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2018, Macroeconomic Theory and the Eurozone Crisis
Journal of Nanoscience and Technology
Analysis of Mechanical Parameters of Zinc Oxide Nanoparticles using Williamson–Hall MethodHerald of Khmelnytskyi National University. Technical sciences
SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF ZnO NANOPARTICLESIn the present work, zinc oxide (ZnO) nanoparticles were synthesized by direct precipitation method in aqueous solution using zinc acetate dihydrate and sodium hydroxide as precursors. The molar ratio of Zn2+ to OH– was 1:2. The obtained precipitated compound was treated at different temperatures. The crystal phase and structural parameters of each prepared ZnO samples such as interplanar spacing, crystallite size, dislocation density, micro strain were determined by X-ray diffraction (XRD) analysis for different crystallographic planes. Other crystallite parameters such as lattice constants, unit cell volume, Zn–O bond length, crystallinity of synthesized ZnO samples also were calculated from the XRD data. The XRD patterns show the successfully synthetized ZnO phase with wurtzite hexagonal structure and average crystallite sizes of 24.6 nm, 25.6 nm and 28.1 nm for the samples that dried at room temperature without heat treatment (S1), dried at 60°C without calcination (S2), dried a...
Solid State Sciences
X-ray analysis of ZnO nanoparticles by Williamson–Hall and size–strain plot methodsZnO nanoparticles (ZnO-NPs) were prepared by a sol–gel combustion method from a zinc acetate precursor and acetic acid. The ZnO-NPs were synthesized at calcination temperatures of 650 °C and 750 °C for 1 h. The synthesized ZnO-NPs were characterized by X-ray diffraction analysis (XRD) and TEM. The XRD results revealed that the sample product was crystalline with a hexagonal wurtzite phase. High-magnification transmission electron microscopy (TEM) showed single-crystal ZnO-NPs with nearly spherical shapes. The crystalline development in the ZnO-NPs was investigated by X-ray peak broadening. The Williamson–Hall (W–H) analysis and size–strain plot method were used to study the individual contributions of crystallite sizes and lattice strain on the peak broadening of the ZnO-NPs. The physical parameters such as strain, stress and energy density values were calculated more precisely for all the reflection peaks of XRD corresponding to the wurtzite hexagonal phase of ZnO lying in the range of 20°–100° from the modified form of the W–H plot assuming a uniform deformation model (UDM), uniform stress deformation model (USDM), uniform deformation energy density model (UDEDM) and by the size–strain plot method (SSP). The results obtained showed that the mean particle size of the ZnO-NPs estimated from the TEM, W–H analysis and the SSP method were highly intercorrelated.
a b s t r a c t ZnO nanoparticles (ZnO-NPs) were prepared by a solegel combustion method from a zinc acetate precursor and acetic acid. The ZnO-NPs were synthesized at calcination temperatures of 650 C and 750 C for 1 h. The synthesized ZnO-NPs were characterized by X-ray diffraction analysis (XRD) and TEM. The XRD results revealed that the sample product was crystalline with a hexagonal wurtzite phase. Highmagnification transmission electron microscopy (TEM) showed single-crystal ZnO-NPs with nearly spherical shapes. The crystalline development in the ZnO-NPs was investigated by X-ray peak broadening. The WilliamsoneHall (WeH) analysis and sizeestrain plot method were used to study the individual contributions of crystallite sizes and lattice strain on the peak broadening of the ZnO-NPs. The physical parameters such as strain, stress and energy density values were calculated more precisely for all the reflection peaks of XRD corresponding to the wurtzite hexagonal phase of ZnO lying in the range of 20e100 from the modified form of the WeH plot assuming a uniform deformation model (UDM), uniform stress deformation model (USDM), uniform deformation energy density model (UDEDM) and by the sizeestrain plot method (SSP). The results obtained showed that the mean particle size of the ZnONPs estimated from the TEM, WeH analysis and the SSP method were highly intercorrelated. 2010 Elsevier Masson SAS. All rights reserved.
Journal of Theoretical and Applied Physics
Estimation of lattice strain in ZnO nanoparticles: X-ray peak profile analysis2014 •
3RD INTERNATIONAL CONFERENCE ON CONDENSED MATTER AND APPLIED PHYSICS (ICC-2019)
Synthesis of zinc oxide nanoparticles2018 •
The paper introduces a cost effective method to develop zinc oxide nanoparticles using abundant non-toxic precursors and low energy process. In this paper, co-precipitation method with selected precursors was used for the first time to synthesize Zinc oxide nanoparticles without using any capping agent. The ZnO nanoparticles were characterized by X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM). By analyzing the results of XRD and SEM it was found that majority of ZnO nanoparticles pertain an average crystallite size of ~40 nm. These ZnO nanoparticles have potential commercial value in tailored product formulations to meet the specific demand of the consumer [1].
2010 •
Very prospective area of usage nanocomposite systems is paint industry, when addition of small amount of suitable nanoparticles leads to positive affecting a number of properties of modified materials. Option of suitable nanoparticles, their compatibility with final mediums, eventually suitable option of dispersing methods are important for application. For paint industry are very important nanoparticles, which positively influence several properties of paint film at once. As a sample of such material it is possible to state nanoparticle zinc oxide. Zinc oxide was prepared by precipitation method. Methods acoustic spectrometry, atomic force microscopy and transmission electron microscopy were used for evaluation of shape and size distribution of ZnO nanoparticles.
In this work, zinc oxide (ZnO) nanostructures were synthesized by using zinc chloride and sodium hydroxide as the precursors at different temperatures. The ZnO nanostructures obtained were characterized by X-ray diffraction (XRD), Scanning Electronic Microscopy (SEM), Energy Dispersive X ray Spectroscopy (EDAX).The ZnO powders have hexagonal wurtzite structure and nanometric-sized crystallites. The size of the particle increases as the reaction temperature is increased. An attempt has been made to find out the effect of temperature on the morphology as well as particle size and to optimize the value of temperature for stable smaller sized particles. Once the temperature is optimised effect of base concentration is studied.
Zinc oxide nanoparticle is the second most abundant metal oxide after iron and it is inexpensive, safe, and as well as it can be prepared easily. Physical and chemical behaviour of zinc oxide nanoparticle can be easily turned by changing the morphology by using different synthesis routes. Zinc is an indispensable inorganic element universally used in medicine, biology, and industry. Its daily intake in an adult is 8-15 mg/day, of which approximately 5-6 mg/day is lost through urine and sweat. The Zn Nanoparticles obtained from ZnO are less toxic and are showing good characteristics in UV and IR regions.
AL-Mukhatabat Journal issue 44/Octobre-Décembre
AL-MUKHATABAT JOURNAL / ISSUE 44, OCTOBER-DECEMBER 2022 EDITED BY HAMDI MLIKA2022 •
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