Search Results (267)

This study aims to develop the marine geo-polymer cement that was produced with seawater, recycled particles from paste, recycled particles from glass, and alkaline activators, including NaOH or Na₂O·3.3SiO₂. The physicochemical properties and strength of MGPC were investigated with a Uniaxial Compression Test, Particle Size Analysis, Energy Dispersive Spectrometer, X-ray Diffraction, and Thermal-field Emission Scanning Electron Microscopy. The results indicated that the main hydration products in MGPC were calcium carbonate (CaCO₃), silica (SiO₂), sodium aluminosilicate hydrate (Na₂O·Al₂O₃·xSiO₂·2H₂O, N-A-S-H), and aluminum calcium silicate hydrate (CaO·Al₂O₃·2SiO₂·4H₂O, C-A-S-H). The calcium carboaluminate (3CaO·Al₂O₃·CaCO₃·32H₂O, CO₃-AFm) in MGPC was converted into CaCO₃ and Friedel’s salt (3CaO·Al₂O₃·CaCl₂·10H₂O), which prompted the carbon sequestration. The microstructure of MGPC prepared using Na₂O·3.3SiO₂ was based on RPG as the matrix, with N-A-S-H, C-A-S-H, and fibrous AFt growing on the periphery. This structure reduces the impact of the alkali–silica reaction on the material and improves its compressive strength. Therefore, the MGPC developed in this study shows the exact benefits of freshwater and natural minerals saving, carbon sequestration, and damage resistance. Full article

Cemented backfill represents a significant trend in mine filling methods; however, it often exhibits high brittleness and limited resistance to failure, which can restrict its practical application. This study investigates the mechanical properties and damage evolution of fiber-reinforced coal gangue cemented materials (CGCMs) at various curing times using uniaxial compressive tests, acoustic emission (AE) analysis, and scanning electron microscopy (SEM). Specimens were created with different fillers, including carbon fibers (CFs), steel fibers (SFs), and carbon black (CB), and subjected to uniaxial compression until failure. Control specimens without fillers were also tested for comparison. The microstructure of the specimens was examined using scanning electron microscopy (SEM). The findings indicate that (1) the compressive strength of filler-reinforced CGCMs increases between 7 and 14 days of curing but decreases thereafter, with CB significantly improving early-age strength; (2) specimens reinforced with CFs and SFs exhibit significantly enhanced toughness in their post-cracking response; (3) AE events during specific stages can effectively identify the reinforcing effects of CFs and SFs; (4) the presence of fillers improves resistance to shear cracks, with CFs and SFs being more effective than CB; and (5) adding CB results in a denser and more stable hydration product structure, while CFs and SFs lead to a more porous structure with increased cracking. Full article

In this experiment, plasma-enhanced chemical vapor deposition technology was used to deposit diamond-like carbon thin films on the surface of a 2024 aluminum alloy. The effects of deposition temperature on the microstructure, carbon, silicon, and aluminum element distribution, and film substrate adhesion of diamond-like carbon thin films were studied using field emission scanning electron microscopy, energy-dispersive spectroscopy, XRD, scratch gauge, and ultra-depth-of-field microscopy. The results showed that with the increase in deposition temperature, the thickness of DLC film decreased from 8.72 μm to 5.37 μm, and the film bonded well with the substrate. There is a clear transition layer containing silicon elements between the DLC film and the aluminum alloy substrate. The transition layer is a solid solution formed by aluminum and silicon elements, which increases the bonding strength between the film and substrate. C-Si and C-C exist in the form of covalent bonds and undergo orbital hybridization, making the DLC film more stable. When the deposition temperature exceeds the aging temperature of a 2024 aluminum alloy, it will affect the properties of the aluminum alloy substrate. Therefore, the deposition temperature should be below the aging temperature of the 2024 aluminum alloy for coating. At a deposition temperature of 100 °C, the maximum membrane substrate bonding force is 14.45 N. When a continuous sound signal appears and the friction coefficient is the same as that of the substrate, the film is completely damaged. From the super-depth map of the scratch morphology, it can be seen that, at a deposition temperature of 100 °C, a small amount of thin film detachment appears around the scratch. Full article

