Search Results (10)

A cryogenic hose is used to transport liquefied natural gas at sea, where flexible fittings are sealed by corrugated lining and end flange welding. However, the extreme cryogenic temperatures of the conveyed fluid introduce substantial challenges to the integrity of the fitting seals’ structure during the LNG transfer process. In order to study the sealing performance of the fitting under LNG conveying conditions, this paper was based on the general finite element software ABAQUS 6.11 to carry out a thermo-mechanical coupling analysis of the end sealing stress. This paper also established a sealing performance analysis model of the corrugated fitting welding area under the fitting action of LNG load and internal pressure load. A sensitivity analysis was conducted on the influence of weld clearance, blunt edge size, and weld residual height on the weld stress of a fitting ring. The results show that, under the combined action of the medium internal pressure and cryogenic load, the size design of the weld area significantly affects the sealing performance of the fitting, among which the equivalent force of the weld clearance butt sealing area has the greatest impact. Moreover, it was found that a pressure of 5 MPa was 2 mm when the weld clearance was 2 mm, and the average stress at the weld was 53.68 MPa. Further, considering the synergistic influence of the blunt edge size, the weld clearance was 3 mm, the stress was minimal when the blunt side size was 4 mm, and the average stress was 17.42 MPa. These research results can serve as a reference for the design and analysis of the sealing structure of non-adhesive inner corrugated cryogenic hose fittings. Full article

To cater to the problems of a poor working environment, a large amount of rebound, and the high energy consumption of sprayed concrete in tunnel engineering, this paper proposes a new support scheme with a steel corrugated plate combined with mold bag concrete. Analytical solutions of stresses for steel corrugated plate and mold bag concrete were deduced based on the thin-walled cylinder, and then their strength safety factors were presented. Subsequently, a series of numerical simulations were conducted to investigate the mechanical performance of the third ring of the main structure based on the ‘load-structure’ 3D model. The numerical results were verified using the classical theoretical analysis and the proposed model, and then parametric studies were performed through the numerical method. Finally, field tests in a circular shaft were carried out to verify the feasibility of the structure and process and the engineering effect. The results show that the combination of steel corrugated plate and mold bag concrete is feasible and can realize rapid support technology for underground engineering, which provides a new idea for the supporting technology of underground engineering such as tunnels. Full article

This paper presents a novel single-layer dual band-rejection-filter based on Spoof Surface Plasmon Polaritons (SSPPs). The filter consists of an SSPP-based transmission line, as well as six coupled circular ring resonators (CCRRs) etched among ground planes of the center corrugated strip. These resonators are excited by electric-field of the SSPP structure. The added ground on both sides of the strip yields tighter electromagnetic fields and improves the filter performance at lower frequencies. By removing flaring ground in comparison to prevalent SSPP-based constructions, the total size of the filter is significantly decreased, and mode conversion efficiency at the transition from co-planar waveguide (CPW) to the SSPP line is increased. The proposed filter possesses tunable rejection bandwidth, wide stop bands, and a variety of different parameters to adjust the forbidden bands and the filter’s cut-off frequency. To demonstrate the filter tunability, the effect of different elements like number (n), width ($W_R$), radius ($R_R$) of CCRRs, and their distance to the SSPP line ($y_R$) are surveyed. Two forbidden bands, located in the X and K bands, are 8.6–11.2 GHz and 20–21.8 GHz. As the proof-of-concept, the proposed filter was fabricated, and a good agreement between the simulation and experiment results was achieved. Full article

Stability analysis of a corrugated ring subjected to uniform external pressure is under consideration. Two main approaches to solving this problem are analyzed. The equivalent bending stiffness approach is often used in engineering practice. It is based on some plausible assumptions about the behavior of a structure. Its advantage is the simplicity of the obtained relations; the disadvantage is the difficulty in estimating the area of applicability. In this paper, we developed an asymptotic homogenization method for calculating the critical pressure for a corrugated ring, which made it possible to mathematically substantiate and refine the equivalent bending stiffness approach. To evaluate the results obtained using the equivalent stiffness approach and asymptotic homogenization method, the imperfection method is used. The influence of the corrugation parameters on buckling pressure is analyzed. Full article

High performance concrete (HPC) is a high strength concrete that undergoes a lot of early-age autogenous shrinkage (AS). If shrinkage is restrained, then micro-cracks arise and threaten the durability of the structure. Superabsorbent polymers (SAPs) can reduce/mitigate the autogenous shrinkage, due to their promising application as internal curing agents. In this paper, large-scale demonstrators were built to investigate the efficiency of SAPs to mitigate autogenous shrinkage in HPC. For this purpose, different measurement techniques were used like embedded fiber optic sensors and demountable mechanical strain gauges, complemented by AS measurements in corrugated tubes and restrained ring tests. The SAP wall showed an AS reduction of 22%, 54%, and 60% at the bottom, middle, and top, respectively, as recorded by the sensors (in comparison with the reference wall (REF)). In the corrugated tubes, mitigation of AS was shown in the SAP mixture, and under restrained conditions, in the ring test, the reference mixture cracked after two days, while the SAP mixture had not cracked at the end of the measurement period (20 days). Cracks were shown on REF wall after one day, while the SAP wall was crack-free. Water flow tests performed on the main crack of the REF wall confirmed that the flow rate is related to the third power of the crack width. All tests showed that SAPs could highly reduce AS in HPC and avoid cracking. Full article

