The earliest Svecofennian magmatism in southern Finland has been dated at 1.90-1.88Ga. As an example of this, the Orijärvi (ca. 1.89Ga) and Enklinge (ca. 1.88Ga) volcanic centres comprise bimodal plutonic batholiths surrounded by volcanic... more
The earliest Svecofennian magmatism in southern Finland has been dated at 1.90-1.88Ga. As an example of this, the Orijärvi (ca. 1.89Ga) and Enklinge (ca. 1.88Ga) volcanic centres comprise bimodal plutonic batholiths surrounded by volcanic rocks of comparable ages and chemical compositions. Here, we report geochemical and Sm-Nd isotope data from intrusive and extrusive samples, combined with zircon U-Pb and Lu-Hf isotopes for granodiorites from both study areas. The samples range from gabbros to granites and indicate a subduction-related continental margin setting. The zircons from the Orijärvi granodiorite define an age of 1892±4Ma whereas the Enklinge granodiorite yields an age of 1882±6Ma. Several inherited ages of 2.25-1.95Ga as well as younger ages of 1.86-1.80Ga were found in the Enklinge granodiorite. The initial εNd values from the mafic rocks from both locations fall in the range +1.1 to +2.9 whereas the felsic rocks exhibit initial εNd values of -0.4 to +1.2. The magmatic zircons from the Orijärvi and Enklinge granodiorites show average initial εHf values of -1.1 (at 1892Ma) and zero (at 1882Ma), respectively, each with a spread of about 7 ε-units. The initial εHf values for the inherited zircons from Enklinge range from +3.5 to +7.6 with increasing age. The Sm-Nd data indicate that the mafic rocks were derived from a “mildly depleted” mantle source while the felsic rocks show larger crustal contribution. Also, the variation in εHf values indicates minor mixing between mildly depleted mantle derived magmas and crustal sources. U-Pb ages and Hf isotopes for inherited zircons in the Enklinge granodiorite suggest the presence of juvenile Svecofennian “proto-crust” at depth.
The studied sulfide mineralizations of Atshan and Darhib areas are related to the south Eastern Desert shear zones. They are hosted in talc-and tremolite-talc-rich rocks and also in meta-basaltic dykes and quartz-veins. The principal... more
The studied sulfide mineralizations of Atshan and Darhib areas are related to the south Eastern Desert shear zones. They are hosted in talc-and tremolite-talc-rich rocks and also in meta-basaltic dykes and quartz-veins. The principal mineralization in Atshan includes sphalerite, pyrite, chalcopyrite, galena and pyrrhotite, whereas that in Darhib comprises chalcopyrite, sphalerite, pyrite, and galena with subordinate bornite and covellite. Darhib mineralization contains traces of altaite and electrum. Altaite has the highest Te concentrations suggesting crystallization under low fS 2 and/or high fTe 2 conditions, probably due to S budget consumption from the hydrothermal fluids in the late stage of deposition. Electrum has the highest Au contents with gold fineness value falling within the range of epithermal Au-Ag deposits. The dominance of recrystallized and replacement textures in the studied mineralizations suggests a secondary or post-depositional metamorphic overprint. The significant Cd contents in sphalerite from remobilized massive mineralizations hosted in tremolite-talc-rich rocks indicate crystallization at ~250-300 °C. Galena hosted in tremolite-talc-rich rocks is characterized by exceptionally high selenium and tellurium contents, indicating its generation from relatively Se-Te-enriched hydrothermal fluids. Pyrrhotite hosted in quartz-veins from Atshan was formed under lower sulfur activity (aS 2) and oxygen fugacity (fO 2). Covellite and bornite were formed due to chalcopyrite oxidation, revealing a role of supergene process. Shear zones, possibly produced during later thrust faulting, were acted as channel ways for hydrothermal mineralizing fluids that may have modified and/or precipitated the mineralization. Mineralizing fluids have probably resulted from dehydration during metamorphism and/or late-magmatic fluids from nearby granitic intrusions.
The earliest Svecofennian magmatism in southern Finland has been dated at 1.90-1.88Ga. As an example of this, the Orijarvi (ca. 1.89Ga) and Enklinge (ca. 1.88Ga) volcanic centres comprise bimodal plutonic batholiths surrounded by volcanic... more
The earliest Svecofennian magmatism in southern Finland has been dated at 1.90-1.88Ga. As an example of this, the Orijarvi (ca. 1.89Ga) and Enklinge (ca. 1.88Ga) volcanic centres comprise bimodal plutonic batholiths surrounded by volcanic rocks of comparable ages and chemical compositions. Here, we report geochemical and Sm-Nd isotope data from intrusive and extrusive samples, combined with zircon U-Pb and Lu-Hf isotopes for granodiorites from both study areas. The samples range from gabbros to granites and indicate a subduction-related continental margin setting. The zircons from the Orijarvi granodiorite define an age of 1892±4Ma whereas the Enklinge granodiorite yields an age of 1882±6Ma. Several inherited ages of 2.25-1.95Ga as well as younger ages of 1.86-1.80Ga were found in the Enklinge granodiorite. The initial e Nd values from the mafic rocks from both locations fall in the range +1.1 to +2.9 whereas the felsic rocks exhibit initial e Nd values of -0.4 to +1.2. The magmatic...
