In this work we report a study of the magnetic behavior of ferrimagnetic oxide CoFe2O4 and ferrimagnetic oxide/ferromagnetic metal CoFe2O4/CoFe2 nanocomposites. The latter compound is a good system to study hard ferrimagnet/soft... more
In this work we report a study of the magnetic behavior of ferrimagnetic oxide CoFe2O4 and ferrimagnetic oxide/ferromagnetic metal CoFe2O4/CoFe2 nanocomposites. The latter compound is a good system to study hard ferrimagnet/soft ferromagnet exchange coupling. Two steps were used to synthesize the bimagnetic CoFe2O4/CoFe2 nanocomposites: (i) first preparation of CoFe2O4 nanoparticles using the a simple hydrothermal method and (ii) second reduction reaction of cobalt ferrite nanoparticles using activated charcoal in inert atmosphere and high temperature. The phase structures, particle sizes, morphology, and magnetic properties of CoFe2O4 nanoparticles have been investigated by X-Ray diffraction (XRD), Mossbauer spectroscopy (MS), transmission electron microscopy (TEM), and vibrating sample magnetometer (VSM) with applied field up to 3.0 kOe at room temperature and 50K. The mean diameter of CoFe2O4 particles is about 16 nm. Mossbauer spectra reveal two sites for Fe3+. One site is related to Fe in an octahedral coordination and the other one to the Fe3+ in a tetrahedral coordination, as expected for a spinel crystal structure of CoFe2O4. TEM measurements of nanocomposite show the formation of a thin shell of CoFe2 on the cobalt ferrite and indicate that the nanoparticles increase to about 100 nm. The magnetization of nanocomposite showed hysteresis loop that is characteristic of the exchange spring systems. A maximum energy product (BH)max of 1.22 MGOe was achieved at room temperature for CoFe2O4/CoFe2 nanocomposites, which is about 115% higher than the value obtained for CoFe2O4 precursor. The exchange-spring interaction and the enhancement of product (BH)max in nanocomposite CoFe2O4/CoFe2 have been discussed.
In this work we report a study of the magnetic behavior of ferrimagnetic oxide CoFe2O4 and ferrimagnetic oxide/ferromagnetic metal CoFe2O4/CoFe2 nanocomposites. The latter compound is a good system to study hard ferrimagnet/soft... more
In this work we report a study of the magnetic behavior of ferrimagnetic oxide CoFe2O4 and ferrimagnetic oxide/ferromagnetic metal CoFe2O4/CoFe2 nanocomposites. The latter compound is a good system to study hard ferrimagnet/soft ferromagnet exchange coupling. Two steps were used to synthesize the bimagnetic CoFe2O4/CoFe2 nanocomposites: (i) first preparation of CoFe2O4 nanoparticles using the a simple hydrothermal method and (ii) second reduction reaction of cobalt ferrite nanoparticles using activated charcoal in inert atmosphere and high temperature. The phase structures, particle sizes, morphology, and magnetic properties of CoFe2O4 nanoparticles have been investigated by X-Ray diffraction (XRD), Mossbauer spectroscopy (MS), transmission electron microscopy (TEM), and vibrating sample magnetometer (VSM) with applied field up to 3.0 kOe at room temperature and 50K. The mean diameter of CoFe2O4 particles is about 16 nm. Mossbauer spectra reveal two sites for Fe3+. One site is related to Fe in an octahedral coordination and the other one to the Fe3+ in a tetrahedral coordination, as expected for a spinel crystal structure of CoFe2O4. TEM measurements of nanocomposite show the formation of a thin shell of CoFe2 on the cobalt ferrite and indicate that the nanoparticles increase to about 100 nm. The magnetization of nanocomposite showed hysteresis loop that is characteristic of the exchange spring systems. A maximum energy product (BH)max of 1.22 MGOe was achieved at room temperature for CoFe2O4/CoFe2 nanocomposites, which is about 115% higher than the value obtained for CoFe2O4 precursor. The exchange-spring interaction and the enhancement of product (BH)max in nanocomposite CoFe2O4/CoFe2 have been discussed.
We have performed micromagnetic simulations to investigate the magnetic behavior of exchange spring grains for hard disk recording applications. The thickness ratio between magnetically hard and soft layers was varied while the soft layer... more
We have performed micromagnetic simulations to investigate the magnetic behavior of exchange spring grains for hard disk recording applications. The thickness ratio between magnetically hard and soft layers was varied while the soft layer anisotropy was altered to maintain a suitable energy barrier between opposite magnetization states. The minimum required magnetic field for switching a grain and the corresponding field angle were both significantly reduced in exchange spring material compared with single-phase grains. This could lead to reduced cross-track write errors in hard drive systems and assist the development of magnetic multilayer recording technologies.
Many modern technologies require permanent magnets with combinations of properties that cannot be met by conventional metallic or ceramic magnets. Ferrite/polymer composite magnets are a type of rare-earth free magnet with a wide range of... more
Many modern technologies require permanent magnets with combinations of properties that cannot be met by conventional metallic or ceramic magnets. Ferrite/polymer composite magnets are a type of rare-earth free magnet with a wide range of magnetic and material property combinations. The uncertainty surrounding the supply and pricing of rare-earth elements, along with environmental issues of using these elements, have motivated many researchers to develop high-performance ferrite-based magnets via an exchange spring method. The present study explores magnetite coated M-type ferrite nanocomposites synthesised via a hydrothermal and coprecipitation method, and investigates the mechanical and magnetic properties of warm compressed high-performance exchange-coupled nanocomposites in an epoxy matrix. We show how the powder-to-resin ratio and preparation conditions lead to optimised mechanical properties, and enhancement in the maximum energy product of the composite magnet by up to 120% compared to a commercial SrM bonded plasto-ferrite magnet. These high performance composite magnets can lower the final cost of ferrite based bonded magnets without reducing the permanent magnetic properties or can be used in applications that a ferrite magnet has inadequate performances.
FREE DOWNLOAD FOR 50 DAYS AT: https://authors.elsevier.com/c/1ZSaY3IWkbyVh3 Recent economic and environmental concerns have prompted intensive research on the development and optimisation of rare-earth free permanent magnets, in... more
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https://authors.elsevier.com/c/1ZSaY3IWkbyVh3 Recent economic and environmental concerns have prompted intensive research on the development and optimisation of rare-earth free permanent magnets, in particular of ferrites. M-type barium hexaferrites (BaFe12O19, BaM) are a type of technologically important, low-cost permanent magnet, with high Tc and high resistance to oxidation and corrosion. Their magnetic performance can be improved upon by exploring exchange-coupling mechanisms, to increase their competitiveness with existing rare-earth magnets. The present investigation explores core-shell-like BaM/Fe3O4 nanocomposites, where BaM flake-like particles where prepared via the sol-gel auto-combustion method, and then coated by magnetite spinel nanoparticles via a hydrothermal method, requiring no post-heat treatment. We show how optimised hard to soft magnetic phase ratio and preparation conditions lead to a significant enhancement to the saturation magnetization and remanence, and consequently to an increase of over 75% in the maximum energy product, compared to the parent BaM hexagonal ferrite compound.
A numerical model has been developed for simulating magnetic domain configurations, remanence, and viscosity curves in systems with strong perpendicular anisotropy and strong disorder, starting from internal switching field distributions... more
A numerical model has been developed for simulating magnetic domain configurations, remanence, and viscosity curves in systems with strong perpendicular anisotropy and strong disorder, starting from internal switching field distributions for pinning and nucleation processes in the slow dynamics regime. In the considered systems, the domains expand in a percolationlike manner and domain configuration displays fractal properties. The simulations show
