Search Results (14,413)

Aceclofenac (ACF), a non-steroidal anti-inflammatory drug, was obtained in its amorphous state by cooling from melt. The glass transition was investigated using dielectric and calorimetric techniques, namely, dielectric relaxation spectroscopy (DRS), thermally stimulated depolarization currents (TSDC), and conventional and temperature-modulated differential scanning calorimetry (DSC and TM-DSC). The dynamic behavior in both the glassy and supercooled liquid states revealed multiple relaxation processes. Well below the glass transition, DRS was able to resolve two secondary relaxations, γ and β, the latter of which was also detectable by TSDC. The kinetic parameters indicated that both processes are associated with localized motions within the molecule. The main (α) relaxation was clearly observed by DRS and TSDC, and results from both techniques confirmed a non-Arrhenian temperature dependence of the relaxation times. However, the glass transition temperature (T_g) extrapolated from DRS data significantly differed from that obtained via TSDC, which in turn showed reasonable agreement with the calorimetric T_g (T_g-DSC = 9.2 °C). The values of the fragility index calculated by the three experimental techniques converged in attributing the character of a moderately fragile glass former to ACF. Above the α relaxation, TSDC showed a well-defined peak. In DRS, after “removing” the high-conductivity contribution using ε’ derivative analysis, a peak with shape parameters α_HN = β_HN = 1 was also detected. The origin of these peaks, found in the full supercooled liquid state, has been discussed in the context of structural and dynamic heterogeneity. This is supported by significant differences observed between the FTIR spectra of the amorphous and crystalline samples, which are likely related to aggregation differences resulting from variations in the hydrogen bonds between the two phases. Additionally, the pronounced decoupling between translational and relaxational motions, as deduced from the low value of the fractional exponent x = 0.72, derived from the fractional Debye–Stokes–Einstein (FDSE) relationship, further supports this interpretation. Full article

The present article presents the results of physical and chemical studies of opoka. In particular, the opoka was subjected to chemical analysis, X-ray phase, differential thermal analysis, scanning microscopy, and X-ray energy dispersive elemental microanalysis. The opoka was studied with the aim of using it as an available raw material for obtaining a sodium silicate mixture and, in the future, developing an energy-saving technology for obtaining a building heat-insulating and sound-insulating foam glass material based on it, using synthesis. As a result of the studies, the chemical composition of the opoka was determined, which is 69–80% represented by silica. The elemental composition of the opoka was established, which is represented by 94.25% oxides of Si, Al, and Fe. The presence of such oxides makes it an ideal raw material component of a silicate-sodium mixture for the subsequent synthesis of foam glass material from it. Experimental exploratory studies on the synthesis of foam glass based on opoka have been carried out. The experimentally obtained sample of foam glass material consists of 93.37% Si, Al, Mg, and Na oxides, has a porous structure with a pore size of 2–5 microns, an average density of 375 kg/m³, thermal conductivity of 0.063 W/(m °C) at 25 °C, and noise absorption of 51.6 Db. Full article

Water use efficiency (WUE) reflects the quantitative relationship between vegetation gross primary productivity (GPP) and surface evapotranspiration (ET), serving as a crucial indicator for assessing the coupling of carbon and water cycles in ecosystems. As a sensitive region to climate change, the Qinghai Tibetan Plateau’s WUE dynamics are of significant scientific interest for understanding carbon water interactions and forecasting future climate trends. However, due to the scarcity of observational data and the unique environmental conditions of the plateau, existing studies show substantial errors in GPP simulation accuracy and considerable discrepancies in ET outputs from different models, leading to uncertainties in current WUE estimates. This study addresses these gaps by first employing a machine learning approach (random forest) to integrate observed GPP flux data with multi-source environmental information, developing a predictive model capable of accurately simulating GPP in the Qinghai Tibetan Plateau (QTP). The accuracy of the random forest simulation results, RF_GPP (R² = 0.611, RMSE = 69.162 gC·m⁻²·month⁻¹), is higher than that of the multiple linear regression model, regGPP (R² = 0.429, RMSE = 86.578 gC·m⁻²·month⁻¹), and significantly better than the accuracy of the GLASS product, GLASS_GPP (R² = 0.360, RMSE = 91.764 gC·m⁻²·month⁻¹). Subsequently, based on observed ET flux data, we quantitatively evaluate ET products from various models and construct a multiple regression model that integrates these products. The accuracy of REG_ET, obtained by integrating five ET products using a multiple linear regression model (R² = 0.601, RMSE = 21.04 mm·month⁻¹), is higher than that of the product derived through mean processing, MEAN_ET (R² = 0.591, RMSE = 25.641 mm·month⁻¹). Finally, using the optimized GPP and ET data, we calculate the WUE during the growing season from 1982 to 2018 and analyze its spatiotemporal evolution. In this study, GPP and ET were optimized based on flux observation data, thereby enhancing the estimation accuracy of WUE. On this basis, the interannual variation of WUE was analyzed, providing a data foundation for studying carbon water coupling in QTP ecosystems and supporting the formulation of policies for ecological construction and water resource management in the future. Full article