The Sawlava ophiolite is situated on the Iran–Iraq border within the Walash-Kermanshah ophiolitic belt and represents remnants of the Cenozoic southern Neo-Tethys Ocean, which was located between the Arabian plate and the Sanandaj–Sirjan... more
The Sawlava ophiolite is situated on the Iran–Iraq border within the Walash-Kermanshah ophiolitic belt and represents remnants of the Cenozoic southern Neo-Tethys Ocean, which was located between the Arabian plate and the Sanandaj–Sirjan zone. It contains a complete ophiolitic sequence started from harzburgites with foliated/discordant dunites, gabbroic bodies, a dyke complex, and pillow as well as massive basaltic lavas. The whole-rock and mineral chemistry of the Sawlava peridotites suggest that they are a mantle residuum after ca. 20–30% partial melting and melt extraction in the suprasubduction zone (SSZ) setting. The volcanic rocks generally range from island arc tholeiite to calc-alkaline affinities. Whole-rock chemistry indicates that volcanic units have compositions akin to depleted- and enriched-types mid-ocean ridge basalts (E-MORB). Layered- and isotropic gabbros show geochemical affinity similar to the normal mid-ocean ridge basalt (N-MORB) and E-MORB compositions, respectively. Their llight rare earth elements (LREE) observed in both N-MORB-like and E-MORB-like rocks, define two main basic geochemical types (LREE-enriched and LREE-depleted), suggesting several magmatic pulses from different mantle compositions that reveal mantle evolution and heterogeneity across the study area. Basaltic lavas weakly depleted in LREE show relatively flat REE patterns and (La/Yb)N values of 0.77 to 1.24, whereas LREE-enriched rocks have a (La/Yb)N mean values of 1.7, and lack an Eu anomaly. These subgroups of basaltic rocks show different extrusion ages – Paleocene–Eocene (59–50 Ma) and Oligocene (29 Ma), respectively. Petrogenetic modeling shows that mafic N- and E-MORB type rocks of Sawlava, which have (La/Yb)N = 0.97 and 1.7 and (Dy/Yb)N = 1.13 and 1.1, respectively, formed due to partial melting of a mantle source less enriched in LREE than an garnet lherzolite ((La/Yb)N = 0.88 and (Dy/Yb)N = 0.94) source or, alternatively, from very low degree (<2%) partial melting of a spinel-bearing DMM. The La/Yb–Dy/Yb systematics of these rocks are interpreted to be compatible with ~2 to 10% and ~ 20% of partial melting of a garnet bearing spinel lherzolite source for the N- and E-MORB type rocks, respectively. The geochemical data and results reveal that magmatic-originated rocks from both Paleocene-Eocene and Oligocene lavas seem to be less heterogeneous compared with the mantle sources of the Walash-Kermanshah ophiolites, likely due to different slab-fluid components and variations of partial melting degrees. The studied volcanic rocks therefore possibly record chemical heterogeneity due to magmatic activity at an oceanic spreading center alongside slab rollback and back-arc extension at the Eurasian continental margin.
The earliest Svecofennian magmatism in southern Finland has been dated to 1.90-1.88Ga. As an example of this, the Orijärvi (ca. 1.89Ga) and Enklinge (ca. 1.88Ga) volcanic centres comprise bimodal plutonic batholiths surrounded by volcanic... more
The earliest Svecofennian magmatism in southern Finland has been dated to 1.90-1.88Ga. As an example of this, the Orijärvi (ca. 1.89Ga) and Enklinge (ca. 1.88Ga) volcanic centres comprise bimodal plutonic batholiths surrounded by volcanic rocks of comparable ages and chemical compositions. The rock types range from gabbros to granites and indicate a subduction-related continental margin setting. The zircons from the Orijärvi granodiorite define an age of 1892±4Ma whereas the Enklinge granodiorite yields an age of 1882±6Ma. Several inherited ages of 2.25-1.95Ga as well as younger metamorphic ages of 1.86-1.80Ga were found in the Enklinge granodiorite. The initial εNd values of the mafic rocks from both locations fall in the range +1.1 to +2.9, whereas the felsic rocks exhibit initial εNd values of -0.4 to +1.2. The magmatic zircons from the Orijärvi and Enklinge granodiorites show average initial εHf values of -1.1 (at 1892Ma) and zero (at 1882Ma), respectively, both with a spread of...