The existing literature covers the topic of environmental pollution, but there is a scarcity of research that specifically examines the factors contributing to financial losses caused by carbon emissions. In this perspective, this ongoing analysis provides an understanding of the impact of environmental technology, energy efficiency, renewable energy consumption, natural resources, and economic growth on carbon dioxide damage in Organization for Economic Cooperation and Development (OECD) countries from 2000 to 2021 using the “Method of Moments Quantile Regression (MMQR)”, and “Dumitrescu–Hurlin (D-H)” causality test. The findings from the MMQR revealed that environmental control technology, renewable energy consumption, and energy efficiency contribute to reducing carbon dioxide damage at different quantiles. It was also found that economic growth and natural resources contribute to the increase in carbon dioxide damage in various quantities. Additionally, a one-way causality result was obtained from environmental technology, energy efficiency, renewable energy consumption, natural resources, and economic growth towards carbon dioxide damage. These results indicate that policymakers in OECD nations should provide suggestions on the efficient utilization of renewable energy sources and environmentally friendly technologies to minimize carbon dioxide damage. Full article

Freezing damage to tunnels in cold regions has long posed a threat to the safe operation of high-speed trains and other means of transportation. Finding a reasonable and effective solution to this problem, while also considering green, low-carbon, energy-saving, and environmental protection measures, has garnered widespread attention. Herein, the concept of a novel coupled energy tunnel is proposed, which combines the technologies of an air curtain and ground source heat pump (GSHP). The aim is to effectively address the issue of freezing damage in tunnels located in cold regions, while ensuring traffic safety. First, the multifunctional experimental apparatus for testing the anti-freezing and insulation performance of a coupled energy tunnel was independently designed and developed for laboratory experiments. Second, single-factor experiments and orthogonal experiments are conducted, and the influences of five key factors (i.e., the air outlet hole diameter, air outlet hole spacing, circulating water temperature of the GSHP, wind speed at the tunnel model entrance, and airflow jet angle) on the internal temperature field of the tunnel model are discussed. Third, combined with range analysis and variance analysis, the ranking of importance for each key factor and the optimal scheme of the coupled energy tunnel are obtained as follows: wind speed at the tunnel model entrance D > circulating water temperature of GSHP C > airflow jet angle E > air outlet hole spacing B > air outlet hole diameter A, and the optimal scheme is A₂B₁C₄D₁E₂, i.e., the air outlet hole diameter is 3 mm, the air outlet hole spacing is 10 mm, the circulating water temperature of GSHP is 50 °C, the wind speed at the tunnel model entrance is 1.5 m/s and the airflow jet angle is 45°. In conclusion, the research achievements presented in this paper can offer a new perspective for the structural design of tunnels in cold regions. Additionally, they contribute to the early achievement of a carbon dioxide emissions peak and carbon neutrality, and provide some valuable and scientific references for both innovators and practitioners. Full article

Polyethylene mulching film, which is widely utilized in arid and semi-arid agriculture, leaves residual pollution. A novel approach to addressing this issue is microbial degradation. To screen the strains that degrade polyethylene efficiently and clarify the effect of degrading strains on the turnover of soil organic carbon, a polyethylene-degrading fungus PF2, identified as Trichoderma asperellum, was isolated from long-time polyethylene-covered soil. Strain PF2 induced surface damage and ether bonds, ketone groups and other active functional groups in polyethylene, with 4.15% weight loss after 30 days, where laccase plays a key role in the degradation of polyethylene. When applied to soil, the Trichoderma-to-soil weight ratios were the following: B1: 1:100; B2: 1:200; B3: 1:300 and B4: 1:400. Trichoderma asperellum significantly increased the cumulative CO₂ mineralization and soil organic carbon mineralization in the B1 and B2 treatments compared with the control (B0). The treatments B1, B3 and B4 increased the stable organic carbon content in soil. An increase in the soil organic carbon content was observed with the application of Trichoderma asperellum, ranging from 27.87% to 58.38%. A positive correlation between CO₂ emissions and soil organic carbon was observed, with the soil carbon pool management index (CPMI) being most correlated with active organic carbon. Trichoderma treatments improved the CPMI, with B3 showing the most favorable carbon retention value. Thus, Trichoderma asperellum not only degrades polyethylene but also contributes to carbon sequestration and soil fertility when applied appropriately. Full article

