production of mutations by means of X-ray irradiation" 1947 Carl Ferdinand Cori "for their discovery of the course of the catalytic conversion of glycogen" Gerty Theresa Cori, née Radnitz 1948 Bernardo Alberto "for his discovery of the part played by the hormone of Houssay the anterior pituitary lobe in the metabolism of sugar" Paul Hermann Müller "for his discovery of the high efficiency of DDT as a contact poison against several arthropods" 1949 Walter Rudolf Hess "for his discovery of the functional organization of the interbrain as a coordinator of the activities of the internal organs" 1950 António Caetano Egas "for his discovery of the therapeutic value of leucotomy Moniz (lobotomy) in certain psychoses" Philip Showalter Hench "for their discoveries relating to the hormones of the adrenal cortex, their structure and biological effects" Edward Calvin Kendall Tadeusz Reichstein 565 1951 Max Theiler "for his discoveries concerning yellow fever and how to combat it" 1952 1953 Selman Abraham "for his discovery of streptomycin, the Waksman first antibiotic effective against tuberculosis" Sir Hans Adolf Krebs "for his discovery of the citric acid cycle" Fritz Albert Lipmann "for his discovery of co-enzyme A and its importance for intermediary metabolism" 1954 John Franklin Enders "for their discovery of the ability of poliomyelitis viruses to grow in cultures of various types of tissue" Frederick Chapman Robbins Thomas Huckle Weller 1955 1956 Axel Hugo Theodor "for his discoveries concerning the nature and mode of Theorell action of oxidation enzymes" André Frédéric "for their discoveries concerning heart Cournand catheterization and pathological changes in the circulatory system" Werner Forssmann Dickinson W. Richards 1957 Daniel Bovet "for his discoveries relating to synthetic compounds that inhibit the action of certain body substances, and 566 especially their action on the vascular system and the skeletal muscles" 1958 George Wells Beadle "for their discovery that genes act by regulating definite chemical events" Edward Lawrie Tatum Joshua Lederberg "for his discoveries concerning genetic recombination and the organization of the genetic material of bacteria" 1959 Arthur Kornberg "for their discovery of the mechanisms in the biological synthesis of ribonucleic acid and deoxyribonucleic acid" Severo Ochoa 1960 Sir Frank Macfarlane "for discovery of acquired immunological tolerance" Burnet Sir Peter Brian Medawar 1961 Georg von Békésy "for his discoveries of the physical mechanism of stimulation within the cochlea" 1962 Francis Harry Compton "for their discoveries concerning the molecular Crick structure of nucleic acids and its significance for information transfer in living material" James Dewey Watson Maurice Hugh Frederick Wilkins 567 1963 Sir John Carew Eccles "for their discoveries concerning the ionic mechanisms involved in excitation and inhibition in the peripheral Sir Alan Lloyd Hodgkin and central portions of the nerve cell membrane" Sir Andrew Fielding Huxley 1964 Konrad Bloch "for their discoveries concerning the mechanism and regulation of the cholesterol and fatty acid metabolism" Feodor Lynen 1965 François Jacob "for their discoveries concerning genetic control of enzyme and virus synthesis" André Lwoff Jacques Monod 1966 Peyton Rous "for his discovery of tumour-inducing viruses" Charles Brenton Huggins "for his discoveries concerning hormonal treatment of prostatic cancer" 1967 Ragnar Granit "for their discoveries concerning the primary physiological and chemical visual processes in the eye" Haldan Keffer Hartline George Wald 1968 Robert W. Holley "for their interpretation of the genetic code and its 568 function in protein synthesis" Har Gobind Khorana Marshall W. Nirenberg 1969 Max Delbrück "for their discoveries concerning the replication mechanism and the genetic structure of viruses" Alfred D. Hershey Salvador E. Luria 1970 Julius Axelrod "for their discoveries concerning the humoral transmittors in the nerve terminals and the Ulf von Euler mechanism for their storage, release and inactivation" Sir Bernard Katz 1971 Earl W. Sutherland, Jr. "for his discoveries concerning the mechanisms of the action of hormones" 1972 Gerald M. Edelman "for their discoveries concerning the chemical structure of antibodies" Rodney R. Porter 1973 Karl von Frisch "for their discoveries concerning organization and elicitation of individual and social behavior patterns" Konrad Lorenz Nikolaas Tinbergen 569 1974 Albert Claude "for their discoveries concerning the structural and functional organization of the cell" Christian de Duve George E. Palade 1975 David Baltimore "for their discoveries concerning the interaction between tumour viruses and the genetic material of the cell" Renato Dulbecco Howard Martin Temin 1976 Baruch S. Blumberg "for their discoveries concerning new mechanisms for the origin and dissemination of infectious diseases" D. Carleton Gajdusek 1977 Roger Guillemin "for their discoveries concerning the peptide hormone production of the brain" Andrew V. Schally Rosalyn Yalow "for the development of radioimmunoassays of peptide hormones" 1978 Werner Arber "for the discovery of restriction enzymes and their application to problems of molecular genetics" Daniel Nathans Hamilton O. Smith 570 1979 Allan M. Cormack "for the development of computer assisted tomography" Sir Godfrey N. Hounsfield 1980 Baruj Benacerraf "for their discoveries concerning genetically determined structures on the cell surface that Jean Dausset regulate immunological reactions" George D. Snell 1981 Roger W. Sperry "for his discoveries concerning the functional specialization of the cerebral hemispheres" David H. Hubel "for their discoveries concerning information processing in the visual system" Torsten