Augmented reality display performance depends strongly on features of the human visual system. This is especially true for retinal scan glasses, which use laser beam scanning and transparent holographic optical combiners. Human-centered approaches allow us to go beyond conventional optical metrology and evaluate display performance as it is perceived in actual augmented reality use cases. Here, we first present a theoretical formula for the retinal scan luminance and ambient contrast ratio calculated from optical powers, wavelengths, field of view, and human pupil diameter. As a promising insight, we found that the pupil diameter dependence is beneficial in assimilating the virtual image luminance to the ambient luminance. Second, we designed and performed a psychophysical experiment to assess perceived resolution in augmented reality settings using a fully functional retinal scan glasses prototype. We present the results of the trials and illustrate how this approach can be used in the further development of augmented reality smart glasses. Full article

This study investigates the development and application of climate friendly processes in the foundry industry, particularly with regard to the use of inorganic binders to reduce emissions and pollution. An inorganic binder system based on water glass, which is used in 3D printing technology for the production of sand molds and core, is being tested and the possibility of determining a kinetic model for the curing kinetics of sodium silicate as an inorganic binder is investigated. The aim is to use a kinetic model to better describe the microwave process currently required in binder jetting for drying the binder and catalyzing the chemical reaction of the binder during curing. For sodium silicate in particular, there is still no scientific knowledge available in this respect, which is why basic investigations based on thermogravimetry or heat flow difference calorimetry must first be carried out. In this way, it should be possible to simulate the drying process in the microwave, which has so far been based on empirical values, in order to maximize the efficiency of this process and also the quality of the components. The results indicate that the weight loss and weight changes depend on the heating rates and that a heating rate of 30 K/min is not sufficient to fully cure the sample at 500 °C. The thermogravimetric analysis (TGA) shows that the fastest weight loss occurs at the beginning of the measurement, indicating a partial pre-curing of the sample before the measurement. From the measurements, an average activation energy of 144.18 kJ/mol could be determined using the Friedman method and 123.36 kJ/mol and 123.31 kJ/mol using the Ozawa–Flynn–Wall and Kissinger–Akahira–Sunose methods, respectively. Measurements of the heat flow at a heating rate of 30 K/min indicate partially exothermic reactions during the curing process. Full article

G protein-coupled receptors (GPCRs) exist in the conformational equilibrium between inactive state and active state, where the proportion of active state in the absence of a ligand determines the basal activity of GPCRs. Although many GPCRs have different basal activity, it is still unclear whether physiological stresses such as substrate stiffness affect the basal activity of GPCRs. In this study, we identified that purinergic P2Y₆ receptor (P2Y₆R) induced spontaneous Ca²⁺ oscillation without a nucleotide ligand when cells were cultured in a silicon chamber. This P2Y₆R-dependent Ca²⁺ oscillation was absent in cells cultured in glass dishes. Coating substrates, including collagen, laminin, and fibronectin, did not affect the P2Y₆R spontaneous activity. Mutation of the extracellular Arg-Gly-Asp (RGD) motif of P2Y₆R inhibited spontaneous activity. Additionally, extracellular Ca²⁺ was required for P2Y₆R-dependent spontaneous Ca²⁺ oscillation. The GPCR screening assay identified cells expressing 10 GPCRs, including purinergic P2Y₁R, P2Y₂R, and P2Y₆R, that exhibited spontaneous Ca²⁺ oscillation under cell culture soft substrate. Our results suggest that stiffness of the cell adhesion surface modulates spontaneous activities of several GPCRs, including P2Y₆R, through a ligand-independent mechanism. Full article