Traditional energy systems pose a significant threat to human social development due to fossil fuel depletion and environmental pollution. Integrated energy systems (IESs) are widely studied and applied due to their clean and low-carbon characteristics to achieve sustainable development. However, as integrated energy systems expand, their impact on ecosystems becomes more pronounced. This paper introduces the concept of the ecological damage index (EDI) to promote the sustainable development of integrated energy systems. Moreover, the introduction of a capacity tariff mechanism will impact the energy structure, making it essential to consider its effects on capacity allocation within integrated energy systems. This paper proposes a multiobjective optimization framework for constructing a capacity planning model for integrated energy systems, focusing on achieving a multidimensional balance between the economy, environment, and ecosystem using the life cycle assessment (LCA) method. Finally, the nondominated sorting genetic algorithm-II (NSGA-II) is employed to optimize the three objectives and obtain the Pareto frontier solution set. The optimal solution is selected from the solution set by combining the technique for order preference by similarity to ideal solution (TOPSIS) and Shannon entropy method. In comparison to scenarios with incomplete considerations, the multiobjective capacity optimization model proposed in this study exhibits significant improvements across the three metrics of cost, carbon emissions, and the ecological damage index, with a 19.05% reduction in costs, a 26.24% decrease in carbon emissions, and an 8.85% decrease in the ecological damage index. The study demonstrates that the model abandons traditional single-objective research methods by incorporating a multidimensional balance of the economy, environment, and ecosystems. This approach forms a foundational basis for selecting the optimal energy mix and achieving sustainable development in integrated energy systems. The life cycle assessment methodology evaluates impacts across all stages of integrated energy systems, providing a comprehensive basis for assessing and planning the sustainable development of the systems. The study offers guidance for the rational allocation of the integrated energy system capacity and advances the sustainable development of such systems. Full article

Forest fires are increasingly destructive, contributing to significant ecological damage, carbon emissions, and economic losses. Monitoring these fires promptly and accurately, particularly by delineating fire perimeters, is critical for mitigating their impact. Satellite-based remote sensing, especially using active fire products from VIIRS and MODIS, has proven indispensable for real-time forest fire monitoring. Despite advancements, challenges remain in accurately clustering and delineating fire perimeters in a timely manner, as many existing methods rely on manual processing, resulting in delays. Active fire perimeter (AFP) and Timely Active Fire Progression (TAFP) models were developed which aim to be an automated approach for clustering active fire data points and delineating perimeters. The results demonstrated that the combined dataset achieved the highest matching rate of 85.13% for fire perimeters across all size classes, with a 95.95% clustering accuracy for fires ≥100 ha. However, the accuracy decreased for smaller fires. Overall, 1500 m radii with alpha values of 0.1 were found to be the most effective for fire perimeter delineation, particularly when applied at larger radii. The proposed models can play a critical role in improving operational responses by fire management agencies, helping to mitigate the destructive impact of forest fires more effectively. Full article

Epidemiological studies have consistently linked air pollution to severe health risks. One strategy to reduce the impact of combustion products from engines is adding additives to the fuel. Potential benefits have been observed in terms of performance and emissions, as well as in decreasing fuel consumption. However, the associated emission of particulate matter into the environment may have unforeseen health effects. This study examines the effects of diesel exhaust particles (DEPs) from diesel fuel mixed with amide-functionalized carbon nanotubes (CNTF). The aim is to analyze the properties of DEPs and determine their toxic effects on lung cells. The DEPs were characterized using scanning and transmission electron microscopy, while the polycyclic aromatic hydrocarbons (PAHs) were analyzed through gas chromatography. Various assays were conducted to assess cell viability, apoptosis, oxidative stress, and DNA damage. The addition of CNTF to diesel fuel altered the morphology and size of the particles, as well as the quantity and composition of PAHs. At the cellular level, diesel DEPs induce higher levels of reactive oxygen species (ROS) production, DNA damage, apoptosis, and cytotoxicity compared to both CNTF and diesel–CNTF DEPs. These findings suggest that the nano-additives enhance energy efficiency by reducing pollutants without significantly increasing cell toxicity. Full article

