Predicting trip purpose from comprehensive and continuous smart card data is beneficial for transport and city planners in investigating travel behaviours and urban mobility. Here we propose a framework, ActivityNET, using machine learning (ML) algorithms to predict passengers’ trip purpose from smart card data and Points-of-Interest (POIs) data. The feasibility of the framework is demonstrated in two phases. Phase I focuses on extracting activities from individuals’ daily travel patterns from smart card data and combining them with POIs using the proposed ‘activity-POIs consolidation algorithm’. Phase II feeds the extracted features into an artificial neural network (ANN) with multiple scenarios and predicts trip purpose under primary activities (home and work) and secondary activities (entertainment, eating, shopping, child drop-offs/pick-ups and part-time work) with high accuracy. As a case study, the proposed ActivityNET framework is applied in Greater London and illustrates a robust competence to predict trip purpose. The promising outcomes demonstrate that the cost-effective framework offers high predictive accuracy and valuable insights into transport planning.

Asymmetric lithium salts, such as Lithium (difluoromethanesulfonyl)(trifluoromethanesulfonyl)imide (LiDFTFSI), have been demonstrated to surpass traditional symmetric lithium salts with improved Li+ conductivity and the capacity to generate stable solid electrolyte interphase (SEI) while maintaining compatibility with aluminum (Al0) current collector. However, the intrinsic reductive mechanism through which LiDFTFSI influences battery performance remains unclear and under debate. Herein, the detailed SEI reactions of LiDFTFSI-based electrolytes were investigated by combining density functional theory and molecular dynamics, aiming to clarify the formation process and atomic structure of SEI. Our results show that asymmetric DFTFSI– weakens the interaction between carbonate solvents and Li+, and substantially alter the solvation structure, exhibiting a well-balanced coordination capacity to bis(trifluoromethanesulfonyl)imide (TFSI–). Nanoseconds hybrid molecular dynamics simulation further reveals that the preferential decomposition of LiDFTFSI produces sufficient LiF and Li2O to facilitate a robust SEI. Moreover, the abundant F– generated from LiDFTFSI decomposition accumulates on the Al surface and subsequently combines with Al3+ from the current collector to form AlF3, potentially inhibiting corrosion of the current collector. Overall, these findings elucidate how LiDFTFSI regulates the solvation sheath and SEI structure, advancing the development of high-performance electrolytes compatible with current collector.