filter membrane
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Currently, almost 70% of the world’s population occupies urban areas. Owing to the high population density in these regions, they are exposed to various types of air pollutants. Fine particle air pollutants (<2.5 μm) can easily invade the human respiratory system, causing health issues. For fine particulate matter filtration, the use of a face mask filter is efficient; however, its use is accompanied by a high-pressure drop, making breathing difficult. Electrostatic interactions in the filter of the face mask constitute the dominant filtration mechanism for capturing fine particulate matter; these masks are, however, significantly weakened by the high humidity in exhaled breath. In this study, we demonstrate that a filter with an electrostatically rechargeable structure operates with normal breathing air power. In our novel face mask, a filter membrane is assembled by layer-by-layer stacking of the electrospun PVDF nanofiber mat formed on a nylon mesh. Tribo/piezoelectric characteristics via multilayer structure enhance filtration performance, even under air-powered filter bending taken as a normal breathing condition. The air gap between nanofiber and mesh layers increases air diffusion time and preserves the electrostatic charges within the multi-layered nanofiber filter membrane under humid air penetration, which is advantageous for face mask applications.

Formaldehyde is a poisonous and harmful gas, which is ubiquitous in our daily life. Long-term exposure to formaldehyde harms human body functions; therefore, it is urgent to fabricate sensors for the real-time monitoring of formaldehyde concentrations. Metal oxide semiconductor (MOS) gas sensors is favored by researchers as a result of their low cost, simple operation and portability. In this paper, the mechanism of formaldehyde detection by gas sensors is introduced, and then the ways of ameliorating the response of gas sensors for formaldehyde detection in recent years are summarized. These methods include the control of the microstructure and morphology of sensing materials, the doping modification of matrix materials, the development of new semiconductor sensing materials, the outfield control strategy and the construction of the filter membrane. These five methods will provide a good prerequisite for the preparation of better performing formaldehyde gas sensors.

The ongoing global pandemic has bestowed high priority uponthe separation of air-borne particulate matters (PMs), aerosols, etc. using nonwoven fibrous materials, especially for face masks as a means of personal protection. Although spunbond or meltblown nonwoven materials are amongst the forerunners for polymer microfiber-based face mask or air filter development in mass scale, relatively new process of nonwoven manufacturing such as electrospinning is gaining a lot of momentum amongst the filter membrane manufacturers for its scalability of nanofiber-based filter membrane fabrication. There are several nanofiber-based face masks developing industries, which claim a very high efficiency in filtration of particulate matters (PM0.1–10) as well as other aerosols for their products. Polyvinylidene fluoride (PVDF), which is commonly known for its use of tactile sensors and energy harvesters, due to its piezoelectric property, is slowly gaining popularity among researchers and developers as an air filter material. Electrospun PVDF nanofibers can be as fine as 50 nm in mass scale, which allows the membrane to have large surface area compared to its volume, enhancing nanofiber–PM interaction. At the same time, the breathability index can be improved through these PVDF nanofiber membranes due to their architectural uniqueness that promotes slip flow around the fibers. The conductive nature of PVDF makes it advantageous as a promising electret filter allowing better capturing of ultrafine particles. This review aims to provide a comprehensive overview of such PVDF nanofiber-based filter membranes and their roles in air filtration, especially its application in filtrate of air-borne PMs.