Neoliberal environmental policies operate through markets, including for carbon, water, ecosystem services, or—as in contemporary Chile—for environmental scientific knowledge. Chile illustrates how markets for science operate, such as for monitoring data or environmental impact assessments, and their negative impacts on public trust in science and on the state’s regulatory efforts. In a society governed by a market for science, environmental scientists cannot escape the suspicion that conflicts of interest compromise their independence and the credibility of their work. Chile’s neoliberal 1980 Constitution sustains this market for knowledge but will be reformed following national demonstrations in 2019. The health of Chile’s environment depends on a new constitution that democratizes both democracy and science. Rights of nature doctrines, as in Ecuador’s 2008 Constitution, can provide the constitutional foundation for strong mutual accountability between science, the state, society, and nature.