With the increase of working frequency, the feature size of a corrugated horn will be greatly reduced, causing challenges for fabrication. This paper investigated wire electrochemical micromachining (WECMM) of aluminum rings for assembly of a mandrel for electroforming, which has been a primary method for producing corrugated horns. By utilizing a rotary helical electrode and green additives, the removal efficiency of electrolytic products in WECMM was improved. It was found that the machined slits had good unilateral consistency on the left side of the electrode feeding direction when the electrode rotated clockwise. Complexing agent glutamic diacetic acid (GLDA) can compete with OH⁻ for Al³⁺ and has an obvious effect in reducing insoluble electrolytic products. From experimental investigations on typical parameters, an optimal parameter combination considering slit homogeneity and machining efficiency was obtained. In an electrolyte solution containing 15 g/L sodium nitrate solution and 15 g/L GLDA, 100 μm-thick aluminum rings with good edge and surface qualities were fabricated at a rate of 1.2 μm/s using a helical electrode with a diameter of 0.3 mm. Finally, these aluminum rings were successfully applied to make an internal corrugated sample with a rib width of 100 μm and a groove depth of 500 μm. Full article

We demonstrate the multiband color filtering of a standard RGB color and a complementary CMY color by a plasmonic color filter, composed of concentric corrugated metallic thin film rings. The surface plasmon resonance is excited by the periodic corrugation, and the coupled light is transmitted through the central subwavelength aperture. Color selectivity is achieved not only in the visible but also in the near-infrared (NIR) region. Therefore, simultaneous imaging with visible and NIR can be realized by the integration of plasmonic color filters with sensors. We investigate the angle of incidence dependence of the transmission color selectivity and the color purity of the fabricated plasmonic color filter array. Full article

Melamine (C₃H₆N₆; 1,3,5-triazine-2,4,6-triamine) is an aromatic substituted s-triazine, with carbon and nitrogen atoms forming the ring body, and amino groups bonded to each carbon. Melamine is widely used to produce laminate products, adhesives, and flame retardants, but is also similar chemically and structurally to many energetic materials, including TATB (2,4,6-triamino-1,3,5- trinitrobenzene) and RDX (1,3,5-trinitroperhydro-1,3,5-triazine). Additionally, melamine may be a precursor in the synthesis of superhard carbon-nitrides, such as β-C₃N₄. In the crystalline state melamine forms corrugated sheets of individual molecules, which are stacked on top of one another, and linked by intra- and inter-plane N-H hydrogen bonds. Several previous high-pressure X-ray diffraction and Raman spectroscopy studies have claimed that melamine undergoes two or more phase transformations below 25 GPa. Our results show no indication of previously reported low pressure polymorphism up to approximately 30 GPa. High-pressure crystal structure refinements demonstrate that the individual molecular units of melamine are remarkably rigid, and their geometry changes very little despite volume decrease by almost a factor of two at 30 GPa and major re-arrangements of the intermolecular interactions, as seen through the Hirshfeld surface analysis. A symmetry change from monoclinic to triclinic, indicated by both dramatic changes in diffraction pattern, as well as discontinuities in the vibration mode behavior, was observed above approximately 36 GPa in helium and 30 GPa in neon pressure media. Examination of the hydrogen bonding behavior in melamine’s structure will allow its improved utilization as a chemical feedstock and analog for related energetic compounds. Full article

High-resistance paper was manufactured by laccase-grafting of carboxymethyl cellulose (CMC) and chitosan (CPX) on Kraft pulp fiber. The reaction was mediated in the presence of laccase by one of the following polyphenols in the presence of air: gallic acid (GA), vanillic acid (VA) and catechol (1,2–DHB). Enzyme was added at constant loading (24 kg ton⁻¹), 1% pulp consistency, 0.005% CMC, pH = 6.3 ± 0.5 and 2 mM of mediator. CPX content was assessed at two levels (0% and 0.005%). Treated pulps were analyzed by different mechanical tests (ring crush, mullen, corrugating medium test (CMT) flat crush of corrugating medium test and tension). An improvement in these parameters was obtained by biopolymer coupling and selected mediator. When using GA, three parameters increased more than 40%, while ring crush increased 120%. For the case of VA, properties were enhanced from 74% to 88% when CPX was added. For 1,2–DHB, there was not found a statistically significant difference between the results in the presence of CPX. Scanning electron microscopy, confocal microscopy, FTIR and ¹³C NMR were used in all papers in order to evaluate grafting. Hence, it was possible to correlate polymerization with an improvement of paper’s mechanical properties. Full article

The bimetallic cluster Na[W₂(μ-Cl)₃Cl₄(THF)₂]·(THF)₃ ({W₂}, {W ³ W}⁶⁺, a′²e′⁴), which features a triple metal-metal bond, is a highly efficient room-temperature initiator for ring opening metathesis polymerization (ROMP) of norbornene (NBE) and norbornadiene (NBD), providing high-cis polymers. In this work, {W₂} was used for the copolymerization of the aforementioned monomers, yielding statistical poly(norbornene)/poly(norbornadiene) PNBE/PNBD copolymers of high molecular weight and high-cis content. The composition of the polymer chain was estimated by ¹³C CPMAS NMR data and it was found that the ratio of PNBE/PNBD segments in the polymer chain was relative to the monomer molar ratio in the reaction mixture. The thermal properties of all copolymers were similar, resembled the properties of PNBD homopolymer and indicated a high degree of cross-linking. The morphology of all materials in this study was smooth and non-porous; copolymers with higher PNBE content featured a corrugated morphology. Glass transition temperatures were lower for the copolymers than for the homopolymers, providing a strong indication that those materials featured a branched-shaped structure. This conclusion was further supported by viscosity measurements of copolymers solutions in THF. The molecular structure of those materials can be controlled, potentially leading to well-defined star polymers via the “core-first” synthesis method. Therefore, {W₂} is not only a cost-efficient, practical, highly active, and cis-stereoselective ROMP-initiator, but it can also be used for the synthesis of more complex macromolecular structures. Full article