Using 3D-printed (3DPd) polymers and their composites as shape memory materials in various smart engineering applications has raised the demand for such functionally graded sustainable materials. This study aims to investigate the viscoelastic, shape memory, and fracture toughness properties of the epoxy-based ultraviolet (UV)-curable resin. A UV-based DLP (Digital Light Processing) printer was employed for the 3D printing (3DPg) epoxy-based structures. The effect of the hydrothermal accelerated ageing on the various properties of the 3DPd components was examined. The viscoelastic performance in terms of glass transition temperature (T_g), storage modulus, and loss modulus was evaluated. The shape memory polymer (SMP) performance with respect to shape recovery and shape fixity (programming the shape) were calculated through dynamic mechanical thermal analysis (DMTA). DMTA is used to reveal the molecular mobility performance through three different regions, i.e., glass region, glass transition region, and rubbery region. The shape-changing region (within the glass transition region) between the T_g value from the loss modulus and the T_g value from the tan(δ) was analysed. The temperature memory behaviour was investigated for flat and circular 3DPd structures to achieve sequential deployment. The critical stress intensity factor values of the single-edge notch bending (SENB) specimens have been explored for different crack inclination angles to investigate mode I (opening) and mixed-mode I/III (opening and tearing) fracture toughness. This study can contribute to the development of highly complex shape memory 3DPd structures that can be reshaped several times with large deformation. Full article

This research studied the recycling of borosilicate glass wastes from damaged laboratory glassware. The luminescent glasses were prepared by doping glass waste powder with rare earth ions, namely, dysprosium ions (Dy³⁺) and samarium ions (Sm³⁺), as well as co-doping with Dy³⁺ and Sm³⁺ at a concentration of 2% by weight. The sintering process was conducted in a microwave oven for a duration of 15 min. The photoluminescence spectra of the doped glasses were obtained under excitation at 401 nm and 388 nm. The results showed that the emission characteristics depended on the doping concentrations of Dy³⁺ and Sm³⁺ and the excitation wavelengths. Upon excitation at 401 nm, the co-doped glasses exhibited the maximum emission peak of Sm³⁺ at 601 nm (yellowish and orange region in the CIE chromaticity diagram) due to the energy transition from ⁴G_5/2 to ⁶H_7/2. When excited at 388 nm, however, the emission spectra of the co-doped glasses were similar to the characteristic emission peaks of Dy³⁺ (white region in the CIE chromaticity diagram), but the peak position exhibits a red shift. This could be attributed to an increase in the amount of non-bridging oxygens (NBOs) by co-doping. Full article

Perovskite solar cells (PSCs) have emerged as a promising photovoltaic technology, yet their stability under environmental stressors remains a critical challenge. This study examines the substrate-dependent degradation mechanisms of perovskite films and evaluates the role of methylammonium chloride (MACl) incorporation. Devices fabricated on ITO and glass substrates exhibited markedly different stability behaviors under high-humidity conditions. ITO substrates delayed the phase transition from the black α-phase to the yellow δ-phase due to stronger substrate–film interactions and reduced defect densities, while glass substrates facilitated rapid degradation through moisture infiltration and grain boundary instability. MACl incorporation enhanced the initial crystallinity and optoelectronic properties of the perovskite films, as evidenced by superior power conversion efficiency and photon absorption. However, residual MACl under humid conditions introduced structural instability, particularly on glass substrates. To address these challenges, a fully coated ITO structure, referred to as the Island Type design, was proposed. This structure eliminates exposed glass regions, leveraging the stabilizing properties of ITO to suppress moisture infiltration and prolong device durability. The findings provide a comprehensive understanding of the interplay between substrate properties and material composition in PSC stability and highlight the potential of structural optimizations to balance efficiency and durability for commercial applications. Full article