N. Wiesel 1982 Sune K. Bergström "for their discoveries concerning prostaglandins and related biologically active substances" Bengt I. Samuelsson Sir John R. Vane 1983 Barbara McClintock "for her discovery of mobile genetic elements" 1984 Niels K. Jerne "for theories concerning the specificity in development and control of the immune system and the discovery of Georges J.F. Köhler the principle for production of monoclonal antibodies" 571 César Milstein 1985 Michael S. Brown "for their discoveries concerning the regulation of cholesterol metabolism" Joseph L. Goldstein 1986 Stanley Cohen "for their discoveries of growth factors" Rita Levi-Montalcini 1987 Susumu Tonegawa "for his discovery of the genetic principle for generation of antibody diversity" 1988 Sir James W. Black "for their discoveries of important principles for drug treatment" Gertrude B. Elion George H. Hitchings 1989 J. Michael Bishop "for their discovery of the cellular origin of retroviral oncogenes" Harold E. Varmus 1990 Joseph E. Murray "for their discoveries concerning organ and cell transplantation in the treatment of human disease" E. Donnall Thomas 1991 Erwin Neher "for their discoveries concerning the function of 572 single ion channels in cells" Bert Sakmann 1992 Edmond H. Fischer "for their discoveries concerning reversible protein phosphorylation as a biological regulatory mechanism" Edwin G. Krebs 1993 Sir Richard J. Roberts "for their discoveries of split genes" Phillip A. Sharp 1994 Alfred G. Gilman "for their discovery of G-proteins and the role of these proteins in signal transduction in cells" Martin Rodbell 1995 Edward B. Lewis "for their discoveries concerning the genetic control of early embryonic development" Christiane NüssleinVolhard Eric F. Wieschaus 1996 Peter C. Doherty "for their discoveries concerning the specificity of the cell mediated immune defence" Rolf M. Zinkernagel 1997 Stanley B. Prusiner "for his discovery of Prions - a new biological principle of infection" 1998 Robert F. Furchgott "for their discoveries concerning nitric oxide as a 573 signaling molecule in the cardiovascular system" Louis J. Ignarro Ferid Murad 1999 Günter Blobel "for the discovery that proteins have intrinsic signals that govern their transport and localization in the cell" 2000 Arvid Carlsson "for their discoveries concerning signal transduction in the nervous system" Paul Greengard Eric R. Kandel 2001 Leland H. Hartwell "for their discoveries of key regulators of the cell cycle" Sir Tim Hunt Sir Paul M. Nurse 2002 Sydney Brenner "for their discoveries concerning 'genetic regulation of organ development and programmed cell death'" H. Robert Horvitz Sir John E. Sulston 2003 Paul Lauterbur "for their discoveries concerning magnetic resonance imaging" Sir Peter Mansfield 574 2004 Richard Axel "for their discoveries of odorant receptors and the organization of the olfactory system" Linda B. Buck 2005 Barry J. Marshall "for their discovery of the bacterium Helicobacter pylori and its role in gastritis and peptic ulcer disease" J. Robin Warren 2006 Andrew Z. Fire "for their discovery of RNA interference - gene silencing by double-stranded RNA" Craig C. Mello 2007 Mario R. Capecchi "for their discoveries of principles for introducing specific gene modifications in mice by the use of embryonic stem cells." Sir Martin J. Evans Oliver Smithies 2008 Harald zur Hausen "for his discovery of human papilloma viruses causing cervical cancer" Françoise Barré-Sinoussi "for their discovery of human immunodeficiency virus" Luc Montagnier 2009 Elizabeth H. Blackburn "for the discovery of how chromosomes are protected by telomeres and the enzyme telomerase" Carol W. Greider 575 Jack W. Szostak 2010 Sir Robert G. Edwards "for the development of in vitro fertilization" 2011 Bruce A. Beutler "for their discoveries concerning the activation of innate immunity" Jules A. Hoffmann Ralph M. Steinman "for his discovery of the dendritic cell and its role in adaptive immunity" 2012 Sir John B. Gurdon "for the discovery that mature cells can be reprogrammed to become pluripotent" Shinya Yamanaka 2013 James E. Rothman "for their discoveries of machinery regulating vesicle traffic, a major transport system in our cells" Randy W. Schekman Thomas C. Südhof 2014 John O'Keefe "for their discoveries of cells that constitute a positioning system in the brain" May-Britt Moser Edvard I. Moser 2015 William C. Campbell "for their discoveries concerning a novel 576 Satoshi Ōmura Tu Youyou therapy against infections caused by roundworm parasites" "for her discoveries concerning a novel therapy against malaria" 2016 Yoshinori Ohsumi "for his discoveries of mechanisms for autophagy" 2017 Jeffrey C. Hall "for their discoveries of molecular mechanisms controlling the circadian rhythm" Michael Rosbash Michael W. Young 2018 James P. Allison "for their discovery of cancer therapy by inhibition of negative immune regulation" Tasuku Honjo 2019 William Kaelin Jr. "for their discoveries of how cells sense and adapt to oxygen availability" Peter J. Ratcliffe Gregg L. Semenza 2020 Harvey J. Alter "for the discovery of Hepatitis C virus" Michael Houghton Charles M. Rice 577 In Mathematics the art of proposing a question must be held of higher value than solving it. ― Georg Cantor A mathematical proof should resemble a simple and clear-cut constellation, not a scattered cluster in the Milky Way. ― G.H. Hardy 578 "{Replying to G. H. Hardy's suggestion that the number of a taxi (1729) was 'dull', showing off his spontaneous mathematical genius} No, it is a very interesting number; it is the smallest number expressible as a sum of two cubes in two different ways, the two ways being 13 + 123 and 93 + 103." — Srinivasa Ramanujan Source of Information:  https://www.wikipedia.org 579