Due to its relatively low cost, high hydrogen yield, and environmentally friendly hydrolysis byproducts, magnesium hydride (MgH
2) appears to be an attractive candidate for hydrogen generation. However, the hydrolysis reaction of MgH
2 is rapidly inhibited by the formation of a
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Due to its relatively low cost, high hydrogen yield, and environmentally friendly hydrolysis byproducts, magnesium hydride (MgH
2) appears to be an attractive candidate for hydrogen generation. However, the hydrolysis reaction of MgH
2 is rapidly inhibited by the formation of a magnesium hydroxide passivation layer. To improve the hydrolysis properties of MgH
2-based hydrides we investigated three different approaches: ball milling, synthesis of MgH
2-based composites, and tuning of the solution composition. We demonstrate that the formation of a composite system, such as the MgH
2/LaH
3 composite, through ball milling and
in situ synthesis, can improve the hydrolysis properties of MgH
2 in pure water. Furthermore, the addition of Ni to the MgH
2/LaH
3 composite resulted in the synthesis of LaH
3/MgH
2/Ni composites. The LaH
3/MgH
2/Ni composites exhibited a higher hydrolysis rate—120 mL/(g·min) of H
2 in the first 5 min—than the MgH
2/LaH
3 composite— 95 mL/(g·min)—without the formation of the magnesium hydroxide passivation layer. Moreover, the yield rate was controlled by manipulation of the particle size via ball milling. The hydrolysis of MgH
2 was also improved by optimizing the solution. The MgH
2 produced 1711.2 mL/g of H
2 in 10 min at 298 K in the 27.1% ammonium chloride solution, and the hydrolytic conversion rate reached the value of 99.5%.
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