Despite the potential of glass fiber (GF) membranes for oil-water emulsion separations, efficient surface modification methods to enhance fouling resistance while preserving membrane performance and stability remain lacking. We report a silica nanocoating method to modify GF membranes through a vapor deposition method. The high smoothness (<1 nm r.m.s.) and high conformality of the vapor-deposited silica nanocoatings enabled the preservation of membrane microstructure and permeability, which, combined with the enhanced surface hydrophilicity, led to an oil rejection rate exceeding 99% and more than a 40% improvement in permeate flux in oil-water emulsion separations. Furthermore, the silica nanocoatings provided the membranes with excellent wet strength and stability against organic solvents, strong acids, oxidants, boiling, and sonication. The silica-nanocoated membrane demonstrated enhanced fouling resistance, achieving flux recovery higher than 75% during repeated oil-water emulsion separations and bovine serum albumin and humic acid fouling tests. Full article

This research aimed to provide valuable insights for future studies and enhance manufacturing processes by investigating the effect of incorporating fibers into 3D printing to improve the mechanical properties of fabricated components. The experimental design was carried out using Design-Expert software, employing the Central Composite Design (CCD) methodology. Seventeen experiments were conducted, with predefined input parameters, layer height, filler ratio, and printing speed, analyzed through the Response Surface Methodology (RSM) using Design-Expert version 12. An Analysis of Variance (ANOVA) revealed that the filler ratio had the most significant effect on fracture strength. The influence of different printing parameters printing speed, layer height, and filler ratio on the mechanical properties and print quality was systematically investigated. The results indicated that the filler ratio was the most critical factor, with a 100% fill ratio yielding the highest tensile strength. Conversely, a 50% fill ratio significantly reduced production costs, but at the expense of mechanical performance. Thus, if strength is the primary requirement, a higher fill ratio is recommended. The effect of printing speed was found to be less significant compared to layer height and filler ratio. The maximum recorded tensile strength was 540.65 N, achieved with a layer height of 0.5 mm, a 100% fill ratio, and a printing speed of 8 mm/s. In contrast, the lowest recorded tensile strength was 389.93 N, observed with a layer height of 0.4 mm, a 50% fill ratio, and a printing speed of 4 mm/s. After applying a transformation function, the data showed good alignment with the normal distribution on the probability plot, indicating that the assumption of normality was satisfied. Additionally, the incorporation of glass fibers significantly enhanced the mechanical strength of the printed samples. Full article

The improper disposal of construction and demolition waste (CDW) exacerbates the consumption of raw materials and emissions of greenhouse gasses. In this study, due to the high recycling rate, focusing on the meltable materials of CDW, the recycling phase of CDW is divided into four stages, namely the on-site disposal stage, the transportation stage, the reprocessing stage, and the reproduction stage. Second, based on these four stages, a carbon emission accounting model (CEAM) is established to evaluate the carbon emission benefits of meltable materials during these stages. Third, the CEAM is applied to a typical old residential area to evaluate the carbon emission reduction benefits of the CDW recycling. The results indicate that (1) the full-process carbon emissions of recycled steel, recycled flat glass, and recycled aluminum per unit mass are 677.77 kg/t, 1041.54 kg/t, and 845.39 kg/t, respectively, which are far lower than their corresponding ordinary meltable building materials (OMBMs); (2) the carbon emissions during the reproduction stage represent the primary component of carbon emissions in the MW recycling phase, accounting for 88.52% to 97.45% of the total carbon emissions; and (3) the carbon emissions generated by the recycling of cullet per unit mass are very high, reaching 1768 kg/t, which is 4.3 times that of scrap steel (409.05 kg/t) and 3.6 times that of scrap aluminum (483.76 kg/t). The research findings could provide theoretical methods and experimental data for decision-makers to formulate treatment plans for meltable materials in CDW, thereby empowering urban carbon emission reduction and promoting sustainable development. Construction parties engaged in demolition tasks should enhance on-site sorting and collaborate with recycling companies to ensure its efficient recycling. Recycling companies need to focus on high-carbon-emission stages, such as the reproduction stage, and strengthen technological research to improve carbon reduction benefits. Full article