The monitoring of carbon emissions is increasingly becoming a sustainability issue worldwide. Despite being largely unnoticed, the toxic gas carbon monoxide (CO) is ubiquitous in mechanized tunnel driving, but the individual sources, release and enrichment mechanisms are often unknown. In this study, the generation of CO from organic matter containing sedimentary rocks was investigated during mechanized tunnel driving and by reacting claystone and sandstone with 10 mM NaCl solutions for 2 months at 70 °C and 140 °C. The mineralogical and geochemical evolution of the solids and fluids was assessed by CO measurements and the XRD, DTA, TOC, IC and ICP-OES methods. The CO concentration in the atmosphere reached up to 1920 ppm (100 ppm on average) during tunnel driving, which is more than three times higher than the legal daily average dose for tunnellers, thus requiring occupational safety operations. Mineral-specific dissolution processes and the rapid decomposition of labile organic matter upon thermal alteration contributed to the liberation of CO and also carbon dioxide (CO₂) from the host rocks. In mechanized tunnel driving, frictional heat and ‘cold’ combustion with temperatures reaching 50–70 °C at the drill head is an important mechanism for increased CO and CO₂ generation, especially during drilling in sedimentary rocks containing significant amounts of OM and when the ventilation of the tunnel atmosphere and air mixing are limited. Under such conditions, human health damage due to CO exposure (HHD_CO) can be 30 times higher compared to tunnel outlets, where CO is emitted from traffic. Full article

Bacterial infections and their increasing resistance to antibiotics pose a significant challenge in medical treatment. This study presents the synthesis and characterization of novel carbon dots (CDs) using levofloxacin (Lf), curcumin (Cur), and tea polyphenols (TP) through a facile hydrothermal method. The synthesized curcumin-tea polyphenol@carbon dots (Cur-TP@CDs) and levofloxacin-tea polyphenol@carbon dots (Lf-TP@CDs) were characterized using transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy, confirming their unique structural and chemical properties. Cur-TP@CDs exhibited an average particle size of 1.32 nanometers (nm), while Lf-TP@CDs averaged 1.58 nm. Both types demonstrated significant antibacterial activity, with Lf-TP@CDs showing superior effectiveness against Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli) in broth dilution and disc diffusion assays. Biofilm inhibition assays revealed a significant reduction in biofilm formation at higher concentrations. The ultraviolet-visible (UV-vis) and photoluminescence (PL) spectral analyses indicated efficient photon emission, and electron paramagnetic resonance (EPR) analysis showed increased singlet oxygen generation, enhancing bactericidal effects. Live and dead bacterial staining followed by scanning electron microscopy (SEM) analysis confirmed dose-dependent bacterial cell damage and morphological deformities. These findings suggest that Cur-TP@CDs and Lf-TP@CDs are promising antibacterial agents, potentially offering a novel approach to combat antibiotic-resistant bacterial infections. Full article

Calcined clays (CCs) as supplementary cementitious materials (SCMs) can be a promising option to reduce clinker content and CO₂ emissions in eco-friendly concretes. Although CCs as components of composite cements in combination with Ordinary Portland Cement (OPC) and limestone powder (LSP) have attracted industry interest, their use as concrete additives is limited. This study investigates the effects of the addition of CCs on the fresh and hardened properties of industry-standard ready-mixed concretes. Four concrete mix designs, each with three superplasticizer dosages, were tested, resulting in 12 variations. The CCs used, which are typical of 2:1 bentonite clays with low metakaolin content, reflect the clays available in Germany. The results showed that CCs significantly influenced the workability, which could be controlled with a high superplasticizer dosage. Increased CC contents reduced bleeding tendencies, which was beneficial for certain structural applications. Early age strength decreased with CCs, but the 28-day strength exceeded that of pure OPC concretes up to 30 wt% CCs. Resistance to CO₂-induced carbonation decreased with higher levels of CCs but was comparable up to 15 wt%. Freeze–thaw damage decreased, and chloride migration resistance improved due to a denser microstructure. The global warming potential (GWP) of the concretes tested is in line with that reported in the literature for concretes made from highly blended cements, suggesting that CCs can improve the sustainability of concrete production. Full article