Long-term reliability is crucial for the commercialization of semi-transparent photovoltaic panels based on Luminescent Solar Concentrators (LSCs). This study addresses key challenges such as photodegradation and hail resistance using glazed LSC prototypes functionalized with organic Lumogen F dyes. A pilot-scale batch of LSC prototypes (10 × 10 cm²) underwent extensive outdoor exposure tests following the IEC 62108 “10.15 Outdoor Exposure Test” to evaluate long-term stability under natural solar radiation. Continuous monitoring revealed that prototypes with Lumogen F Red 305 experienced a 29% efficiency drop initially, which stabilized over time, indicating potential long-term stability. In contrast, those with Lumogen F Violet 570 showed minimal degradation, with only a 9% efficiency reduction. Additionally, the hail resistance of LSC panels was tested using the IEC 62108 “10.9 Hail Impact Test”. Panels with varying glass thickness, tempering methods, and surface areas were subjected to impact from 25 mm hailstones launched at 22.4 ± 5% m/s. All samples remained undamaged, highlighting their excellent hail resistance, a critical feature for preserving performance despite potential surface damage. This study demonstrates that combining glazed lightguides with polyvinyl butyral improves photostability and provides a cost-effective alternative to expensive fluorophores, while ensuring compliance with hail resistance standards. Full article

Aim: To compare caregiver satisfaction and children’s acceptance of silver fluoride/potassium iodide (AgF+KI) treatment (Riva Star Aqua^®, SDI Limited, Victoria, Australia) and glass-ionomer cement (GIC) application (Ionostar Plus + Easy Glaze, VOCO, Germany) in reducing hypersensitivity in permanent molars affected by molar incisor hypomineralisation (MIH) with the MIH treatment need index (MIH-TNI) 3 and 4 immediately after its application and after 12 weeks. Materials and Methods: This prospective, comparative, clinical study recruited schoolchildren with at least one hypersensitive MIH molar with a Schiff cold air sensitivity score (SCASS) of 2 and 3. Caregivers in both groups (AgF+KI and GIC + glaze) answered a questionnaire (5-Point Likert Scale) regarding the perception of the treatment immediately (15 min post application) and in the 12 weeks follow-up. Children’s behaviour during both applications was assessed using FBRS (Frankl Behaviour Rating Scale). Results: A total number of 47 children (n = 22 for AgF/KI and n = 25 for GIC) with a mean age of 8.6 ± 1.42 were recruited. A high proportion of the children in both arms (n = 40 out of 44; 90.1%) reported a reduction in hypersensitivity in the last 12 weeks. On average, children (n = 39; FBRS ≥ 3) in both groups showed positive behaviour, with a significantly more definitely positive behaviour in the GIC group (p < 0.05, independent student t-test). Caregiver satisfaction with both study procedures was high after immediate assessment (n = 19 out of 22, 86.4% for AgF/KI and n = 19 out of 25, 76.0% for GIC application) and in 12 weeks of follow-up (n = 17 out of 20, 85.0% for AgF/KI and n = 22 out of 24, 91.6% for GIC application). However, the taste AgF/KI is more frequently considered not acceptable for the child (n = 10; 45%) than smell (n = 2; 9%). Interestingly, there was a statistically significant difference in caregivers’ preference toward alternative desensitisation treatment (tooth restoration coverage, desensitisation paste, stainless steel crown and fluoride varnish) in both treatment groups (p < 0.05, Mann–Whitney U test). Conclusions: Both GIC and AgF/KI applications can be considered acceptable approaches to reduce hypersensitivity in permanent molars affected by MIH both immediately and in long-term follow-up for schoolchildren based on caregivers’ assessments. Full article

An innovative glass substrate surface technology including integrated micro-electro-mechanical systems (MEMS) is presented as an advanced light modulation, heat control, and energy management system. This smart technology is based on millions of metallic micromirrors per square meter fabricated on the glass surface, which are arranged in arrays and electrostatically actuated. The smart window application exploits an elaborate MEMS glass technology for active daylight steering and energy management in buildings, enabling energy saving, CO₂ emission reduction, a positive health impact, and improved well-being. When light interacts with a glass substrate that has regular, repetitive patterning at the microscopic scale on its surface, these microstructures can cause the diffraction of the transmitted light, resulting in the potential deterioration of the view quality through the smart glass. A reduction in optical artifacts for improved clear view is presented by using irregular geometric micromirror apertures. Several non-periodic, irregular micromirror aperture designs are compared with corresponding periodic regular designs. For each considered aperture geometry, the irregular array reveals a reduction in optical artifacts and, therefore, by far a clearer view than the corresponding regular array. A systematic and comprehensive study was conducted through design, simulation, technological fabrication, experimental characterization, and analysis. Full article