Although soil stabilization with cement and lime is widely used to overcome the low shear strength of soft clay, which can cause severe damage to the infrastructures founded on such soils, such binders have severe impacts on the environment in terms of increasing emissions of carbon dioxide and the consumption of energy. Therefore, it is necessary to investigate soil improvement using sustainable materials such as byproducts or natural resources as alternatives to conventional binders—cement and lime. In this study, the combination of cement kiln dust as a byproduct and zeolite was used to produce an alkali-activated matrix. The results showed that the strength increased from 124 kPa for the untreated clay to 572 kPa for clay treated with 30% activated stabilizer agent (activated cement kiln dust). Moreover, incorporating zeolite as a partial replacement of the activated cement kiln dust increased the strength drastically to 960 and 2530 kPa for zeolite ratios of 0.1 and 0.6, respectively, which then decreased sharply to 1167 and 800 kPa with further increasing zeolite/pr to 0.8 and 1.0, respectively. The soil that was improved with the activated stabilizer agents was tested under footings subjected to eccentric loading. The results of large-scale loading tests showed clear improvements in terms of increasing the bearing capacity and decreasing the tilt of the footings. Also, a reduction occurred due to the eccentricity decreasing as a result of increasing the thickness of the treated soil layer beneath the footing. Full article

In the ecological context of global climate change, ensuring the stable carbon sequestration capacity of forest ecosystems, which is among the most important components of terrestrial ecosystems, is crucial. Forest fires are disasters that often burn vegetation and damage forest ecosystems. Accurate recognition of firegrounds is essential to analyze global carbon emissions and carbon flux, as well as to discover the contribution of climate change to the succession of forest ecosystems. The common recognition of firegrounds relies on remote sensing data, such as optical data, which have difficulty describing the characteristics of vertical structural damage to post-fire vegetation, whereas airborne LiDAR is incapable of large-scale observations and has high costs. The new generation of satellite-based photon counting radar ICESat-2/ATLAS (Advanced Topographic Laser Altimeter System, ATLAS) data has the advantages of large-scale observations and low cost. The ATLAS data were used in this study to extract three significant parameters, namely general, canopy, and topographical parameters, to construct a recognition index system for firegrounds based on vertical structure parameters, such as the essential canopy, based on machine learning of the random forest (RF) and extreme gradient boosting (XGBoost) classifiers. Furthermore, the spatio-temporal parameters are more accurate, and widespread use scalability was explored. The results show that the canopy type contributed 79% and 69% of the RF and XGBoost classifiers, respectively, which indicates the feasibility of using ICESat-2/ATLAS vertical structure parameters to identify firegrounds. The overall accuracy of the XGBoost classifier was slightly greater than that of the RF classifier according to 10-fold cross-validation, and all the evaluation metrics were greater than 0.8 after the independent sample test under different spatial and temporal conditions, implying the potential of ICESat-2/ATLAS for accurate fireground recognition. This study demonstrates the feasibility of ATLAS vertical structure parameters in identifying firegrounds and provides a novel and effective way to recognize firegrounds based on different spatial–temporal vertical structure information. This research reveals the feasibility of accurately identifying fireground based on parameters of ATLAS vertical structure by systematic analysis and comparison. It is also of practical significance for economical and effective precise recognition of large-scale firegrounds and contributes guidance for forest ecological restoration. Full article

This work presents the study of a reproducible acoustic emission method based on the launching of a metallic sphere and low-cost piezoelectric diaphragm. For this purpose, tests were first conducted on a carbon fiber-reinforced polymer structure, and then on an aluminum structure for comparative analysis. The pencil-lead break (PLB) tests were also conducted for comparisons with the proposed method. Different launching heights and elastic deformations of the structures were investigated. The results show higher repeatability for the sphere impact method, as the PLB is more affected by human inaccuracy, and it was also effective in damage detection. Full article